AIR FORCE MIL-PRF-25508 H-2011 PROPELLANT OXYGEN《富氧推进剂》.pdf

1、MIL-PRF-25508H 27-October-2011 SUPERSEDING MIL-PRF-25508G 21 November 2006 PERFORMANCE SPECIFICATION PROPELLANT, OXYGEN This specification is approved for use by all Departments and Agencies of the Department of Defense. AMSC N/A FSC 9135 DISTRIBUTION STATEMENT A. Approved for public release; distri

2、bution is unlimited. METRIC Comments, suggestions, or questions on this document should be addressed to AFPA/PTPT, 2430 C Street, Bldg 70, Area B, Wright-Patterson AFB OH 45433-7632 or e-mailed to AFPET.AFTTwpafb.af.mil. Since contact information can change, you may want to verify the currency of th

3、is address information using the ASSIST Online database at https:/assist.daps.dla.mil. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-25508H 2 This specification is approved for use by all Departments and Agencies of the Department of Defens

4、e. 1. SCOPE 1.1 Scope1.2 . This specification covers the requirements for three grades and two types of oxygen. Classification1.2.1 . The oxygen will be of the following types and grades as specified (see 6.2). TypesType I Gaseous . The types of oxygen are as follows: Type II Liquid 1.2.2 GradesGrad

5、e A 99.6 percent pure, standard . The grades of oxygen are as follows: Grade B 99.5 percent pure, reduced standard Grade F 99.990 percent pure, fuel cell and breathing 1.3 Part or identifying number (PIN)M 25508 - X X Example of PIN: M25508-2B . The PINs to be used for oxygen acquired to this specif

6、ication are created as follows: Grade (see 1.2.2). Type (see 1.2.1). Use 1 for Type I, 2 for Type II. Specification number. Prefix for military specification. 2. APPLICABLE DOCUMENTS 2.1 General2.2 . The documents listed in this section are specified in sections 3, 4, or 5 of this specification. Thi

7、s section does not include documents cited in other sections of this specification or recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users are cautioned that they must meet all specified requirements of docume

8、nts cited in sections 3, 4, or 5 of this specification, whether or not they are listed. Government documents2.2.1 . Specifications, standards, and handbooks. The following standard forms a part of this document to the extent specified herein. Unless otherwise specified, the issues of this document a

9、re those cited in the solicitation or contract (see 6.2). Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-25508H 3 COMMERCIAL ITEM DESCRIPTION A-A-58092 Tape, Antiseize, Polytetrafluorethylene (Copies of this document is available online at h

10、ttps:/assist.daps.dla.mil/quicksearch/ or https:/assist.daps.dla.mil or by mail from the Standardization Document Order Desk, 700 Robbins Avenue, Bldg 4D, Philadelphia PA 19111-5094.) 2.3 Non-government publicationsASTM INTERNATIONAL (ASTM) . The following documents form a part of this document to t

11、he extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. ASTM E29 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications (DoD adopted) ASTM F307 Standard Practice for Sampl

12、ing Pressurized Gas for Gas Analysis (DoD adopted) ASTM F310 Standard Practice for Sampling Cryogenic Aerospace Fluids (DoD adopted) (Copies of these documents are available online at http:/www.astm.org or by mail from ASTM International, 100 Barr Harbor Drive, P.O. Box C700, West Conshohocken, PA,

13、19428-2959) COMPRESSED GAS ASSOCIATION (CGA) CGA G-4.3 Commodity Specification for Oxygen CGA P-15 Filling of Industrial and Medical Nonflammable Compressed Gas Cylinders (Copies of these documents are available online at http:/ or by mail from the Compressed Gas Association, Inc., 4221 Walney Road,

14、 5thFloor, Chantilly, VA 20151). 2.4 Order of precedence3. REQUIREMENTS . In the event of a conflict between the text of this document and the references cited herein (except for related specification sheets), the text of this document takes precedence. Nothing in this document, however, supersedes

15、applicable laws and regulations unless a specific exemption has been obtained. 3.1 Grade requirements3.2 . The purity and impurity concentrations as applicable to each grade of oxygen shall conform to the limits of Table I when tested in accordance with the applicable test method also specified in T

16、able I. Other limits and tests may be specified by the procuring activity (see 6.2). Limiting values. The following applies to all specified limits in this specification. For purposes of determining conformance with these requirements, an observed value or a calculated value shall be rounded off “to

17、 the nearest unit” in the last right-hand digit used in expressing the specification limit according to the rounding-off method of ASTM E29 Standard Practice for using Significant Digits in Test Data to Determine Conformance with Specifications. Provided by IHSNot for ResaleNo reproduction or networ

18、king permitted without license from IHS-,-,-MIL-PRF-25508H 4 3.3 FilterTABLE I. Grade limits for oxygen. . A filter with no more than a 10-micrometer nominal and 40-micrometer absolute rating shall be installed between the manufacturers plant system and the manifold used to fill the gas or liquid co

19、ntainers for delivery. Grade Test Method A B F Purity, percent by volume, min 99.6 99.5 99.990 4.4.1 Impurities, ppm by volume, max 4000 5000 100 4.4.1 Total hydrocarbons as methane 50 67.7 20 4.4.2 Water 3 26.3 3 4.4.2 Methane Note a Note a 16 4.4.2 Ethane Note a Note a 2 4.4.2 Propane and higher h

20、ydrocarbons as propane Note a Note a 1 4.4.2 Nitrous oxide Note a Note a 1 4.4.2 Halogenated hydrocarbons Note a Note a 1 4.4.2 Carbon monoxide and carbon dioxide Note a Note a 1 4.4.2 Other (N, Ar, Kr, etc.) Note a Note a 75 4.4.2 Odor Note a Note a None 4.4.2 Particulateb, mg/L, max 1.0 1.0 1.0 4.

21、4.3 Notes: a. No limit for this grade. b. Applies to Type II product only. The particulate test requirement and limit may be deleted by the procuring activity (see 6.2). 3.4 Filled containers (Type I only)3.4.1 . Filling Pressure3.4.2 . The container filling pressure shall not differ from that requi

22、red by the contract by more than 1.0% at 70F when tested as specified in 4.5.1. In no case shall the filling pressure exceed the rated service pressure of the container. Pressure-Temperature Filling Charts in CGA P-15 may be used. Leakage. Cylinders shall not leak when tested according to 4.5.2. Pro

23、vided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-25508H 5 4. VERIFICATION 4.1 Points of inspection (see 6.2)4.2 . Unless otherwise specified, acceptance tests shall be conducted at the site of filling prior to shipment or departure. Conformance i

24、nspectiona. Individual tests (Type I only) 4.2.1 b. Sampling tests 4.2.2 . Quality conformance tests shall consist of the following: 4.2.1 Individual tests (Type I only)a. Filling pressure 4.5.1 b. Leakage 4.5.2 . Each container (cylinder or tube) shall be subjected to the following tests as describ

25、ed under 4.5. 4.2.2 Sampling testTable II. Sampling for test. . The number of oxygen containers shall be selected in accordance with Table II and subjected to the tests required by Table I. Number of containers in lot Number of containers to be sampled 1 1 2 40 2 41 70 3 71 over 4 4.2.3 4.2.3.1 Lot

26、and Container Definitions Lota. All of the oxygen supplied in one or more containers filled from one manifold at the same time. : A lot shall be defined as one of the following b. All of the oxygen filled from a single storage tank that is homogenous at the time of withdrawal and is not added to whi

27、le being withdrawn. After each addition to the storage tank, the contents shall constitute a separate lot. 4.2.3.2 Container4.2.4 : A container is defined as a shipping conveyance consisting of one cylinder or tube, or multiple cylinders or tubes that are interconnected by a single manifold that equ

28、alizes the pressure across all the cylinders or tubes to form one unit. Sample. Each sample shall be of sufficient size to conduct all the quality conformance tests as specified herein. Unless otherwise specified, the quality conformance tests shall be performed on each required sample (see 6.2). Wh

29、en required, an equivalent sample shall be forwarded to a laboratory designated by the procuring activity for testing. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-25508H 6 4.2.4.1 Sampling methodsa. Type I, gaseous oxygen may be sampled i

30、n accordance with ASTM F307, for Type II, liquid oxygen may be sampled in accordance with ASTM F310. It is critical that the outlet of the sampling port and the other equipment used in this process meet oxygen system cleanliness standards. Use an oxygen compatible cleaning solvent in accordance with

31、 local procedures for oxygen cleanliness. . All apparatus used shall be made of suitable materials. Each sample taken for analysis shall be representative of the entire contents of the container being sampled. Unless otherwise specified in the acquisition requirements (see 6.2), sampling may be acco

32、mplished by the following methods. b. By connecting the shipping container being sampled directly to the analytical equipment using suitable pressure regulation as required. It is critical that the outlet of the sampling port and the other equipment used in this process meet oxygen system cleanlines

33、s standards. Use an oxygen compatible cleaning solvent in accordance with local procedures for oxygen cleanliness. 4.2.5 Non-bulk Containers4.2.6 . Non bulk containers are defined as containers with a water capacity of 400 liters, or less. The number of non-bulk containers Type I (gaseous) or Type I

34、I (liquid) oxygen will be in accordance with Table II. Containers to be sampled may be selected at random. Bulk Containers4.2.6.1 . Bulk containers are defined as having a water capacity in excess of 400 liters. Each bulk container filled with Type I (gaseous) and Type II (liquid) oxygen constitutes

35、 a lot and shall be sampled. Continuous service.4.3 (see 6.4.1) Unless otherwise specified by the procuring activity, the following sample option for oxygen shall be used for storage and transport tanks engaged in continuous oxygen service (see 6.2). Contractor shall sample the contents of each tran

36、sport tank engaged in continuous oxygen service at least once every seven days at uniform intervals of time. Samples shall be taken from the filled transport tanks. Contractor shall sample the contents of each transport tank when entering continuous service and when the transport tank has remained e

37、mpty for a period greater than 24 hours. When empty, all ports and vents shall remain closed to the atmosphere. While in continuous service, compliance with quality conformance tests specified herein shall be determined by sampling the filling point storage tank after each addition or, in case of co

38、ntinuous production, at established intervals not less frequent than once every 24 hours. When a storage tank is being filled during a change of duty shift, sampling shall be performed after filling. Rejection4.4 . When any sample tested in accordance with 4.4 fails to conform to the requirements sp

39、ecified herein, the entire lot represented by the sample shall be rejected. Analytical procedures4.4.1 . Unless otherwise specified, samples shall be analyzed according to the procedures described below (see 6.2). Calibration gas standards may be required to calibrate (zero and span) analytical inst

40、ruments used to determine the purity and impurity contents of the oxygen. The accuracy of the calibration gas standards is to be traceable to the National Institute of Standards and Technology (NIST). Purity= lO4210100%. Methods shall be selected from CGA G-4.3 except for grade F. The purity of grad

41、e F shall be determined by difference as follows: where l equals the sum of the water content, total hydrocarbons, nitrous oxide, carbon dioxide, carbon monoxide, and inert gases in ppm by volume. 4.4.2 Impurities. Methods for analyzing impurities shall be selected from those of CGA G-4.3. Provided

42、by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-25508H 7 4.4.3 Particulate content. A filter holder assembly (Pall Life Sciences part No. 2220) or equivalent, modified as shown in Figure 1, shall be attached to the withdrawal line of the vessel to be

43、utilized to fill the tanks. A preweighed filter paper (47 mm glass fiber paper, type A/E or equivalent) shall be placed on top of another filter of the same kind. The filters shall then be placed on the porous filter support, which, in turn, shall be placed in the filter holder as shown in Figure 1.

44、 The male threads of the filter holder shall be wrapped with thin, nonadhesive-backed polytetrafluorethylene tape A-A-58092, or technical equivalent, to prevent galling of the threads. The holder shall be tightened by hand as tight as possible to prevent bypassing of the filter element. The discharg

45、e liquid from the filter housing shall be collected in a clean, uninsulated, ambient temperature vessel marked to indicate when 5 liters of liquid have been collected. The liquid flow shall be terminated when 5 liters of liquid have been collected. The filter holder shall be removed from the line an

46、d permitted to reach ambient temperature. The warmup to ambient temperature may be expedited by use of an oven or other heat source. Care shall be exercised to ensure that any airflow which enters the unit will be directed through the inlet of the assembly to prevent displacing and particles from th

47、e surface of the filter. Upon warmup, the other side of the holder shall be wiped with a clean cloth and the holder then disassembled. The filter paper shall be closely inspected. The test shall be repeated if evidence of either (a) the filter not being securely clamped by uniform depression of its

48、edge; (b) the filter having been cut by the holder; or (c) when dirt particles are detected in the clamped area indicating bypassing had been encountered. The test shall also be repeated when either the bottom filter shows any discoloration or when leakage of liquid from the filter holder is detected. Upon completion of a valid test the filter shall be removed from the housing and weighed to the nearest 0.1 mg. Figure 1. Filter Cryogenic Liquids Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-25508H 8 4.5 Containers of Type I oxy