ARMY MIL-PRF-680 C-2010 DEGREASING SOLVENT《脱脂溶剂》.pdf

1、Beneficial comments (recommendations, additions, deletions) and any pertinent data which may be of use in improving this document should be addressed to: U.S. Army Tank-Automotive Research Methods of Testing. (Unless otherwise indicated, copies of the above specifications, standards, and handbooks a

2、re available from the Document Automation and Production Service, 700 Robbins Avenue, Building 4D, Philadelphia, PA 19111-5094 or at https:/assist.daps.dla.mil. 2.2.2 Other Government documents, drawings and publications. The following other Government documents, drawings, and publications form a pa

3、rt of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. ENVIRONMENTAL PROTECTION AGENCY (EPA) EPA Method 420.1 - Methods for Phenolics, Total Recoverable (Spectrophotometric, Manual 4-AAP with Dist

4、illation) EPA Method 3585 - Method for Waste Dilution for Volatile Organics. EPA Method 8260B - Method for Volatile Organic Compounds by Gas Chromatography/ Mass Spectrometry (GC/MS). (Application for copies should be addressed to the US EPA Headquarters, 401 M Street SW, mail code 3204, Washington,

5、 DC 20460 or at http:/www.epa.gov). SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT (SCAQMD) SCAQMD Method 313 - Determination of Volatile Organic Compounds (VOC) by Gas Chromatography/Mass Spectrometry (GC/MS). (Application for copies should be addressed to the South Coast Air Quality Management Distri

6、ct, 21865 Copley Drive, Diamond Bar, CA 91765 or at http:/www.aqmd.gov) 2.3 Non-Government publications. The following document forms a part of this document to the extent specified herein. Unless otherwise specified, the issues of the documents which are DoD adopted are those listed in the issue of

7、 the DoDISS cited in the solicitation. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-680C 3 Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. AMERICAN SOCIETY FOR QUALITY (ASQ) Z1.4 -

8、 Sampling Procedures and Tables for Inspection by Attributes (DoD adopted). (Application for copies should be addressed to the American Society for Quality, P.O. Box 3005, Milwaukee, WI 53201-3005 or at http:/www.asq.org). ASTM INTERNATIONAL D 56 - Standard Test Method for Flash Point by Tag Closed

9、Cup Tester D 86 - Standard Test Method for Distillation of Petroleum Products at Atmospheric Pressure D 130 - Standard Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test D 156 - Standard Test Method for Saybolt Color of Petroleum Products (Saybolt Chromometer Method

10、) D 235 - Standard Test Method for Mineral Spirits (Petroleum Spirits) (Hydrocarbon Dry-Cleaning Solvent) D 847 - Standard Test Method for Acidity of Benzene, Toluene, Xylenes, Solvent Naphthas, and Similar Industrial Aromatic Hydrocarbons D 1133 - Standard Test Method for Kauri-Butanol Value of Hyd

11、rocarbon Solvents D 1296 - Standard Test Method for Odor of Volatile Solvents and Diluents D 1298 - Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method D 1353 - Standard Test Method for Nonvolatil

12、e Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products D 2879 - Standard Test Method for Vapor Pressure-Temperature Relationship and Initial Decomposition Temperature of Liquids by Isoteniscope D 3257 - Standard Test Method for Aromatics in Mineral Spirits by Gas Chro

13、matography D 4057 - Standard Practice for Manual Sampling of Petroleum and Petroleum Products D 4177 - Standard Practice for Automatic Sampling of Petroleum and Petroleum Products Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-680C 4 F 483 -

14、 Standard Practice for Total Immersion Corrosion Test for Aircraft Maintenance Chemicals F 945 - Standard Test Method for Stress-Corrosion of Titanium Alloys by Aircraft Engine Cleaning Materials F 1110 - Standard Test Method for Sandwich Corrosion Test (Application for copies should be addressed to

15、 ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959 or at http:/www.astm.org). SOCIETY OF AUTOMOTIVE ENGINEERS (SAE) INTERNATIONAL AMS-QQ-A-250 - Aluminum and Aluminum Alloy, Plate and Sheet, General Specification for (DoD adopted). AMS 2470 - Anodic Treatment of Aluminum Al

16、loys Chrome Acid Process (DoD adopted). AMS M 3171 - Magnesium Alloy, Processes for Pretreatment and Prevention of Corrosion on (DoD adopted). AMS 4377 - Magnesium Alloy, Sheet and Plate 3.0A1-1.0Zn-0.20Mn (AZ31B-H24) Cold Rolled, Partially Annealed AMS 4911 - Titanium Alloy Sheet, Strip, and Plate,

17、 6AI-4V Annealed AMS 5046 - Carbon Steel Sheet, Strip, and Plate, (SAE 1020 and 1025) Annealed (Application for copies should be addressed to 400 Commonwealth Drive, Warrendale, PA 15096-0001 or at http:/www.sae.org). 2.4 Order of precedence. Unless otherwise noted herein or in contact, in the event

18、 of a conflict between the text of this specification and the references cited herein, the text of this specification takes precedence. Nothing in this specification, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3. REQUIREMENTS 3.1 Qualification.

19、 Solvents furnished under this specification shall be products that are authorized by the qualifying activity for listing on applicable qualified products list before contract award (see 4.2 and 6.3). Any change in the formulation of a qualified product will necessitate its requalification. 3.2 Mate

20、rials. The hydrocarbon solvent shall be a virgin grade or recycled solvent derived from petroleum distillates, fraction from reclaiming and re-refining processes, or a mixture of these fractions. The d-limonene and hydrocarbon blended solvent is permitted as a Type IV solvent. The EPA exempt materia

21、ls and hydrocarbon blended solvent is also permitted as a Type V solvent. The resultant solvent must be produced in such a manner as is necessary to meet the specified requirements. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-680C 5 3.3 A

22、ppearance. The solvent shall be clear and free from suspended matter and undissolved water when observed at a temperature between 60.1 and 78.1F (15.6 and 25.6 C). 3.4 Toxicity. The solvent shall have no adverse effects on human health when used as intended (see 6.1 and 6.6). 3.5 Carcinogenicity. Th

23、e solvent shall contain no chemicals listed as carcinogens (see 6.7). Any carcinogenic components in the solvent in a concentration of 0.1 percent (%) or greater by weight (wt) or volume (vol) will be regarded as the presence of a carcinogen in the solvent. 3.6 Hazardous Air Pollutants. The solvent

24、shall contain no chemicals listed as Hazardous Air Pollutants (HAPs) (see 6.7). Any HAP components in the solvent in a concentration of 1.0 percent (%) or greater by weight (wt) or volume (vol) will be regarded as the presence of a HAP in the solvent. The product containing less than 1 % of HAP shal

25、l be considered as a HAP free solvent. For carcinogenic HAPs see 3.5. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-680C 6 3.7 Physical and chemical property requirements. The solvents shall conform to the physical and chemical requirements

26、 in Table I when tested as specified in Table II. TABLE I. Degreasing solvent properties. Characteristics Type I Type II Type III Type IV Type V Flash point (pt), C (F) 38-60 6192 93-116 6192 61-92 (100-140) (141-198) (200-241) (141-198) (141-198) Distillation, C: Initial boiling pt., minimum (min)

27、149 177 220 171 177 Dry point, C, maximum (max) 208 212 300 240 212 Kauri-Butanol value 27 to 45 27 to 45 27 to 45 27 to 45 NR 4/ Aromatic content, vol %, max 1 1 1 1 1 Total phenol content, parts per million (ppm), max 0.5 0.5 0.5 0.5 0.5 Dichlorobenzene, milligrams per liter (mg/L), max 0.5 0.5 0.

28、5 0.5 0.5 Benzene, mg/L, max 0.5 0.5 0.5 0.5 0.5 Tetrachloroethylene, mg/L, max 0.7 0.7 0.7 0.7 0.7 Trichloroethylene, mg/L, max 0.5 0.5 0.5 0.5 0.5 Apparent specific gravity, 60/60F 0.754 to 0.820 0.754 to 0.820 0.754 to 0.840 0.754 to 0.820 0.754 to 0.980 Total chlorine content (ppm), Max 100 100

29、100 100 100 Non-volatile residue, (mg/100 mL), max 8 8 8 8 8 Color, min 25 25 25 25 25 Odor 1/ Low and 29 CFR 1910.1200 requires that the MSDS for each hazardous chemical used in an operation must be readily available to personnel using the material. Contracting officers will identify the activities

30、 requiring copies of the MSDS (see 3.4 and 4.4.4). 6.7 Definitions. 6.7.1 Carcinogens. The Occupational Safety and Health Administration (OSHA) definition of carcinogens are those chemicals / processes appearing in lists 1, 2A, and 2B of the International Agency for Research on Cancer (IARC) 1/; sub

31、stances known to be carcinogenic and occupational exposures associated with a technological process known to be carcinogenic by the National Toxicology Program (NTP) Report on Carcinogens (latest annual report) 2/; and OSHA regulated carcinogens. 6.7.2. Hazardous Air Pollutant (HAP). HAP is defined

32、as any substance listed under Section 112 of the Clean Air Act or its modifications. The text of the Clean Air Act, listed pollutants and modifications are kept by the Environmental Protection Agency (EPA) and are accessible through the website: http:/www.epa.gov 1/ Copies of these volumes may be fo

33、und in medical libraries or through the World Health Organization, 1211 Geneva 27, Switzerland. 2/ Copies may be obtained from the Public Health Service, National Toxicology Program, Public Information Office, P.O. Box 12233, MD B2-04, Research Triangle Park, NC 27709 or at http:/ntp-server.niehs.ni

34、h.gov Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-PRF-680C 12 6.8 Subject term (key word) listing. d-limonene d-limonene/hydrocarbon blended solvent (type IV) Mineral Spirits Naphtha Petroleum Spirits (USA) Stoddard Solvent (type I) 141 F Sol

35、vent (type II) 200 F Solvent (type III) Low VOC Solvent (type V) 6.9 Changes from previous issues. Marginal notations are not used in this revision to identify changes with respect to the previous issue due to the extensiveness of the changes. Custodians: Preparing Activity: Army - AT Army - AT Air

36、Force - 68 Navy AS (Project 6850-2010-007) Review Activities: Army - AV, EA, MD1, MI, MR, SM Air Force - 03, 11, 50 Navy - MC, SH DLA - GS, GS3, DP DTRA - DS GSA/GSS - FAS MISC MP NOTE: The activities listed above were interested in this document as of the date of this document. Since organizations and responsibilities can change, you should verify the currency of the information above using the ASSIST Online database at https:/assist.daps.dla.mil. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-