ARMY MIL-STD-286 C CHG NOTICE 2-2010 PROPELLANTS SOLID SAMPLING EXAMINATION AND TESTING.pdf

1、INCH-POUND MIL-STD-286C w/CHANGE 2 13 October 2010 SUPERSEDING MIL-STD-286C CHANGE NOTICE 1 8 January 1994 MILITARY STANDARD PROPELLANTS, SOLID: SAMPLING, EXAMINATION AND TESTING AMSC N/A FSC 1376 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Provided by IHSNot fo

2、r ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 FOREWARD 1. This Military Standard is approved for use by all Departments and Agencies of the Department of Defense. 2. Comments, suggestions, or questions this document should be addressed to: Comma

3、nder, U S Army ARDEC, ATTN: RDAR-QES-E, Picatinny Arsenal, NJ 07806-5000 or emailed to ardecstdznpica.army.mil. Since contact information can change, you may want to verify the currency of this address information using the ASSIST Online database at https:/assist.daps.dla.mil. 3. Test methods added:

4、 217.5, Diphenylamine and its Major Derivatives (HPLC Method); and 202.3, Ethyl Centralite and its Major Derivatives, Akardite II (HPLC Method). iiProvided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 CONTENTS Page Alphabetical Inde

5、x of Test Methods iv Numerical Index of Test Methods ix Scope 1 Applicable Documents 2 Definitions 4 General Requirements 5 Detail Requirements 6 Test Methods Group 100 - General test methods Group 200 - Quantitative methods for organic ingredients Group 300 - Quantitative methods for inorganic ingr

6、edients Group 400 - Stability tests Group 500 - Physical test methods Group 600 - Standard solutions Group 700 - Indicator solutions Group 800 - Special test methods iii Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 ALPHABET

7、ICAL INDEX OF TEST METHODS TITLE METHOD NO. Acidity or Alkalinity of Casting Solvent 107.1 Airspace 508.1.3 Aluminum (Gravimetric Method) 314.1 Aluminum and Zirconium 315.1 Ammonium Perchlorate (Non-Aqueous Titrimetry) 216.1 Ammonium Thiocyanate Indicator Solution (20 percent) 706.1 Ash (Lead Salts

8、With or Without Potassium Salts Present) 106.4.2 Ash (No Organic Additives Present) 106.1.2 Ash (Potassium Salts Present) 106.2.3 Ash (Potassium Salts and Tin Present) 106.3.2 Aurine 212.1 Available Stabilizer (DPA or EC) 217.2.1 Barium Nitrate (Gravimetric Method) 304.1.3 Barium Diphenylamine Sulfo

9、nate Indicator Solution 708.1 Bromthymol Blue Indicator Solution (0.1 Weight Percent in Ethanol) 709.1 Bulk Density 502.1.1 Bulk Density (Pounds per Cubic Foot) 502.2.1 Calcium Carbonate - Sodium Sulfate - Graphite (Morpholine Method) 305.1.2 Candelilla Wax 228.1.1 Carbon Black or Graphite (Gravimet

10、ric Method) 309.1.2 Carbon Black (Photometric Method) 309.2.2 Casting Powder Dimensions 504.4 Compressibility of Grains 505.1 iv Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 ALPHABETICAL INDEX OF TEST METHODS (Contd) TITLE

11、METHOD NO. Cryolite (Sodium Aluminum flouride) 307.1.2 2,4,6,8 Cyclotetrametylene Tetranitramine (HMX) (Infrared Method) 229.1.1 Density of Loading 507.1 Density (Air Pycnometer Method) 510.3.1 Dibutylphthalate (Difference Method) 204.1.2 Diethylphthalate of Dibutylphthalate (Zinc Reduction-Volumetr

12、ic Method) 203.5 Dimethyl, Diethyl and Dibutyl Phthalates (Gas Chromatographic Method) 204.2.1 Dimensions of Grains 504.1.1 Dimensions of Grains (Image Analyzer) 504.6.1 Dimensions of Grains after Quick Shrinkage 504.2.1 Dimensions of Sheet Propellant (Increment Propellant) 504.3 Dinitrotoluene (Nit

13、rate Esters Absent) 205.1.2 Dinitrotoluene (Nitrate Esters Present) 205.2.3 Dinitrotoluene (Infrared Method) 205.3.1 Dinitrotoluene, Stabilizers, and Plasticizers (Gas Chromatographic Method) 226.2.1 Diphenylamine (Gravimetric Method) 201.2.3 Diphenylamine (Solvent Extraction - Bromination Method) 2

14、01.1.4 Diphenylamine and Ethyl Centralite in Admixture or Separately 201.4.2 (Steam Distillation Spectrophotometric Method) Diphenylamine or Ethyl Centralite (Steam Distillation Volumetric 217.3.1 Bromination Method) Diphenylamine and Ethyl Centralite in Admixture or Separately 217.4.1 (Distillation

15、 Gravimetric and Volumetric Bromination) Diphenylamine and its Major Derivatives (HPLC Method) 217.5 vProvided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 ALPHABETICAL INDEX OF TEST METHODS (Contd) TITLE METHOD NO. Dust and Foreign

16、 Material 501.1.3 Ethyl Centralite (Volumetric Bromination Method) 202.2.3 Ethyl Centralite and its Major Derivatives, Akardite II (HPLC Method) 202.3 Ethylene Dimethacrylate (Infrared Method) 224.1.1 Ethylene Dimethacrylate (Bromination Method) 224.2.1 Ethylene Dimethacrylate (Saponification Method

17、) 224.3.1 Ferric Ammonium Sulfate Indicator Solution 705.1 Ferric Ammonium Sulfate (0.15N Standard Solution) 603.1 Ferrous Ammonium Sulfate (0.7N Solution) 604.1.1 Grains per Pound 511.1 Granulation 506.1 Graphite and Carbon Black 308.1.4 Grain Dimensions of Flake Propellant 504.5.1 Heat of Explosio

18、n (Combustion) (Adiabatic Calorimetric Method) 802.1 Heat Tests (120 and 134.5C) 404.1.2 Hygroscopicity, Small Arms Propellant 503.1.3 Hygroscopicity, Cannon Propellants (Equilibrium Method) 503.2.2 Inorganic Nitrate in Nitrocellulose - Base Propellant (Calorimetric Method) 313.1 Iodine (0.02N Stand

19、ard Solution) 609.1 Isopropyl Alcohol, Ethyl Acetate and Benzene (Gas Chromatography Method) 103.6.1 Lead (Atomic Absorption) 311.6.1 Linear Burning Rate of Propellants (Strand Burner Method) 803.1.1 Magnesium Salts (Flame Spectrophotometric Method) 312.1.1 vi Provided by IHSNot for ResaleNo reprodu

20、ction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 ALPHABETICAL INDEX OF TEST METHODS (Contd) TITLE METHOD NO. Metals (Atomic Absorption) 316.1.1 Methyl Orange Indicator Solution 704.1 Methyl Red Indicator Solution 702.1 Moisture (Distillation Method) 102.1.3 Moisture

21、 (Desiccation Method) 101.3.2 Moisture (Electrolytic Hygrometer Method) 101.4 Moisture (Karl Fischer Method) 101.5 Moisture (Gas Chromatography Method) 101.6.1 Moisture and Volatiles (Oven Method) 101.2.2 Moisture and Volatiles (Vacuum Oven Method) 101.1.2 Nitrate Esters 208.1.3 Nitrate Esters, Stab

22、ilizers and Plasticizers (Gas - Liquid Chromatographic Method) 208.4.1 Nitrocellulose (Acetic Acid Extraction Method) 209.6.2 Nitrocellulose (Difference Method) 209.2.1 Nitrocellulose (Nitrometer Method) 209.3.2 Nitrocellulose (Infrared Method) 209.10.1 2-Nitrodiphenylamine (Spectrophotometric Metho

23、d) 218.4.3 2-Nitrodiphenylamine (Titanous Chloride - Buffer Method) 218.2.1 2-Nitrodiphenylamine (Volumetric Brominating Method) 218.1.2 2-Nitrodiphenylamine (2 NDPA) Resorcinal (Liquid Chromatography Method) 218.5.1 Nitrogen in Nitrocellulose or Nitrocellulose in Propellant (Ferrous Titanous Chlori

24、de Method) 209.7 Nitrogen in Nitrocellulose on a Macro and Semi-micro Scale (Infrared Method) 209.8.1 vii Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 ALPHABETICAL INDEX OF TEST METHODS (Contd) TITLE METHOD NO. Nitrogen Con

25、tent of Nitrocellulose in Spherical Powder (Analyzer Method) 209.9.1 Nitrogen Content of Nitrocellulose (Ferrous Sulfate Titration Method) 209.11.1 Nitrogen Content of Nitroglycerin and DEGDN (Ferrous Sulfate Titration Method) 209.12 Nitrogen Oxide Evolution Profile (NEP) 409.1.1 Nitroglycerin (Acet

26、ic Acid Extraction Method) 208.2.2 Nitroglycerin, Plasticizers, and Stabilizers (Liquid Chromatography Method) 208.3.1 Nitroglycerin, 2-4 Dinitrotoluene, Diphenylamine and Dibutylphthalate (Liquid Chromatography Method) 208.5.1 Nitroguanidine (Salicyclic Acid Transnitration Method) 213.2 Nitroguanid

27、ine (Spectrophotometric Method) 213.3.1 Nitroguanidine (Titanous Chloride Buffer Method) 213.4 Nitroguanidine (Water Extraction Method) 213.1.4 Nitroguanidine, Nitroglycerin and Ethyl Cenlralite (Liquid Chromatography Method) 213.5.1 Nitroguanidine (Non-Aqueous Titrimetric Method) 213.6.1 Oxamide (P

28、ermanganate Titration Method) 219.1 Oxamide (Spectrophotometric Method) 219.2.1 Oxamide (Volumetric Method) 219.3.1 Oxamide (Infrared Method) 219.4.1 Packing Density 502.3.1 Perchlorates (Explosion - Volhard Method) 303.1.3 Phenolphthalate Indicator Solution 703.1 Phthalate Esters (Saponification Sp

29、ectro-Photometric Method) 221.1.1 Plasticizers Ester (Infrared Method) 222.1.1 Potassium Bromate - Bromide Solution 605.1 viii Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 ALPHABETICAL INDEX OF TEST METHODS (Contd) TITLE ME

30、THOD NO. Potassium Permanganale (0.1N Standard Solution) 606.1.1 Potassium Salts (Flame Spectrophotometric Method) 310.3.1 Potassium Salts (Tetraphenylboron Method) 310.4.2 Potassium Thiocyanate (Standard Solutions) 608.1 Preparation of Propellant Samples 509.3 Quickness and Force Measurement of Pro

31、pellant (Closed Bomb Method) 801.1.2 Quickness and Force Measurement of Propellant (Alternate Closed bomb Method) 804.1 Reactivity Test (90 and 100C) 408.1.1 Residual Solvent 103.4.1 Resorcinol (Volumetric Bromination Method) 223.1 Salicylate Salts (Calorimetric Method) 225.1.1 Silver Nitrate (Stand

32、ard Solutions) 807.1 Sodium, Calcium, Barium and Potassium (Atomic Absorption Method) 317.1.1 Sodium Diphenylbenzidine Sulfonate Indicator Solution 707.1 Sodium Thiosulfate (0.2N Standard Solution) 602.1 Solvent Extractive Matter 104.1.3 Sol-Gel Extraction and Functional Group Analysis (ANB-3066 Pro

33、pellant) 230.1.1 Specific Gravity (Pycnometer Method) 510.1.1 Specific Gravity of Liquids (Westphal Method) 510.2.1 Starch 210.1.2 Starch Indicator Solution 701.1 Sulfates (Spectrophotometric Method) 227.1 Surveillance Test (65.5C) 407.1 ix Provided by IHSNot for ResaleNo reproduction or networking

34、permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 ALPHABETICAL INDEX OF TEST METHODS (Contd) TITLE METHOD NO. Taliani Test 406.1.3 Tin and Graphite (Gravimetric Method) 306.2.3 Tin (lodimetric Method) 306.1.4 Tin (Polarographic Method) 306.3.1 Titanous Chloride (0.2N Solution, Standard)

35、 601.1.1 Total Lead (Chromate Method) 311.2.2 Total Lead (Molybdate Method) 311.4 Total Lead (Polarographic Method), 311.3.2 Total Lead (Sulfate Method) 311.1.3 Total Volatiles (Dish and Cone Method) 103.1.3 Total Volatiles (Gas Chromatographic Method) 103.5.2 Total Volatiles (Solution Evacuation Me

36、thod) 103.3.3 Trinitrotoluene (Nitrate Esters Absent) 206.1.2 Trinitrotoluene (Nitrate Esters Present) 206.3.3 Vacuum Stability Tests (90 and 100C) 403.1.3 xProvided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 NUMERICAL INDEX OF TE

37、ST METHODS GENERAL TEST METHODS GROUP 100 METHOD NO. TITLE 101.1.2 Moisture and Volatiles (Vacuum Oven Method) 101.2.2 Moisture and Volatiles (Oven Method) 101.3.2 Moisture (Desiccation Method) 101.4 Moisture (Electrolytic Hygrometer Method) 101.5 Moisture (Karl Fischer Method) 101.6.1 Moisture (Gas

38、 Chromatography Method) 102.1.3 Moisture (Distillation Method) 103.1.3 Total Volatiles (Dish and Cone Method) 103.3.3 Total Volatiles (Solution-Evacuation Method) 103.4.1 Residual Solvent 103.5.2 Total Volatiles (Gas Chromatographic Method) 103.6.1 Isopropyl Alcohol, Ethyl Acetate and Benzene (Gas C

39、hromatography Method) 104.1.3 Solvent Extractive Matter 106.1.2 Ash (No Inorganic Additives Present) 106.2.3 Ash (Potassium Salts Present) 106.3.2 Ash (Potassium Salts and Tin Present) 106.4.2 Ash (Lead Salts With or Without Potassium Salts Present) 107.1 Acidity or Alkalinity of Casting Solvent xi

40、Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-STD-286C w/CHANGE 2 NUMERICAL INDEX OF TEST METHODS (Contd) QUANTITATIVE METHODS FOR ORGANIC INGREDIENTS GROUP 200 METHOD NO. TITLE 201.1.4 Diphenylamine (Solvent Extraction-Bromination Method) 201.

41、2.3 Diphenylamine (Gravimetric Method) 201.4.2 Diphenylamine and Ethyl Centralite in Admixture or Separately (Steam Distillation Spectrophotometric Method) 202.2.3 Ethyl Centralite (Volumetric Brominatton Method) 202.3 Ethyl Centralite and its Major Derivatives, Akardite II (HPLC) 203.5 Diethylphtha

42、late or Dibutylphthalate (Zinc Reduction-Volumetric Method) 204.1.2 Dibutylphthalate (Difference Method) 204.2.1 Dimethyl, Diethyl and Dibutyl Phthaiates (Gas Chromatographic Method) 205.1.2 Dinitrotoluene (Nitrate Esters Absent) 205.2.3 Dinitrotoluene (Nitrate Esters Present) 205.3.1 Dinitrotoluene

43、 (Infrared Method) 206.1.2 Trinitrotoluene (Nitrate Esters Absent) 206.3.3 Trinitrotoluene (Nitrate Esters Present) 208.1.3 Nitrate Esters 208.2.2 Nitroglycerin (Acetic Acid Extraction Method) 208.3.1 Nitroglycerin Plasticizers and Stabilizers (Liquid Chromatography Method) 208.4.1 Nitrate Esters, S

44、tabilizers and Plasticizers (Gas-Liquid Chromatographic Method) 208.5.1 Nitroglycerin, 2-4 Dinitrotoluene, Diphenylamine and Dibutyl-phthalate (Liquid Chromatography Method) 209.2.1 Nitrocellulose (Difference Method) 209.3.2 Nitrocellulose (Nitrometer Method) 209.6.2 Nitrocellulose (Acetic Acid Extr

45、action Method) 209.7 Nitrogen in Nitrocellulose or Nitrocellulose in Propellant (Ferrous Titanous Chloride Method) 209.8.1 Nitrogen in Nitrocellulose on a Macro or Semimicro Scale (Infrared Method) 209.9.1 Nitrogen Content of Nitrocellulose in Spherical Powder (Analyzer Method) 209.10.1 Nitrocellulo

46、se (Infrared Method) 209.11.1 Nitrogen Content of Nitrocellulose (Ferrous Sulfate Titration Method) 209.12 Nitrogen Content of Nitroglycerin and DEGDN (Ferrous Sulfate Titration Method) 210.1.2 Starch 212.1 Aurine xii Provided by IHSNot for ResaleNo reproduction or networking permitted without licen

47、se from IHS-,-,-MIL-STD-286C w/CHANGE 2 NUMERICAL INDEX OF TEST METHODS (Contd) QUANTITATIVE METHODS FOR ORGANIC INGREDIENTS GROUP 200 (Contd) METHOD NO. TITLE 213.1.4 Nitroguanidine (Water Extraction Method) 213.2 Nitroguanidine (Salicylic Acid Transnitration Method) 213.3.1 Nitroguanidine (Spectro

48、photometric Method) 213.4 Nitroguanidine (Titanous Chloride-Buffer Method) 213.5.1 Nitroguanidine, Nitroglycerin and Ethyl Centralite (Liquid Chromatography Method) 213.6.1 Nitroguanidine (Non-Aqueous Titrimetric Method) 216.1 Ammonium Perchlorate (Non-Aqueous Titrimetry) 217.2.1 Available Stabilizer (DPA or EC) 217.3.1 Diphenylamine or Ethyl Centralite (Steam Distillation Volumetric Bromination Method) 217.4.1 Diphenylamine and Ethyl Centralite in Admixture or Separately