ARMY MMM-A-189 C-1985 ADHESIVE SYNTHETIC-RUBBER THERMOPLASTIC GENERAL PURPOSE《一般用途的热塑性的合成橡胶粘合剂》.pdf

1、t -., * _ MUM-A-187C 80 9 7777774 000682V it 9 r Rolled, Drawn, or Cold Finished, 2024. - Brass, Leaded and Nonleaded: Rod, Shapes, Forgings, and Flat Products with Finished edges (Bar and Strip - Steel, Sheet and Strip, Low Carbon. - Toluene, Technical. - Cloth, Sheeting, Cotton, and Polyester and

2、Cotton. - BOX, Folding, Paperboard. - Boxes: Paperboard, Metal Edged and Components. - Boxes , Setup. - Cans, Metal, 28 Gage and Lighter. - Pails, Metal.(Shipping, Steel, 1 through 12 Gallon). / FSC 8040 / / THIS DOCUMENT CONTAINS / Methods of Inspection, Sampling and Testing. Fed. Test Method No. 1

3、41/5132 - Chlorinated Compound (Presence of). Fed. Test Method No. 141/7356 - Solvent Content of Enamels and Enamel Thinners (Gas Liquid Chromatography). (Activities outside the Federal Government may obtain copies of Federal specifications, standards, and commercial item descriptions as outlined un

4、der general information in the Index of Federal Specifications, Standards and Commercial Item Descriptions, The Index, which includes cumulative bi-monthly supplements as issued, is for sale on a subscription basis by the Superinten- dent of Documents, U.S. Government Printing Office, Washington, D.

5、C, 20402.) (Single copies of this specification and other Federal specifications and commercial item descriptions required by activities outside the Federal Government for: bidding purposes, are available without charge from the General Services Administration Business Service Centers in Boston, MA,

6、 New York, NY, Washington, D.C., Atlanta, GA, Chicago, IL, Kansas City, MO, Fort Worth, TX, Houston, TX, Denver, CO, San Francisco, CA, Los Angeles, CA, and Seattle, WA.) (Federal Government activities may obtain copies of Federal Standardization, Documents and the Index of Federal Specifications, S

7、tandards and Commercial Item Descriptions from established distribution points in their agencies.) Military Standards : MIL-STD-105 - Sampling Procedures and Tables for Inspection by Attributes. MIL-STD-129 - Marking for Shipment and Storage. (Copies of Military specifications and standards required

8、 by contractors in connection with specific procurement functions should be obtained from the procuring activity or as directed by the contracting officer.) Laws and Regulations: U,S. Department of Transportation (DOT) : Code of Federal Regulations, Title 49 - Transportation, Parts 100-199 Rules and

9、 Regulations for the Transportation of Hazardous Materials. (The Code of Federal Regulations (CFR) and the Federal Register (FR) are for sale on a subscription basis by the Superintendent of Documents, U.S. Govern- ment Printing Office, Washington, D.C. 20402. When indicated, reprints of certain reg

10、ulations may be obtained from the Federal agency responsible for issuance thereoe.) 2.2 Other publications. The following documents form a part of this specification to the extent specified herein. identified, the issue in effect on date of invitation for bids or request for proposal shall apply. Un

11、less a specific issue is 2 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MMM-A-L87C 80 = 7797774 000b2b -9 MMM-A- 189C National Motor Freight Traffic Association, Inc., Agent: National Motor Freight Classification (Application for copies should be

12、addressed to the American Trucking Associations Inc., Tariff Order Section, 1616 P Street, N.W., Washington, D.C. 20036. ) Uniform Classification Committee, Uniform Freight Classification (Application for copies should be addressed to the Uniform Classification Committee, Room 1106, 222 South Rivers

13、ide Plaza, Chicago, IL 60606) American Societv for Testins and Materials (ASTM) D 86 - Test for Distillation of Petroleum Products. D 903 - Test for Peel or Stripping Strength of Adhesive Bonds. D 1002 - Test for Strength Properties of Adhesives in Shear by Tension D 1084 - Test Methods for Viscosit

14、y of Adhesives. Loading (Metal-to-Metal). (Application for copies should be addressed to the American Society for Testing and Materials, 1916 Race Street, Philadelphia, Pennsylvania 19103.) 3. REQUIREMENTS 3.1 Materials. The adhesive shall be a thermoplastic synthetic rubber base material dissolved

15、in an organic solvent or blend of solvents, modified to the extent that the requirements of this specification are met (see 4.1.1). a 3.1.1 The manufacturer is given latitude in the selection of solvents or blend of solvents, provided the material meets the requirements specified in 3.1.1.1 and 3.1.

16、1.2. 3.1.1.1 The solvent system when tested as specified in 4.3.2.6 shall contain no benzene (benzol) nor halogenated compounds. 3.1.1.2 The volatile solvent when tested as specified in 4.3.2.6 shall conform by volume to the requirements controlling the emission of solvents into the atmosphere as ca

17、lled out in (a), (b), (c), (d), and (e). (a) A combination of aldehydes or branched chain ketones: 20 percent maximum. C A combination of aromatic compounds with eight or more carbon atoms to the molecule except ethylbenzene: 8 percent maximum. A combination of ethylbenzene or toluene: 20 percent ma

18、ximum. d) A combination of solvents with an olefinic or cyclo-olefinic type of unsaturation: 5 percent maximum. e) Total of (a) + (b) + (c) + (d) = 20 percent maximum. 3 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-3.2 Condition in container. When

19、 tested as specified in 4.2.5 the adhesive shall be homogeneous and intimately compounded and have no other undesirable qualities. 3.3 Specific gravity, The specific gravity of the adhesive shall be not less than 0.80 nor more than 0.98 when tested as specified in 4.3.2.1. 3.4 Viscosity. 3.4.1 Visco

20、sity (class 1). less than 10 seconds nor more 4.3.2.2, 3.4.2 Viscosity (class 2). less than 15 seconds nor more 4.3.2.2. The viscosity of class 1 adhesive shall be not than 40 seconds when tested as specified in The viscosity of class 2 adhesive shall be not than 45 seconds when tested as specified

21、in 3.5 Nonvolatile content. The nonvolatile content of the adhesive when tested as specified in 4.3.2.3 shall be as follows: Minimum Maximum Percent Percent Class 1 (20 percent nonvolatile content) 18 Class 2 (30 percent nonvolatile content) 28 22 32 3.6 Ash content of nonvolatile natter. The ash co

22、ntent o the nonvolatile matter in the adhesive shall not exceed 18 percent when tested in accordance with 4.3.2.4. 3.7 pH of adhesive-water mixture. The pH of a water-adhesive mixture shall be not less than 5.5 nor more than 9.0 when tested in accordance with 4.3.2.5. 3.8 Shear strength, Both classe

23、s of adhesive shall conform to the requirements listed in table I when tested in accordance with 4.3.2.8. 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MMM-A-I7C 0 W 777777q 000bLi28 I W MMM-A-184C TABLE I. Shear Strength Minimum Minimum average

24、individual value, value, Conditioning time lbs. per lbc. per and temperature Test temperature sq. inch sq. inch 25O + 2OC (77O + 3.6OF) - - 24 hrs. at 250 + 2% - (77O - + 3.6OF) 1200 1000 25O + 2OC (77O + 3.6OF) 1200 1000 - - 24 hrs. at 77O + 2% (170.6O + 3,6OF), then 2 hFs. at 25% + 2OC (77O + 3.6O

25、F) - - 25O + 2OC (77O + 3.6OF) - - 24 hrs. immersion in toluene at 250 + 20C (77O - + 3.6OF) - 50 + 2OC (122O + 3.6OF) - - 2 hrs. at 50 + 2% (122 - + 3.6OF) - 1000 800 700 500 3.9 Peel strength. The adhesive shall have a minimum peel strength of 12 pounds per inch width and minimum individual value

26、of 10 pounds per inch width when tested in accordance with 4.3.2.8. 3.10 Corrosivity. The adhesive shall not be corrosive to steel, aluminum, or brass when tested in accordance with 4.3.2.9. 3.11 Shelf storage life. When the adhesive is stored as specified in 4.3.2.10 there shall be no gelling, curd

27、ling, stringing or other nonuniformity; the viscosity shall not have changed more than 10 percent plus or minus from the originally-specified viscosity (see 3.3); and the strength values shall be not less than the minimums specified in table I (first condition only) and 3.9 (see 4.1.1.). 3.12 Toxici

28、ty. The material shall have no adverse effect on the health of personnel when used for its intended purpose. Questions pertinent to this effect shall be referred by the procuring agency to the appropriate department medical service who will act as an advisor to the procuring agency. In the case of A

29、rmy procurement, the Surgeon General of the Army will act as advisor (sec 4.3.2.11). 3.13 Compatibility (reactivity and storage characteristics). When compatibility for use with a particular explosive or propellant is required, special tests shall be conducted at a Government laboratory. The procuri

30、ngagency shall request that these tests be conducted and shall specify the particular explosive or propellant to be used in the tests (see 6.3). 5 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-W-A- 1.8 9C 4. QUALITY ASSURANCE PROVISIONS “ 4.1 Respo

31、nsibility for inspection. Unless otherwise specified in the contract, the contractor is responsible for the performance of all inspection requirements as specified herein. Except as otherwise specified in the contract! the contractor may use his own or any other facilities suitable for the performan

32、ce of the inspection requirements specified herein, unless disapproved by the Government. The Government reserves the right to perform any of the inspections set forth in the specification where such inspections are deemed necessary to assure that supplies and services conform to prescribed requirem

33、ents. 4.1.1 The supplier shall submit to the contracting officer a certificate of compliance indicating that the adhesive complies with the shelf storage life requirement as specified in 3.11. When certificates of compliance are submitted, the Government reserves the right to check test such items t

34、o determine the validity of the certificate. 4.2 Quality conformance inspection. 4.2.1 Lot formation. A lot shall consist of adhesive from one batch. A batch is defined as that quantity of material which has been subjected to some unit chemical or physical mixing process intended to make the final p

35、roduct substantially uniform. 4.2.2 Sampling. Sampling of the adhesive shall be performed as directed by the procuring agency either (a) in a thoroughly-mixed batch of adhesive before packaging, or (b) on a lot of packaged adhesives (filled containers). Sampling for preparation for delivery shall be

36、 made on the packaged, or packaged and packed lot. 4.2.3 Examination of filled containers. When the examination is to be performed on filled containers, a random sample of such containers shall be selected for examination from each lot in accordance with MIL-STD-105. From these containers 8-ounce sa

37、mples shall be selected, one from each of two containers! the contents of which appear to have different consistencies. less than two samples shall be taken. Not 4.2.4 Examination of adhesive before packaging. For tests when the sampling is to be perormed on the adhesive before packaging, an 8-ounce

38、 representative sample shall be selected from each batch. 4.2.5 Condition in container. The condition in the container shall be determined as follows: Each container in the sample shall be opened and sufficient adhesive shall be poured into a clean, dry vessel to permit the remainder of the adhesive

39、 to be stirred without spilling. The adhesive shall be stirred with a clean paddle reaching to the bottom of the container, presence of segregation, caking, lumps, skins or solid particles shall be observed! and differences in consistency between sample units shall be determined by feeling the resis

40、tance to movement of the paddle and by observing the material as it drains off the paddle. shall then be returned to the container. The The material removed 6 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-t MMM-A-It87C 80 W 7777779 0006830 T I MMM-

41、A-189C 4.2.6 Disposition of sample. Sample units selected as specified in 4.2.3 and 4.2.4 shall be tested separately for specific gravity (see 3.2) and composite sample used for the other tests. A portion of this composite sample shall be placed in an airtight container and labeled to show the batch

42、 number, the name of the material, manufacturer, plant, contract or purchase order number, date of sampling, and identification mark of samples. I 4.3.1.1 Periodic lot-check tests. Periodic lot-check tests shall be I performed on the first lot of adhesive offered to the Government against this I spe

43、cification and once on every 20 lots thereafter, or once every 2 years, whichever is the more frequent, and shall consist of all tests of this specification. Whenever a lot is tested and fails to pass one or more of the periodic lot-check tests, either regular or recheck, no further lot will be acce

44、pted until the supplier has presented sufficient evidence to show that the cause of the failure has been corrected. i. I 1 4.3.1.2 Lot acceptance tests. Lot acceptance tests shall be made on each lot of product and shall be the basis for acceptance or rejection of the lot. The lot acceptance tests s

45、hall consist of the following tests: 4.2.7 Examination. Sample units selected in accordance with 4.2.3 shall be examined for the defects at the acceptable quality level (AQL) shown in table II. This examination is to determine that the adhesive meets the acceptable quality requirements and the prepa

46、ration for delivery requirements specified in section 5. 4.3 Tests. 4.3.1 Classification of tests. All tests shall be performed in accordance with 4.1 and shall be classified as follows: (a) Periodic lot-check tests (see 4.3.1.1). (b) Lot acceptance tests (see 4.3.1.2.). Specific gravity (see 3.3).

47、Viscosity (see 3.4). I 7 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-f4ml-A- 189C TABLE LI, Classification of Defects Cla ssi f ic at ion AQL of Method oe major defects Defect inspection - Mat e ria 1 percent Adhesive (see 3.2) 2.5 101 Not intima

48、tely Visual Visual 102 Not homogeneous. compounded. Unit container (see 2.5 5,1.1.lr 5.1.2.1 or 5.1.3 as applicable . and 5.3 and 5.4) 103 improper fiil .L/ Visual and 104 Wrong type or size. Visual 105 Leakage. Visual Improper closure. Visual 106 107 Marking improper or Visual scale21 unidentifiabl

49、e. Intermediate (if required 5.1.2.21 5.3 package 2.5 and 5.4 1 (see Wrong number of Visual 108 109 Wrong type. Visual 11 o Wrong size. Visual 111 Marking improper or Visual unit containers. unidentifiable. Box open (see 5.2.11 2.5 5.2.2 or 5.2.3) a 112 Wrong type or size. Visual 113 Lack ofr or improper Visual strapping. BOX closed (see 5.2.1r 2.5 5.2.2 or 5.2.3/ 5.3 and 5.4) 114 Gross Weight maximum. Approved 115 Improperly closed. Vi sua1 116 Mark