SAE AMS 3025D-2017 Polyalkylene Glycol Heat Treat Quenchant.pdf

1、 SAE Technical Standards Board Rules provide that: “This report is published by SAE to advance the state of technical and engineering sciences. The use of this report is entirely voluntary, and its applicability and suitability for any particular use, including any patent infringement arising there

2、from, is the sole responsibility of the user.” SAE reviews each technical report at least every five years at which time it may be revised, reaffirmed, stabilized, or cancelled. SAE invites your written comments and suggestions. Copyright 2017 SAE International All rights reserved. No part of this p

3、ublication may be reproduced, stored in a retrieval system or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of SAE. TO PLACE A DOCUMENT ORDER: Tel: 877-606-7323 (inside USA and Canada) Tel: +1 724-776-497

4、0 (outside USA) Fax: 724-776-0790 Email: CustomerServicesae.org SAE WEB ADDRESS: http:/www.sae.org SAE values your input. To provide feedback on this Technical Report, please visit http:/standards.sae.org/AMS3025D AEROSPACE MATERIAL SPECIFICATION AMS3025 REV. D Issued 1980-04 Revised 2017-03Supersed

5、ing AMS3025C Polyalkylene Glycol Heat Treat Quenchant RATIONALE AMS3025D revises Properties (Table 2), Requirements for Testing (4.3), Sampling and Testing (4.4.1.1, 4.4.2.1, 4.4.3.3.1, 4.4.3.4), Reports (4.5.3), and is a Five-Year Review and update of this specification. 1. SCOPE 1.1 Form This spec

6、ification covers two types of polyalkylene glycol in the form of a liquid. 1.2 Application This product has been used typically as a quenching medium for solution heat treatment of aluminum alloys to minimize distortion and reduce residual stresses. 1.3 Safety - Hazardous Materials While the materia

7、ls, methods, applications, and processes described or referenced in this specification may involve the use of hazardous materials, this specification does not address the hazards which may be involved in such use. It is the sole responsibility of the user to ensure familiarity with the safe and prop

8、er use of any hazardous materials and to take necessary precautionary measures to ensure the health and safety of all personnel involved. 1.4 Classification Quenchants covered by this specification are classified as: Type 1 - Single Polymer Type 2 - Multiple Polymer 1.4.1 The type supplied shall be

9、as specified on the purchase order. 2. APPLICABLE DOCUMENTS The issue of the following documents in effect on the date of the purchase order forms a part of this specification to the extent specified herein. The supplier may work to a subsequent revision of a document unless a specific document issu

10、e is specified. When the referenced document has been cancelled and no superseding document has been specified, the last published issue of that document shall apply. SAE INTERNATIONAL AMS3025D Page 2 of 9 2.1 SAE Publications Available from SAE International, 400 Commonwealth Drive, Warrendale, PA

11、15096-0001, Tel: 877-606-7323 (inside USA and Canada) or +1 724-776-4970 (outside USA), www.sae.org. AMS2770 Heat Treatment of Wrought Aluminum Alloy Parts AMS2772 Heat Treatment of Aluminum Alloy Raw Materials ARP1917 Clarification of Terms Used in Aerospace Metals Specifications 2.2 ANSI Accredite

12、d Publications Copies of these documents are available online at http:/webstore.ansi.org/. ANSI H35.2 Dimensional Tolerances for Aluminum Mill Products ANSI H 35.2M Dimensional Tolerances for Aluminum Mill Products (Metric) ANSI Z400.1 Material Safety Data Sheets Preparation 2.3 ASME Publications Av

13、ailable from ASME, P.O. Box 2900, 22 Law Drive, Fairfield, NJ 07007-2900, Tel: 800-843-2763 (U.S./Canada), 001-800-843-2763 (Mexico), 973-882-1170 (outside North America), www.asme.org. ASME B46.1 Surface Texture (Surface Roughness, Waviness, and Lay) 2.4 ASTM Publications Available from ASTM Intern

14、ational, 100 Barr Harbor Drive, P.O. Box C700, West Conshohocken, PA 19428-2959, Tel: 610-832-9585, www.astm.org. ASTM B557 Tension Testing Wrought and Cast Aluminum and Magnesium Alloy Products ASTM B557M Tension Testing Wrought and Cast Aluminum and Magnesium Alloy Products (Metric) ASTM D445 Kine

15、matic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity) ASTM D1218 Refractive Index and Refractive Dispersion of Hydrocarbon Liquids ASTM D1298 Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method ASTM D4057

16、Manual Sampling of Petroleum and Petroleum Products ASTM D6200 Determination of Cooling Characteristics of Quench Oils by Cooling Curve Analysis ASTM D6482 Determination of Cooling Characteristics of Aqueous Polymer Quenchants by Cooling Curve Analysis with Agitation (Tensi Method) ASTM D6549 Determ

17、ination of Cooling Characteristics of Aqueous Polymer Quenchants by Cooling Curve Analysis with Agitation (Drayton Unit) ASTM D6666 Evaluation of Aqueous Polymer Quenchants ASTM E203 Water Using Volumetric Karl Fischer Titration SAE INTERNATIONAL AMS3025D Page 3 of 9 3. TECHNICAL REQUIREMENTS 3.1 Ma

18、terial Shall be polyalkylene glycol and shall meet the requirements of 3.2 and 3.3. 3.2 Properties Quenchant shall conform to the following requirements; tests shall be performed in accordance with specified test methods on quenchant supplied both in concentrated form and at the dilution specified i

19、n Table 1. Table 1 - Properties Paragraph/Test Value Test Method 3.2.1 Condition: As-received in concentrated form: 3.2.1.1 Water Content (Chemically Combined, By Weight) ASTM E203 Type 1 45-48% Type 2 57-63% 3.2.1.2 Specific Gravity ASTM D1298 Type 1 1.094 0.005 Type 2 1.080 0.025 3.2.1.3 Refractiv

20、e Index at 68 F (20 C) ASTM D1218 Type 1 1.4140 0.0050 Type 2 1.3910 0.0050 3.2.1.4 Viscosity at 104 F (40 C) ASTM D445 Type 1 535 cSt 70 cSt Type 2 300 cSt 20 cSt 3.2.2 Condition: Diluted to 20% 0.50% by Volume, with Water 3.2.2.1 Viscosity at 104 F (40 C) 4.4.1.1 Type 1 5.5 cSt 0.5 cSt Type 2 4.4

21、cSt 0.5 cSt 3.2.2.2 Separation Temperature 4.4.1.2 Type 1 165 F 5 F (74 C 3 C) Type 2 165 F 5 F (74 C 3 C) SAE INTERNATIONAL AMS3025D Page 4 of 9 3.3 Quenching Capability The minimum tests for qualification shall be those specified in Table 2. Table 2 - Required preproduction tests Panel Alloy Panel

22、 Form Panel Dimensions (1) Inches (mm) Panel Final Temper Cooling Rate Tensile and Yield Strength Intergranular Corrosion Resistance 2024 Bare Sheet 0.063 u 1 u 3 (1.60 u 25 u 76) T42 - - Yes 7075 Bare Sheet 0.063 u 1 u 3 (1.60 u 25 u 76) W Yes - - 7075 Plate 0.250 u 6 u 9 (6.35 u 152 u 229) T62 Yes

23、 Yes - 7075 Forging (2) 1.000 u 5 u 4 (25.40 u 127 u 102) T6 Yes Yes - 7075 Forging (2) 2.000 u 8 u 7 (50.80 u 203 u 178) T73 - Yes - NOTES: (1) Width and length dimensions are minimums and apply to tensile tests only. Width and length dimensions for cooling rate panels shall be four times the thick

24、ness. Tolerance on width and length are 1/8 inch (3.2 mm). Tolerances on thickness of sheet and plate shall be as specified in ANSI H35.2 or ANSI H35.2M. (2) Plate may be used to simulate forgings (see 4.4.3.1). 3.3.1 Cooling Rates The cooling rates from 750 to 550 F (399 to 288 C), measured in acco

25、rdance with 4.4.2, shall be specified in Table 3. Table 3 - Cooling rate Nominal Thickness Inch Nominal Thickness Millimeters Cooling Rate Degrees/Second F Cooling Rate Degrees/Second C 0.063 1.60 900 to 1800 482 to 982 0.250 6.35 240 to 360 116 to 182 1.000 25.40 50 to 75 10 to 24 3.3.2 Tensile Str

26、ength The longitudinal tensile and yield strengths of panels heat treated with a glycol quench shall be equivalent to those of identical panels quenched in water, determined in accordance with 4.4.3. 3.3.2.1 The strengths shall be judged equivalent if the average of all results from glycol-quenched

27、panels is within 2000 psi (13.8 MPa) of those of water-quenched panels, providing that the averages for a single test lot do not differ by more than 3000 psi (20.7 MPa). 3.3.3 Intergranular Corrosion Resistance Panels of 2024 aluminum alloy as in Table 2, solution heat treated with a glycol quench,

28、shall not exhibit intergranular corrosion more severe than that of identical panels quenched in water, determined in accordance with 4.4.4. 3.4 Quality The quenchant shall be homogeneous and free from contamination. The constituents in the quenchant shall not adversely affect its use as a low-distor

29、tion quenchant or the alloy being quenched. SAE INTERNATIONAL AMS3025D Page 5 of 9 4. QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for Inspection The producer of the quenchant shall supply all samples for producers tests and shall be responsible for the performance of all required tests. Purchase

30、r reserves the right to sample and to perform any confirmatory testing deemed necessary to ensure that the quenchant conforms to specified requirements. 4.2 Classification of Tests 4.2.1 Preproduction Tests All technical requirements are preproduction tests. 4.2.2 Acceptance Tests Water content (3.2

31、1.1), specific gravity (3.2.1.2), and refractive index (3.2.1.3) as-received, and for viscosity (3.2.2.1) and separation temperature (3.2.2.2) of a 20% dilution are acceptance tests and shall be performed on each lot. 4.3 Requirements for Testing 4.3.1 Preproduction tests shall be conducted by the

32、producer on the quenchant to qualify the quenchant to this specification prior to the first production lot. These tests shall be performed prior to or on the initial shipment of quenchant to a purchaser, when a change in ingredients and/or processing requires reapproval as in 4.3.1.1, and when a pur

33、chaser deems confirmatory testing to be required. 4.3.1.1 New preproduction tests shall be required if the producer finds it necessary to make any change in polymer type or polymer molecular weight, in type of equipment for processing, or in manufacturing procedures. Changes in additive packages to

34、satisfy regulations (Federal, State or Local), do not require new preproduction tests, as long as the quenching characteristics are not changed, as measured by cooling curve measurements performed in accordance with ASTM D6200 and ASTM D6482 or ASTM D6549. 4.3.1.2 Testing in accordance with ASTM D62

35、00 and ASTM D6482 or ASTM D6549 shall be conducted three times, and the averaged results shall be considered identical to the control testing of preproduction material before change if the results of testing satisfy the bias and precision of ASTM D6482 or ASTM D6549. 4.3.1.3 Material qualified to pr

36、evious revisions of this specification shall not require requalification, unless purchaser deems confirmatory testing will be required. 4.4 Sampling and Testing Shall be in accordance with ASTM D4057; a lot shall be one batch or tank of quenchant offered for delivery at one time. A lot shall not exc

37、eed 10000 gallons (37854 L). 4.4.1 Test Methods 4.4.1.1 Viscosity The as-produced quenchant shall be diluted to a concentration of 20% + 0.5% by volume of quenchant, using distilled or deionized water. When diluting to 20% by volume with water, the initial water content (chemically combined with gly

38、col) shall not be considered as a part of the water of dilution. The viscosity of the diluted sample shall be determined at 104 F 1 F (40 C 0.6 C) in accordance with ASTM D445. 4.4.1.2 Separation Temperature Shall be determined by the following procedure: 4.4.1.2.1 Heat not less than a 250 mL portio

39、n of a well-mixed representative sample of diluted quenchant in a 25 150 mm Pyrex test tube. SAE INTERNATIONAL AMS3025D Page 6 of 9 4.4.1.2.2 Fit a cork stopper with a 0 to 212 F (-18 to +100 C) thermometer, so that the thermometer bulb is completely immersed in the liquid. The cork stopper should f

40、it snugly in the test tube, but should have a small V-notch on one side to vent the vapor space in the test tube. 4.4.1.2.3 Immerse the test tube in a suitable heating bath (water or clear oil) so that the liquid in the test tube is below the bath surface. Keep the test tube away from the sides and

41、bottom of the heating bath. 4.4.1.2.4 Heat the bath slowly (about 5 F (3 C) minute) with a suitable heater and closely observe the sample in the test tube. Continue heating, (but higher than 175 F (79 C) until the sample becomes hazy. 4.4.1.2.5 When the sample exhibits some haze, immediately remove

42、the test tube from the bath long enough to swirl the contents. The haze should disappear. Return the test tube to the bath and repeat this procedure until a permanent haze persists throughout the sample. Immediately observe the sample temperature. 4.4.1.2.6 Cool the sample slightly with agitation un

43、til the solution is again clear. Re-immerse in the heating bath and repeat the previous step until the haze persists again. Re-observe the sample temperature and average with the first temperature observation. 4.4.1.2.7 The two readings should differ by no more than 2 F (1 C). If the readings differ

44、 by more than 2 F (1 C), repeat the entire process with three test temperature observations until all three observations are within 2 F (1 C). 4.4.2 Cooling Rates Shall be determined by quenching the panels specified in Table 2. 4.4.2.1 For the 0.250 inch (6.35 mm) and 1.0 inch (25 mm) thick panels,

45、 an electrically insulated chromel-alumel thermocouple, not larger than 24 gauge (0.533 mm), shall be inserted in a blind hole to the mid-thickness 0.020 inch (0.51 mm) at the geometric center. The thermocouple shall be inserted in a manner that ensures intimate contact with the panel for optimum th

46、ermal transfer and shall be sealed to prevent intrusion of moisture and quenchant. Before each test, thermocouple contact with the part shall be verified with electrical resistance tests. A second thermocouple of the same size shall be positioned on the outside surface to determine the instant the s

47、pecimen enters the quenchant. Panels shall have a surface finish of 32 to 63 microinches (0.8 to 1.6 micrometers) Ra determined in accordance with ASME B46.1 and shall be chemically deoxidized prior to heating. 4.4.2.2 The 0.063 inch (1.60 mm) thick panel shall only have a thermocouple attached to t

48、he surface at the center. 4.4.2.3 The panels shall be soaked at the solution heat treating temperature specified in AMS2770 and quenched in the glycol/water solution maintained at 85 to 90 F (29 to 32 C). The glycol concentration used shall be the maximum specified in AMS2770 for the alloy/form/thic

49、kness. The tolerance on the glycol concentration shall be +0, 1%. The quench tank shall have no agitation. 4.4.2.4 The time/temperature cooling curve shall be recorded using a high speed oscillographic recorder or a computer based data acquisition system. The temperature recording instrument shall be calibrated prior to testing using a te