ASTM D2320-98(2017) Standard Test Method for Density (Relative Density) of Solid Pitch (Pycnometer Method).pdf

1、Designation: D2320 98 (Reapproved 2017)Standard Test Method forDensity (Relative Density) of Solid Pitch (PycnometerMethod)1This standard is issued under the fixed designation D2320; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision,

2、the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method covers the determination of density andrelative density by pycnometer, and can be used fo

3、r pitch thatcan be handled in fragments.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the

4、 user of this standard to establish appro-priate safety, health, and environmental practices and deter-mine the applicability of regulatory limitations prior to use.1.4 This international standard was developed in accor-dance with internationally recognized principles on standard-ization established

5、 in the Decision on Principles for theDevelopment of International Standards, Guides and Recom-mendations issued by the World Trade Organization TechnicalBarriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standards:2D4296 Practice for Sampling PitchE11 Specification for Woven Wire Tes

6、t Sieve Cloth and TestSieves3. Terminology3.1 Definitions:3.1.1 densitythe mass per unit of volume at a standard testtemperature.3.1.2 relative densitythe ratio of the mass of a givenvolume of the material at a standard test temperature to that ofan equal volume of water at the same temperature.4. S

7、ummary of Test Method4.1 The sample is weighed and its volume determined bythe mass of water displaced.5. Significance and Use5.1 Values of density and relative density are used forconverting volumes to units of mass as required in otherASTMstandards and in sales transactions.6. Apparatus6.1 Glass P

8、ycnometer, capacity about 25 mL, with accu-rately fitting glass stopper with a capillary tube 1.0 mm to2.0 mm in diameter.6.2 Water Bath, maintained at 25.0 C 6 0.1 C and pro-vided with mechanical stirring.6.3 Vacuum Pump or Aspirator, capable of producing avacuum of 2.7 kPa (20 torr).NOTE 120 torr

9、= 20 mm Hg = 2.66 kPa.6.4 Manometer, suitable for measuring the specifiedvacuum.6.5 Vacuum Desiccator with Guard.6.6 Sieves, U.S. Standard 2.36 mm (No. 8) and 600 m(No. 30) conforming to Specification E11.7. Reagents and Materials7.1 Wetting Agent, 0.1 gmL Aerosol OT.7.2 Wetting Agent, 0.1 gmL BRU 3

10、5 (Alyoxyethylene do-decyl ether, detergent.8. Bulk Sampling8.1 Samples from shipments shall be taken in accordancewith Practice D4296 and shall be free of foreign substances.Thoroughly mix the sample immediately before removing arepresentative portion for the determination or for dehydration.9. Deh

11、ydration9.1 All bulk samples suspected of having free moisture shallbe air-dried or oven-dried at 50 C in a forced-air oven beforeanalyzing.1This test method is under the jurisdiction of ASTM Committee D02 onPetroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility ofSubcommi

12、ttee D02.05 on Properties of Fuels, Petroleum Coke and Carbon Material.Current edition approved Oct. 1, 2017. Published November 2017. Originallyapproved in 1964. Last previous edition approved in 2012 as D2320 98 (2012).DOI: 10.1520/D2320-98R17.2For referenced ASTM standards, visit the ASTM website

13、, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United StatesTh

14、is international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for theDevelopment of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (

15、TBT) Committee.110. Preparation of Test Sample10.1 Crush a 50 g to 100 g representative portion of the drypitch until all of it passes through the 2.36 mm (No. 8) sieve.Avoid grinding the pitch. Remove the fines by screeningthrough the 600 m (No. 30) sieve and use the pitch retained onthis sieve as

16、the test sample. If desired, small lumps of pitchmay be used without crushing, provided the lumps pass the2.36 mm sieve and are retained on the 600 m sieve. In eithercase, follow the evacuation steps described in 12.2. In case ofdispute use the crushing method.11. Calibration of Pycnometer11.1 Weigh

17、 the thoroughly clean, dry, and assembled pyc-nometer to the nearest 0.5 mg and record the mass.11.2 Fill the pycnometer with freshly boiled distilled waterthat has been cooled to about 20 C. Insert the stopper with arotary motion to secure a firm seat, making sure that no air isentrapped, then comp

18、letely immerse the pycnometer in thewater bath at 25 C for a minimum of 30 min. Remove andwipe the filled pycnometer as described in 12.4; then immedi-ately weigh to the nearest 0.5 mg. Remove the stopper andrepeat the operations until three successive weighings agreewithin 0.5 mg. Record the averag

19、e mass of the pycnometerwith water.12. Procedure12.1 Place not less than 5 g of the prepared crushed or lumpsample in the dry, tared pycnometer and weigh with the stopperto the nearest 0.5 mg. Record the mass. Cover the pitch to adepth of about 10 mm with freshly boiled distilled watercooled to a te

20、mperature of about 20 C. Add several drops of astock solution of Aerosol OT containing 0.1 gmL of solutionor other wetting agent.12.2 Place the unstoppered pycnometer in the vacuumdesiccator and evacuate the air at such a rate that no sudden orviolent ebullition occurs. Maintain a pressure in the de

21、siccatorof 2.7 kPa to 3.3 kPa (20 torr to 25 torr), as measured by themanometer, for at least 15 min to remove all entrapped airbubbles. If air bubbles persist, add more wetting agent andcontinue the process until no air bubbles are visible.12.3 Remove the pycnometer from the desiccator and fillwith

22、 freshly boiled distilled water that has been cooled to about20 C. Insert the stopper with a rotary motion to secure a firmseat, making sure that no air is entrapped. Then completelyimmerse the pycnometer in the water bath at 25 C for aminimum of 30 min.12.4 After 30 min, raise the pycnometer until

23、the top of thestopper is above the water level, then quickly and carefullywipe the water off the flat surface of the stopper, taking care notto remove water from the capillary tube. Remove the pycnom-eter from the bath and dry with a clean, dry cloth or with soft,absorbent paper. Weigh immediately t

24、o the nearest 0.5 mg andrecord the mass.13. Calculation13.1 Calculate the relative density of the pitch as follows:sp gr 5 W32 W1!/W22 W1! 2 W42 W3!# (1)5W/W 2 W42 W2!#where:W = mass of sample (W3 W1),W1= mass of pycnometer,W2= mass of pycnometer filled with water at 25 C,W3= mass of pycnometer with

25、 sample, andW4= mass of pycnometer with sample filled with water at25 C.13.2 Calculate the density of the pitch as follows:Density 5 relative density 3 WT(2)where:relative density = calculation from 13.1, andWT= density of water at test temperature indesired units.Density of Water,3Test Temperature

26、g/cm3kg/m325 C 0.9970 997.014. Report14.1 Report the relative density of the pitch to the thirddecimal place, expressed as specific gravity, 25 C25 C.14.2 Report the density to the nearest third decimal place ing/cm3and with four significant figures in kg/m3, expressed asdensity at 25 C.15. Precisio

27、n and Bias15.1 The following criteria shall be used for judging theacceptability of results (95 % probability):15.1.1 RepeatabilityDuplicate values by the same opera-tor shall not be considered suspect unless they differ by morethan the following:Relative density: 0.011Density: 0.007 g cm3or 7.0 kg

28、m315.1.2 ReproducibilityThe values reported by each of twolaboratories, representing the arithmetic average of duplicatedeterminations, shall not be considered suspect unless thereported values differ by more than the following:Relative density: 0.001Density: 0.011 g cm3or 11.0 kg m315.1.3 BiasThe p

29、rocedure for relative density has no biasbecause the value of relative density is defined only in terms ofthis test method.16. Keywords16.1 density; gravity; pitch; pycnometer3Density of water from CRC Handbook of Chemistry and Physics, 76th ed.,CRC Press, 1995.D2320 98 (2017)2ASTM International tak

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32、sed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at th

33、e address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 98 (2017)3