1、 Collection of SANS standards in electronic format (PDF) 1. Copyright This standard is available to staff members of companies that have subscribed to the complete collection of SANS standards in accordance with a formal copyright agreement. This document may reside on a CENTRAL FILE SERVER or INTRA
2、NET SYSTEM only. Unless specific permission has been granted, this document MAY NOT be sent or given to staff members from other companies or organizations. Doing so would constitute a VIOLATION of SABS copyright rules. 2. Indemnity The South African Bureau of Standards accepts no liability for any
3、damage whatsoever than may result from the use of this material or the information contain therein, irrespective of the cause and quantum thereof. ISBN 978-0-626-24018-9 SANS 11014:2010Edition 1ISO 11014:2009Edition 1SOUTH AFRICAN NATIONAL STANDARD Safety data sheet for chemical products Content and
4、 order of sections This national standard is the identical implementation of ISO 11014:2009 and is adopted with the permission of the International Organization for Standardization. Published by SABS Standards Division 1 Dr Lategan Road Groenkloof Private Bag X191 Pretoria 0001Tel: +27 12 428 7911 F
5、ax: +27 12 344 1568 www.sabs.co.za SABS SANS 11014:2010 Edition 1 ISO 11014:2009 Edition 1 Table of changes Change No. Date Scope Foreword This South African standard was approved by National Committee SABS SC 1060B, National committee for dangerous goods standards Classification and information, in
6、 accordance with procedures of the SABS Standards Division, in compliance with annex 3 of the WTO/TBT agreement. This SANS document was published in April 2010. This SANS document supersedes SANS 11014-1:1994 (first edition). Reference numberISO 11014:2009(E)ISO 2009INTERNATIONAL STANDARD ISO11014Fi
7、rst edition2009-03-01Safety data sheet for chemical products Content and order of sections Fiches de donnes de scurit pour les produits chimiques Contenu et plan type SANS 11014:2010This s tandard may only be used and printed by approved subscription and freemailing clients of the SABS .ISO 11014:20
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11、COPYRIGHT PROTECTED DOCUMENT ISO 2009 All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address b
12、elow or ISOs member body in the country of the requester. ISO copyright office Case postale 56 CH-1211 Geneva 20 Tel. + 41 22 749 01 11 Fax + 41 22 749 09 47 E-mail copyrightiso.org Web www.iso.org Published in Switzerland ii ISO 2009 All rights reservedSANS 11014:2010This s tandard may only be used
13、 and printed by approved subscription and freemailing clients of the SABS .ISO 11014:2009(E) ISO 2009 All rights reserved iiiContents Page Foreword iv Introduction v 1 Scope . 1 2 Normative reference . 1 3 Terms and definitions. 1 4 General. 3 5 Contents and general layout of an SDS . 4 Annex A (nor
14、mative) Instruction for the compilation and completion of an SDS. 6 Bibliography . 13 SANS 11014:2010This s tandard may only be used and printed by approved subscription and freemailing clients of the SABS .ISO 11014:2009(E) iv ISO 2009 All rights reservedForeword ISO (the International Organization
15、 for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has
16、the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. Intern
17、ational Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publicati
18、on as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent right
19、s. ISO 11014 was prepared by Technical Committee ISO/TC 47, Chemistry. This first edition of ISO 11014 cancels and replaces the first edition of ISO 11014-1:1994, which has been technically revised to align it with GHS:20072. SANS 11014:2010This s tandard may only be used and printed by approved sub
20、scription and freemailing clients of the SABS .ISO 11014:2009(E) ISO 2009 All rights reserved vIntroduction The safety data sheet (SDS) for chemical products gives information on the safety, health and environmental protection aspects of these substances or mixtures. The SDS supplies, for these aspe
21、cts, basic knowledge of the chemical products, and recommendations on protective measures and emergency actions. In some countries, this sheet is called a material safety data sheet (MSDS). Throughout this International Standard, the term SDS is used. The SDS is a means of transferring essential haz
22、ard information (including information on transport, handling, storage and emergency actions) from the supplier of a chemical product to the recipient of the chemical product. It may also be used to transfer this information to institutions, services and other bodies that play a role in dealing with
23、 the chemical product. The objective of this International Standard is to create consistency in providing information on safety, health and environmental matters for chemical products. In order to establish uniformity, certain requirements have been laid down as to how information on the chemical pr
24、oduct shall be given (for instance the wording, numbering and sequence of the headings). This International Standard provides flexibility to accommodate different text-processing/transmission systems. The predecessor to this International Standard, ISO 11014-1:1994, has been applied worldwide since
25、its publication. In 1992, the UN Conference on the Environment and Development (UNCED) adopted Agenda 21, in which UNCED recommended a globally harmonized system of classification and labelling of chemicals (GHS2) including safety data sheets as one of the six areas for action identified in Chapter
26、19 on environmentally sound management of toxic chemicals. It includes guidance on the preparation of safety data sheets. Some of the regional and national standards on SDS have been revised to be in line with the GHS. The systematic review of ISO 11014-1:1994, conducted in 2006, resulted in the com
27、mittee decision to revise. Accordingly, this International Standard has been developed by aligning the predecessor text with the GHS as regards hazard communication. ISO 11014-2 was never published. Hence this International Standard is designated as the first edition of ISO 11014. It does not necess
28、arily reflect or represent the different international, regional, national or local regulatory requirements that may be specific for certain regions/countries/states. It is therefore recommended that reviews outlining the different international, regional, national or local regulatory requirements r
29、elevant to SDSs be made available to those who prepare SDSs. The provision of this knowledge to SDS authors is intended to promote the establishment and acceptance of a unique SDS per chemical product in different regions/countries/states, enabling fully consistent information to be provided. The ob
30、ligations of the recipient of an SDS are beyond the scope of this International Standard. Some of them are included, however, to clearly differentiate between the obligations of the SDS and those of the recipient of the SDS. SANS 11014:2010This s tandard may only be used and printed by approved subs
31、cription and freemailing clients of the SABS .SANS 11014:2010This s tandard may only be used and printed by approved subscription and freemailing clients of the SABS .INTERNATIONAL STANDARD ISO 11014:2009(E) ISO 2009 All rights reserved 1Safety data sheet for chemical products Content and order of s
32、ections 1 Scope This International Standard defines sections, content, and general format of the safety data sheet (SDS) for chemical products. This International Standard does not define a fixed format, nor does it include a blank SDS. 2 Normative reference The following referenced documents are in
33、dispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 1000, SI units and recommendations for the use of their multiples and of certain other
34、 units ISO 80000-9, Quantities and units Part 9: Physical chemistry and molecular physics 3 Terms and definitions For the purposes of this International Standard, the following terms and definitions apply. 3.1 chemical product substance or mixture 3.2 exposure control full range of precautionary mea
35、sures to protect a user of a chemical product (3.1) 3.3 GHS classification classification of substances and mixtures by the harmonized criteria in the Globally harmonized system of classification and labelling of chemicals2according to their physical, health and environmental hazards 3.4 harm physic
36、al injury or damage to health of people, or damage to property or the environment ISO/IEC Guide 51:19991, definition 3.3 3.5 hazard potential source of harm (3.4) ISO/IEC Guide 51:19991, definition 3.5 SANS 11014:2010This s tandard may only be used and printed by approved subscription and freemailin
37、g clients of the SABS .ISO 11014:2009(E) 2 ISO 2009 All rights reserved3.6 hazard statement statement assigned to a hazard class and category that describes the nature of the hazard (3.5) of a hazardous product, including, where appropriate, the degree of hazard GHS:20072, 1.2. 3.7 intended use use
38、of a chemical product (3.1), process or service in accordance with information provided by a supplier (3.18) NOTE Adapted from ISO/IEC Guide 51:1999 1, 3.13. 3.8 label element one type of information that has been harmonized for use in a label EXAMPLES Pictogram, signal word. NOTE Adapted from GHS:2
39、0072, 1.2. 3.9 mixture mixture or solution composed of two or more substances in which they do not react GHS:20072, 1.2. 3.10 pictogram graphical composition that may include a symbol (3.19) plus other graphic elements, such as a border, background pattern or colour that is intended to convey specif
40、ic information GHS:20072, 1.2. 3.11 precautionary statement phrase (and/or pictogram) that describes recommended measures that should be taken to minimize or prevent adverse effects resulting from exposure to a hazardous chemical product (3.1), or improper storage or handling of a hazardous chemical
41、 product (3.1) NOTE Adapted from GHS:20072, 1.2. 3.12 reasonably foreseeable misuse use of a chemical product (3.1), process or service in a way not intended by a supplier (3.18) but which may result from readily predictable human behaviour NOTE Adapted from ISO/IEC Guide 51:1999 1, 3.14. 3.13 recip
42、ient party receiving a chemical product (3.1) for industrial or professional use, such as storage, handling, processing or packaging, from a supplier (3.18) 3.14 risk combination of the probability of occurrence of harm (3.4) and the severity of that harm (3.4) ISO/IEC Guide 51:19991, definition 3.2
43、 SANS 11014:2010This s tandard may only be used and printed by approved subscription and freemailing clients of the SABS .ISO 11014:2009(E) ISO 2009 All rights reserved 33.15 safety freedom from unacceptable risk (3.14) ISO/IEC Guide 51:1999 1, definition 3.1 3.16 signal word word used to indicate t
44、he relative level of severity of hazard (3.5) and alert the reader to a potential hazard on the label EXAMPLES In the GHS, “danger” and “warning” are used as signal words. NOTE Adapted from GHS:20072, 1.2. 3.17 substance chemical elements and their compounds in the natural state or obtained by any p
45、roduction process, including any additive necessary to preserve the stability of the product and any impurities deriving from the process used, but excluding any solvent which may be separated without affecting the stability of the substance or changing its composition GHS:20072, 1.2. 3.18 supplier
46、party responsible for making a chemical product (3.1) available to a recipient (3.13) 3.19 symbol graphical element intended to succinctly convey information GHS:20072, 1.2. 4 General An SDS applies to a chemical product as a whole. Information contained in an SDS is non-confidential information on
47、composition and ingredients may be given in a different way, provided Clause A.4 is observed. Any supplier should provide a complete SDS to the recipient and shall report relevant information on safety, health and environment. The supplier shall keep the SDSs up to date and provide the recipient wit
48、h the latest edition. The recipient of an SDS is responsible for: acting in accordance with a risk assessment in regard of the conditions of chemical product use; taking necessary precautionary measures in a given work situation; and keeping users informed appropriately about hazards relevant to the
49、ir individual workplace. When formulating specific instructions for the workplace, the recipient should consider the general recommendations of relevant SDSs. Since an SDS is merely chemical product related, it cannot take into account all the possible situations which may arise at any given workplace. Therefore an SDS only constitutes a part of the information necessary to establish a safety programme. Comprehensive information about a substance or mixture should be provided by an SDS fo
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