EN 17034-2018 Chemicals used for treatment of water intended for human consumption - Aluminium chloride anhydrous aluminium chloride basic dialuminium chloride .pdf

1、BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06Chemicals used for treatment of water intended for human consumption Aluminium chloride anhydrous, aluminium chloride basic, dialuminium chloride pentahydroxide and aluminium chloride hydroxide sulfateBS EN 17034:2018EU

2、ROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 17034 January 2018 ICS 71.100.80 Supersedes EN 881:2004, EN 883:2004English Version Chemicals used for treatment of water intended for human consumption - Aluminium chloride anhydrous, aluminium chloride basic, dialuminium chloride pentahydroxide an

3、d aluminium chloride hydroxide sulfate Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - Chlorure daluminium anhydre, chlorure daluminium basique, pentahydroxychlorure de dialuminium et hydroxychlorosulfate daluminium Produkte zur Aufbereitung von Wasser fr den

4、menschlichen Gebrauch - Aluminiumchlorid, wasserfrei, Aluminiumchlorid, basisch, Dialuminiumchloridpentahydroxid und Aluminiumchloridhydroxidsulfat This European Standard was approved by CEN on 30 November 2017. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulat

5、e the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Stan

6、dard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the nat

7、ional standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Se

8、rbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation in any form a

9、nd by any means reserved worldwide for CEN national Members. Ref. No. EN 17034:2018 ENational forewordThis British Standard is the UK implementation of EN 17034:2018. It supersedes BS EN 881:2004 and BS EN 883:2004, which are withdrawn.The UK participation in its preparation was entrusted to Technic

10、al Committee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Th

11、e British Standards Institution 2018 Published by BSI Standards Limited 2018ISBN 978 0 580 94363 8ICS 71.100.80Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 28

12、 February 2018.Amendments/corrigenda issued since publicationDate Text affectedBRITISH STANDARDBS EN 17034:2018EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 17034 January 2018 ICS 71.100.80 Supersedes EN 881:2004, EN 883:2004English Version Chemicals used for treatment of water intended for h

13、uman consumption - Aluminium chloride anhydrous, aluminium chloride basic, dialuminium chloride pentahydroxide and aluminium chloride hydroxide sulfate Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - Chlorure daluminium anhydre, chlorure daluminium basique, pe

14、ntahydroxychlorure de dialuminium et hydroxychlorosulfate daluminium Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Aluminiumchlorid, wasserfrei, Aluminiumchlorid, basisch, Dialuminiumchloridpentahydroxid und Aluminiumchloridhydroxidsulfat This European Standard was approved by

15、CEN on 30 November 2017. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national stand

16、ards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and no

17、tified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary,

18、Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-C

19、ENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 17034:2018 EBS EN 17034:2018EN 17034:2018 (E) 2 Contents Page European foreword . 4 Introduction 5 1 Scope 6 2 Nor

20、mative references 6 3 Description 6 3.1 Identification 6 3.1.1 Chemical names . 6 3.1.2 Synonym or common names . 6 3.1.3 Relative molecular mass . 6 3.1.4 Empirical formula . 7 3.1.5 Chemical formula 7 3.1.6 CAS Registry Number 7 3.1.7 EINECS reference 7 3.2 Commercial forms . 7 3.3 Physical proper

21、ties . 7 3.3.1 Appearance 7 3.3.2 Density 8 3.3.3 Solubility 8 3.3.4 Vapour pressure 8 3.3.5 Boiling point at 100 kPa . 8 3.3.6 Crystallization point . 8 3.3.7 Specific heat 8 3.3.8 Viscosity (dynamic) 9 3.3.9 Critical temperature 9 3.3.10 Critical pressure 9 3.3.11 Physical hardness . 9 3.4 Chemica

22、l properties . 9 4 Purity criteria . 9 4.1 General 9 4.2 Composition of commercial product . 10 4.3 Impurities and main by-products 10 4.4 Chemical parameters 10 5 Test methods . 11 5.1 Sampling 11 5.1.1 General . 11 5.1.2 Liquid 11 5.2 Analyses . 12 6 Labelling - Transportation - Storage . 12 6.1 M

23、eans of delivery . 12 6.2 Risk and safety labelling in accordance with EU rules 12 6.3 Transportation regulations and labelling . 13 6.4 Marking 15 6.5 Storage . 15 6.5.1 General . 15 BS EN 17034:2018EN 17034:2018 (E) 3 6.5.2 Long term stability . 15 6.5.3 Storage incompatibilities . 15 Annex A (inf

24、ormative) General information on aluminium chloride anhydrous, aluminium chloride basic, dialuminium chloride pentahydroxide and aluminium chloride hydroxide sulfate 17 A.1 Origin 17 A.1.1 Raw materials 17 A.1.2 Manufacturing process . 17 A.2 Quality of commercial product 17 A.3 Use 22 A.3.1 Functio

25、n . 22 A.3.2 Form in which the products are used 22 A.3.3 Treatment dose . 22 A.3.4 Means of application 22 A.3.5 Secondary effects 22 A.3.6 Removal of excess product 22 Annex B (normative) General rules relating to safety . 23 B.1 Rules for safe handling and use . 23 B.2 Emergency procedures . 23 B

26、2.1 Accident 23 B.2.2 Spillage . 23 B.2.3 Fire . 23 Bibliography . 24 BS EN 17034:2018EN 17034:2018 (E) 4 European foreword This document (EN 17034:2018) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be gi

27、ven the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2018 and conflicting national standards shall be withdrawn at the latest by July 2018. Attention is drawn to the possibility that some of the elements of this document may be th

28、e subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 883:2004, EN 881:2004. Significant technical differences between this edition and EN 883:2004 and EN 881:2004 are as follows: a) adding the product

29、aluminium chloride basic and the information related to it; b) deletion of the reference to EU Directive 80/778/EEC of 15 July 1980; c) Annex A is informative; d) Annex B is normative. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries

30、are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,

31、Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 17034:2018EN 17034:2018 (E) 5 Introduction In respect of potential adverse effects on the quality of water intended for human consumption, caused by the product covered by this document: a

32、) this document provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the charac

33、teristics of this product remain in force. NOTE Conformity with this document does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this document is subject to regulation or control by National Authorities. BS

34、EN 17034:2018EN 17034:2018 (E) 6 1 Scope This document is applicable to aluminium chloride anhydrous, aluminium chloride basic, dialuminium chloride pentahydroxide and aluminium chloride hydroxide sulfate used for treatment of water intended for human consumption. It describes the characteristics an

35、d specifies the requirements of aluminium chloride basic, polyaluminium chloride hydroxide and polyaluminium chloride hydroxide sulfate and refers to the corresponding analytical methods. It gives information for their use in water treatment. It also gives the usable rules relating to safe handling

36、and use of these aluminium salts (see Annex B). 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition

37、 of the referenced document (including any amendments) applies. EN 1302, Chemicals used for treatment of water intended for human consumption Aluminium-based coagulants Analytical methods ISO 3165, Sampling of chemical products for industrial use Safety in sampling ISO 6206, Chemical products for in

38、dustrial use Sampling Vocabulary 3 Description 3.1 Identification 3.1.1 Chemical names a) Aluminium chloride anhydrous b) Aluminium chloride, basic c) Dialuminium chloride pentahydroxide d) Aluminium chloride hydroxide sulfate 3.1.2 Synonym or common names a) Aluminium (III) chloride, Aluminium tric

39、hloride b) Aluminium chloride, polyaluminium chloride, polyaluminium chloride hydroxide PAC, PACl NOTE In French, the term “Polychlorure daluminium” is deprecated. c) Aluminium chloro hydrate, Polyaluminium chloride d) Polyaluminium chloride, PAC; polyaluminium chloride sulfate, PACS 3.1.3 Relative

40、molecular mass Variable (see 3.1.4). BS EN 17034:2018EN 17034:2018 (E) 7 3.1.4 Empirical formula a) AlCl3b) Al(OH)aClb(a+b) = 3 a 0 c) Al2(OH)5Cl d) Al(OH)aCl(3-a-2b)(SO4)ba = 0,6-2,5 b = 0,05-0,5 (a+b)/2 2,4 3.1.5 Chemical formula Variable (see 3.1.4). 3.1.6 CAS Registry Number 1)(a) 7446-70-0 (b1)

41、 1327-41-9 (b2) 14215-15-7 (a = 1 b = 2) (b3) 10284-64-7 (a = 2, b = 1) (c) 12042-91-0 (d) 39290-78-3 3.1.7 EINECS reference 2)(a) 231-208-1 (b1) 215-477-2 (b2) 238-071-7 (b3) 233-632-2 (c) 234-933-1 (d) 254-400-7 3.2 Commercial forms Except aluminium chloride anhydrous, which is solid, these produc

42、ts are generally available as solutions. 3.3 Physical properties 3.3.1 Appearance The product is colourless to yellow. 1)Chemical Abstracts Service Registry Number. 2)European Inventory of Existing Commercial Chemical Substances. BS EN 17034:2018EN 17034:2018 (E) 8 3.3.2 Density The density depends

43、on the particular composition, especially the aluminium ion content, expressed as mass fraction of aluminium (Al %). Typical values: a) Aluminium chloride anhydrous, 2,5 g/ml b) Aluminium chloride solution, 1,30 g/ml for 5,8 % Al c) Polyaluminium chloride solution, 1,35-1,40 g/ml for 9,0 % Al d) Alu

44、minium chloride hydroxide sulfate solution, 1,20 1,25 g/ml for 5,3 % Al 3.3.3 Solubility All products in solution are fully miscible with water. Aluminium chloride anhydrous will react in water with a solubility of 45,8 g/100 ml (20 C). NOTE Depending on the particular product, dilute solutions can

45、hydrolyze and form a precipitate. 3.3.4 Vapour pressure The vapour pressure for aluminium chloride anhydrous is 133,3 Pa (99 C). 3.3.5 Boiling point at 100 kPa 3)The boiling point for aluminium chloride anhydrous is 182,7 C. 3.3.6 Crystallization point Typical values for solutions: a) Aluminium chlo

46、ride solution, - 20 C for 5,8 % Al b) Polyaluminium chloride hydroxide solution, 20C for 9,0 % Al c) Dialuminium chloride pentahydroxide solution; 0 C for 12,5 % Al d) Aluminium chloride hydroxide sulfate solution, 10 C for 5,3 % Al 3.3.7 Specific heat Not known. 3)100 kPa = 1 bar. BS EN 17034:2018E

47、N 17034:2018 (E) 9 3.3.8 Viscosity (dynamic) Typical values: a) Aluminium chloride anhydrous, 0,35 mPa s (197 C) b) Aluminium chloride solution, 10 mPa s to 30 mPa s for 5,8 % Al (20 C) c) Polyaluminium chloride hydroxide solution, 10 mPa s to 50 mPa s for 9,0 % Al (20 C) d) Dialuminium chloride pen

48、tahydroxide solution; 10 mPa s to 30 mPa s for 12,5 % Al (20 C) e) Aluminium chloride hydroxide sulfate solution, 10 mPa s to 30 mPa s for 5,3 % Al (20 C) 3.3.9 Critical temperature Not applicable. 3.3.10 Critical pressure Not applicable. 3.3.11 Physical hardness Not applicable. 3.4 Chemical propert

49、ies Aluminium chloride anhydrous will react in water. Aluminium chloride basic, dialuminium chloride pentahydroxide and aluminium chloride hydroxide sulfate hydrolyse are acidic liquids which hydrolyse and form a precipitate of aluminium hydroxide when diluted beyond a particular level. Since aluminium compounds are amphoteric in nature, the solubility of aluminium depends on the pH value and the products should be used within an appropriate pH range. NOTE A characteristic of these products is their high t