AIR FORCE MIL-DTL-87107 E-2012 PROPELLANT HIGH DENSITY SYNTHETIC HYDROCARBON TYPE GRADE JP-10《JP-10级高密度合成碳氢推进剂》.pdf

1、MIL-DTL-87107E 12-January-2012 SUPERSEDING MIL-DTL-87107D 28-December-2006 DETAIL SPECIFICATION PROPELLANT, HIGH DENSITY SYNTHETIC HYDROCARBON TYPE, GRADE JP-10 AMSC N/A FSC 9135 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. METRIC Comments, suggestions, or questi

2、ons on this document should be addressed to AFPA/PTPT, 2430 C Street, Bldg 70, Area B, Wright-Patterson AFB OH 45433-7632 or e-mailed to AFPET.AFTTwpafb.af.mil. Since contact information can change, you may want to verify the currency of this address information using the ASSIST Online database at h

3、ttps:/assist.daps.dla.mil. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-87107E 2 This specification is approved for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope1.2 . This specification covers one gra

4、de of high density synthetic hydrocarbon type propellant. ClassificationGrade . Description JP-10 High density hydrocarbon fuel, composed solely of exo-tetrahydrodicyclopentadiene 2. APPLICABLE DOCUMENTS 2.1 General2.2 . The documents listed in this section are specified in sections 3, 4, or 5 of th

5、is specification. This section does not include documents cited in other sections of this specification or recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users are cautioned that they must meet all specified r

6、equirements of documents cited in sections 3, 4, or 5 of this specification, whether or not they are listed. Government documents2.2.1 . Specifications, standards, and handbooksFEDERAL STANDARDS . The following specifications, standards and handbooks form a part of this document to the extent specif

7、ied herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. FED-STD-313 Material Safety Data, Transportation Data and Disposal Data for Hazardous Materials Furnished to Government Activities DEPARTMENT OF DEFENSE SPECIFICATIONS MIL-DTL-85470

8、 Inhibitor, Icing, Fuel System, High Flash NATO Code Number S-1745 DEPARTMENT OF DEFENSE STANDARDS MIL-STD-290 Packing of Petroleum and Related Products (Copies of these documents are available online at https:/assist.daps.dla.mil or from the Standardization Document Order Desk, 700 Robbins Avenue,

9、Bldg 4D, Philadelphia PA 19111-5094.) 2.3 Non-Government publicationsASTM International . The following documents form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. ASTM D56 Standard

10、Test Method for Flash Point by Tag Closed Cup Tester (DoD Adopted) ASTM D93 Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester (DoD Adopted) ASTM D156 Standard Test Method for Saybolt Color of Petroleum Products (Saybolt Chromometer Method) (DoD Adopted) Provided by IHSNot for

11、 ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-87107E 3 ASTM D240 Standard Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter (DoD Adopted) ASTM D381 Standard Test Method for Gum Content in Fuels by Jet Evaporation (DoD Adopted) AS

12、TM D445 Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and the Calculation of Dynamic Viscosity) (DoD Adopted) ASTM D976 Standard Test Method for Calculated Cetane Index of Distillate Fuels (DoD Adopted) ASTM D1298 Standard Test Method for Density, Relative Density (

13、Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method (DoD Adopted) ASTM D2276 Standard Test Method for Particulate Contaminant in Aviation Fuel by Line Sampling (DoD Adopted) ASTM D3241 Standard Test Method for Thermal Oxidation Stability of Aviatio

14、n Turbine Fuels (DoD Adopted) ASTM D3828 Standard Test Methods for Flash Point by Small Scale Closed Cup Tester (DoD Adopted) ASTM D4052 Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter (DoD Adopted) ASTM D4057 Standard Practice for Manual Sampl

15、ing of Petroleum and Petroleum Products (DoD Adopted) ASTM D4176 Standard Test Method for Free Water and Particulate Contamination in Distillate Fuels (Visual Inspection Procedures) (DoD Adopted) ASTM D4809 Standard Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter (

16、Precision Method) (DoD Adopted) ASTM D5006 Standard Test Method for Measurement of Fuel System Icing Inhibitors (Ether Type) in Aviation Fuels (DoD Adopted) ASTM D5452 Standard Test Method for Particulate Contamination in Aviation Fuels by Laboratory Filtration (DoD Adopted) ASTM D6045 Standard Test

17、 Method for Color of Petroleum Products by the Automatic Tristimulus Method ASTM E29 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications (DoD Adopted) (Copies of these documents are available online at http:/www.astm.org or from ASTM International

18、, 100 Barr Harbor Drive, West Conshohocken PA 19428-2959) 2.4 Order of precedence3. REQUIREMENTS . Unless otherwise noted herein or in the contract, in the event of a conflict between the text of this document and the references cited herein, the text of this document takes precedence. Nothing in th

19、is document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3.1 Materials. Except as otherwise specified herein, Grade JP-10 shall consist solely of exo-tetrahydrodicyclopentadiene. Provided by IHSNot for ResaleNo reproduction or networking permitt

20、ed without license from IHS-,-,-MIL-DTL-87107E 4 3.1.1 Recycled, recovered, or environmentally preferable materials3.2 . Recycled, recovered, or environmentally preferable materials should be used to the maximum extent possible, provided that the material meets or exceeds the operational and mainten

21、ance requirements, and promotes economically advantageous life cycle costs. Chemical and physical requirements3.3 . The chemical and physical requirements of the finished fuel shall conform to those listed in Table I. Requirements contained herein are not subject to correction for test tolerances. I

22、f multiple determinations are made, results falling within any specified repeatability and reproducibility tolerances may be averaged. For rounding off of significant figures, ASTM E29 shall apply to all tests required by this specification. Additives3.3.1 . The additives listed shall be used in com

23、bination in amounts not to exceed those specified. The type and amount of each additive used shall be reported. Antioxidantsa. 2,6-di-. The following active inhibitors shall be blended separately or in combination into the fuel in total concentration of 90 parts per million (minimum) to 110 parts pe

24、r million (maximum), by weight, not including weight of solvent, in order to prevent the formation of polymeric oxidation products: tertb. 6-butyl-4-methylphenol tertc. 2,6-di-butyl-2,4-dimethylphenol tert3.3.2 -butylphenol Fuel system icing inhibitor3.4 . Fuel system icing inhibitor (FSII) shall on

25、ly be used at the request of the user. When requested by the user, the FSII shall conform to MIL-DTL-85470. Workmanship4. VERIFICATION . The finished fuel blend shall be visually free from undissolved water, sediment or suspended matter and shall be clear and bright at the ambient temperature or at

26、21C (70F), whichever is higher. ASTM D4176 describes a suitable test method for determining if the fuel is clear and bright. 4.1 Classification of inspection4.2 . The inspection requirements specified herein are classified as quality conformance inspection (4.2). Conformance inspections4.2.1 . For a

27、cceptance purposes, individual lots shall be examined as specified herein and subject to tests for all requirements cited in section 3. Inspection lot4.2.1.1 . Bulk lot4.2.1.2 . A bulk lot shall consist of an indefinite quantity of a homogenous mixture of material offered for acceptance in a single

28、isolated container. Packaged lot4.2.2.1 . A packaged lot shall consist of an indefinite number of 55-gallon drums or smaller unit packages of identical size and shape offered for acceptance and filled from the isolated tank containing a homogenous mixture of material. Sampling for verification of pr

29、oduct quality4.2.2.2 . Each bulk or packaged lot of material shall be sampled for verification of product quality in accordance with ASTM D4057 except where individual test procedures contain specific sampling instructions. Sampling for examination of filled containers for delivery4.3 . A random sam

30、ple of filled containers shall be selected from each lot. The samples shall be examined in accordance with 4.4.3. Inspection4.4 . Inspection shall be in accordance with 4.4.3 of this specification. Examinations4.4.1 . Examination of products4.4.2 . Samples selected in accordance with 4.2.2.1 shall b

31、e visually examined for compliance with 3.4. Examination of empty containers. Prior to filling, each empty unit container shall be visually inspected for cleanliness and suitability. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-87107E 5 TA

32、BLE I. Chemical and physical requirements and test methods. Property Min Max ASTM Standards Color, Saybolt +25 D156 1or D6045 Chemical Analysis, wt percent exo-tetrahydrodicyclopentadiene other hydrocarbons 298.5 100.0 1.5 Flash point, C (F) 54.4 (130) D56, D93 1, or D3828 Density, 15 C, kg/L (API G

33、ravity) 0.934 (20.0) 0.943 (18.5) D1298 or D4052 1Viscosity, mm2/s at C (F) -54 (-65) -18 (0) 40 10 D445 Net heat of combustion MJ/kg (Btu/lb) MJ/m (Btu/gal) 42.1 (18,100) 39,400 (141,500) D240 or D4809 Thermal stability change in pressure drop, mm Hg heater tube deposit visual rating 10 less than c

34、ode 3 D3241 4Existent gum, mg/100 mL 5.0 D381 5Particulate matter, mg/L 1.0 D2276 or D5452 FSII, vol. percent 60.10 0.15 D5006 Notes 1. Referee test method. 2. Test procedure and required equipment outlined in Appendix A. 3. This is for reference only, not a requirement. 4. See 4.5.1.1 for ASTM D324

35、1 test conditions and test limits. 5. If air is used instead of steam while performing ASTM D381, it must be reported. In the case of a failure with air, the sample must be retested using steam. 6. As required by user, see 3.3.2. 4.4.3 Examination of filled containers4.5 . Samples taken as specified

36、 in 4.2.2.2 shall be examined for conformance to MIL-STD-290 with regard to fill, closure, sealing, leakage, packaging, packing, and markings. Any container having one or more defects under the required fill shall be rejected. Test methods4.5.1 . Tests to determine conformance to chemical and physic

37、al requirements shall be conducted in accordance with the applicable ASTM standards, or in the case of unique requirements, the test procedures as outlined in Table I and described in the attached Appendix. Thermal stability4.5.1.1 . ASTM D32414.5.1.1.1 . The thermal stability test shall be conducte

38、d and the tube shall be rated using ASTM D 3241 (JFTOT). ASTM D3241 test conditionsa. Heater tube temperature at maximum point: 300C (572F). . b. Fuel system pressure: 3.43 MPa (500 psig). c. Fuel flow rate: 3.0 ml/minute. d. Test duration: 150 minutes. Provided by IHSNot for ResaleNo reproduction o

39、r networking permitted without license from IHS-,-,-MIL-DTL-87107E 6 4.5.1.1.2 Resultsa. The maximum visual rating of the heated tube deposits is less than a code 3. . The fuel sample is acceptable if all the following criteria are met: b. The visual rating of the heater tube show neither peacock ty

40、pe deposit (code P) nor abnormal type deposits (code A). c. The maximum differential pressure across the test filter does not exceed 10 millimeters of mercury (mm Hg). 4.5.1.1.3 ASTM D3241 reported dataa. Differential pressure in mm Hg at 150 minutes, or time to differential pressure of 10 mm Hg, wh

41、ichever occurs first. . The following data shall be reported: b. Heater tube deposit visual rating code at the end of the test. 5. PACKAGING 5.1 Packaging6. NOTES . For acquisition purposes, the packaging requirements shall be as specified in the contract or order (see 6.2). When packaging of materi

42、el is to be performed by DoD or in-house contractor personnel, these personnel need to contact the responsible packaging activity to ascertain packaging requirements. Packaging requirements are maintained by the Inventory Control Points packaging activities within the Military Service or Defense Age

43、ncy, or within the military services system commands. Packaging data retrieval is available from the managing Military Departments or Defense Agencys automated packaging files, CD-ROM products, or by contacting the responsible packaging activity. (This section contains information of a general or ex

44、planatory nature that may be helpful, but is not mandatory.) 6.1 Intended use6.2 . The fuel covered by this specification is intended for use in military gas turbine engines or military ramjet engines for missile application. Acquisition requirementsa. Title, number, and date of the specification. .

45、 Acquisition documents must specify the following: b. Quantity required and size containers required. c. Level of packaging and packing required. d. When blocking and bracing is specified. 6.2.1 Additive6.3 . Type and amount of additive (3.3). Precaution of mixing additives6.4 . To prevent any possi

46、ble reaction between the concentrated forms of the different additives (3.3) the fuel contractor is cautioned not to commingle additives prior to their addition to the fuels. Subject term (key word) listingexo-Tetrahydrodicyclopentadiene . Missile Fuel Ramjet 6.5 Material Safety Data Sheets6.6 . Con

47、tracting officers will identify those activities that require copies of completed Material Safety Data Sheets (MSDS) prepared in accordance with FED-STD-313. The pertinent Government mailing addresses for submission of data are listed in FED-STD-313. Changes from previous issue. Marginal notations a

48、re not used in this revision to identify changes with respect to the previous issue due to the extent of the changes. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-87107E APPENDIX A 7 METHOD OF TEST FOR ANALYSIS OF GRADE JP-10 FUEL BY GAS C

49、HROMATOGRAPHY A.1 SCOPE A.1.1 ScopeA.2 SUMMARY . This method provides for the quantitative determination of the purity of exo- tetrahydrodicyclopentadiene, the single chemical structure of JP-10. This Appendix is a mandatory part of the specification. The information contained herein is intended for compliance. A.2.1 Summary of methodsA.3 APPARATUS