ARMY MIL-P-47067-1974 2 4 - PENTANEDIONE《2 4-戊二酮》.pdf

1、- MIL-P-47067 68 W 7777706 0320874 3 /-/-a4kr MIL-P-47067 (MI) 10 14ay 1974 MIS 16415A 17 June 1969 SUPERSEDING MILITARY SPECIFICATION 2, 4 - PENTANED IONE This specification is approved for use by all departments and agencies of the Department of Defense, 1. SCOPE 1.1 SCO e. This specification cove

2、rs one grade of 2, 4-pentane ap lone. 2. APPLICABLE DOCUMENTS 2.1 Government documents. The following documents of the issue in effect on date of invitation for bids or request for proposal, form a part of the specification to the extent specified herein. Mi 1 it arv MIL - STD - 12 9 Marking for Shi

3、pment and Storage MIL - STD - 414 Sampling Procedures and Tables for Inspection By Variables for Percent Defective FSC 6810 /.- THIS DOCUMENT CONTAINS 8- PAGES. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-P-47067 (MI) (Copies of specification

4、s, standards, drawings, and publi- cations required by suppliers in connection with specific procurement functions should be obtained from the procuring activity or as directed by the contracting officer.) 2.2 Other publications. The following documents form a part of this specification to the exten

5、t specified herein. Unless otherwise specified, the issue in effect on the date of invitation for bids or requests for proposal shall apply, Uniform Classification Committee Uniform Freight Classification Rules (Application for copies should be addressed to Uniform Classi- fication Committee, 202 Ch

6、icago Union Station, Chicago, Illinois 60606.) American Trucking Association Publication National Motor Freight Classification Rules and Container Regulations (Application for copies should be addressed to the National Classification Board, 1424 Sixteenth Street, N.W., Washington, D.C. 20013.) 3. RE

7、QUIREMENTS 3.1 Properties. The material shall conform to the following properties: Max - Min - a. Assay, 2, 4-pentanedione, weight 95.0 -_ percent Celsius (C) b. Specific gravity, 20/20 degrees 0.972 0.978 3.2 Workmanshi . The material shall be free from all impurities -hll-c; an ot er efects that c

8、ould adversely affect its performance. The material shall be uniform in quality and shall be manufactured in accordance with standard manufacturing procedures of the industry. 4. QUALITY ASSURANCE PROVISIONS 2 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from

9、IHS-,-,-MIL-P-47067 68 W 9999906 0220896 7 W Characteristic Acceptable Quality Levels (%I (LSL) (U SL 1 a. Assay 1.0 - b. Specific gravity 1.5 1.5 MIL-P-47067 (MI) Tes t. Method 4.4.1 4.4.2 4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchase order, the supplier

10、is responsible for the performance of all inspection require- ments as specified herein. Except as otherwise Specified in the contract or order, the supplier may use his own or any other facilities suitable for the performance of the inspection requirements specified herein, unless disapproved by th

11、e Government. The Government reserves the right to perform any of the inspections set forth in the specification where such inspections are deemed necessary to assure supplies and services conform to prescribed requirements. 4.2 Lot size. A lot shall be as defined in MIL-STD-414 with the following a

12、dditional requirements: if manufacture is by batch process, each batch, blend of batches, or fraction thereof, shall constitute a lot. 4.3 Sam ling. Sampling shall be in accordance with MIL-STD-414-tion Level III, Sections A and C, at the acceptable quality levels shown in Table I for the lower spec

13、ification limits (LSL) and upper specification limits (USL). 4.4 Quality conformance tests and methods. Quality conformance tests and test methods shall be as specified in Table I. 4.4.1 Assa . The assay of the material shall be determined as + ollows: a. Dissolve 25 grams (g) of cupric acetate mono

14、-hydrate and 100 g of reagent-grade sodium acetate trihydrate in sufficient water to make one liter of solution. Filter before using. 3 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-P-q7067 68 7777706 0120877 7 W MI L - P - 4 7 O 6 7 (Pl I ) b.

15、 Pipet 100 milliliters (ml) of the acetate solution into a SOO-ml iodine flask containing 75 ml distilled water. Reserve this solution as a blank for the procedure described in (tl. c. Pipet 100 ml of the acetate solution into a 250 ml glass-stoppered flask. d. Add 1.2000 to 1.5000 g of the sample b

16、y means of a weighing pipet. e. Allow the flask to stand for five minutes with occasional shaking. f. Fit a 50 ml sintered-glass filter of medium porosity into the top of a 500 ml pear- shaped separatory funnel having a suitable stopcock sealed to the shoulder of the funnel. Apply vacuum to the funn

17、el through this stopcock. Clcse the stopcock at the bottom of the funnel. g. Carefully add the contents of the flask to the filter and allow the filtrate to drain - into the funnel. h. Rinse the inside walls of the flask with four 5-ml portions of distilled water, using the rinsir,gs to wash the pre

18、cipitate deposited on the filter, completely through the filter before adding the next washing. i. Close the side-arm stopcoc.k, liscc.nect the vacuum line, and remcve the filter. j. Add 20 ml of reagent-grade chloroform to the separatory funnel, replace the stopper, invert, and shake vigorously wit

19、h frequent venting for one minute. Allow the layers to separate and draw off the chloroform layer into a 250-ml separatory funnel containing 40 ml of distilled water. Allow each washing to pass k. 1. Stcpper the funnel, invert, and shake m. Allow the layers to separate and discard the vigorously wit

20、h frequent venting for 30 seconds. lower layer. 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-P-47067 68 m 7777706 OL2087B O n. O. P. 9 r. S. t. U. v. W. MIL-P-47067 (MI) Add 20 ml of the chloroform to the 500-nil funnel, replace the stopper,

21、 invert, and shake vigorously for 30 seconds. Allow the layers to seprate and draw off the lower layer into the 250-nil funnel containing the upper layer from (m). Stopper this funnel, invert, and shake vigorously for 30 seconds. Allow the la.yers tc separate and disca-rd the lower 1 ayer. Repe8.t t

22、he extractions with additional 20-nil portions of the chloroform, usir,g the procedure describes in (a) to (9) Until the chloroforn from the last extraction is colorless. Transfer the upper layer from both separatory funnels to a SOO-ml iodine flask. Rinse each funnel with three 5-ml portions of dis

23、tilled water and add t.he rinsings to the flask. Add 15 ml of six normal (N) hydrochloric acid and 8 g of chemically-pure potassium iodine crystals to both this flask and the blank prepared in (b). Replace the stoppers, seal with water, and allow the lasks and contents to stand fGr 10 minutes with o

24、ccasional swirling. Titrate the contents of each flask with standard 0.1N scdium thiosulfate to a light brown color. Add 10 ml of a freshly prepared 1.0 percent starch solLtion and continue the titration until the blue color just disappears. Calculation: Weight percent 2, 4-pentanedione = (13-A) (N)

25、 (20.02) s amp1 e we igh t Where: A = Sodium thiosulfate required for sample, ml 5 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-P-47067 68 7799706 OL20899 2 MIL-P- 470 67 (MI) B = Sodium thiosulfate required for the blank, ml N = Normality of

26、sidium thiosulfate solut ion 4.4.2 Specific gravity. The specific gravity of the material shall b e determined with a Westphal specific gravity balance in accordance with the following procedure. a. Calbirate the balance at the test temperature by the following procedure, Fill the sample graduate wi

27、th freshly boiled, cool, distilled water. Clamp the graduate in place in a constant temperature bath set at 20 plus or minus 10 degrees C. Allow 15 minutes conditioning time to achieve temperature equilibrium. Remove the sample graduate from the bath and place it on the balance. Insert the plumb bob

28、 in the distilled water. Adjust the rider and vernier scale on the balance to give a reading of 1.000. This is the specific gravity of distilled water at the test temperature. b. Fill a sample graduate with the liquid to be tested. Clamp the graduate in place in the constant temperature bath and con

29、dition the sample for 15 minutes. c. Remove the graduate from the bath and place it on the balance and read the balance when it reaches equilibrium. Perform this step as rapidly as possible to minimize temperature changes. For accurate work, the plumb bob should be immersed to the same depth for eac

30、h determination. d. Record the balance reading as the specific gravity of test sample at the conditioning temperature. Duplicate results must check within plus or minus 0.002 unit or additional samples must be run. 6 Provided by IHSNot for ResaleNo reproduction or networking permitted without licens

31、e from IHS-,-,-L NIL-P-LI7067 68 W 9999906 OL20700 5 W MIL-P-47067 (MI) 4.5 Examination. Packaging and marking of the container shall be inspected for conformance to the require- ments of Section 5. 5. PREPARATION FOR DELIVERY 5.1 Packa in Material shall be preserved and packaged to afford a + equat

32、e protection against corrosion, deterioration, and damage during shipment from supply source to first receiving activity (see 6.2). 5.2 Packing. Packaged material shall be secured and packed in s-ping containers in a manner to insure carrier acceptance and safe delivery at destination at the lowest

33、transportation rate. Coiitainers shall comply with Uniform Freight Classification Rules or National Motor Freight Rules as applicable. with MIL-STD-129. Marking shail include, but not be limited to, the following information: - 5.3 Marking. Containers shall be marked in accordance a. b. C. d. e. f.

34、g. h. i. h. NOTES blanufacturer Is name. Material trade name and chemical name. Lot number. Date of manufacture. Number and revision letter of this specification. Storage requirements. Toxicity precautions, if required. Net weight. Fire prevention precautions. 6.1 Intended use. The material is inten

35、ded for use in solid propellants for rocket motors. 6.2 Ordering data. Procurement documents should specify, but not be limited to the following information: a. Rumber and revision letter of this specification. 7 Provided by IHSNot for ResaleNo reproduction or networking permitted without license fr

36、om IHS-,-,-MIL-P-47067 (MI) b. Requirements for preservation, packaging, packing, and marking, if different (see 5.1). c. Place of inspection. d. Minimum lot size, if applicable. e. Place of delivery. f. Request for three copies of laboratory analysis, if inspected by supply source. g. Request for u

37、nusual storage requirements and toxicity. 6.3 Supersession data. This specification includes the requirements of MIS-l6415A, dated 17 June 1969. Custodian: ARMY-MI Preparing Activity : Prnj ect No. 6810 -AA14 ARMY - MI * U. S. GOVERNMENT PRINTING OFFICE: 1974 -713-154.5577 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-