EN ISO 23900-2-2018 Pigments and extenders - Methods of dispersion and assessment of dispersibility in plastics - Part 2 Determination of colouristic properties.pdf

1、BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06Pigments and extenders - Methods of dispersion and assessment of dispersibility in plasticsPart 2: Determination of colouristic properties and ease of dispersion in plasticized polyvinyl chloride by two-roll millingBS E

2、N ISO 23900-2:2018EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 23900-2 January 2018 ICS 87.060.10 Supersedes EN 13900-2:2003English Version Pigments and extenders - Methods of dispersion and assessment of dispersibility in plastics - Part 2: Determination of colouristic properties and ea

3、se of dispersion in plasticized polyvinyl chloride by two-roll milling (ISO 23900-2:2015) Pigments et matires de charge - Mthodes de dispersion et valuation de laptitude la dispersion dans les plastiques - Partie 2: Dtermination des proprits colorimtriques et de la facilit de dispersion dans le poly

4、chlorure de vinyle plastifi par calandrage sur bicylindre (ISO 23900-2:2015) Pigmente und Fllstoffe - Dispergierverfahren und Beurteilung der Dispergierbarkeit in Kunststoffen - Teil 2: Bestimmung der koloristischen Eigenschaften und der Dispergierhrte in weichmacherhaltigen Polyvinylchlorid (PVC-P)

5、 - Formmassen im Walztest (ISO 23900-2:2015) This European Standard was approved by CEN on 4 January 2018. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterati

6、on. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by

7、 translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

8、Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR S

9、TANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 23900-2:2018 ENational forew

10、ordThis British Standard is the UK implementation of EN ISO 23900-2:2018. It is identical to ISO 23900-2:2015. It supersedes BS EN 13900-2:2003 and BS ISO 23900-2:2015, which are withdrawn.The UK participation in its preparation was entrusted to Technical Committee STI/1, Pigments.A list of organiza

11、tions represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2018 Published by BSI Standards Limited 2018IS

12、BN 978 0 580 98296 5ICS 87.060.10Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 28 February 2018.Amendments/corrigenda issued since publicationDate Text affecte

13、d28 February 2018 This corrigendum renumbers BS ISO 23900-2:2015 as BS EN ISO 23900-2:2018BRITISH STANDARDBS EN ISO 23900-2:2018EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 23900-2 January 2018 ICS 87.060.10 Supersedes EN 13900-2:2003English Version Pigments and extenders - Methods of di

14、spersion and assessment of dispersibility in plastics - Part 2: Determination of colouristic properties and ease of dispersion in plasticized polyvinyl chloride by two-roll milling (ISO 23900-2:2015) Pigments et matires de charge - Mthodes de dispersion et valuation de laptitude la dispersion dans l

15、es plastiques - Partie 2: Dtermination des proprits colorimtriques et de la facilit de dispersion dans le polychlorure de vinyle plastifi par calandrage sur bicylindre (ISO 23900-2:2015) Pigmente und Fllstoffe - Dispergierverfahren und Beurteilung der Dispergierbarkeit in Kunststoffen - Teil 2: Best

16、immung der koloristischen Eigenschaften und der Dispergierhrte in weichmacherhaltigen Polyvinylchlorid (PVC-P) - Formmassen im Walztest (ISO 23900-2:2015) This European Standard was approved by CEN on 4 January 2018. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which sti

17、pulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European

18、 Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are th

19、e national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romani

20、a, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation in any f

21、orm and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 23900-2:2018 EBS EN ISO 23900-2:2018EN ISO 23900-2:2018 (E) 3 European foreword The text of ISO 23900-2:2015 has been prepared by Technical Committee ISO/TC 256 “Pigments, dyestuffs and extenders” of the International

22、Organization for Standardization (ISO) and has been taken over as EN ISO 23900-2:2018 by Technical Committee CEN/TC 298 “Pigments and extenders” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical tex

23、t or by endorsement, at the latest by July 2018, and conflicting national standards shall be withdrawn at the latest by July 2018. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying a

24、ny or all such patent rights. This document supersedes EN 13900-2:2003. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denma

25、rk, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorse

26、ment notice The text of ISO 23900-2:2015 has been approved by CEN as EN ISO 23900-2:2018 without any modification. BS EN ISO 23900-2:2018ISO 23900-2:2015(E)Foreword iv1 Scope . 12 Normative references 13 Terms and definitions . 14 Principle 25 Material 26 Apparatus . 27 Sampling 28 Procedure. 38.1 M

27、illing at (160 5) C . 38.1.1 Premixing of the test materials . 38.1.2 Two-roll milling 38.1.3 Pressing . 38.2 Milling at (130 5) C . 49 Photometric measurement 410 Evaluation 410.1 Evaluation of colouristic properties in a white reduction . 410.2 Evaluation of the ease of dispersion . 411 Test repor

28、t . 412 Precision . 5Annex A (informative) Description of the basic compound 6Bibliography 8 ISO 2015 All rights reserved iiiContents PageBS EN ISO 23900-2:2018ISO 23900-2:2015(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (

29、ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, go

30、vernmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maint

31、enance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Atten

32、tion is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction

33、 and/or on the ISO list of patent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformit

34、y assessment, as well as information about ISOs adherence to the WTO principles in the Technical Barriers to Trade (TBT), see the following URL: Foreword Supplementary information .The committee responsible for this document is ISO/TC 256, Pigments, dyestuffs and extenders.ISO 23900 consists of the

35、following parts, under the general title Pigments and extenders Methods of dispersion and assessment of dispersibility in plastics: Part 1: General introduction Part 2: Determination of colouristic properties and ease of dispersion in plasticized polyvinyl chloride by two-roll milling Part 3: Determ

36、ination of colouristic properties and ease of dispersion of black and colour pigments in polyethylene by two-roll milling Part 4: Determination of colouristic properties and ease of dispersion of white pigments in polyethylene by two-roll milling Part 5: Determination by filter pressure value test P

37、art 6: Determination by film testiv ISO 2015 All rights reservedBS EN ISO 23900-2:2018Pigments and extenders Methods of dispersion and assessment of dispersibility in plastics Part 2: Determination of colouristic properties and ease of dispersion in plasticized polyvinyl chloride by two-roll milling

38、1 ScopeThis part of this ISO 23900 specifies a method of determining the colouristic properties of a test pigment relative to a standard, and the ease of dispersion DHPVC-Pof pigments from the differences in colour strength on dispersing colouring materials under various conditions in plasticized po

39、lyvinyl chloride (PVC-P) compounds.The method is appropriate for use with organic and inorganic black and colour pigments and for pigment preparations.The ease of dispersion determined in this way is valid only for the dispersion equipment, dispersion conditions and dispersion medium being used. The

40、 use of test conditions differing from those specified may give different results; this applies both to the absolute magnitude and to the relation between values of the ease of dispersion of various pigments. The subscript DHPVC-Pis therefore used to designate the value obtained as specified in this

41、 part of ISO 23900.The principle of this part of ISO 23900 may also be used for routine quality control purposes by reference to the photometric data generated from the sheets milled at 130 C. For quality control purposes, the ratio of pigment to TiO2may be agreed between the interested parties. Rat

42、ios of 1:10 for organic pigments and 0,2 to 0,5:1 for inorganic pigments are suggested as convenient and widely used standard ratios.Annex A is informative and gives a description of a suitable basic compound.2 Normative referencesThe following documents, in whole or in part, are normatively referen

43、ced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 787-24:1985, General methods of test for pigments and extenders Part 24:

44、Determination of relative tinting strength of coloured pigments and relative scattering power of white pigments Photometric methodsISO 15528, Paints, varnishes and raw materials for paints and varnishes SamplingISO 18314-11), Analytical colorimetry Part 1: Practical colour measurementEN 12877-1, Col

45、ouring materials in plastics Determination of colour stability to heat during processing of colouring materials in plastics Part 1: General introduction3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.1) To be published.INTERNATIONAL STANDARD ISO 23

46、900-2:2015(E) ISO 2015 All rights reserved 1BS EN ISO 23900-2:2018ISO 23900-2:2015(E)3.1ease of dispersionDHPVC-Pmeasure of the rate at which or the degree to which a pigment or extender achieves a given level of dispersion when dispersed in a plastics materialNote 1 to entry: The DHPVC-Pis derived

47、from the increase in colour strength achieved by two-roll milling as specified in 8.2, relative to the colour strength achieved as specified in 8.1.4 PrincipleUsing a two-roll mill, the pigment under test is dispersed at (160 5) C in the basic compound. The milled sheet obtained in this way is then

48、subjected to the higher shearing forces resulting from two-roll milling at (130 5) C. The resulting increase in colour strength is a measure of the ease of dispersion DHPVC-P.5 MaterialA suitable and recommended basic compound is described in Annex A. An alternative compound may be agreed between th

49、e interested parties and is to be mentioned in the test report.The quantity of the pigment used shall be such that a depth of shade (as specified in EN 12877-1) of approximately 1/25 SD is achieved.6 Apparatus6.1 Two-roll mill. Equipped with heating facilities and having rollers adjustable for spacing. The roll diameter shall be between 80 mm and 200 mm, and the ratio of the speeds of rotation of the two rollers shall be between 1:1,1 and 1:1,2.NOTE It has been found that comparable results on diffe