ARMY MIL-DTL-11195 H-2011 ENAMEL LUSTERLESS FAST DRY VOC COMPLIANT (FOR USE ON AMMUNITION AND OTHER METALS).pdf

1、 MIL-DTL-11195H 10 November 2011 SUPERSEDING MIL-DTL-11195G 31 July 2003 DETAIL SPECIFICATION ENAMEL, LUSTERLESS, FAST DRY, VOC COMPLIANT, (FOR USE ON AMMUNITION AND OTHER METALS) This specification is approved for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope.

2、 This specification covers a fast drying, lusterless, low volatile organic compound (VOC) content alkyd enamel for use on exterior and interior metal surfaces. This enamel is formulated free of lead and chromate (hexavalent chromium), with a maximum VOC content of 420 grams/liter (g/l) (3.5 pounds/g

3、allon (lbs/gal) as applied. The specified type II coating contains corrosion inhibiting pigments, formulated free of hazardous air pollutants (HAP-free). 1.2 Part or identifying number (PIN). Use the following example to create the PINs to be used for coatings acquired to this specification. M11195

4、- X - XXXX - XXXXX Specification Coating type designator Container size designator Color designator Identifier Type II = 2 1 pint = 001P FED-STD-595 1 quart = 001Q color chip number 1 gallon = 001G 1ounce = 01OZ AMSC N/A FSC 8010 NOT MEASUREMENT SENSITIVE Comments, suggestions, or questions on this

5、document should be addressed to: Director, U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Materials Manufacturing Technology Branch, Specifications and Standards Office, ATTN: RDRL-WMM-D, Aberdeen Proving Ground, MD 21005-5069 or emailed to richard.j.squillacioti.civmail.

6、mil. Since contact information can change, you may want to verify the currency of this address information using the ASSIST Online database at https:/assist.daps.dla.mil/. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-11195H 2 2. APPLICABLE

7、 DOCUMENTS 2.1 General. The documents listed in this section are specified in sections 3, 4, or 5 of this specification. This section does not include documents cited in other sections of this specification or recommended for additional information or as examples. While every effort has been made to

8、 ensure the completeness of this list, document users are cautioned that they must meet all specified requirements of documents cited in sections 3, 4, or 5 of this specification, whether or not they are listed. 2.2 Government documents. 2.2.1 Specifications, standards, and handbooks. The following

9、specifications, standards, and handbooks form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. FEDERAL STANDARDS FED-STD-313 - Material Safety Data, Transportation Data, And Disposal Dat

10、a For Hazardous Materials Furnished To Government Activities. FED-STD-595/30117 - Brown, Flat or Lusterless. FED-STD-595/31136 - Red, Flat or Lusterless. FED-STD-595/31158 - Red, Flat or Lusterless. FED-STD-595/33446 - Tan, Flat or Lusterless. FED-STD-595/33538 - Yellow, Flat or Lusterless. FED-STD-

11、595/33655 - Yellow, Flat or Lusterless. FED-STD-595/34079 - Green, Flat or Lusterless. FED-STD-595/34082 - Green, Flat or Lusterless. FED-STD-595/34088 - Olive Drab, Flat or Lusterless. FED-STD-595/34108 - Green, Flat or Lusterless. FED-STD-595/34540 - Green, Flat or Lusterless. FED-STD-595/34558 -

12、Green, Flat or Lusterless. FED-STD-595/35044 - Blue, Flat or Lusterless. FED-STD-595/35109 - Blue, Flat or Lusterless. FED-STD-595/35193 - Blue, Flat or Lusterless. FED-STD-595/36118 - Gray, Flat or Lusterless. FED-STD-595/36231 - Gray, Flat or Lusterless. FED-STD-595/36375 - Gray, Flat or Lusterles

13、s. FED-STD-595/36440 - Gray, Flat or Lusterless. FED-STD-595/37038 - Miscellaneous, Flat or Lusterless (Black). FED-STD-595/37142 - Miscellaneous, Flat or Lusterless. FED-STD-595/37875 - Miscellaneous, Flat or Lusterless (White). FED-STD-595/37925 - Miscellaneous, Flat or Lusterless (White). (Copies

14、 of these documents are available online at https:/assist.daps.dla.mil/quicksearch/ or from the Standardization Document Order Desk, 700 Robbins Avenue, Building 4D, Philadelphia, PA 19111-5094.) Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DT

15、L-11195H 3 2.2.2 Other Government documents, drawings, and publications. The following other Government documents, drawings, and publications form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or

16、contract. UNITED STATES ENVIRONMENTAL PROTECTION AGENCY (EPA) EPA Method 311 - Analysis of Hazardous Air Pollutant Compounds in Paints and Coatings by Direct Injection into a Gas Chromatograph. (Copies of this document are available online at http:/www.epa.gov/ttn/emc/ or from the Environmental Prot

17、ection Agency, Ariel Rios Building, 1200 Pennsylvania Avenue, N.W., Washington, DC 20460.) 2.3 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitati

18、on or contract. ASTM INTERNATIONAL ASTM B117 - Standard Practice for Operating Salt Spray (Fog) Apparatus. (DoD adopted) ASTM D185 - Standard Test Methods for Coarse Particles in Pigments. (DoD adopted) ASTM D476 - Standard Classification for Dry Pigmentary Titanium Dioxide Products. (DoD adopted) A

19、STM D522 - Standard Test Methods for Mandrel Bend Test of Attached Organic Coatings. (DoD adopted) ASTM D523 - Standard Test Method for Specular Gloss. (DoD adopted) ASTM D562 - Standard Test Method for Consistency of Paints Measuring Krebs Unit (KU) Viscosity Using a Stormer Type Viscometer. (DoD a

20、dopted) ASTM D610 - Standard Practice for Evaluating Degree of Rusting on Painted Steel Surfaces. (DoD adopted) ASTM D1210 - Standard Test Method for Fineness of Dispersion of Pigment Vehicle Systems by Hegman Type Gage. (DoD adopted) ASTM D1364 - Standard Test Method for Water in Volatile Solvents

21、(Karl Fischer Reagent Titration Method). (DoD adopted) ASTM D1640 - Standard Test Methods for Drying, Curing, or Film Formation of Organic Coatings at Room Temperature. (DoD adopted) ASTM D1654 - Standard Test Method for Evaluation of Painted or Coated Specimens Subjected to Corrosive Environments.

22、(DoD adopted) ASTM D1729 - Standard Practice for Visual Appraisal of Colors and Color Differences of Diffusely Illuminated Opaque Materials. (DoD adopted) ASTM D2369 - Standard Test Method for Volatile Content of Coatings. (DoD adopted) ASTM D2371 - Standard Test Method for Pigment Content of Solven

23、t Reducible Paints. (DoD adopted) ASTM D2805 - Standard Test Method for Hiding Power of Paints by Reflectometry. (DoD adopted) Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-11195H 4 ASTM D3271 - Standard Practice for Direct Injection of Sol

24、vent Reducible Paints Into a Gas Chromatograph for Solvent Analysis. (DoD adopted) ASTM D3335 - Standard Test Method for Low Concentrations of Lead, Cadmium, and Cobalt in Paint by Atomic Absorption Spectroscopy. (DoD adopted) ASTM D3359 - Standard Test Methods for Measuring Adhesion by Tape Test. A

25、STM D3363 - Standard Test Method for Film Hardness by Pencil Test. (DoD adopted) ASTM D3891 - Standard Practice for Preparation of Glass Panels for Testing Paint, Varnish, Lacquer, and Related Products. ASTM D3924 - Standard Specification for Standard Environment for Conditioning and Testing Paint,

26、Varnish, Lacquer, and Related Materials. (DoD adopted) ASTM D3960 - Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings. (DoD adopted) ASTM D5380 - Standard Test Method for Identification of Crystalline Pigments and Extenders in Paint by X Ray Dif

27、fraction Analysis. ASTM D6677 - Standard Test Method for Evaluating Adhesion by Knife. ASTM E1347 - Standard Test Method for Color and Color Difference Measurement by Tristimulus Colorimetry. (Copies of these documents are available from www.astm.org or ASTM International, 100 Barr Harbor Drive, PO

28、Box C700, West Conshohocken, PA 19428-2959.) 2.4 Order of precedence. Unless otherwise noted herein or in the contract, in the event of a conflict between the text of this document and the references cited herein, the text of this document takes precedence. Nothing in this document, however, superse

29、des applicable laws and regulations unless a specific exemption has been obtained. 3. REQUIREMENTS 3.1 Qualification. The coating furnished under this specification shall be products which are authorized by the qualifying activity for listing on the applicable Qualified Products Database (QPD) at th

30、e time set for opening of bids (see 4.2 and 6.3). Any change in the formulation or processing of a qualified product shall necessitate its requalification. The material supplied under the contract shall be identical, within manufacturing tolerance, to the product that received qualification. 3.2 Mat

31、erials. The materials used in the coating shall be as specified herein. Materials not specified shall be selected by the contractor and shall be subject to all provisions of this specification. 3.2.1 Toxic products and formulations. The material shall have no adverse effect on the health of the pers

32、onnel when used for its intended purpose. Questions pertinent to this effect shall be referred by the contracting activity to the appropriate departmental medical service, which will act as an advisor to the contracting agency. 3.2.2 Hazardous material. The contractor shall comply with the hazardous

33、 material requirements of FED-STD-313 (see 6.4). Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-11195H 5 3.3 Color. When tested as specified in 4.6.4, the color of the enamel shall match that of the standard color chip in FED-STD-595. For co

34、lor 37038, the color of the enamel may be darker or jetter than that of the actual standard color chip, and for color 37925, the enamel shall have a minimum directional reflectance of 83 (see 4.6.26). 3.4 Composition. The material shall meet the requirements of table I. TABLE I. Composition - percen

35、t by weight. Nonvolatile matter - minimum Total pigment - % of nonvolatile - maximum Extender pigment - % total pigment - maximum All Other White Black Colors 75 72 73 73 70 70 65 90 85 Percent of total pigment: Zinc phosphate, % total pigment - minimum 9.0 9.0 9.0 3.4.1 Pigment. The pigments listed

36、 in table II, in any combination, shall be used to match the colors specified. The titanium dioxide shall be a rutile chalk resistant type conforming to ASTM D476, type III or type IV. Lead or chromate (hexavalent) pigments shall not be used. Compounds of antimony, arsenic, beryllium, cadmium, cobal

37、t, chromium, cyanide, lead, manganese, mercury, nickel and selenium shall be absent. Extender pigments shall be siliceous matter and barium sulfate, in any ratio, and shall not exceed the amount specified in table I. The use of the specified pigments does not guarantee that a product will meet all t

38、he requirements of this specification, as the choice of vendors, amounts, methods of dispersion and incorporation can significantly affect the quality of the end product. If other tinting pigments are used to match the spectral characteristics, these additional pigments shall be recommended for exte

39、rior exposure by the pigment supplier. Other corrosion inhibiting pigments, in addition to the specified zinc phosphate in table I can be used. 3.4.2 Lead and chromate (hexavalent) content. When tested as specified, the lead content shall not exceed 0.06 percent by weight of the total nonvolatile co

40、ntent (see 4.6.8) and the test for hexavalent chromium shall be negative (see 4.6.7). 3.4.3 Vehicle. The vehicle shall be a drying oil alkyd, modified or unmodified. 3.4.4 Solvent analysis. When tested as specified in 4.6.9, solvents used shall be in accordance with the guidelines established by loc

41、al, state and federal regulations and shall be volatile organic hazardous air pollutants-free (VOHAP-free). 3.5 Quantitative characteristics. When tested as specified in 4.6.2, the enamel shall conform to the quantitative requirements of table III. Provided by IHSNot for ResaleNo reproduction or net

42、working permitted without license from IHS-,-,-MIL-DTL-11195H 6 TABLE II. Pigmentation. Pigment Color Index Name Color Index Number Titanium Dioxide White Carbon Black Iron Oxide Black Iron Blue Phthalocyanine Blue Phthalocyanine Green Phthalocyanine Green Arylide Yellow Arylide Yellow Diarylide Yel

43、low Benzimidazolone Yellow Iron Oxide Yellow DNA Orange Pyrazolone Orange Benzimidazolone Orange Naphthol Red Quinacridone Red Quinacridone Red Quinacridone Violet Iron Oxide Red Iron Oxide Brown Iron Oxide Brown Aluminum PW6 PBk7 PBkll PB27 PB15 PG7 PG36 PY74 PY65 PY83 PY151 PY42 P05 P034 P036 PR17

44、0 PR202 PR122 PV19 PR101 PBr6 PBr 11 PM 1 77891 77266 77499 77510 74160 74260 74265 11741 11740 21108 13980 77492 12075 21115 11780 12475 73905 73915 46500 77491 77491, 77492, 77499 77495 77000 Note: Phthalocyanine pigments do not contain cyanide compounds. 3.6 Qualitative requirements. 3.6.1 Condit

45、ion in container. When tested as specified in 4.6.14, a freshly opened full container of the enamel shall be free from grit, coarse particles, skins, lumps, seeds, livering or abnormal thickening. The enamel shall show no pigment settling or caking that cannot be readily reincorporated to a smooth h

46、omogeneous state. 3.6.2 Storage stability. 3.6.2.1 Full container. When tested as specified in 4.6.15.1, a full quart of the enamel shall be free from coarse particles, grit, skins, lumps, seeds, livering, hard caking and tough, gummy sediment. The enamel shall remix readily to a smooth homogeneous

47、state, shall show a maximum viscosity increase of 15 KU and shall meet all the requirements of this specification. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-11195H 7 TABLE III. Quantitative requirements of enamel. Characteristics Requir

48、ements Minimum Maximum VOC, grams volatile / liter of enamel reduced for spray (see 4.6.18) - 420 Pigment: Hexavalent chromium, cadmium, cadmium compounds Absent Inorganic HAP compounds Absent VOHAP compounds Absent Water, % by weight of enamel - 0.5 Coarse particles and skins, % by weight of pigment - 0.5 Specular gloss, 60 degree 2 8 Viscosity, reduced as specified in 4.6.11, KU - 70 Fineness of grind 5 - Drying time, air dry: Set to touch, minutes Dry hard, minutes - - 6 12 Contrast ratio: 37925 White 33538 Yellow 33655 Yel