1、Designation: B367 13Standard Specification forTitanium and Titanium Alloy Castings1This standard is issued under the fixed designation B367; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in par
2、entheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification covers titanium and titanium alloycastings inte
3、nded for general corrosion resistant and industrialapplications. as follows:1.1.1 Grade C-2UNS R52550. Unalloyed titanium,1.1.2 Grade C-3UNS R52550. Unalloyed titanium,1.1.3 Grade C-5UNS R56400. Titanium alloy (6 %aluminum, 4 % vanadium),1.1.4 Grade C-7UNS R52700. Unalloyed titanium plus0.12 to 0.25
4、 % palladium,1.1.5 Grade C-8UNS R52700. Unalloyed titanium plus0.12 to 0.25 % palladium,1.1.6 Grade C-9UNS R56320. Titanium alloy (3 %aluminum, 2.5 % vanadium),1.1.7 Grade C-12UNS R53400. Titanium alloy (0.3 %molybdenum, 0.8 % nickel),1.1.8 Grade C-16UNS R52402. Unalloyed titanium plus0.04 to 0.08 %
5、 palladium,1.1.9 Grade C-17UNS R52252. Unalloyed titanium plus0.04 to 0.08 % palladium, and1.1.10 Grade C-38UNS R54250. Titanium alloy (4 %aluminum, 2.5 % vanadium, 1.5 % iron).1.2 This specification is intended for use of purchasersand/or producers of reactive metal castings for defining therequire
6、ments and assuring the properties of castings for uniquecorrosion-resistant applications, that is, not for commodityitems which must meet all potential purchasers requirements.1.2.1 Users are advised to use the specification as a basis forobtaining castings which will meet minimum acceptancerequirem
7、ents established and revised by consensus of themembers of the committee.1.2.2 User requirements considered more stringent may bemet by the addition to the purchase order of one or moresupplementary requirements, which may include, but are notlimited to, those listed in Sections S1 through S8.1.3 Th
8、e values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that are provided for information onlyand are not considered standard.2. Referenced Documents2.1 ASTM Standards:2A802/A802M Practice for Steel Castings, Surface
9、Accep-tance Standards, Visual ExaminationE8 Test Methods for Tension Testing of Metallic MaterialsE10 Test Method for Brinell Hardness of Metallic MaterialsE18 Test Methods for Rockwell Hardness of Metallic Ma-terialsE29 Practice for Using Significant Digits in Test Data toDetermine Conformance with
10、 SpecificationsE94 Guide for Radiographic ExaminationE142 Method for Controlling Quality of Radiographic Test-ing (Withdrawn 2000)3E165 Practice for Liquid Penetrant Examination for GeneralIndustryE446 Reference Radiographs for Steel Castings Up to 2 in.(50.8 mm) in ThicknessE539 Test Method forAnal
11、ysis of TitaniumAlloys by X-RayFluorescence SpectrometryE1409 Test Method for Determination of Oxygen and Nitro-gen in Titanium and Titanium Alloys by the Inert GasFusion TechniqueE1447 Test Method for Determination of Hydrogen in Tita-nium and Titanium Alloys by Inert Gas Fusion ThermalConductivity
12、/Infrared Detection MethodE1941 Test Method for Determination of Carbon in Refrac-tory and Reactive Metals and TheirAlloys by CombustionAnalysisE2371 Test Method for Analysis of Titanium and TitaniumAlloys by Direct Current Plasma and Inductively CoupledPlasma Atomic Emission Spectrometry (Performan
13、ce-Based Test Methodology)1This specification is under the jurisdiction of ASTM Committee B10 onReactive and Refractory Metals and Alloys and is the direct responsibility ofSubcommittee B10.01 on Titanium.Current edition approved July 1, 2013. Published August 2013. Originallyapproved in 1961. Last
14、previous edition approved in 20098 as B367 09. DOI:10.1520/B0367-13.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM w
15、ebsite.3The last approved version of this historical standard is referenced onwww.astm.org.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1E2626 Guide for Spectrometric
16、Analysis of Reactive andRefractory Metals3. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 lot, nshall consist of all castings of the same designproduced from the same pour.3.1.2 pour, nshall consist of all material melted and cast atone time.4. Ordering Information4.1 Orders fo
17、r castings to this specification shall include thefollowing as required, to describe the requirements adequately:4.1.1 Description of the castings by pattern number ordrawing. Dimensional tolerances shall be included on thecasting drawing,4.1.2 Quantity,4.1.3 Grade designation (see Table 1),4.1.4 Op
18、tions in the specification, and4.1.5 Supplementary requirements desired, including thestandards of acceptance.5. Materials and Manufacture5.1 Materials for this specification shall be melted byconventional processes used for reactive metals. Typical meth-ods include the consumable electrode and indu
19、ction-slag,plasma arc, induction-skull, and electron beam melting pro-cesses.6. Chemical Composition6.1 Pour AnalysisAn analysis of each pour shall be madeby the producer from a sample such as a casting or test bar thatis representative of the pour. The chemical composition deter-mined shall conform
20、 to the requirements specified for therelevant grade in Table 1.6.1.1 The elements listed in Table 1 are intentional alloyadditions or elements which are inherent to the manufacture oftitanium sponge, ingot or mill product.6.1.1.1 Elements other than those listed in Table 1 aredeemed to be capable o
21、f occurring in the grades listed in Table1 by and only by way of unregulated or unanalyzed scrapadditions to the ingot melt. Therefore product analysis forelements not listed in Table 1 shall not be required unlessspecified and shall be considered to be in excess of the intentof this specification.6
22、.1.2 Elements intentionally added to the melt must beidentified, analyzed, and reported in the chemical analysis.6.2 When agreed upon by the producer and the purchaserand requested by the purchaser in his written purchase order,chemical analysis shall be completed for specific residualelements not l
23、isted in this specification.6.3 Product AnalysisProduct analysis tolerances do notbroaden the specified heat analysis requirements, but covervariations between laboratories in the measurement of chemi-cal content. The producer shall not ship material which isoutside the limits specified in Table 1 f
24、or the applicable grade.Product analysis limits shall be as specified in Table 2.6.4 SamplingSamples for chemical analysis may be madeby the purchaser on a representative casting from any lot. Dueto the possibility of oxygen or other interstitial contamination,samples for oxygen, carbon, hydrogen, a
25、nd nitrogen analysisshall be taken no closer than14 in. (6.3 mm) to a cast surfaceexcept that castings too thin for this shall be analyzed onrepresentative material. The chemical composition determinedshall conform to the analysis in Table 1 within the checkanalysis variations shown in Table 2 or sh
26、all be subject torejection by the purchaser.7. Heat Treatment7.1 Unless otherwise specified in the contract, all castingswill be supplied in the as-cast condition except when post-weldheat treatment is required.7.2 If post-weld heat treatment is required, it shall consist ofa stress relief performed
27、 at 1075 6 25F (580 6 14C) forGrades C-2, C-3, C-7, C-8, C-12, C-16 and C-17, and 1200 625F (650 6 14C) for Grades C-5, C-6, C-9, C-18, and C-38.Time at temperature shall be a minimum of12 h plus anadditional12 h at temperature per inch of thickness for sectionsizes greater than 1 in. (25 mm). After
28、 heat treatment, thecastings should be cooled in air or in the furnace to ambienttemperature unless otherwise agreed upon between the pur-chaser and producer.8. Methods of Chemical Analysis8.1 The chemical analysis shall normally be conductedusing theASTM standard test methods referenced in 2.1. Oth
29、erindustry standard methods may be used where the ASTM testmethods in 2.1 do not adequately cover the elements in thematerial or by agreement between the producer and purchaser.Alternate techniques are discussed in Guide E2626.9. Workmanship, Finish, and Appearance9.1 All castings shall be made in a
30、 workman-like mannerand shall conform to the dimensions in drawings furnished bythe purchaser before manufacturing is started. If the pattern issupplied by the purchaser, the dimensions of the casting shallbe as predicted by the pattern.9.2 The surface of the casting shall be free of adhering moldma
31、terial, scale, cracks, and hot tears as determined by visualexamination. Other surface discontinuities shall meet the visualacceptance standards specified in the order. Practice A802/A802M or other visual standards may be used to defineacceptable surface discontinuities and finish. Unacceptablesurfa
32、ce discontinuities shall be removed and their removalverified by visual examination of the resultant cavities.10. Repair by Welding10.1 If repairs are required, these shall be made using awelding procedure and operators certified to quality require-ments established by the producer. The procedures d
33、evelopedshall be consistent with standard practices recommended forreactive metal alloys. The producer shall maintain documenta-tion on procedure and welder qualifications. Procedure modi-fications or special arrangements shall be as agreed uponbetween the producer and the purchaser.B367 132TABLE1Ch
34、emicalRequirementsComposition,WeightPercentA,B,C,D,EGradeUNSNumberCarbon,max.Oxygenrangeormax.Nitrogen,max.Hydrogen,max.Ironrangeormax.AluminumVanadiumPalladiumRutheniumNickelMolybdenumChromiumCobaltZirconiumNiobiumTinSiliconOtherElements,max. eachOtherElements,max.totalC-2R525500.100.400.050.0150.2
35、0-0.10.4C-3R525500.100.400.050.0150.25-0.10.4C-5R564000.100.250.050.0150.405.5- 6.753.5-4.5-0.10.4C-6R545200.100.200.050.0150.504.0-6.0-2.0-3.0-0.10.4C-7R527000.100.400.050.0150.20-0.12-0.25-0.10.4C-8R527000.100.400.050.0150.25-0.12-0.25-C-9R563200.100.200.050.0150.252.5-3.52.0-3.0-C-12R534000.100.2
36、50.050.0150.30-0.6-0.90.2-0.4-0.10.4C-16R524020.100.180.030.0150.30-0.04-0.08-0.10.4C-17R522520.100.200.030.0150.25-0.04-0.08-0.10.4C-18R584650.080.200.030.0150.252.5-3.52.0-3.00.04-0.08-0.10.4C-38R542500.080.20-0.300.030.0151.2-1.83.5-4.52.0-3.0-0.10.4AAtminimum,onepouranalysisshallbecompletedandre
37、portedforallelementslistedfortherespectivegradeinthistable.BIfthecastingissubjectedtothermalorchemicalprocessingfollowingthepour,finalproducthydrogenshallbereportedinlieuofpourhydrogen.Lowerhydrogenmaybeobtainedbynegotiationwiththemanufacturer.CSinglevaluesaremaximum.Thepercentageoftitaniumisdetermi
38、nedbydifference.DOtherelementsneednotbereportedunlesstheconcentrationlevelisgreaterthan0.1%each,or0.4%total.Otherelementsmaynotbeaddedintentionally.Otherelementsmaybepresentintitaniumortitaniumalloysinsmallquantitiesandareinherenttothemanufacturingprocess.Intitaniumtheseelementstypicallyincludealumi
39、num,vanadium,tin,chromium,molybdenum,niobium,zirconium,hafnium,bismuth,ruthenium,palladium,yttrium,copper,silicon,cobalt,tantalum,nickel,boron,manganese,andtungsten.EThepurchasermay,inthewrittenpurchaseorder,requestanalysisforspecificelementsnotlistedinthisspecification.B367 13310.2 The composition
40、of the deposited weld metal shall bewithin the chemical requirements for each grade established inTable 1.10.2.1 Unalloyed titanium Grades C-2 and C-3, and low-alloy Grades C-12, C-7, C-8, C-16, and C-17 castings shall bestress-relieved if the repair is considered capable of addingstresses that will
41、 interfere with the purpose for which thecastings are intended. The decision for stress relieving shall bemade by the producer, unless otherwise agreed upon. Thestress-relief cycle shall be in accordance with 7.2 followed byair or furnace cooling to room temperature, or as agreed uponbetween the pur
42、chaser and the producer.10.2.2 Grade C-5 (Ti-6Al-4V), Grade C-6 (Ti-5Al-2.5Sn),Grade C-9, Grade C-18, and C-38 castings shall be stress-relieved after weld repair, if the weld defect or excavation isthrough a wall or exceeds 1 in.3(16.4 cm3) of deposited metal.All welds on Grade C-12 (Ti-.3Mo-.8Ni)
43、castings shall bestress-relieved after weld repair. The stress-relief cycle shall bein accordance with 7.2.10.2.3 Hot isostatic pressing (HIP) may be substituted forrequired thermal treatment provided all requirements for thattreatment are met, and temperatures detrimental to the materialproperties
44、are not reached.11. Referee Test and Analysis11.1 In the event of disagreement between the manufacturerand the purchaser on the conformance of the material to therequirements of this specification, a mutually acceptable ref-eree shall perform the tests in question using the ASTMstandard methods in 2
45、.1. The referees testing shall be used indetermining conformance of the material to this specification.12. Inspection12.1 The producer shall afford the purchasers inspector allreasonable facilities necessary to satisfy him that the materialis being produced and furnished in accordance with thisspeci
46、fication. Foundry inspection by the purchaser shall notinterfere unnecessarily with the producers operations.12.2 If the results of any chemical or mechanical propertytest lot are not in conformance with the requirements of thisspecification, the lot may be retested at the option of theproducer. The
47、 frequency of the retest will double the initialnumber of tests. If the results of the retest conform to thespecification, then the retest values will become the test valuesfor certification. Only original conforming test results or theconforming retest results shall be reported to the purchaser. Ifthe results for the retest fail to conform to the specification, thematerial will be rejected in
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