ARMY MIL-P-46183-1984 PLASTIC MOLDING AND EXTRUSION MATERIAL POLYETHERETHERKETONE (PEEK)《聚醚醚酮(PEEK)注塑加工和挤压成型材料》.pdf

1、MIL-P-4bL83 73 m 777770b 012OYBY b iG57”cI I. SCOPE I,% CIassificatZorr, The PEEK thermoplastic materials shall be af the followfng types and dasses (see 6.2): Type I - Nonrefnforced plaseic 2.1 Government doCumenes, 2-1.1 Specificaions and standards. Unless orherwise specffied, the following specif

2、lcatfons and standards of ehe issue Iisted in that fssue e the Department of Defense Index of Specifications and Stardards (DoDISS) specified fn the soIicitation, form a part of this specification to the extent specif Zed hereh Beneficial comments (recommendations, addieions, delettons) and any pert

3、fnent data whfch may be of use in improving tkEs document should be addressed to: Director, US hrmy MaCerials and Mechanics Research Center, ATTN: DRXMRSMS, Watertown, MA 02x72 by using the self-addressed Standardization Doeument Improvement Propasal (DD Form 1426) appearing at the end of thfs docum

4、ent or 1 THIS DOCUMENT CONTAINS F - - - 3 - - - PAGES Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-SPECIFICATIONS FEDERAL PPP-D-723. - Drums, Fiber PPP-D-729 - Drums, Shipping and Storage, Steel, 55-Gallon, (208 Liters) STANDARDS MILITARY MIL-STD-

5、129 - Marking for Shipment and Storage (Copies of specifications and standards required by manufacturers in connection with specific acquisition functions should be obtained from the contracting activity or as directed by the contracting officer.) 2.2 Other publications. The following document(s) fo

6、rm a part of this specification to the extent specified herein. The issues of the documents which are indicated as DoD adopted shall be the issue listed in the current DoDISS and the supplement thereto, if applicable. AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM) ASTM D 149 - Dielectric Breakdow

7、n Voltage and Dielectric Strength of Solid AS111 D 256 - Impact Resistance of Plastics and Electrical Insulating ASTM D 257 - D-C Resistance or Conductance of Insulating Materials ASTHD 570 - Water Absorption of Plastics ASTMD 638 - Tensile Properties of Plastics ASTM D 648 - Deflection Temperature

8、of Plastics Under Flexural Load ASTM D 790 - Flexural Properties of Unreinforced and Reinforced Plastics ASTM D 792 - Specific Gravity and Density of Plastics by Displacement ASTM D 2863 - Measuring the Minimum Oxygen Concentration to Support Candle Like Combustion of Plastics (Oxygen Index) ASTM D

9、3171 - Fiber Content of Resin-Matrix Composites by Matrix Digestion ASDl D 3418 - Transition Temperatures of Polymers by Thermal Analysis ASTM U 3951 - Practice for Commercial Packaging AST61 E 380 - Metric Practice ASTM P 814 - Test Method for Specific Optical Density of Smoke Generated by Solid Ma

10、terials for Aerospace Applications Electrical Insulating Materials at Commercial Power Frequencies Materials (Applications for copies of ASTM publications should be addressed to the herican Society for Testing and Materials, 1916 Race Street, Philadelphia, PA 19103.) 2 Provided by IHSNot for ResaleN

11、o reproduction or networking permitted without license from IHS-,-,-MIL-P-46183 (Industry association specifications and standards are generally available for reference from libraries. They are also distributed among technical groups and using Federal agencies.) 2.3 Order of precedence. In the event

12、 of a conflict between the text of this specification and the references cited herein, the text of this specification shall take precedence. 3. REQUIREMENTS 3.1 Material. The material shall consist of PEEK thermoplastic granules, pellets or powder, with or without fiber reinforcement. 3.2 Physical a

13、nd mechanical properties. The properties of the PEEK thermoplastic shall be as specified herein when tested in accordance with 4.3. Mechanical properties are to be measured on specimens that have been injection molded to net shape. 3.2.1 Nonreinforced PEEK (type I). The properties of the unpigmented

14、, non- reinforced PEEK thermoplastic shall be as specified in table I. TABLE I. Properties of nonreinforced PEEK (type I) l/. Property Property Values Melting point (minimum) 334OC (633OF) Glass transition temperature (T ), min 143OC (289OF) Specific gravity 1.30 5 0.04 g Tensile strength 21 (minimu

15、m) (at 23%) (at 200OC) 90 MPa (13,000 psi) 20 MPa (2,900 psi) Elongation at break (minimum) 10% Flexural modulus (minimum) 3400 MPa (500,000 psi) Heat deflection temperature (minimum) (at 1820 kPa) 149OC (300OF) Water absorption (maximum) (24-h immersion) o. 2% - 1/ Property values are expressed in

16、SI units in accordance with ASTM E 380. 21 MPa x 145 = psi 3 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-P-46183 3.2.2 Glass fiber reinforced PEEK (type 11). The properties of glass fiber reinforced PEEK thermoplastic shall be as specified in

17、 table II. TABLE II. Properties of glass fiber reinforced PEEK (type 11). Property Values Property Class 1 Class 2 Class 3 (10% glass fiber) (20% glass fiber) (30% glass fiber) Glass fiber content 10 2 2% (by wt) 20 + - 2% (by wt) 30 f 2% (by wt) Specific gravity 1.37 - + 0.04 1.44 - -I- 0.04 1.49 +

18、 0.04 Tensile strength - 11 110 MPa 120 MPa 152 MPa - (minimum) (16,000 psi) (17,400 psi) (22,000 psi) Elongation at break 5% (minimum) 4% 3% Flexural modulus 5000 MPa 6200 MPa 6900 MPa (minimum) (730,000 psi) (900,000 psi) (1,000,000 psi) Impact strength 21 50 J/m 60 J/m 80 J/m 1/ MPa x 145 = psi (

19、minimum) (O. 9 f t-lbf /in) ( l. 1 f t-lbf /in) (1.5 f t.-lbf /in) L 21 Notched, 0.25 in; J/m x 18.73 x 10-3 = ft-lbf/in 3.2.3 Carbon fiber reinforced PEEK (type III). The properties of carbon fiber reinforced PEEK thermoplastic shall be as specified in table III. TABLE III, Properties of carbon fib

20、er reinforced PEEK (type III), Property Values (20% carbon fiber) (30% carbon fiber) Property Class 1 Class 2 Carbon fiber content 20 i- 2% (by wt) 30 + 2% (by wt) Specific gravity 1.38 - + 0.04 1.42 2 0.04 A Tensile strength (minimum) Elongation at break (minimum) Flexural modulus (minimum) 159 MPa

21、 185 MPa (23,000 psi) (27,000 psi) 5% 2% 10,300 MPa 12,800 MPa (1,500,000 psi) (1,850,000 psi) Impact strength (minllmum) (notched, O. 25 in) 45 J/m 50 J/m (unnotched, O. 25 in) 400 J/m 530 J/m (O. 8 f t-lbf /in) (O. 9 ft-lbf /in) (8. O f t-lbf /in) (10. O f t-lbf /in) 4 Provided by IHSNot for Resal

22、eNo reproduction or networking permitted without license from IHS-,-,-MIL-P-qh383 73 W 7779706 0320488 3 W MIL-P-46283 3.3 Form. The form of the PEEK thermoplastic shall be granules, pellets 01: powder. When specified by the procuring activity, the form shall be in the size and shape specified (see

23、6.2). 3.4 Flammability and burning. 3.4.1 Oxygen index. The oxygen index for all types of PEEK thermoplastic shall be 35% minimum (see 4.3). The thicknessof the test specimen shall be 3.2 mm. 3.4.2 Specific optical density. The maximum-specific optical density, Dmax, -in the flaming mode for all typ

24、es of PEEK thermoplastic shall be 25 (see 4.3 and 6.3). The Dm= Zn the nonflaming mo.de shall be 5. Samples for smoke emission tests in accordance with ASTM F 814 (see table V) shall be slabs 0.125 in thick x 3 in x 3 in (3.1 mm thick x 76.2 mm X 76.2 mm). 3.5 Ele-ctrical properties. The electrical

25、properties of the PEEK thermo- plastic shall be as specified in table LV (see 4.3).- TABLE IV. Electrical properties of PEEK. Property Minimum Property-Values Type 1 Type II Type III - (nonreinforced) (30% glass fiber) (3-0% carbon fiber) Volume resistivity 1/ 1015 ohm-cm 1015 ohm-cm 1200 ohm-cm Die

26、lectric strength-2/ - 400 volts/mil 450 volts/mil “ (15.8 MV/m) (17.7 MV/m) - 1/ Volume reszstivity in ohm-m has a value of 1/100 of the value in ohm-cm. - 2/ The thickness of the test specimen shall be 0.125 in (3.1 mm). 4. QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless othe

27、rwise specified in the con- tract or purchase order, the contractor is responsible for the performance of all inspection requirements as specified herein. Except as otherwise specified in the contract or purchase order, the contractor may use his own or any other 5 Provided by IHSNot for ResaleNo re

28、production or networking permitted without license from IHS-,-,-MIL-P-46183 faciJities suitable for the performance of the inspection requirements speci- fied herein, unless disapproved by the Government. The Government reserves the right to perform any of the inspections set forth in the specificat

29、ion where such inspections are deemed necessary to assure supplies and services conform to prescribed requirements. 4.2 Classification of tests. The examination and testing of the plastic molding and extrusion material shall be classified as follows: a. Preproduction tests b. Quality conformance tes

30、ts 4.2.1 Preproduction tests. Unless otherwise specified (see 6.2), prepro- duction tests shall consist of tests for the following properties: a. b. d e. f. g* h. C. Flexural modulus Heat deflection temperature Water absorption Impact strength Oxygen index Specific optical density Volume resistivity

31、 Dielectric strength The supplier shall furnish to the procuring activity (in lieu of continuous lot-to-lot testing) a certificate of compliance, which certifies that the requirements for the properties listed in (a) through (h) above have been met (see 3.2 through 3.5). 4.2.2. Quality conformance t

32、ests, Unless otherwise specified (see 6.2), quality conformance tests shall consist of tests for the following properties: a. Melting point b. Specific gravity c. Tensile strength d. Elongation at break e. Fiber content 4.2.2.1 Lot size. Lot size shall consist of all the molding or extrusion materia

33、l manufactured at one time, from one batch, forming part of one contract or order, and submitted for acceptance at the same time and place, 4.2.2.2 Sampling. Unless otherwise specified (see 6.2), a sufficient quantity of material from one unit representative of each lot (4.2.2.1) shall be selected a

34、t random for quality conformance testing. Each container of material shall be considered as a unit of product. Failure of sample to meet the quality conformance requirements shall be cause or lot rejection. 4.3 Test methods. The properties of the PEEK thermoplastic materials specified in 3.2 through

35、 3.5 shall be determined in accordance with the applicable test method in table V. 6 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-a f ia L 1 i- MIL-P-46183 TABLE V. Test methods. Property Test Method Melting point Glass transition temperature Spec

36、ific gravity Tensile strength Elongation at break Flexural modulus Heat deflection temperature Water absorption Fiber content (types II and III only) Izod impact strength Oxygen index Specific optical density Volume resistivity Dielectric streng th ASTM D 3418 ASTM D 3418 ASTM D 792 ASTM D 638 ASTM

37、D 638 ASTM D 790 ASTM D 648 ASTM D 570 ASTM D 3171 ASTM D 256 ASTM D 2863 ASTM F 814 ASTM D 257 ASTM D 149 5. PACKAGING 5.1 Preservation. Preservation shall be level A or Industrial as specified (see 6.2). 5.1.1 Level A. Unless otherwise specified, the material shall be packed in one of the followin

38、g types of containers: a. -Fiber drums conforming to PPP-D-723, type II, grade A, or type ILI, b. Metal drums conforming to PPP-D-729, type III or type IV, in quantities grade A in quantities of 90 kg (200 lbs) maximum. of 181 kg (400 lbs), maximum. Insofar as practical, drums shall be of uniform sh

39、ape and size, with minimum cube and tare consistent with the protection required. Drums shall contain identical quantities and shall be closed in accordance with the applicable container specification. Piber drums shall be furnished with a 4 mil thick polyethylene liner properly heat sealed. 5.1.2 I

40、ndustrial. The material shall be packed in accordance with ASTM D 3951. 5.2. Marking. In addition to any special marking required by the contract or purchase order, shipping containers shall be marked in accordance with MIL-STD-129, with the exception that industrial marking in accordance with ASTM

41、D 3951 applies for industrial packaging only. 7 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-P-46183 6. NOTES 6.1 Intended use, Polyetheretherketone (PEEK) thermoplastic materials are intended for use as a matrix for glass fiber and carbon-gra

42、phite composites, for injection molded parts and monofilament, and as insulation for electrical wire and cable. The material has very low flammability, low smoke and toxic gas emission, and resistance to gamma radiation. 6.2 Ordering data. 6.2.1 Acquisition requirements. Acquisition documents should

43、 specify the following: a. Title, number and date of this specification. b. Type and class of material. C. Specific pellet size, if required (see 3.3). d, Whether a preproduction sample is required and, if so, pertinent e, Quality conformance tests, if other than specified in 4.2.2, f, Sampling plan

44、, if other than specified in 4.2.2.2. g. Level of packing required (see 5.1). details (see 4.2.1). 6.3 Specific optical density. The maximum specific optical density, Dmax, represents total smoke accummulation. 6.4 Gamma radiation resistance. Polyetheretherketone is extremely resistant to embrittlem

45、ent by gamma radiation, Wire samples, coated with various grades (molecular weights) of PEEK polymer to a total diameter of 1.5 mm, have been exposed to gamma radiation from 6oCo spent fuel cells. Samples were removed at 250 Mrad intervals until a maximum dose of 2000 Mrad had been absorbed. The sam

46、ples were subjected to a wrap test around a 1D mandrel followed by a standard dielectric test (1.5 kv for 1 minute in water). In the range sug- gested for high performance wire covering (melt viscosity = 0.4 to 0.5 kNsm2), the dosage level of gamma radiation required to cause failure of the insulati

47、on is of the order of 1100 Mrad (11 MGy). Note: 1 rad = 0.01 gray. 6.5 Sources of supply. PEEK materials may be obtained from: a. ICI Americas Concord Pike and New Murphy Road Wilmington, DE 19897 b. LNP Corporation 412 King Street Malvern, PA 19355 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-Review Act ivi t ie s : Army - GL, MD, ME, AT, AV Air Force - 15 User Activities: Army - MI Navy - SH (WP# ID-2201A/DISC-0010A, FOR MIRC USE ONLY) Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-