1、 Collection of SANS standards in electronic format (PDF) 1. Copyright This standard is available to staff members of companies that have subscribed to the complete collection of SANS standards in accordance with a formal copyright agreement. This document may reside on a CENTRAL FILE SERVER or INTRA
2、NET SYSTEM only. Unless specific permission has been granted, this document MAY NOT be sent or given to staff members from other companies or organizations. Doing so would constitute a VIOLATION of SABS copyright rules. 2. Indemnity The South African Bureau of Standards accepts no liability for any
3、damage whatsoever than may result from the use of this material or the information contain therein, irrespective of the cause and quantum thereof. ISBN 978-0-626-21227-8 SANS 10304-1:2008Edition 1.1Any reference to SABS 0304-1 is deemedto be a reference to this standard(Government Notice No. 1373 of
4、 8 November 2002)SOUTH AFRICAN NATIONAL STANDARD The classification of pesticides and stock remedies for sale and handling in South Africa Part 1: The classification of pesticides SANS 10304-1:2008 Edition 1.1 Table of changes Change No. Date Scope Amdt 1 2008 Amended to change the designation of SA
5、BS standards to SANS standards, with no technical changes. Foreword This South African standard was approved by National Committee StanSA SC 5140.06X, National committee for dangerous goods standards Classification and information, in accordance with procedures of Standards South Africa, in complian
6、ce with annex 3 of the WTO/TBT agreement. This document was published in April 2008. This document supersedes SABS 0304-1:2002 (edition 1). SANS 10304 consists of the following parts under general title, The classification of pesticides and stock remedies for sale and handling in South Africa: Part
7、1: The classification of pesticides. Part 2: The classification of stock remedies. Annexes A and B form an integral part of this part of SANS 10304. Owing to the fact that information in respect of names and addresses of competent authorities and certification authorities dealing with dangerous good
8、s are subject to change, details of the competent authorities and certification authorities are given in a general advice sheet provided with this part of SANS 10304. This advice sheet will be updated every six months and it is the responsibility of the competent authority/certification authority to
9、 notify the SABS of any changes. The advice sheet will be available, free of charge, from the Standards Sales Department of the South African Bureau of Standards. SANS 10304-1:2008 Edition 1.1 1 Contents Page Foreword 1 Scope . 3 2 Normative references . 3 3 Definitions and abbreviations . 4 3.1 Def
10、initions 4 3.2 Abbreviations 4 4 Listing of pesticides 5 5 Acute toxicity based on health effects . 5 6 Danger grouping of pesticides . 6 6.1 General 6 6.2 Special provisions for the danger grouping for rodenticides . 7 7 Packaging 8 8 Marking and labelling . 9 Annex A (normative) Global Crop Protec
11、tion Federation (GCPF) abbreviations and alphabetical list of pesticides for sale and handling . A1 A.1 GCPF abbreviations A1 A.2 Alphabetical list of pesticides foe sale and handling . A6 Annex B (normative) Alphabetical list of pesticides (technical): Toxicity and notes to the annex . B1 B.1 Alpha
12、betical list of pesticides (technical): Toxicity B1 B.2 Notes to B.1 B18 Bibliography B19 SANS 10304-1:2008 Edition 1.1 2 This page is intentionally left blank SANS 10304-1:2008 Edition 1.1 3 The classification of pesticides and stock remedies for sale and handling in South Africa Part 1: The classi
13、fication of pesticides 1 Scope This part of SANS 10304 covers the classification of pesticides for sale and handling in South Africa. Each pesticide has been allocated to one of five danger groups in accordance with the degree of its intrinsic toxic properties. The allocation is based on World Healt
14、h Organization (WHO) guidelines, as amended in accordance with South African requirements. 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this part of SANS 10304. All standards are subject to revision and, since any r
15、eference to a standard is deemed to be a reference to the latest edition of that standard, parties to agreements based on this part of SANS 10304 are encouraged to take steps to ensure the use of the most recent editions of the standards indicated below. Information on currently valid national and i
16、nternational standards can be obtained from Standards South Africa. Agricultural and Veterinary Chemicals Association of South Africa (AVCASA), Guidelines for the RSA classification code of agricultural stock remedies and associated labelling practice. AVCASA, 1991. British Crop Protection Council.
17、The pesticide manual. Eleventh edition. 1997. ISO 8317, Child-resistant packaging Requirements and testing procedures for reclosable packages. SANS 10228, The identification and classification of dangerous goods for transport. SANS 10229-1, Transport of dangerous goods Packaging and large packaging
18、for road and rail transport Part 1: Packaging. SANS 10304-1:2008 Edition 1.1 4 3 Definitions and abbreviations 3.1 Definitions 3.1.1 competent authority authority designated by legislation as being responsible for the classification of pesticides for sale and handling in South Africa 3.1.2 danger gr
19、oup group symbol that indicates the degree of toxicity or hazard posed by the property of a specific pesticide, in accordance with internationally recognized classifications 3.1.3 marine pollutant substance that meets the definition of a marine pollutant in accordance with protocol 1 to the Internat
20、ional Maritime Organization Pollution Convention (MARPOL 73/78) and indicated with “P“ or “PP“ (in the case of a severe marine pollutant) and, when in a solution or a mixture of one or more marine pollutants, in a concentration which equals or exceeds: a) 10 %, by mass, of the solution or mixture fo
21、r substances marked “P“; or b) 1 %, by mass, of the solution or mixture for substances marked “PP“. 3.1.4 pest insect, rodent or animal, unwanted plant (weed), fungus, or microorganism, for example a bacterium or a virus 3.1.5 pesticide organic or inorganic substance or mixture of substances used to
22、 prevent, destroy, repel or mitigate a pest. The term includes insecticides, herbicides, rodenticides, miticides, fungicides, plant regulators and defoliants, and various other substances used to control pests 3.1.6 United Nations (UN) number serial number assigned to dangerous goods by the United N
23、ations Committee of Experts on the Transport of Dangerous Goods 3.2 Abbreviations 3.2.1 AVCASA acronym for the Crop Protection and Animal Health Association, formerly known as the Agricultural and Veterinary Chemicals Association of South Africa 3.2.2 GCPF Global Crop Protection Federation 3.2.3 P m
24、arine pollutant (see 3.1.3) 3.2.4 PP severe marine pollutant (see 3.1.3) 3.2.5 WHO World Health Organization SANS 10304-1:2008 Edition 1.1 5 4 Listing of pesticides 4.1 Annex A 4.1.1 The GCPF abbreviation (code, term and definition) for each pesticide available for sale and handling in South Africa
25、is given in A.1. 4.1.2 An alphabetical list of pesticides for sale and handling in South Africa is given in A.2. It gives the common name(s) of the active ingredient(s), the GCPF abbreviation (formulation type), the concentration(s) of the active ingredient(s), a description of the physical state of
26、 the product, the UN number (if available), the danger group and the colour code. NOTE Where possible, ISO common names have been used. 4.2 Annex B 4.2.1 An alphabetical list of pesticides is given in B.1. It lists a description of the physical state, the LD50, the danger group and the colour code o
27、f the technical substance, and remarks. 4.2.2 Notes to B.1 are given in B.2. 5 Acute toxicity based on health effects 5.1 The LD50for acute oral toxicity, in milligrams per kilogram of body mass, is that dose of the pesticide that, when administered orally, is most likely to cause the death, within
28、14 d, of 50 % of both male and female young adult albino rats. The number of animals tested shall be sufficient to give a statistically significant result and the test shall comply with good laboratory practice. 5.2 The LD50for acute dermal toxicity, in milligrams per kilogram of body mass, is that
29、dose of the pesticide that, when administered by continuous contact for 24 h with the bare skin of both male and female albino rabbits, is most likely to cause the death, within 14 d, of 50 % of the animals tested. The number of animals tested shall be sufficient to give a statistically significant
30、result and the test shall comply with good laboratory practice. 5.3 The LD50toxicity data of an active ingredient, as determined by the WHO, are used for the classification of a pesticide. If the WHO toxicity data are not available, the value of another internationally recognized source, for example
31、 that of The pesticide manual, can be used. 5.4 Experimental toxicity data take precedence over a calculated toxicity value for the classification of a pesticide formulation. In cases where experimental toxicity data are not available, the procedure given in 6.1.3 to 6.1.9 shall be followed. 5.5 Whe
32、n the acute toxicity in animals of a commercial pesticide has been determined, the pesticide shall be classified in one of five danger groups in accordance with table 1 (also see 6.1). SANS 10304-1:2008 Edition 1.1 6 6 Danger grouping of pesticides 6.1 General 6.1.1 Pesticides for sale and handling
33、in South Africa have been assigned to five danger groups, as follows: danger group Ia: pesticides that present a very severe risk of poisoning danger group Ib: pesticides that present a high risk of poisoning danger group II: pesticides that present a moderate risk of poisoning danger group III: pes
34、ticides that present a slight risk of poisoning danger group IV: pesticides that are unlikely to present a risk of poisoning in the course of normal use. 6.1.2 The danger grouping criteria given in table 1 are applicable to the labelling and marking of pesticides for purposes of sale and handling in
35、 South Africa only. Classification of pesticides for purposes of transportation shall be done in accordance with SANS 10228. Table 1 Danger grouping criteria based on oral toxicity and dermal toxicity 1 2 3 4 5 Danger group Oral toxicity, LD50mg/kg Dermal toxicity, LD50mg/kg Solid Liquid Solid Liqui
36、d la 5 50 20 200 10 100 40 400 ll 50 500 200 2 000 10 1 000 40 4 000 lll 500 2 000 2000 3 000 1 000 4 000 lV 2 000 3 000 6.1.3 In allocating a pesticide to a danger group, cognizance shall be taken of instances of accidental poisoning in humans, any special properties of an individual pesticide (for
37、 example, liquid state or high volatility), any special likelihood of penetration and special biological effects. 6.1.4 In cases where no history of poisoning in humans is available, the allocation of a pesticide to a danger group shall be based on data obtained from animal experiments. 6.1.5 In cas
38、es where two or more routes of administering a pesticide exhibited different orders of toxicity, the allocation of that pesticide to a danger group shall be based on the higher degree of danger. SANS 10304-1:2008 Edition 1.1 7 6.1.6 In cases where it is not practical to determine the experimental to
39、xicity of a solid dry pesticide that contains a single active ingredient and the LD50of the active ingredient is known, the LD50of the pesticide formulation can be calculated by using the following formula: LD50f = aa100PLD 50where LD50fis the LD50value for the pesticide, in milligrams per kilogram;
40、 LD50ais the LD50value for the active ingredient, in milligrams per kilogram; Pais the percentage (by mass) of the active ingredient in the pesticide. 6.1.7 In cases where a pesticide contains several active ingredients, the danger group allocation shall be based on the LD50of the pesticide formulat
41、ion as a whole, in accordance with the criteria given in 6.1.3 to 6.1.5 (inclusive). 6.1.8 In cases where it is not practical to determine the experimental toxicity of a solid, dry pesticide that contains several active ingredients and the LD50s of the individual active ingredients are known, the LD
42、50of the pesticide formulation can be calculated by using the following formula: mzzbbaa100TTCTCTC=+ where C is the concentration of active ingredients a,b.z in the pesticide, as a percentage (by mass); T is the oral LD50of active ingredients a,b.z, in milligrams per kilogram; Tmis the oral LD50of t
43、he pesticide as a whole, in milligrams per kilogram. 6.1.9 The formula given in 6.1.8 can also be used to determine dermal toxicity, provided that information is available on the same route of toxicity for all the active ingredients of the pesticide formulation. The use of this formula does not take
44、 into account any potentiation or protective phenomena. 6.1.10 In cases where it is not practical to determine the experimental toxicity of a liquid pesticide, the formulation shall be classified in accordance with the LD50of the active ingredient. If more than one active ingredient is present in a
45、liquid pesticide, the formulation shall be classified in accordance with the LD50of the most toxic active ingredient. 6.2 Special provisions for the danger grouping of rodenticides The danger groupings of rodenticides for sale and handling in South Africa are allocated as follows: danger group la: l
46、iquid formulations danger group II: single feed formulations danger group III: multiple feed formulations SANS 10304-1:2008 Edition 1.1 8 7 Packaging 7.1 For the purposes of this part of SANS 10304, packaging constitutes the following: a) a sales unit to the consumer at the point of purchase; b) gro
47、uped packaging or secondary packaging of a certain number of sales units to be sold as such to the final user or consumer. The packages can also be used to replenish the shelves of a retailer; and c) transport packaging to facilitate handling and transport of a number of sales units or grouped packa
48、ging in order to prevent damage due to physical handling and transport. NOTE Transport packaging for sale and handling does not include road, rail, ship and air containers. 7.2 Packaging shall be of good fabrication and shall be so designed, constructed and closed as to prevent deformation, leakage
49、or sifting of the contents due to vibration, stacking, impact or changes in environmental conditions, such as temperature, pressure or humidity, that can be encountered during handling and transport. 7.3 A United Nations (UN) number (see 3.1.5 and A.2) is assigned to a pesticide formulation classified as hazardous for transportation in accordance with SANS 10228. The packaging of such a formulation shall comply with the requirements of SANS 10229-1. 7.4 The material that constitutes the packaging and closing devices sha
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