ARMY MIL-STD-1234 CHG NOTICE 3-1973 PYROTECHNICS SAMPLING INSPECTION AND TESTING.pdf

1、MIL-STD-1234 CHANGE NOTICE 3 28 May 1973 MILITARY STANDARDPYROTECHNICS: SAMPLING, INSPECTIONAND TESTINGTO ALL HOLDERS OF MIL-STD-1234:1. The following pages of MIL-STD-1234 have been revised and supercedethe pages listed:NEW PAGE SUPERSEDED PAGE DATEDATEIV 28V 28VI 28I 282. The followingREVISED METH

2、OD301.6.1503.1.13. The followingMay 1973 IV 30 March 1967May 1973 V 30 March 1967May 1973 VI 30 March 1967May 1973 I 22 June 1962methods have been revised and supersede the methods listed:DATE SUPERCEDED METHOD DATE28 May 1973 301.6 22 June 196228 May 1973 503.1 22 June 1962is a cumulative list of e

3、arlier changes:a. Superseded pages.NEW PAGE DATE SUPERCEDED PAGE DATEiiivviiiiiivvvi18 Dec 6518 Dec 6518 Dec 6530 Mar 6730 Mar 6730 Mar 6730 Mar 6730 Mar 67iiivviiiiiivvvi22 Jun 6222 Jun 6222 Jun 6218 Dec 6522 Jun 6218 Dec 6518 Dec 6522 Jun 62FSC: 13701Provided by IHSNot for ResaleNo reproduction or

4、 networking permitted without license from IHS-,-,-MIL-STD-1234b. Superseded Methods. NEW METHOD DATE SUPERSEDED METHOD DATE101.1.1101.2.1101.3.1101.4.1102.1.1102.2.118 December 6518 December 6518 December 6518 December 6518 December 6518 December 65c. New methodsMETHOD NO. TITLE DATE101.5 MoistureM

5、ethod)101.6 MoistureMethod)506.1 FrictionFriction101.1101.2101.3101.4102.1102.2(Karl Fischer Distillation 18 December 65(Electrolytic Hygrometersensitivity (By the Roto-Method)22 June 6222 June 6222 June 6222 June 6222 June 6222 June 6230 March 6730 March 674. Retain notice and insert before table o

6、f contents.b. Holders of MIL-STD-1234 will verify that page changes and additionsindicated have been entered and will destroy the previous notice (notice pageonly) .The latest notice (notice page) will be retained as a check sheet.This issuance, together with appended pages, is a separate publicatio

7、n. Eachnotice is to be retained by stocking points until the Military Standard iscompletely revised or cancelled.CUSTODIANS: PREPARING ACTIVITY:ARMYMU ARMYMUNAVYOSAIR FORCE11REVIEW ACTIVITIES: PROJECT NUMBER: 13700103ARMYMUNAVYOSAIR FORCE702Provided by IHSNot for ResaleNo reproduction or networking

8、permitted without license from IHS-,-,-MlL-STD-123422 June 1962CONTENTSPageAlphabetical Index of Test Methods . . . . . . . . . . . . . . . . . . .Numerical Index of Test Methods . . . . . . . . . . . . . . . . . . . . .SECTION 1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . .

9、. . . . . . . . . . . . . .SAMPLING AND INSPECTION . . . . . . . . . . . . . . . . . . . . . . .TESTING . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .T EST METHODS.GroupGroupGroupGroupGroupGroupGroup100 General test methods.200 Physical test methods.300 Sample preparat

10、ions.400 Chemical test methods.500 Sensitivity brisance and Sta-bility test methods.600 Standard700 Indicatorsolutions.solution.ALPHABETICAL INDEX OF TEST METHODSiiiv123Title Method No.Aluminum (Ammonium Hydroxide Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Aluminum (8-Hydro

11、xy-quinoline Method) . . . . . . . . . . . . . . . . . . . . . . . . . . .Ammonium Thiocyanate Indicator Solution (20-percent) . . . . . . . . . . . . . . . .Antimony Sulfide (Permanganate Method) . . . . . . . . . . . . . . . . .Average Particle Size (Fischer Subsieve Sizer) . . . . . . . . . . . .

12、 . . . . . .Barium Diphenylamine Sulfonate Indicator Solution . . . . . . . . . . . . . .Barium Salts (Chromate Method) . . . . . . . . . . . . . . . .Barium Salts (Sulfate Method) . . . . . . . . . . . . . . . . . . . .Bromophenol Blue Indicator Solution . . . . . . . . . . . . . . .Chlorate (Ferro

13、us Sulfate Method) . . . . . . . . . . . .Chloride (Silver Nitrate Method) . . . . . . . . . . . . . . . .Dissolution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Dissolution-Extraction . . . . . . . . . . . . . . . . . . . . . . . . .407.1407.2706.1410.1202.1708.1406.2406.1710.140

14、2.1401.1301.1301.2Eriochrome BlackExtractionFerric Ammonium Ferric Ammonium Granulation100C. Heat TestHexachlorobenzeneHydrochloric Acid. . . . . . . . . . . . . . . . . . . . .T Indicator Solution . . . . . . . . . . . . . . . . . . 709.1301.3Sulfate Indicator Solution . . . . . . . . . . . . . . .

15、 . . . . . . 705.1Sulfate (0.1N Standard Solution) . . . . . . . . . . . . . . . . 603.1. . . . . .(Para(0.lN. . . . . . . . . . . . . . . . . . . . . . . . . . . . 201.1. . . . . . . . . . . . . . . . 502.1Bomb Method) . . . . . . . . . . . . . . 404.1Standard Solution) . . . . . . . . . . . . . .

16、604.1iiiProvided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MlL-STD-123428 May 1973ALPHABETICAL INDEX OF TEST METHODS ContinuedTitle Method No.Hygroscopicity (Equilibrium Method) . . . . . . . . . . . . . . . . . . . . . . . . .Impact Sensitivity Test (U

17、.S. Bureau of Mines Apparatus) . . . . . . . . . . . . . . . . . . . . . . . . . .75C. International Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Iron (Jones Reductor Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Leaching . . . . . . . . . . . . . . .

18、. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Lead Sulfocyanate (Silver Nitrate Method) . . . . . . . . . . . . . . . . . . . . . . . . . . .Magnesium (Audiometer Method ) . . . . . . . . . . . . . . . . . . . . . . .Magnesium (Pyrophosphate Method) . . . . . . . . . . . . . . .

19、 . . .Methyl Orange Indicator Solution . . . . . . . . . . . . . . .Methyl Red Indicator Solution . . . . . . . . . . . . . . .Moisture (Desiccation Method) . . . . . . . . . . . . . . . .Moisture (Karl Fischer Extraction Method) . . . . . . . . . . . . . . . . . .Moisture (Karl Fischer Method) . .

20、. . . . . . . . . . . . . . . .Moisture (Modified Karl Fischer Method ) . . . . . . . . . . . . . . . .Multiple Solvent Extraction . . . . . . . . . . . . . .Nickel (Dimethylglyoxine Method) . . . . . . . . . . . . . . . . . . . . . .Nitro-Compounds (Titanous chloride Method) . . . . . . . . . . . .

21、 . . . . . . . . . . . .Organic Destruction and Sample Dissolution . . . . . . . . . . . . . . . .Perchlorate (Ammonium Chloride Method) . . . . . . . . . . . .Phenolphthalein Indicator Solution . . . . . . . . . . . . . . . . . .Potassium and Barium Salts (Flame Spectrophotometric Method) . . . . .

22、 . . . . . . . . . . .Potassium Dichromate (0.1N Standard Solution) . . . . . . . . . . . . . . . . . .Potassium Permanganate (0.1N Standard Solution) . . . . . . . . . . . . . . . . . . . . . . . .Potassium Salts (Tetraphnyl Boron Method) . . . . . . . . . . . . . . . . . . . . . . . . . .Potassium

23、 Thiocyanate (0.1N Standard Solution) . . . . . . . . . . . . . . . .Reactivity Test . . . . . . . . . . . . . . . . . . . . . . . . . .Selective Solvent Extraction (Extraction Method) . . . . . . . . . . . . . . .Selective Solvent Extraction (Insoluble Residue Method) . . . . . . . . . . . . . . .

24、. . . .Selective Solvent Extraction (Leaching) . . . . . . . . . . . . . . . . . . . . .Selective Solvent Extraction (Soxhlet Method) . . . . . . . . . . . . . . . . . . .Silver Nitrate (0.lN Standard Solution) . . . . . . . . . . . . . . . . . . . .Sodium Diphenylbenzidine Sulfonate Indicator Solut

25、ion . . . . . . . . . . . . . . . . . . . . . .Sodium Hydroxide (0.1N Standard Solution) . . . . . . . . . . . . . . . . . . . . . . . .Sodium Oxalate (Potassium permanganate Method) . . . . . . . . . . . . . . . . . . . . . . . . . .Soxhlet Extraction . . . . . . . . . . . . . . . . . . . . . . . .

26、 . . . . . . . . .Starch Indicator Solution . . . . . . . . . . . . . . . . . . . . . . . .Strontium Nitrate (Sulfate Method) . . . . . . . . . . . . . . . . . . . . . . . . . .Sulfur (Carbon Disulfide Insoluble) . . . . . . . . . . . . . . . .Sulfur (Carbon Disulfide Soluble) . . . . . . . . . . .

27、. . . . . . .Titanous Chloride (0.2N Standard Solution) . . . . . . . . . . . . . . . . . . . .Titanium and Titanium Dioxide (Jones Reductor Method) . . . . . . . . . . . . . . . . . . . . . . . .Total Lead (Chromate Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Total Lead (Su

28、lfate Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . .100C. Vacuum Stability Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles (Oven Method) . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles (Vacuum Method) . . . . . . . . . . . . . . . . . . . . . . . .

29、 . .Zinc Oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Zirconium or Zirconium Hydride (Cupferron Method) . . . . . . . . . . . . . . . . . . . . . . . .203.1505.1501.1414.1301.4405.1412.1412.2704.1702.1101.1101.4101.2101.3301.7411.1420.1301.5403.1703.1421.1605.1606

30、.1415.1608.1504.1204.2204.4204.1204.3607.1707.1602.1416.1301.6.1701.1418.1409.1409.2601.1413.1408.1408.2503.1.1102.1102.2419.1416.1ivSUPERSEDES PAGE iv OF 30 March 1967Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-123428 May 1973NUMERICAL I

31、NDEX OF TEST METHODSGROUP 100 GENERAL TEST METHODSMethod No.101.1101.2101.3101.4102.1102.2201.1202.1203.1204.1204.2204.3204.4301.1301.2301.3301.4301.5301.6.1 301.7401.1402.1403.1404.1405.1406.1406.2407.1407.2408.1408.2409.1409.2410.1411.1412.1412.2413.1414.1415.1416.1417.1418.1419.1420.1421.1Moistur

32、eMoistureMoistureMoistureVolatilesVolatiles(Desiccation Method)(Karl Fischer Method)(Modified Karl Fischer Method)(Karl Fischer Extraction Method)(Oven Method)(Vacuum Oven Method)GROUP 200 PHYSICAL TEST METHODSGranulationAverage Particle Size (Fischer Subsieve Sizer)Hygroscopicity (Equilibrium Metho

33、d)Selective Solvent Extraction (Leaching Method)Selective Solvent Extraction (Extraction Method)Selective Solvent Extraction (Soxhlet Method)Selective Solvent Extraction (Insoluble Residue Method)GROUP 300 SAMPLE PREPARATIONSDissolutionDissolution ExtractionExtractionLeachingOrganic Destruction and

34、Sample DissolutionSoxhlet ExtractionMultiple Solvent ExtractionGROUP 400 CHEMICAL TEST METHODSChloride (Silver Nitrate Method)Chlorate (Ferrous Sulfate Method)Perchlorate (Ammonium Chloride Method)Hexachlorobenzene (Parr Bomb Method)Lead Sulfocyanate (Silver Nitrate Method)Barium Salts (Sulfate Meth

35、od )Barium Salts (Chromate Method )Aluminum (Ammonium Hydroxide Method)Aluminum (8-Hydroxy-quinoline Method)Total Lead (Chromate Method)Total Lead (Sulfate Method)Sulfur (Carbon Disulfate Insoluble)Sulfur (Carbon Disulfide Soluble)Antimony Sulfide ( Permanganate Method)Nickel ( Dimethylglyoxime Meth

36、od)Magnesium (Audiometer Method)Magnesium (Pyrophosphate Method)Titanium and Titanium Dioxide (Jones Reductor Method)Iron (Jones Reductor Method)Potassium Salts (Tetraphenyl Boron Method)Zirconium or Zirconium Hydride (Cupferron Method)Sodium Oxalate (Potassium Permanganate Method)Strontium Nitrate

37、(Sulfate Method)Zinc Oxide (Formic Acid Method)Nitro-Compounds (Titanous Chloride Method)Potassium and Barium Salts (Flame SpectrophotometricMethod)SUPERSEDES PAGEvv OF 30 March 1967Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MlL-STD-123428 May 1

38、973NUMERICAL INDEX OF TEST METHODSContinuedGROUP 500 SENSITIVITY, BRISANCE AND STABILITYTEST METHODSMethod No.501.1502.1503.1.1 504.1506.1601.1602.1603.1604.1605.1606.1607.1608.1701.1702.1703.1704.1705.1706.1707.1708.1709.1710.175C. International Test100C. Heat Test100C. Vacuum Stability TestReactiv

39、ity TestImpact Sensitivity Test (U.S. Bureau of Mines Apparatus)GROUP 600 STANDARD SOLUTIONSTitanous Chloride (0.2N Standard Solution)Sodium Hydroxide (0.1N Standard Solution)Ferric Ammonium Sulfate (0.15N Standard Solution)Hydrochloric Acid (0.1N Standard Solution)Potassium Bichromate (0.1N Standar

40、d Solution)Potassium Permanganate (0.1N Standard Solution)Silver Nitrate (0.1N Standard Solution)Potassium Thiocyanate (0.1N Standard Solution)GROUP 700 INDICATOR SOLUTIONSStarch Indicator SolutionMethyl Red Indicator SolutionPhenolphthalein Indicator SolutionMethyl Orange Indicator SolutionFerric A

41、mmonium Sulfate Indicator SolutionAmmonium Thiocyanate Indicator Solution (20-Percent)Sodium Diphenylbenzidine Sulfonate IndicatorSolutionBarium Diphenylamine Sulfonate Indicator SolutionEriochrome Black T Indicator SolutionBromophenol Blue Indicator SolutionviSUPERSEDES PAGE vi OF 30 March 1967Prov

42、ided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MlL-STD-123428 May 1973SECTION 1INTRODUCTION1. SCOPE1.1 This standard describes the general methods of sampling, inspecting, and testingpyrotechnics for conformance with the material requirements of the app

43、licable pyrotechnicspecification. In the event of conflict between these methods and those in the applicablepyrotechnic specification, the latter shall take precedence.2. REFERENCED DOCUMENTS2.1 The issue of the following documents in effect on the date invitation forbids forma part of this standard

44、 to the extent specified herein:O-A-51 Acetone.RR-S-366 Sieves, standard for testing purposes.JAN-E-199 Ether, diethyl.MIL-E-463A Alcohol, ethyl (for Ordnance use).1SUPERSEDES PAGE 1 OF 22 June 1962Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-

45、STD-123422 June 19621. SCOPE1.1 This section2. SAMPLING2.1 Selection ofSECTION 2SAMPLING AND INSPECTIONspecifies the procedures for samplingthe required test samples from eachpyrotechnics.lot of the pyrotechnic after thepyrotechnic has been packed and sealed for shipment shall be as stated in the ap

46、plicablespecification.3. PACKING and MARKING3.1 Packing. Transfer samples to approved air tight containers, and seal the containersimmediately. Keep the containers sealed and stored in a safe location at room temperatureuntil ready for testing.3.2 Marking. Label each pyrotechnic container with the f

47、ollowing information:(a) Pyrotechnic designation. (b) Lot number.(c) Lot size.(d) Manufacturers name and plant designation. (e) Contract or purchase4. TEST SPECIMEN4.1 Ballistic samples. Select afication.4.2 Chemical and physical testtechnic unless otherwise specifiedorder number.sample as specified

48、 in the applicable pyrotechnic speci-samples. Select an 8-ounce sample from each lot of pyro-in the applicable pyrotechnic specification.4.3 Surveillance test samples. Select a sample as specified in the applicable pyrotech-nic specification. 5. INSPECTION5.1 Before testing the pyrotechnic inspect t

49、he sample container to see that it is notbroken, unstoppered, or otherwise damaged. Also check that it has been labeled correctly.Discard the contents of damaged or improperly labeled container, and report condition tothe (Government inspector (or other proper official) at the plant.2Provided by IHSNot for ResaleNo reproduction or network