ASTM D7713-2018 Standard Specification for Aqueous Engine Coolant Grade Glycol (53 % by Volume Nominal).pdf

1、Designation: D7713 12D7713 18Standard Specification forAqueous Engine Coolant Grade Glycol (53% (53 % byVolume Nominal)1This standard is issued under the fixed designation D7713; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the

2、year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers both commercial products, engine coolant grade ethylene glycol and propylene glycol,

3、 includingvirgin glycols and those derived from the recycling of vehicle engine coolants and industrial source glycols.1.2 Types EG-1 and PG-1 cover glycols with sufficiently low limits on components to allow a blended coolant to meet mostOEM (Original Equipment Manufacturer) specifications. These t

4、ypes will probably be virgin materials, although redistillationcould produce a sufficiently pure product. Types EG-2 and PG-2 cover glycol that will be suitable for many coolants. These typescan be either redistilled or virgin.1.3 The values stated in SI units are to be regarded as standard. No othe

5、r units of measurement are included in this standard.1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibilityof the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and d

6、etermine theapplicability of regulatory limitations prior to use.1.5 This international standard was developed in accordance with internationally recognized principles on standardizationestablished in the Decision on Principles for the Development of International Standards, Guides and Recommendatio

7、ns issuedby the World Trade Organization Technical Barriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standards:2D1122 Test Method for Density or Relative Density of Engine Coolant Concentrates and Engine Coolants By The HydrometerD1123 Test Methods for Water in Engine Coolant Concent

8、rate by the Karl Fischer Reagent MethodD1177 Test Method for Freezing Point of Aqueous Engine CoolantsD1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)D1287 Test Method for pH of Engine Coolants and AntirustsD1613 Test Method for Acidity in Volatile Solvents and Chemical Intermedi

9、ates Used in Paint, Varnish, Lacquer, and RelatedProductsD3634 Test Method for Trace Chloride Ion in Engine CoolantsD4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density MeterD4725 Terminology for Engine Coolants and Related FluidsD5827 Test Method for Analys

10、is of Engine Coolant for Chloride and Other Anions by Ion ChromatographyD5931 Test Method for Density and Relative Density of Engine Coolant Concentrates andAqueous Engine Coolants by DigitalDensity MeterD6130 Test Method for Determination of Silicon and Other Elements in Engine Coolant by Inductive

11、ly Coupled Plasma-AtomicEmission SpectroscopyD6660 Test Method for Freezing Point of Aqueous Ethylene Glycol Base Engine Coolants by Automatic Phase TransitionMethodD7638D7736 Test Method for Determination of Fatty Acids and Glycol Esters in GlycerinEthylene GlycolE177 Practice for Use of the Terms

12、Precision and Bias in ASTM Test Methods1 This specification is under the jurisdiction of ASTM Committee D15 on Engine Coolants and Related Fluids and is the direct responsibility of Subcommittee D15.07on Specifications.Current edition approved May 1, 2012Nov. 1, 2018. Published June 2012November 201

13、8. Originally approved in 2011. Last previous edition approved in 20112012 asD7713 11.D771312. DOI: 10.1520/D771312.10.1520/D771318.2 For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at serviceastm.org. For Annual Book of ASTM Standardsvolume informa

14、tion, refer to the standardsstandards Document Summary page on the ASTM website.This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Becauseit may not be technically possible to adequa

15、tely depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current versionof the standard as published by ASTM is to be considered the official document.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocke

16、n, PA 19428-2959. United States1E202 Test Methods for Analysis of Ethylene Glycols and Propylene GlycolsE300 Practice for Sampling Industrial ChemicalsE394 Test Method for Iron in Trace Quantities Using the 1,10-Phenanthroline MethodE691 Practice for Conducting an Interlaboratory Study to Determine

17、the Precision of a Test MethodE1177 Specification for Engine Coolant Grade Glycol3. Requirements3.1 Engine coolant grade 53 % (vv) (nominal) ethylene glycol or propylene glycol shall conform to the chemical and physicalproperty requirements in Table 1.4. Sampling4.1 Sample ethylene or propylene glyc

18、ol in accordance with the appropriate sections of Practice E300 for liquid samples.5. Packaging, Package Markings, and Transportation5.1 The packaging, labeling, and transportation of commercial quantities shall conform to applicable federal, state, and localregulations. Conformance is the responsib

19、ility of the manufacturer and the shipper.6. Precision and Bias6.1 The precision of this test method is based on an interlaboratory study of WK25513 Standard Specification for AqueousEngine Coolant Grade Glycol (53 % nominal), conducted in 2010. Each of eight laboratories tested three different mate

20、rials. EveryTABLE 1 Physical and Chemical RequirementsRequirement Value for 53 %Ethylene Glycol, TypeEG-1 53 %Value for 53 %Propylene Glycol, TypePG-1 53 %Value for 53 %Ethylene Glycol, TypeEG-2 53 %Value for 53 %Propylene-Glycol,PG-2 53 %ASTMTestMethodClarity Clear,no suspended matterClear,no suspe

21、nded matterClear,no suspended matterClear,no suspended matterVisualColor, Pt/Co scale 25 max 25 max 100 max 100 max D1209Relative density, 20/20C 1.068 to 1.123 1.025 to 1.0331 1.068 to 1.123 1.025 to 1.0331 D1122, D4052, D5931Relative density, 20/20 C 1.070 to 1.075 1.025 to 1.033 1.070 to 1.075 1.

22、025 to 1.033 D1122, D4052, D5931pH 6.5 to 9.0 6.5 to 9.0 6.5 to 9.0 6.5 to 9.0 D1287Acidity as acetic acid,mass %0.005 max 0.005 max 0.005 max 0.005 max D1613Acidity as acetic acid,mass %0.005 max 0.005 max 0.005 max 0.005 max D1613AEthylene glycol, vol % 50.5 min . 50.5 min . E202Propylene glycol,

23、vol % . 52.4 min . 52.4 min E202Dipropylene glycol, vol % . 0.5 max . 0.5 max E202Other glycols,B vol % 2.5 max 0.1 max 2.5 max 0.1 max E202Total glycols, vol % 53 min 53 min 53 min 53 min E202Freezing Point, C (F) -40 (-40) -38 (-36) -40 (-40) -38 (-36) D1177A , D6660Freezing Point, C (F) 40 (40) m

24、ax 38 (36) max 40 (40) max 38 (36) max D1177,C D6660Glycol esters, mg/L B B B B D7638Glycol esters as acetic acid D D D D D7736ANitrite, Nitrate, Phosphate(total, g/g)5 max 5 max 50 max 25 max D5827Nitrite, Nitrate, Phosphate(total, g g)5 max 5 max 50 max 25 max D5827Silicon, g/g 5 max 5 max 5 max 5

25、 max D6130Chloride ion, mg/L 2.5 max 2.5 max 12.5 max 12.5 max D3634, D5827CChloride ion, g/g 2.5 max 2.5 max 12.5 max 12.5 max D3634, D5827ESulfate, mg/L 5 max 5 max 50 max 50 max D5827Sulfate, g/g 5 max 5 max 50 max 50 max D5827Boron, g/g 5 max 5 max 25 max 25 max D5827Boron, g/g 5 max 5 max 25 ma

26、x 25 max D6130Aluminum, Calcium, Copper,Iron, Magnesium, Lead, Zinc(total, g/g)5 max 5 max 5 max 5 max D6130Aluminum, Calcium, Copper,Iron, Magnesium, Lead,Zinc (total, g/g)5 max 5 max 5 max 5 max D6130Iron, g/g 1.0 max 1.0 max 1.0 max 1.0 max E394, D6130A Atitration test method to determineAcidity

27、and Glycol Esters content in Propylene Glycol is under development. Test Method D7736 is intended for Ethylene Glycol TypeEG-1 and Type EG-2 only.B Other glycols shall be as defined in Terminology D4725.C In case of dispute, Test Method D1177 shall be the preferred test method.D A limit for glycol e

28、sters should be established by agreement between the supplier and the customer.E In case of dispute, Test Method D3634 shall be the preferred test method.D7713 182“test result” represents an individual determination. All laboratories were asked to report three test results from a single operator,for

29、 every material. Except for the inability of all participants to report all requested replicates, Practice E691 was followed for thedesign and analysis of the data; the details are given in ASTM Research Report No. D15-XXXX.36.1.1 Repeatability limit (r)Two test results obtained within one laborator

30、y shall be judged not equivalent if they differ bymore than the “r” value for that material; “r” is the interval representing the critical difference between two test results for the samematerial, obtained by the same operator using the same equipment on the same day in the same laboratory.6.1.1.1 R

31、epeatability limits are listed in Table 2.6.1.2 Reproducibility limit (R)Two test results shall be judged not equivalent if they differ by more than the “R” value for thatmaterial; “R” is the interval representing the critical difference between two test results for the same material, obtained by di

32、fferentoperators using different equipment in different laboratories.6.1.2.1 Reproducibility limits are listed in Table 2.6.1.3 The above terms (repeatability limit and reproducibility limit) are used as specified in Practice E177.6.1.4 Any judgment in accordance with statements 6.1.1 and 6.1.2 has

33、an approximate 95 % probability of being correct.6.2 BiasAt the time of the study, there was no accepted reference material tested to determine the bias for this test method,therefore no statement on bias is being made.6.3 The precision statement was determined through statistical examination of 51

34、results, from eight laboratories, on threematerials. These materials were described as:Sample Aqueous Glycol nom 4555 % “A”Sample Aqueous Glycol nom 4555 % “B”Sample Aqueous Glycol nom 4555 % “C”6.4 To judge the equivalency of two test results, it is recommended to choose the material closest in cha

35、racteristics to the testmaterial.6. Keywords6.1 engine coolant; ethylene; glycol; polyester; propylene glycol, pre-diluted, recycledASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard

36、 are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif n

37、ot revised, either reapproved or withdrawn.Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which

38、you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,Unit

39、ed States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may a

40、lso be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ For a copy of the draft Research Report, please contact Caitlin Farrell at cfarrellastm.orgTABLE 2 Glycol Concentration (%)Material AverageARepeatabilityStandardDeviationReproducibilityStandardDeviationRepeatabilityLimitReproducibilityLimitx sr sR r RSampleA47.4 0.27 0.73 0.77 2.04SampleB52.1 0.47 0.89 1.32 2.50SampleC42.0 0.37 0.89 1.04 2.49A The average of the laboratories calculated averages.D7713 183