ARMY MIL-F-2312 F-1989 FELT HAIR OR WOOL MILDEW RESISTANT AND MOISTURE RESISTANT TREATMENT FOR《丝毛毡的防霉和防湿处理》.pdf

1、MIL-F-2332F 3 797770b 0372738 L IINC“i MIL-F-2312F 24 April1989 SVPERSEDING MIL-F-2312E 28 September 1984 MILITARY SPECIFICATION FELT, HAIR OR WOOL: MILDEW RESISTANT AND MOISTURE RESISTANT TREATMENT FOR This specification is approved for use by all Departments and Agencies of the Department of Defen

2、se. 1. SCOPE 1.1 Scope. This specification governs the mildew resistant and moisture resistant treatment of hair or wool felt. 1.2 Classification. The finished felt treatment shall be of the following types as specified (see 6.2): Type I - Mildew resistant Type II - Moisture resistant Type III - Mil

3、dew resistant and moisture resistant 2, APPLICABLE DOCUMENTS 2.1 Government documents. 2.1.1 Specifications, standards, and handbooks. The following specifi- cations, standards, and handbcoks form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these

4、 documents are those listed in the issue of the Department of Defense Index of Specifications and Standards (DODISS) and supplement thereto, cited in the solicitation (see 6.2). Beneficial comments (recommendations, additions, deletions) and any pertinent data which may be of use in improving this d

5、ocument should be addressed to: U.S. Army Natick Research, Development, and Engineering Center, Natick, MA 01760-5014 by using the self-addressed Standardization Document Improvement Proposal (DD Form 1426) appearing at the end of this document or by letter. msc N/A FSC 8305 DISTRIBUTION STATEMENT A

6、. Approved for public release; distribution is unlimited. O Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-F-2312F STANDARDS FEDERAL FED-STD-191 - Textile Test Methods MILITARY MIL-STD-105 - Sampling Procedures and tables for Inspection by Attri

7、butes. . (Unless otherwise indicated, copies of federal and military specifications, standards, and handbooks are available from the Naval Publications and Forms Center, (ATTN: NPODS), 5801 Tabor Avenue, Philadelphia, PA 19120-5099.) 2.2 Non-Government publications. The following document forms a pa

8、rt of this document to the extent specified herein. Unless otherwise specified, the issues of the documents which are DoD adopted are those listed in the issue of the DODISS cited in the solicitation. Unless otherwise specified, the issues of documents not listed in the DODISS are the issues of the

9、documents- cited in the solicitation (see 6.2). AMERICAN ASSOCIATION OF TEXTILE CHEMISTS AND COLORISTS (AATCC) Chromatic Transference Scale (Application for copies should be addressed to the American Association of Textile Chemists and Colorists, P.O. Box 12215, Research Triangle Park, NC 27709-2215

10、. ) (Non-Government standards and other publications are normally available from the organizations that prepare or which distribute the documents. These documents also may be available in or through libraries or other informational services. 1 2.3 Order of precedence. In the event of a conflict betw

11、een the text of this document and the references cited herein, the text of this document takes precedence. Nothing in this document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3, REQUIREMENTS f c 3.1 Material. The felt to be treated in accordan

12、ce with this document shall conform to the requirements of the felt specification cited in the applicable acquisition document (see 6. i). 3.1.1 Physical requirements. Tests for physical properties of the finished felt specified herein shall be conducted as specified in 4.2.3. 2 Provided by IHSNot f

13、or ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-F-23 12F 3.1.1.1 Finished weight and thickness. The following plus tolerance in weight and thickness will be allowed for the treated felt, based on the maximum specified for the untreated felt, when tested as specified

14、 in 4.2.3. Type I - 15 percent maximum Type II - 15 percent maximum Type III - 20 percent maximum 3.i.2 Color. When undyed felt is specified, the color of the treated felt may deviate from the natural state to that degree imposed by the color of the treating agent used. the finish shall, unless othe

15、rwise specified, match the standard sample. When dyed felt is specified, the color of the treated felt shall be that resulting from the combination of the base color and the color imparted by the specified finish. The color of the dyed felt prior to the application of 3.1.3 Soluble matter, nonfibrou

16、s material, and ash content. The felt, prior to the treatment, shall conform to the applicable requirements of the untreated felt specification for the amount of soluble matter, nonfibrous materials or ash content (see 4.2.3). 3.2 Treatments. 3,2.1 Type I - mildew resistant. The felt shall be treate

17、d with either 2,2 methylene-bis-(4-chlorophenol), salicylanilide or coppes-8-quinolinolate which has been solubilized for solvent application. dispersed and so formulated as to effect uniform penetration into the felt when applied. The materials shall be 3.2.1.1 Application. The application of the m

18、ildew inhibiting agent shall be such that the felt shall be well penetrated; uniform deposit in the material and there shall be no noticeable crystallization of the inhibitor on the feit surface. The process shall provide a 3.2.1.2 Concentration of inhibitors. 3.2.1.2.1 2,2 methylene-bis - (4-chloro

19、phenol). The finished felt shall contain no less than 1.0 percent and no more than 3.0 percent of 2,2 methylene-bis - (4-cholorophenol) when tested as specified in 4.2.3. 3.2.1.2.2 Salicylanilide. The finished felt shall contain no less than 0.5 percent and no more than 1.5 percent of salicylanilide

20、 when tested as specified in 4.2.3. 3.2.1.2.3 Copper-8-quinolinolate. The finished felt shall contain not less than 1.0 percent and not more than 1.5 percent of copper-8-quinolinolate when tested as specified in 4.2.3. 3 Provided by IHSNot for ResaleNo reproduction or networking permitted without li

21、cense from IHS-,-,-MIL-F-2312F 3.2.2 Type II - Moisture resistant. Unless otherwise specified (see 6.2), the felt shall be treated with a wax or metallic-salt-wax compound or emuls ion. 3.2.2.1 Application. The application of the moisture resistant agents shall be such to provide a uniform deposit i

22、n the material and the treated felt shall show no more than 50 percent increase in weight, based on the conditioned weight of the sample, when tested by the immersion test specified in 4.2.3. 3.2.3 Type III - Mildew and moisture resistant. The treatment shall be a combination of type I and type II t

23、reatments and shall conform to the requirements specified for type I and type II when tested as specified in 4.2.3. 3.3 Length and put up, The length and put up shall be as specified in the applicable felt specification. 3.4 Mrking for identification. Each roll or sheet shall be identified in accord

24、ance with the applicable felt specification. 3.5 Fiber label. Fiber identification label or wool content label shall be in accordance with the applicable felt specification. 3.6 WorkmanshiE. The treated felt shall conform to the quality of product established by this specification and the occurrence

25、 of defects shall not exceed the applicable acceptable quality levels. 4. QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless otherwise specified in the contract or mrchase order, the contractor is responsible for the performance of all inspectin requirements (examinations and tes

26、ts) as specified herein. Except as otherwise specified in the contract or purchase order, the contractor may use his own or any other facilities suitable or the performance of the inspection requirements specified herein, unless disapproved by the Government. The Government reserves the right to per

27、form any of the inspections set forth in this specification where such inspections are deemed necessary to ensure supplies and services conform to prescribed requirements. 4.1.1 Responsibility for compliance. All items shall meet all requirements of sections 3 and 5. The inspection set forth in this

28、 specification shall become a part of the contractors overall inspection system or quality program. The absence of any inspection requirements in the specification shall not relieve the contractor of the responsibility of ensuring that all products or supplies submitted to the Government for accepta

29、nce comply with all requirements of the contract. Sampling inspection, as part of manufacturing operations, is an acceptable practice to ascertain conformance to the requirements, however, this does not authorize submission of known defective material, either indicated or actual, nor does it commit

30、the Government to accept defective material. 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,- MIL-F-2312F 3 m 9999906 0372922 3 m a MIL-F-2312F 4.1.2 Certificate of compliance. When certificates of compliance are submitted, the Government reserves

31、the right to inspect such items to determine the validity of the certification. 4.2 Quality conformance inspection. Unless otherwise specified, sampling for inspection shall be performed in accordance with MIL-STD-105. 4.2.1 Component and material inspection. In accordance with 4.1, components and m

32、aterials shall be inspected in accordance with all the requirements of referenced documents unless otherwise excluded, amended, modified, or qualified in this specification or applicable purchase document. 4.2.2 End item visual examination. End item visual examination of the treated felt shall be as

33、 specified for the untreated felt in the applicable felt specification (see 6,2) except that: a. For end item examination for visual or local defects-, the following additional defect shall also apply: Clearly visible crystallization of treatment on surface of felt - Major defect. b. For end item ex

34、amination for overall defects, the following additional defect shall also apply: Non-uniform application of treatment clearly visible. 4.2.3 End item testing. End item testing of the treated felt shall be as specified for the untreated felt in the applicable felt specification (see 6.2) except that:

35、 a. The applicable sample unit shall be increased by 1/2 yard for felt more than 40 inches wide and increased by 1 yard for felt 40 inches and less wide. b. A certificate of compliance will be acceptable as evidence of conformance to the soluble matter,nonfibrous material, and ash content requiremen

36、ts. c. The following additional tests shall also apply: Requirement Test Characteristic pa rag raph method Weight Mildew inhibitor content, percent: 2,2 methylene-bis-(4-chlorophenol) Salicylanilide Copper-8-quinolinolate Moisture resistance 3.1.1.1 3.2.1.2.1 3.2.1.2.2 3.2.1.2.3 3.2.2.1 5041 I/ 2011

37、 - i/ 4.3.2 2060 L/ 4.3.1 - 2/ 5 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-F-2312F - i/ Applicable to FED-STD-191. - 21 Type II and type III treated felt shall be allowed to reach equilibrium under standard conditions as defined in. FED-STD

38、-191 prior to testing. 4.2.4 Packaging examination. Packaging examination of the treated felt shall be as specified for the untreated felt in the applicable felt specification (see 6.1). 4.3 Methods of inspection. 4.3.1 Immersion test. The immersion test shall be conducted in accordance with Method

39、5502 of FED-STD-191. Three 3 by 3-inch test specimens and an immersion time of 20 minutes shall be utilized in the test. The wringer procedure for the removal of the excess water shall not be used. In lieu thereof the following procedure shall be used: After immersion for 20 minutes, the specimen sh

40、all be withdrawn and placed between two sheets of AATCC standard blotting paper. Without exerting extraneous downward pressure, roll once over and back with a 1-kilogram round steel bar approximately 1-3/4 inches in diameter by 3 inches long or equivalent. Remove the specimon quickly from the blotti

41、ng paper and weigh and report as specified. The moisture resistance shall be the average of three determinations to nearest 1.0 percent. 4.3.2 Salicylanilide content test. The salicylanilide content test shall be performed as follows using the procedure and calculations in either 4.3.2.7 or 4.3.2.8.

42、 4.3.2.1 Apparatus. Spectrophotometer Erlenmeyer flasks Volumetric flasks Nessler tubes Glass funnel Glass woo 1 Graduates Pipettes Beakers 6 i Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,- 9 MIL-F-2312F 83 9999906 0372924 7 I! MIL-F-2312F 4.3.2.2

43、 Reagents. All chemicals- shall be reagent grade and all water shall- .“- be distilled water, -. e Salicylanilide Methano 1 Ammonium hydroxide Disodium phosphate (Na2HP04.12 H20) Monosodium phosphate (NaH2P04*H20) Sodium nitrite p-nitro-aniline-sulfonic acid (Na salt) or Z-amino-.5-nitrobenzene HCL

44、(2N) sulfonic acid 4.3.2.3 Salicylanilide stock solution (O. 1 mg/inL, see 4.,3.2.7 and 4.3.2.8). Dissolve 1 g of salicylanilide in 20 mL of methanol. Add 4 mL fresh concentrated ammonium hydroxide. Dilute solution to 100 mL (ia a 100 mL volumetric flask) with warm water. dilute to 1 L in volumetric

45、 flask to obtain a stock solution which has a concentration of 0.1 mg/mL of salicylanilide. Take a 10 mL aliquot out of the above and 4.3.2.4 Neutral buffer solution. Dissolve 161.5 g disodium phosphate .12H2O and 41.5 g of monosodium phosphate .H20 in water and dilute to 1 L in a volumetric flask.

46、The solution shall yield a PH of 6.5 to 7.5. 4.3.2.5 Color indicator. Dissolve 0.10 g of p-nitro-aniline-sulfonic acid (Na salt) or 2-amino-5-nitrobenzene sulfonic acid in 50 mL water in a 250 mL beaker. temperature. Allow 5 minutes for color development, then dilute to 100 mL in a volumteric flask,

47、 Add 2.50 mL 2N HC1 and 0.30 mL of 2N sodium nitrite (138 g/L) at room 4.3.2.6 Extraction of salicylanilide. Condition untreated and treated felt at standard conditions. Cut a 1.1Og sample of untreated felt for use as a blank. Cut two 1.1Og samples from the same general area of the treated felt and

48、identify as “A“ and “B“. Weigh the three conditioned samples to the nearest 0.01g and record as the conditioned weights. determine the salicylanilide content. 105 to llOC, weigh and record as the dry weight of sample B (use this value to calculate the dry weight of sample A, see 4.3.2.7). Since sali

49、cylanilide may be decomposed and driven off at high temperature, llOC should not be exceeded. place in separate 250 mL Erlenmeyer flasks. Add 50 mL methanol and 25 mL neutral buffer solution to each flask. frequently. Decant, leaving felt samples in flask, pour through glass wool lined funnel into 500 mL graduates. Repeat three times: the addition of methanol without buffer; the 15 minute standing (shaking frequently); and decanting through gla