1、8452018( ) ( )9130 21 Cr2O3K2OA 6 12 B 6 6 C 4 12 D 4 62 RA R316 R3B 16 R3R3C 16 R3R3D R316 R33 KFAlF3BaOMgOAl2O35MgSiO3A Ba2+Mg2+OH-F-K+B Ba2+Mg2+O2-F-K+C OH-F-K+Ba2+D O2-F-K+Ba2+42A B C D5 150A BC D6 R2O-SiO2R+O/SiLi+Na+K+A SiO4R-OB rLi+ rNa+rK+Li+C SiO4R+SiO4Si-OD Si-O7 PA TiO2-xZn1+xO B UO2+xCu2
2、-xOC ZnO1-xCa1-xO D Cr2+xO3Co1-xO8 110 100 111 0.7850.555 0.907A 100 B 110 C 1119A 0 B 1 C 2 D 3310A B C11A B C D12A G 0 B H 0 C H0 D S=013A B C D14A 0 B 45 C 90 D 18015A B C D30 11 Fe3O4(1) (2) 342 ABX34 5 6ABX373 8 9104 Y115 1213 146157 16 17 18198 2021 22 2324 259 2627 28 2930570 1011 Al3+Si4+Si4
3、+Al3+6 Al3+Si4+O2-0.53 0.40 1.402PO43-SO32-AlPO42 1163 PLZT2 PLZT245 a a0G06 312 Na+737 ZrO2ZrO2,251.013 10Hp PaH298kJ/molT(J/(mol K)1000K 1400K 1800K 2100KZrO2-1097.463 83.703 101.608 117.259 127.322H20 145.403 152.906 159.123 163.173Zr 0 52.95 61.17 67.94 72.219H2O -241.814 206.716 216.285 224.487 229.978820A-B-C 4 D AmBnMAxByCz1.2.3. E1E2E3E44. F94
