1、Designation: B216 16Standard Specification forTough-Pitch Fire-Refined CopperRefinery Shapes1This standard is issued under the fixed designation B216; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A num
2、ber in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This specification establishes the requirements fortough-pitch fire-refined copper wire bars, cakes, slabs, andbillets for fabricating in
3、to wrought products and ingot andingot bars for use in the manufacture of copper and copperalloy castings. This copper is not intended for electricalpurposes.1.2 Copper under this specification corresponds to thedesignation “FRTP” (UNS C12500) as shown in ClassificationB224. This copper may also be
4、used to produce other desig-nations of copper where the chemical composition limits arenot lower then those listed for C12500 in Table 1.1.3 Although this specification includes certain UNS desig-nations as described in Practice E527, these designations arefor cross reference only and are not specif
5、ication requirements.Therefore, in case of conflict, this ASTM specification shallgovern.1.4 UnitsThe values stated in inch-pound units are to beregarded as standard. The values given in parentheses aremathematical conversions to SI units that are provided forinformation only and are not considered
6、standard.1.5 The following safety hazard caveat pertains only to thetest method described in the annex of this specification:Thisstandard does not purport to address all of the safety concerns,if any, associated with its use. It is the responsibility of the userof this standard to establish appropri
7、ate safety and healthpractices and to determine the applicability of regulatorylimitations prior to use.2. Referenced Documents2.1 ASTM Standards:2B224 Classification of CoppersB846 Terminology for Copper and Copper AlloysE29 Practice for Using Significant Digits in Test Data toDetermine Conformance
8、 with SpecificationsE50 Practices for Apparatus, Reagents, and Safety Consid-erations for Chemical Analysis of Metals, Ores, andRelated MaterialsE53 Test Method for Determination of Copper in UnalloyedCopper by GravimetryE255 Practice for Sampling Copper and Copper Alloys forthe Determination of Che
9、mical CompositionE527 Practice for Numbering Metals and Alloys in theUnified Numbering System (UNS)3. Terminology3.1 For definitions of terms related to copper and copperalloys, refer to Classification B224 and Terminology B846.4. Ordering Information4.1 Include the following specified choices when
10、placingorders for product under this specification, as applicable:4.1.1 ASTM designation and year of issue,4.1.2 Shape and Size: wire bar, cake, slab, billet, ingot, oringot bar,4.1.3 Quantity: total weight or number of pieces for eachshape and size, and4.2 When material is purchased for the U.S. go
11、vernment,this shall be specified in the contract or purchase order, and thematerial shall conform to the supplementary requirements asdefined herein.4.3 The following options are available but may not beincluded unless specified at the time of placing of the orderwhen required:4.3.1 Certification (S
12、ection 16),4.3.2 Test Report (Section 17).5. Material5.1 Any copper that will yield a product with a chemicalcomposition conforming to the requirements of Table 1 may beused.6. Chemical Composition6.1 The product material shall conform to the requirementsof Table 1.1This specification is under the j
13、urisdiction ofASTM Committee B05 on Copperand Copper Alloys and is the direct responsibility of Subcommittee B05.07 onRefined Copper.Current edition approved April 1, 2016. Published May 2016. Originallyapproved in 1946. Last previous edition approved in 2010 as B216 10. DOI:10.1520/B0216-16.2For re
14、ferenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes section appears at the end of this standardCop
15、yright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States16.2 These composition limits do not preclude the presenceof other elements. By agreement between the manufacturer andpurchaser, limits may be established and analysis required forunnamed el
16、ements.7. Dimensions, Mass, and Permissible Variations7.1 A permissible variation of 65 % in weight and 614 in.(6.35 mm) in any dimension from the manufacturers pub-lished list or the purchasers specified size shall be consideredgood delivery; provided, however, that cakes may vary 63%from the liste
17、d or specified size in any dimension greater than8 in. (203.2 mm). The weight of copper in ingots and ingot barsshall not exceed that specified by more than 10 %, butotherwise its variation is not important.8. Workmanship, Finish, and Appearance8.1 Shapes intended for fabrication shall be substantia
18、llyfree of shrink holes, cold sets, pits, sloppy edges, concave tops,and similar defects in set or casting. This requirement shall notapply to ingots or ingot bars, in which physical defects are ofno consequence.9. Sampling9.1 For routine sampling, the sampling practice shall be atthe discretion of
19、the sampler.9.2 In case of dispute the lot size, portion size, and selectionof pieces shall be as follows:9.2.1 Lot SizeAn inspection lot shall consist of all piecesthe same shape and size from the same production lot orfraction thereof.9.2.2 Portion SizeThe portion shall be four or more piecesrando
20、mly selected to be representative of the lot. Should the lotconsist of less than five pieces, each piece shall be sampled.9.3 Chemical Analysis:9.3.1 In case of dispute the sample for chemical analysisshall be taken from the pieces selected in 9.2.2 and combinedinto one composite sample in accordanc
21、e with Practice E255for a product in its final form. The minimum weight of thecomposite sample shall be 150 g.9.3.2 Instead of sampling in accordance with 9.2.2, themanufacturer shall have the option of taking samples at thetime the castings are poured.9.3.2.1 When composition of the material has be
22、en deter-mined during the course of manufacture, sampling of thefinished product by the manufacturer is not required.9.3.3 The number of samples to be taken for determinationof chemical composition shall be as follows:9.3.3.1 When sampled at the time the castings are poured, atleast two samples, one
23、 soon after the start of the pour and onenear the end of the pour, shall be taken for each group ofcastings poured from the same source of molten metal.10. Number of Tests and Retests10.1 TestsThe chemical composition shall be determinedas the average of results obtained from at least two replicatea
24、nalyses for each specified element.10.2 Retests:10.2.1 When requested by the manufacturer or supplier, aretest shall be permitted when test results obtained by thepurchaser fail to conform with the product specification re-quirement(s).10.2.2 Retesting shall be as directed in the product specifi-cat
25、ion for the initial test except for the number of testspecimens which shall be twice that required for the originaltest. Test results for all specimens shall conform to the productspecification requirement(s) in retest and failure to complyshall be cause for lot rejection.11. Specimen Preparation11.
26、1 The preparation of the analytical specimen is theresponsibility of the reporting laboratory.12. Test Methods12.1 For routine analysis, the method of analysis shall be atthe discretion of the reporting laboratory.12.2 In case of dispute concerning copper content, themethod of analysis shall be in a
27、ccordance with Test MethodE53.12.3 In case of dispute concerning antimony, arsenic,bismuth, lead, nickel, selenium, or tellurium content, themethod of analysis shall be by electrothermal atomizationatomic absorption spectrometry as described in the Annex.12.4 Test method(s) for the determination of
28、element(s)resulting from contractual or purchase order agreement shall beas agreed upon between the manufacturer or supplier and thepurchaser.13. Significance of Numerical Limits13.1 Calculated values shall be rounded to the nearest unitin the last right-hand significant digit used in expressing the
29、limiting value in accordance with the rounding method inPractice E29.14. Inspection14.1 The manufacturer, or supplier, shall inspect and maketests necessary to verify the furnished product conforms to thespecification requirements.15. Rejection and Rehearing15.1 Rejection:15.1.1 Product that fails t
30、o conform to the specificationrequirements when tested by the purchaser or purchasers shallbe subject to rejection.TABLE 1 Chemical RequirementsAElement Composition, %Copper (including silver), min 99.88Arsenic, max 0.012Antimony, max 0.003Bismuth, max 0.003Lead, max 0.004Nickel, max 0.050Selenium +
31、 Tellurium, max 0.025AAnalytical variance is not incorporated into the specified limits. Refer to 10.1.B216 16215.1.2 Rejection shall be reported to the manufacturer, orsupplier, promptly. In addition, a written notification of rejec-tion shall follow.15.1.3 In case of dissatisfaction with the resul
32、ts of the testupon which rejection was based, the manufacturer, or suppliermay make claim for a rehearing.15.2 RehearingAs a result of product rejection, themanufacturer, or supplier shall have the option to make claimfor a retest to be conducted by the manufacturer, or supplier,and the purchaser. S
33、amples of the rejected product shall betaken in accordance with the product specification and sub-jected to test by both parties using the test method(s) specifiedin the product specification, or, alternatively, upon agreementby both parties, an independent laboratory may be selected forthe tests us
34、ing the test method(s) specified in the productspecification.16. Certification16.1 When specified in the purchase order or contract, thepurchaser shall be furnished certification that samples repre-senting each lot have been tested and inspected as directed inthe product specification and the requir
35、ements have been met.17. Test Report17.1 When specified in the contract or purchase order, areport of test results shall be furnished.18. Product Marking18.1 All shapes intended for fabrication shall be identifiedwith the producers brand, furnace charge, or other identifyingnumber.18.2 Ingots and in
36、got bars shall have a brand identificationbut need have no other number.19. Packaging and Package Marking19.1 Packaging:19.1.1 The product shall be separated by size and compo-sition and prepared for shipment by common carrier in such amanner to afford protection from the normal hazards oftransporta
37、tion.19.2 Package Marking:19.2.1 Each shipping unit shall be legibly marked with thepurchase order number, metal or alloy designation, size, shape,gross and net weight, and name of supplier.19.2.2 When specified in the contract or purchase order, theproduct specification number shall be shown.20. Ke
38、ywords20.1 fire refined copper; refinery shapes; tough pitch copperSUPPLEMENTARY REQUIREMENTSThe following supplementary requirements shall apply only when specified by the purchaser in theinquiry, contract, or order, for agencies of the U.S. government.S1. Referenced DocumentsS1.1 The following doc
39、uments of the issue in effect on dateof material purchase form a part of this specification to theextent referenced herein:S1.1.1 ASTM Standard:B900, Practice for Packaging of Copper and Copper AlloyMill Products for U.S. Government AgenciesS1.1.2 Federal Standards:3Fed. Std. No. 102 Preservation, P
40、ackaging and PackingLevelsFed. Std. No. 123 Marking for Shipment (Civil Agencies)Fed. Std. No. 185 Identification Marking of Copper andCopper-Base Alloy Mill ProductsS1.1.3 Military Standard:3MIL-STD-129 Marking for Shipment and StorageS2. Quality AssuranceS2.1 Responsibility for InspectionUnless ot
41、herwise speci-fied in the contract or purchase order, the manufacturer isresponsible for the performance of all inspection and testrequirements specified. Except as otherwise specified in thecontract or purchase order, the manufacturer may use his ownor any other suitable facilities for the performa
42、nce of theinspection and test requirements unless disapproved by thepurchaser at the time the order is placed. The purchaser shallhave the right to perform any of the inspections or tests setforth when such inspections and tests are deemed necessary toensure that the material conforms to prescribed
43、requirements.S3. Identification MarkingS3.1 All material shall be properly marked for identificationin accordance with Fed. Std. No. 185 except that the ASTMspecification number and the alloy number shall be used.S4. Preparation for DeliveryS4.1 Preservation, Packaging, Packing:S4.1.1 Military Agenc
44、iesThe material shall be separatedby size, composition, grade, or class and shall be preserved andpackaged, Level A or C, packed, Level A, B, or C as specifiedin the contract or purchase order, in accordance with therequirements of B900.S4.1.2 Civil AgenciesThe requirements of Fed. Std. No.102 shall
45、 be referenced for definitions of the various levels ofpackaging protection.S4.2 Marking:3Available from DLA Document Services, Building 4/D, 700 Robbins Ave.,Philadelphia, PA 19111-5094, http:/quicksearch.dla.mil.B216 163S4.2.1 Military AgenciesIn addition to any special mark-ing required by the co
46、ntract or purchase order, marking forshipment shall be in accordance with MIL-STD-129.S4.2.2 Civil AgenciesIn addition to any special markingrequired by the contract or purchase order, marking forshipment shall be in accordance with Fed. Std. No. 123.ANNEX(Mandatory Information)A1. TEST METHOD FOR D
47、ETERMINATION OF COMPLIANCE WITH CHEMICAL COMPOSITIONAL REQUIREMENTFOR ANTIMONY, ARSENIC, BISMUTH, LEAD, NICKEL, SELENIUM, AND TELLURIUM IN SPECIFICATION B216 BYELECTROTHERMAL ATOMIZATION ATOMIC ABSORPTION SPECTROMETRYA1.1. ScopeA1.1.1 This test method covers the analysis of antimony,arsenic, bismuth
48、 lead, nickel, selenium, and tellurium intough-pitch fire-refined copper.A1.1.2 UnitsThe values stated in SI units are to beregarded as standard. No other units of measurement areincluded in this standard.A1.1.3 This standard may involve hazardous materials,operations, and equipment. This standard
49、does not purport toaddress all of the safety concerns associated with its use. It isthe responsibility of the user of this standard to establishappropriate safety and health practices and determine theapplicability of regulatory limitations prior to use.A1.2. Summary of Test MethodA1.2.1 The test sample is dissolved in nitric acid and thesolution diluted to a known volume. An aliquot is introducedinto an electrothermal atomic absorption spectrometer, withbackground correction capability. The absorbance of the reso-nance line energy from the spectrum of the element
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