SAE AMS 2643E-2012 Structural Examination of Titanium Alloys Chemical Etch Inspection Procedure《钛合金结构检查 化学腐蚀检查规程》.pdf

1、_ SAE Technical Standards Board Rules provide that: “This report is published by SAE to advance the state of technical and engineering sciences. The use of this report is entirely voluntary, and its applicability and suitability for any particular use, including any patent infringement arising there

2、from, is the sole responsibility of the user.” SAE reviews each technical report at least every five years at which time it may be reaffirmed, revised, or cancelled. SAE invites your written comments and suggestions. Copyright 2012 SAE International All rights reserved. No part of this publication m

3、ay be reproduced, stored in a retrieval system or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of SAE. TO PLACE A DOCUMENT ORDER: Tel: 877-606-7323 (inside USA and Canada) Tel: +1 724-776-4970 (outside U

4、SA) Fax: 724-776-0790 Email: CustomerServicesae.org SAE WEB ADDRESS: http:/www.sae.org SAE values your input. To provide feedback on this Technical Report, please visit http:/www.sae.org/technical/standards/AMS2643E AEROSPACE MATERIAL SPECIFICATION AMS2643 REV. E Issued 1972-11 Revised 2012-09 Super

5、seding AMS2643D Structural Examination of Titanium Alloys Chemical Etch Inspection Procedure RATIONALE This document revision removes the requirement for heat treatment of macrostructure specimens to avoid conflict with OEM procedures and clarifies inspection procedure. 1. SCOPE 1.1 Purpose This spe

6、cification covers a procedure for revealing the macrostructure and microstructure of titanium alloys. 1.2 Application This inspection procedure has been used typically for detecting defects and segregation in titanium alloys. This procedure should not be used on finished parts. 1.3 Safety - Hazardou

7、s Materials While the materials, methods, applications, and processes described or referenced in this specification may involve the use of hazardous materials, this specification does not address the hazards which may be involved in such use. It is the responsibility of the user to ensure familiarit

8、y with the safe and proper use of any hazardous materials and to take necessary precautionary measures to ensure the health and safety of all personnel involved. 2. APPLICABLE DOCUMENTS The issue of the following document in effect on the date of the purchase order forms a part of this specification

9、 to the extent specified herein. The supplier may work to a subsequent revision of a document unless a specific document issue is specified. When the referenced document has been canceled and no superseding document has been specified, the last published issue of that document shall apply. 2.1 ASME

10、Publications Available from American Society of Mechanical Engineers, 22 Law Drive, P.O. Box 2900, Fairfield, NJ 07007-2900, Tel: 973-882-1170, www.asme.org. ASME B 46.1 Surface Texture, Roughness, Waviness and Lay SAE AMS2643E Page 2 of 5 3. TECHNICAL REQUIREMENTS 3.1 Materials and Solutions 3.1.1

11、Specimens for Revealing Macrostructure 3.1.1.1 Bars, Extrusions, Plates, and Stock for Forging or Extruding Specimens shall be transverse cross-sections not less than 0.50 inch (12.7 mm) thick cut from the product to be tested in the transverse direction. Surface roughness shall be of 70 microinches

12、 (1.8 m) AA or less, determined in accordance with ASME B 46.1. 3.1.1.2 Forgings When dimensions permit, forgings shall be rough-machined to clean up and to ensure freedom from alpha case. A minimum of 0.030 inch (0.76 mm) of material shall be left on the surfaces of the forgings between final etchi

13、ng and finish machined configuration to ensure freedom from intergranular attack and hydrogen pickup on finished parts. If forgings are to be inspected by ultrasonic inspection procedures, the configuration used for such inspection is acceptable. Surface roughness shall be 130 microinches (3.3 m) AA

14、 or less, determined in accordance with ASME B 46.1. 3.1.2 Specimens for Revealing Microstructure The specimens on which macrostructure was revealed shall be sectioned through any areas of concern and, also, where practical, shall be sectioned for examination of other planes as needed to provide rep

15、resentative sampling of the product. 3.2 Equipment 3.2.1 The etchant tank, fixtures, racks, and baskets shall be lined/coated with or fabricated from a material that will not react with the etchant (See Table 1). 3.2.2 The tank shall be equipped with exhaust ventilation to vent gases from the vigoro

16、us reaction. 3.3 Preparation Specimens shall be free from water breaks. If water breaks are observed, parts shall be recleaned and reinspected for water break until no water breaks are observed. 3.4 Procedure 3.4.1 Macrostructure Inspection 3.4.1.1 Macrostructure etch Specimens shall be etched in an

17、 aqueous acid solution, maintained at room temperature, for sufficient time to develop a well-defined macrostructure (See 8.2). The solution in Table 1, or an alternative solution acceptable to purchaser, shall be used. TABLE 1 - ETCHANT Ingredient Grams per liter Nitric Acid, Technical Grade 142 20

18、 Hydrofluoric Acid, Technical Grade 60 9 Water Balance * Expressed as HNO3or HF respectively by mass. The etching rate of the solution shall be maintained to remove 0.002 to 0.004 inch (0.05 to 0.10 mm) of metal in a five minute period. SAE AMS2643E Page 3 of 5 3.4.1.2 Rinse and Dry Specimens shall

19、be rinsed immediately in clean water for several minutes followed, as required, by pressurized spraying or wiping with a cloth to remove smut. Remove water from specimens by blowing dry with clean air. 3.4.1.3 Inspection Specimens shall be visually inspected for macrostructure and indications of def

20、ects, such as segregation, (See 8.2), laps, folds, cracks, and inclusions, using 1X magnification and a light intensity not lower than 200 foot-candles (2153 lx). 3.4.1.3.1 Specimens showing significant indications shall be evaluated as necessary to interpret the indications, by additional sectionin

21、g and repeated macroscopic etch and inspection, or microstructure inspection (3.4.2), as needed. 3.4.2 Microstructure Inspection If examination of the macrostructure indicates the need for further evaluation, the microstructure shall be developed as follows: 3.4.2.1 The specimens to be examined shal

22、l be polished and etched using metallographic techniques that will clearly reveal the microstructure to be evaluated (See 8.3). 3.4.2.2 The specimens shall be examined to determine the microstructure and the nature of indications found in the macrostructure. 4. QUALITY ASSURANCE PROVISIONS 4.1 Accep

23、tance Tests Tests for macrostructure (3.4.1) and, when applicable, microstructure (3.4.2) shall be performed to determine product acceptance. 4.2 Periodic Test The test to maintain the etchant solution (3.4.1.1) is a periodic test and shall be performed at a frequency selected by the processor unles

24、s frequency of testing is specified by the cognizant engineering organization. See 8.4. 5. PREPARATION FOR DELIVERY Not applicable. 6. ACKNOWLEDGMENT The processor shall mention this specification number and its revision letter in all quotations and when acknowledging purchase orders. 7. REJECTIONS

25、Not applicable. SAE AMS2643E Page 4 of 5 8. NOTES 8.1 A change bar (l) located in the left margin is for the convenience of the user in locating areas where technical revisions, not editorial changes, have been made to the previous issue of this specification. An (R) symbol to the left of the docume

26、nt title indicates a complete revision of the specification, including technical revisions. Change bars and (R) are not used in original publications, nor in specifications that contain editorial changes only. 8.2 Segregation Segregation is similar to other material defects in that it can occur thro

27、ughout the product in any frequency, size, shape, form, or severity. However, the extreme ends of the ingot are most likely to have segregation.Segregation will appear, after macroetching, as an area of high silvery luster on a matte grey background. Typical segregation in titanium 6Al-4V alloy bill

28、et is shown in Figure 1. Segregation can be distinguished from staining or other discoloration by rubbing the surface with a rubber eraser. Segregation cannot be rubbed out whereas staining or discoloration will disappear. After segregation has been obliterated by rubbing with abrasive paper, it wil

29、l reappear after localized re-etching. 8.3 The preferred procedure for preparing specimens for examination of microstructure is as follows: 8.3.1 Polish electrolytically in the following solution at 40 volts 1 direct current for approximately five seconds: 78 mL perchloric acid 120 mL reagent water

30、(See ASTM D 1193 Type II) 700 mL ethanol 100 mL 2-butoxy ethanol 8.3.2 Etch with Krolls reagent (5% hydrofluoric acid, (sp gr 1.15), 12% nitric acid, (sp gr 1.42), 83% water, by volume), for sufficient time to develop the microstructure, wash in warm running water, and dry. Specimens may be rinsed i

31、n a solution of sodium bicarbonate and again rinsed in warm running water, if desired, between the rinsing and drying operations. 8.3.3 Mechanical polishing or other suitable means may be used provided equivalent microstructural presentations are developed. 8.4 ARP4992, Periodic Test Plan for Proces

32、s Solutions, is recommended to satisfy the requirements for the control of processing solutions. 8.5 Terms used in this AMS are clarified in ARP1917. 8.6 Dimensions and properties in inch/pound units and the Fahrenheit temperatures are primary; dimensions and properties in SI units and the Celsius temperatures are shown as the approximate equivalents of the primary units and are presented only for information. PREPARED BY AMS COMMITTEE “B” SAE AMS2643E Page 5 of 5 FIGURE 1 - TYPICAL SEGREGATION IN TITANIUM 6AL-4V AFTER ETCHING, 2X MAGNIFICATION