ASTM B265-2008a Standard Specification for Titanium and Titanium Alloy Strip Sheet and Plate.pdf

1、Designation: B 265 08aStandard Specification forTitanium and Titanium Alloy Strip, Sheet, and Plate1This standard is issued under the fixed designation B 265; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revisio

2、n. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This specification2covers annealed titanium and t

3、ita-nium alloy strip, sheet, and plate as follows:1.1.1 Grade 1Unalloyed titanium,1.1.2 Grade 2Unalloyed titanium,1.1.2.1 Grade 2HUnalloyed titanium (Grade 2 with 58ksi minimum UTS),1.1.3 Grade 3Unalloyed titanium,1.1.4 Grade 4Unalloyed titanium,1.1.5 Grade 5Titanium alloy (6 % aluminum, 4 % vana-di

4、um),1.1.6 Grade 6Titanium alloy (5 % aluminum, 2.5 % tin),1.1.7 Grade 7Unalloyed titanium plus 0.12 to 0.25 %palladium,1.1.7.1 Grade 7HUnalloyed titanium plus 0.12 to 0.25 %palladium (Grade 7 with 58 ksi minimum UTS),1.1.8 Grade 9Titanium alloy (3.0 % aluminum, 2.5 %vanadium),1.1.9 Grade 11Unalloyed

5、 titanium plus 0.12 to 0.25 %palladium,1.1.10 Grade 12Titanium alloy (0.3 % molybdenum,0.8 % nickel),1.1.11 Grade 13Titanium alloy (0.5 % nickel, 0.05 %ruthenium),1.1.12 Grade 14Titanium alloy (0.5 % nickel, 0.05 %ruthenium),1.1.13 Grade 15Titanium alloy (0.5 % nickel, 0.05 %ruthenium),1.1.14 Grade

6、16Unalloyed titanium plus 0.04 to 0.08 %palladium,1.1.14.1 Grade 16HUnalloyed titanium plus 0.04 to0.08 % palladium (Grade 16 with 58 ksi minimum UTS),1.1.15 Grade 17Unalloyed titanium plus 0.04 to 0.08 %palladium,1.1.16 Grade 18Titanium alloy (3 % aluminum, 2.5 %vanadium) plus 0.04 to 0.08 % pallad

7、ium,1.1.17 Grade 19Titanium alloy (3 % aluminum, 8 %vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum),1.1.18 Grade 20Titanium alloy (3 % aluminum, 8 %vanadium, 6 % chromium, 4 % zirconium, 4 % molybdenum)plus 0.04 % to 0.08 % palladium,1.1.19 Grade 21Titanium alloy (15 % molybdenum, 3 %aluminum

8、, 2.7 % niobium, 0.25 % silicon),1.1.20 Grade 23Titanium alloy (6 % aluminum, 4 %vanadium with extra low interstitial elements, ELI),1.1.21 Grade 24Titanium alloy (6 % aluminum, 4 %vanadium) plus 0.04 % to 0.08 % palladium,1.1.22 Grade 25Titanium alloy (6 % aluminum, 4 %vanadium) plus 0.3 % to 0.8 %

9、 nickel and 0.04 % to 0.08 %palladium,1.1.23 Grade 26Unalloyed titanium plus 0.08 to 0.14 %ruthenium,1.1.23.1 Grade 26HUnalloyed titanium plus 0.08 to0.14 % ruthenium (Grade 26 with 58 ksi minimum UTS),1.1.24 Grade 27Unalloyed titanium plus 0.08 to 0.14 %ruthenium,1.1.25 Grade 28Titanium alloy (3 %

10、aluminum, 2.5 %vanadium) plus 0.08 to 0.14 % ruthenium,1.1.26 Grade 29Titanium alloy (6 % aluminum, 4 %vanadium with extra low interstitial elements, ELI) plus 0.08 to0.14 % ruthenium,1.1.27 Grade 30Titanium alloy (0.3 % cobalt, 0.05 %palladium),1.1.28 Grade 31Titanium alloy (0.3 % cobalt, 0.05 %pal

11、ladium),1.1.29 Grade 32Titanium alloy (5 % aluminum, 1 % tin,1 % zirconium, 1 % vanadium, 0.8 % molybdenum),1.1.30 Grade 33Titanium alloy (0.4 % nickel, 0.015 %palladium, 0.02 5 % ruthenium, 0.15 % chromium),1.1.31 Grade 34Titanium alloy (0.4 % nickel, 0.015 %palladium, 0.025 % ruthenium, 0.15 % chr

12、omium),1.1.32 Grade 35Titanium alloy (4.5 % aluminum, 2 %molybdenum, 1.6 % vanadium, 0.5 % iron, 0.3 % silicon),1.1.33 Grade 36Titanium alloy (45 % niobium),1.1.34 Grade 37Titanium alloy (1.5 % aluminum), and1.1.35 Grade 38Titanium alloy (4 % aluminum, 2.5 %vanadium, 1.5 % iron).NOTE 1H grade materi

13、al is identical to the corresponding numericgrade (that is, Grade 2H = Grade 2) except for the higher guaranteed1This specification is under the jurisdiction of ASTM Committee B10 onReactive and Refractory Metals and Alloys and is the direct responsibility ofSubcommittee B10.01 on Titanium.Current e

14、dition approved Aug. 1, 2008. Published August 2008. Originallyapproved in 1952. Last previous edition approved in 2008 as B 265 08.2For ASME Boiler and Pressure Vessel Code applications see related Specifi-cations SB-265 in Section II of that Code.1Copyright ASTM International, 100 Barr Harbor Driv

15、e, PO Box C700, West Conshohocken, PA 19428-2959, United States.minimum UTS, and may always be certified as meeting the requirementsof its corresponding numeric grade. Grades 2H, 7H, 16H, and 26H areintended primarily for pressure vessel use.The H grades were added in response to a user association

16、request basedon its study of over 5200 commercial Grade 2, 7, 16, and 26 test reports,where over 99 % met the 58 ksi minimum UTS.1.2 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that are provided for info

17、rmation onlyand are not considered standard.2. Referenced Documents2.1 ASTM Standards:3E8 Test Methods for Tension Testing of Metallic MaterialsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE 190 Test Method for Guided Bend Test for Ductility ofWel

18、dsE 539 Test Method for X-Ray Fluorescence SpectrometricAnalysis of 6Al-4V Titanium AlloyE 1409 Test Method for Determination of Oxygen andNitrogen in Titanium and Titanium Alloys by the Inert GasFusion TechniqueE 1447 Test Method for Determination of Hydrogen inTitanium and Titanium Alloys by the I

19、nert Gas FusionThermal Conductivity/Infrared Detection MethodE 1941 Test Method for Determination of Carbon in Refrac-tory and Reactive Metals and Their AlloysE 2371 Test Method for Analysis of Titanium and TitaniumAlloys by Atomic Emission Plasma SpectrometryE 2626 Guide for Spectrometric Analysis

20、of Reactive andRefractory Metals3. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 Any product 0.187 in. (4.75 mm) and under inthickness and less than 24 in. (610 mm) in width is classifiedas strip; products 0.187 in. (4.75 mm) and under in thicknessand 24 in. (610 mm) or more in

21、 width are classified as sheet;any product over 0.187 in. (4.75 mm) in thickness and over 10in. (254 mm) in width is classified as plate.4. Ordering Information4.1 Orders for materials under this specification shall in-clude the following information as applicable:4.1.1 Grade number (Section 1),4.1.

22、2 Product limitations (Section 3),4.1.3 Special mechanical properties (Table 1),4.1.4 Marking (Section 16),4.1.5 Finish (Section 8),4.1.6 Packaging (Section 16),4.1.7 Required reports (Section 15), and4.1.8 Disposition of rejected material (Section 14).5. Chemical Composition5.1 The grades of titani

23、um and titanium alloy metal coveredby this specification shall conform to the chemical compositionrequirements prescribed in Table 2.5.1.1 The elements listed in Table 2 are intentional alloyadditions or elements which are inherent to the manufacture oftitanium sponge, ingot or mill product.5.1.1.1

24、Elements other than those listed in Table 2 aredeemed to be capable of occurring in the grades listed in Table2 by and only by way of unregulated or unanalyzed scrapadditions to the ingot melt. Therefore, product analysis forelements not listed in Table 2 shall not be required unlessspecified and sh

25、all be considered to be in excess of the intentof this specification.5.1.2 Elements intentionally added to the melt must beidentified, analyzed, and reported in the chemical analysis.5.2 When agreed upon by producer and purchaser andrequested by the purchaser in his written purchase order,chemical a

26、nalysis shall be completed for specific residualelements not listed in this specification.5.3 Product AnalysisProduct analysis tolerances do notbroaden the specified heat analysis requirements but covervariations between laboratories in the measurement of chemi-cal content. The manufacturer shall no

27、t ship material that isoutside the limits specified in Table 2 for the applicable grade.Product analysis limits shall be as specified in Table 3.5.4 At least two samples for chemical analysis shall betested to determine chemical composition. Samples shall betaken from the ingot or the extremes of th

28、e product to beanalyzed.6. Mechanical Properties6.1 Material supplied under this specification shall conformto the mechanical property requirements given in Table 1 forthe grade specified.6.2 Tension testing specimens are to be machined and testedin accordance with Test Methods E8. Tensile propertie

29、s shallbe determined using a strain rate of 0.003 to 0.007 in./in./minthrough the specified yield strength, and then increasing therate so as to produce failure in approximately one additionalminute.6.3 For sheet and strip, the bend test specimen shall with-stand being bent cold through an angle of

30、105 without fracturein the outside of the bent portion. The bend shall be made ona diameter equal to that shown in Table 1 for the applicablegrade.7. Permissible Variations in Dimensions7.1 Dimensional tolerances on titanium and titanium alloymaterial covered by this specification shall be as specif

31、ied inTables 4-13, as applicable.8. Finish8.1 Titanium and titanium alloy sheet, strip, and plate shallbe free of injurious external and internal imperfections of anature that will interfere with the purpose for which it isintended. Annealed material may be furnished as descaled, assandblasted, or a

32、s ground, or both sandblasted and ground. If3For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.B 265 08a2shipped

33、 as descaled, sandblasted, or ground, the manufacturershall be permitted to remove minor surface imperfections byspot grinding if such grinding does not reduce the thickness ofthe material below the minimum permitted by the tolerance forthe thickness ordered.9. Sampling for Chemical Analysis9.1 Samp

34、les for chemical analysis shall be representative ofthe material being tested. The utmost care must be used insampling titanium for chemical analysis because of its greataffinity for elements such as oxygen, nitrogen, and hydrogen.Therefore, in cutting samples for analysis, the operation shouldbe ca

35、rried out insofar as possible in a dust-free atmosphere.Chips should be collected from clean metal and tools should beclean and sharp. Samples for analysis should be stored insuitable containers.10. Methods of Chemical Analysis10.1 The chemical analysis shall normally be conductedusing theASTM stand

36、ard test methods referenced in 2.1. Otherindustry standard methods may be used where the ASTM testmethods in 2.1 do not adequately cover the elements in thematerial or by agreement between the producer and purchaser.Alternate techniques are discussed in Guide E 2626.TABLE 1 Tensile RequirementsAGrad

37、eTensile Strength, min Yield Strength, 0.2 % OffsetElongation in2 in. or 50 mm,min, %Bend TestBksi MPamin max Under 0.070 in.(1.8 mm) inThickness0.070 to 0.187 in.(1.84.75 mm) inThicknessksi MPa ksi MPa1 35 240 20 138 45 310 24 3T 4T2 50 345 40 275 65 450 20 4T 5T2HC,D58 400 40 275 65 450 20 . .3 65

38、 450 55 380 80 550 18 4T 5T4 80 550 70 483 95 655 15 5T 6T5 130 895 120 828 . . 10E9T 10T6 120 828 115 793 . . 10E8T 9T7 50 345 40 275 65 450 20 4T 5T7HC,D58 400 40 275 65 450 20 . .9 90 620 70 483 . . 15F5T 6T11 35 240 20 138 45 310 24 3T 4T12 70 483 50 345 . . 18 4T 5T13 40 275 25 170 . . 24 3T 4T

39、14 60 410 40 275 . . 20 4T 5T15 70 483 55 380 . . 18 4T 5T16 50 345 40 275 65 450 20 4T 5T16HC,D58 400 40 275 65 450 20 . .17 35 240 20 138 45 310 24 3T 4T18 90 620 70 483 . . 15F5T 6T19G,H115 793 110 759 . . 15 6T 6T20G,H115 793 110 759 . . 15 6T 6T21G,H115 793 110 759 . . 15 6T 6T23G,H120 828 110

40、759 . . 10 9T 10T24 130 895 120 828 . . 10 . .25 130 895 120 828 . . 10 . .26 50 345 40 275 65 450 20 4T 5T26HC,D58 400 40 275 65 450 20 . .27 35 240 20 138 45 310 24 3T 4T28 90 620 70 483 . . 15 5T 6T29 120 828 110 759 . . 10 9T 10T30 50 345 40 275 65 450 20 4T 5T31 65 450 55 380 80 550 18 4T 5T32

41、100 689 85 586 . . 10E7T 9T33 50 345 40 275 65 450 20 4T 5T34 65 450 55 380 80 550 18 4T 5T35 130 895 120 828 . . 5 16T 16T36 65 450 60 410 95 655 10II37 50 345 31 215 65 450 20 4T 5T38 130 895 115 794 . . 10 8T 9TAMinimum and maximum limits apply to tests taken both longitudinal and transverse to t

42、he direction of rolling. Mechanical properties for conditions other than annealedor plate thickness over 1 in. (25 mm) may be established by agreement between the manufacturer and the purchaser.BT equals the thickness of the bend test specimen. Bend tests are not applicable to material over 0.187 in

43、. (4.75 mm) in thickness.CMaterial is identical to the corresponding numeric grade (that is, Grade 2H = Grade 2) except for the higher guaranteed minimum UTS, and may always be certifiedas meeting the requirements of its corresponding numeric grade. Grade 2H, 7H, 16H, and 26H are intended primarily

44、for pressure vessel use.DThe H grades were added in response to a user association request based on its study of over 5200 commercial Grade 2, 7, 16, and 26 test reports, where over 99 %met the 58 ksi minimum UTS.EFor Grades 5, 6 and 32 the elongation on materials under 0.025 in. (0.635 mm) in thick

45、ness may be obtained only by negotiation.FElongation for continuous rolled and annealed (strip product from coil) for Grade 9 and Grade 18 shall be 12 % minimum in the longitudinal direction and 8 % minimumin the transverse direction.GProperties for material in the solution treated condition.HMateri

46、al is normally purchased in the solution treated condition. Therefore, properties for aged material shall be negotiated between manufacturer and purchaser.IAs agreed upon between purchaser and supplier.B 265 08a3TABLE 2 Chemical RequirementsAComposition, %ElementGrade 1 Grade 2 Grade 2H Grade 3 Grad

47、e 4 Grade 5 Grade 6 Grade 7 Grade 7H Grade 9 Grade 11 Grade 12 Grade 13 Grade 14Nitrogen, max 0.03 0.03 0.03 0.05 0.05 0.05 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03Carbon, max 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08Hydrogen,B,Cmax 0.015 0.015 0.015 0.015 0.015 0.015 0.01

48、5 0.015 0.015 0.015 0.015 0.015 0.015 0.015Iron, max 0.20 0.30 0.30 0.30 0.50 0.40 0.50 0.30 0.30 0.25 0.20 0.30 0.20 0.30Oxygen, max 0.18 0.25 0.25 0.35 0.40 0.20 0.20 0.25 0.25 0.15 0.18 0.25 0.10 0.15Aluminum . . . . . 5.56.754.06.0. . 2.53.5. . . .Vanadium . . . . . 3.54.5. . . 2.03.0. . . .Tin

49、. . . . . . 2.03.0. . . . . . .Ruthenium . . . . . . . . . . . . 0.040.060.040.06Palladium . . . . . . . 0.120.250.120.25. 0.120.25. . .Cobalt . . . . . . . . . . . . . .Molybdenum . . . . . . . . . . 0.20.4. .Chromium . . . . . . . . . . . . . .Nickel . . . . . . . . . . . 0.60.90.40.60.40.6Niobium . . . . . . . . . . . . . .Zirconium . . . . . . . . . . . . . .Silicon . . . . . . . . . . . . . .Residuals,D,E,Fmax each0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1Residuals,D,E,Fmax total0.4 0.4 0.4 0.4 0.4 0.4 0.4