SAE J 1787-2011 Measurement of the Total Ash Content of Aviation Piston Engine Oils by a Calculation Method《通过计算法测量航空活塞发动机油的灰分总含量》.pdf

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4、SA) Fax: 724-776-0790 Email: CustomerServicesae.org SAE WEB ADDRESS: http:/www.sae.orgSAE values your input. To provide feedbackon this Technical Report, please visit http:/www.sae.org/technical/standards/J1787_201108SURFACEVEHICLERECOMMENDEDPRACTICEJ1787 AUG2011 Issued 1995-10 Revised 2011-08Supers

5、eding J1787 MAY2005 Measurement of the Total Ash Content of Aviation Piston Engine Oils by a Calculation Method RATIONALE This standard was revised based on recommendations made at the 22 April 2010 SAE E-38 Aviation Piston Engine Fuels and Lubricants Committer meeting. It is part of the standard SA

6、E five-year review process and it includes only editorial changes. The name of the preparing SAE committee has changed to E-38 and is now under the Aerospace Council. 1. SCOPE This SAE Recommended Practice describes an empirical method for determining the theoretical ash content of aviation piston e

7、ngine lubricating oils by calculating the equivalent weight of metallic oxides formed at 775 C based on the metallic elemental concentration. The calculation method of ash determination may be used as an alternate to ASTM D 482 for application to the standards for aviation piston engine lubricating

8、oils. 1.1 Field of Application This procedure is recommended for use in the qualification, manufacturing, and quality assurance testing of aviation piston engine lubricating oils where the ash content is limited to a maximum of 0.011%. 1.2 Background 1.2.1 The ash content as measured by ASTM D 482 h

9、as very poor precision and repeatability for lubricants having low ash content. The precision statement for the method states that the reproducibility of a sample in the range of 0.001 to 0.079% ash content is 0.005%. Further, the bias of the test cannot be determined and there is no standard refere

10、nce material containing a known level of ash for this method. This poor precision has led to numerous problems concerning the actual ash content of products on many occasions. The test method is valuable when run by experienced operators, but can provide dubious information if run under the general

11、conditions stated in the method. For example, to obtain repeatable results, a platinum crucible must always be used in place of the silica or porcelain crucibles listed as equivalent substitutes. Meticulous care and procedural knowledge must be used by experienced operators for the method to be prod

12、uctive. 1.2.1.1 The notes provided in ASTM D 482 also suggest that this method may not be appropriate for oils containing ashless additives or for oils containing certain phosphorous compounds which may now be in use in aviation lubricants. For oils containing additives an alternate method, ASTM D 8

13、74, is suggested. However, ASTM D 874 includes additional restrictions and reservations which question the suitability of that method as an acceptable alternate or replacement for ASTM D 482 for low ash containing lubricating oils. SAE J1787 Revised AUG2011 Page 2 of 4 1.2.1.2 These contradictions h

14、ave led to the development of a “calculated ash content” method as a recommended alternative for use with aviation piston engine oils. This procedure is based on the ideal conversion of selected metallic elements to their theoretical oxide weights and then summing the components to obtain a total va

15、lue. The seven metallic elements chosen were selected as being those most likely to be present in lubricant manufacturing and packaging plants. As such they would also be the most likely contaminants to be found in the aviation lubricants specified. 2. REFERENCES 2.1 Applicable Documents The followi

16、ng publications form a part of this specification to the extent specified herein. Unless otherwise indicated, the latest issue of SAE publications shall apply. 2.1.1 SAE Publication Available from SAE International, 400 Commonwealth Drive, Warrendale, PA 15096-0001, Tel: 877-606-7323 (inside USA and

17、 Canada) or 724-776-4970 (outside USA), www.sae.org.SAE J1899 Lubricating Oil, Aircraft Piston Engine (Ashless Dispersant) 2.1.2 ASTM Publications Available from ASTM International, 100 Barr Harbor Drive, P.O. Box C700, West Conshohocken, PA 19428-2959, Tel: 610-832-9585, www.astm.ASTM D 482 Standar

18、d Test Method for Ash from Petroleum Products ASTM D 874 Standard Test Method for Sulfated Ash from Lubricating Oils and Additives 2.2 Related Publications The following publications are provided for information purposes only and are not a required part of this SAE Technical Report.2.2.1 SAE Publica

19、tion Available from SAE International, 400 Commonwealth Drive, Warrendale, PA 15096-0001, Tel: 877-606-7323 (inside USA and Canada) or 724-776-4970 (outside USA), www.sae.org.SAE J1966 Lubricating Oils, Aircraft Piston Engine (Non-Dispersant Mineral Oil) SAE J1787 Revised AUG2011 Page 3 of 4 2.2.2 A

20、STM Publications Available from ASTM International, 100 Barr Harbor Drive, P.O. Box C700, West Conshohocken, PA 19428-2959, Tel: 610-832-9585, www.astm.org.ASTM D 4628 Standard Test Method for Analysis of Barium, Calcium, Magnesium and Zinc in Unused Lubricating Oils by Atomic Absorption Spectrometr

21、y ASTM D 4951 Standard Test Method for Determination of Additive Elements in Lubricating Oils by Inductively Coupled Plasma Atomic Emission Spectrometry ASTM D 5185 Determination of Additive Elements, Wear Metals, and Contaminants in Used Lubricating Oils by Inductively Coupled Plasma Atomic Emissio

22、n Spectrometry 3. TEST REQUIREMENTS 3.1 Measurements 3.1.1 The concentration of the selected metallic elements are determined by the appropriate ASTM test method listed in Section 2. The measurements for iron, copper, and silicon have no specified ASTM method and, therefore, are to be determined usi

23、ng standard accepted laboratory methods. For military qualification purposes, the trace metal content for iron, copper, and silicon shall be obtained using the procedure noted in 4.5.2 of SAE J1899. The values are recorded as Kg/mg (parts per million, ppm) of each element. The elements to be measure

24、d are listed in Table 1. TABLE 1 - ELEMENTS TO BE MEASURED Element Oxide Conversion Factors Magnesium 1.66 x 104Zinc 1.24 x 104Calcium 1.40 x 104Sodium 1.35 x 104Iron 1.43 x 104Copper 1.25 x 104Silicon 2.14 x 1043.2 Calculations 3.2.1 The concentration of each metal element is then converted to its

25、equivalent oxide mass by multiplying the obtained elements ppm value by the corresponding oxide conversion factor shown in Table 1. The product for each conversion is reported individually as “metal oxide, percent mass” for each element. The sum of these combined metal oxide masses are then computed

26、. SAE J1787 Revised AUG2011 Page 4 of 4 4. REPORT 4.1 The ash content for the sample is then recorded as required by the standard or specification. The result is reported as the “Calculated Ash Value” of the sample tested. 5. NOTES 5.1 Marginal Indicia A change bar (l) located in the left margin is

27、for the convenience of the user in locating areas where technical revisions, not editorial changes, have been made to the previous issue of this document. An (R) symbol to the left of the document title indicates a complete revision of the document, including technical revisions. Change bars and (R) are not used in original publications, nor in documents that contain editorial changes only. PREPARED BY SAE E-38, AVIATION PISTON ENGINE FUELS AND LUBRICANTS COMMITTEE