ASTM B727-2004(2009) Standard Practice for Preparation of Plastics Materials for Electroplating《电镀用塑料材料制备标准》.pdf

1、Designation: B727 04 (Reapproved 2009)Standard Practice forPreparation of Plastics Materials for Electroplating1This standard is issued under the fixed designation B727; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of l

2、ast revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This practice is a guide to the surface preparation ofplastic materials for decorative and functional electroplating,wh

3、ere the sequence of chemical treatments may include:cleaning, conditioning, etching, neutralizing, catalyzing, accel-erating, and autocatalytic metal deposition. Surface preparationalso includes electrodeposition of metallic strike coatingsimmediately after autocatalytic metal deposition. These trea

4、t-ments result in the deposition of thin conductive metal films onthe surface of molded-plastic materials, and are described inthis practice.1.2 Once molded-plastics materials have been made con-ductive, they may be electroplated with a metal or combinationof metals in conventional electroplating so

5、lutions. The electro-plating solutions and their use are beyond the scope of thispractice.1.3 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.1.4 This standard does not purport to address all of thesafety concerns, if any, asso

6、ciated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use. (See Section 4.)2. Referenced Documents2.1 ASTM Standards:2B532 Specification for Appearance of Ele

7、ctroplated PlasticSurfacesB533 Test Method for Peel Strength of Metal ElectroplatedPlasticsB553 Test Method for Thermal Cycling of ElectroplatedPlastics3B604 Specification for Decorative Electroplated Coatingsof Copper Plus Nickel Plus Chromium on Plastics3. Significance and Use3.1 A variety of meta

8、ls can be electrodeposited on plasticsfor decorative or engineering purposes. The most widely usedcoating consists of three layerscopper plus nickel pluschromiumfor decorative applications. However, brass, sil-ver, tin, lead, cadmium, zinc, gold, other metals, and combi-nations of these are used for

9、 special purposes. The key toproducing electroplated plastics of high quality lies in the caretaken in preparing plastics for electroplating. The informationcontained in this practice is useful in controlling processes forthe preparation of plastics for electroplating.4. Hazards4.1 Some chemical sol

10、utions are exothermic upon mixing orin use, thereby requiring cooling and proper containment toprevent injury to personnel.4.2 For details on the proper operation and safety precau-tions to be followed by vapor degreasing, seeASTM STP 310.45. General Considerations5.1 Nature of Plastics Suitable for

11、 Electroplating:5.1.1 Plastics suitable for electroplating may be a combina-tion of one or more polymers so formulated as to allowselective etching of one or more constituents. The mostcommonly electroplated material, acrylonitrile-butadiene-styrene (ABS), is a terpolymer. During etching, soft butad

12、ienerubber particles dispersed in the acrylonitrile-styrene matrixare selectively attacked. The microscopic pockets formed bythe etching process provide sites for the physical interlockingof the plastic substrate and subsequently applied metalliccoatings. The resultant mechanical bonding is instrume

13、ntal inachieving metal to plastic adhesion.5.2 Plastics Suitable for Electroplating:5.2.1 The plastics materials commonly used for injectionmolded articles to be electroplated are:5.2.1.1 Acrylonitrile-butadiene-styrene (ABS),5.2.1.2 Polypropylene,5.2.1.3 Polysulfone,5.2.1.4 Modified Polyphenylene O

14、xide,5.2.1.5 Polycarbonate,1This practice is under the jurisdiction of ASTM Committee B08 on Metallicand Inorganic Coatings and is the direct responsibility of Subcommittee B08.02 onPre Treatment.Current edition approved Sept. 1, 2009. Published December 2009. Originallyapproved in 1983. Discontinue

15、d January 2004 and reinstated in 2004 as B72704.Last previous edition approved in 2004 as B72704. DOI: 10.1520/B0727-04R09.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, re

16、fer to the standards Document Summary page onthe ASTM website.3Withdrawn.4Handbook of Vapor Degreasing, ASTM STP 310A, ASTM, 1976.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.5.2.1.6 Polyester, and5.2.1.7 Nylon.5.2.2 The preparati

17、on of these materials for electroplatinggenerally involves the basic steps described in this practice, butsubstantial variations may be necessary to achieve optimumresults with plastics other than ABS.5.3 Molding Considerations:5.3.1 The chemical nature of plastics combined with thenature of the inj

18、ection molding process produces plastic partsthat are somewhat heterogeneous in composition and structure.During the molding of ABS, for example, the shape, size, anddistribution of butadiene rubber particles may vary consider-ably within a part and may affect the uniformity of subsequentsurface etc

19、hing treatments.As a result, under- and over-etchingof the surface may occur, either of which can interfere with theadhesion of metal coatings. The use of a properly formulatedetchant combined with an organic conditioner may overcomeproblems of nonuniform etching.5.3.2 Although it may be possible to

20、 overcome problems ofnonuniform etching by suitable chemical treatments, control ofthe injection molding process is critical if plastic parts are to beelectroplated successfully. It is essential that the resin bethoroughly dried before molding. The temperature of the moldand all heating zones, the p

21、ressure, the total cycle time, and thefill time must be controlled and monitored. Devices exist forcontrolling all molding parameters precisely.5.3.3 The visible defects that may arise in the moldingprocess are described in Specification B532. Molded parts thatare obviously defective should not be p

22、rocessed without theapproval of the purchaser.5.3.4 Mold release agents interfere with the adhesion ofmetallic coatings on plastic substrates and should not be used.5.4 Process Selection:5.4.1 Due to the complexity and proprietary nature ofcommercially available processes for preparing plastics fore

23、lectroplating, a complete process should be selected for aspecific type of plastic, and operated according to the specificinstructions of the supplier of the process.5.5 Handling of Molded Plastic Parts:5.5.1 Molded-plastic parts must be kept clean and carefullyhandled. It is a common practice to us

24、e cotton gloves inremoving parts from the mold and for all subsequent handling.5.5.2 The trimming of plastic parts and the removal of flashand runners should be done with care to avoid introducingsurface defects. These and other mechanical finishing opera-tions should be completed before beginning t

25、he chemicaltreatment of parts for electroplating. Runners are sometimesleft intact to facilitate racking for electroplating at a later stage.5.6 Racking:55.6.1 Molded-plastic parts can be prepared for electroplat-ing in barrels, trays, or baskets and then transferred to racksdesigned specifically fo

26、r electroplating, or they can be pro-cessed on racks that are used in both the preparation andelectroplating cycles. Which method of racking to use may bedictated by the size of the parts, by efficiency, and otherconsiderations. The first is the bulk method; the second iscalled “through-racking.”5.6

27、2 Bulk MethodSmall parts are often processed inpolypropylene baskets or plastic-coated steel baskets. Some-what larger parts can be processed in layered baskets made ofstainless steel (UNS Types S30400 or S31600), titanium, orplastic-coated mild steel. Parts are placed as closely as possiblecompati

28、ble with the need to provide for complete solutionwetting and drainage.5.6.3 Through-Racking:5.6.3.1 The design of racks to be used in both preparationand electroplating processes is dictated by the requirements ofelectroplating and the corrosive nature of the solutions.5.6.3.2 Rack splines and hook

29、s are generally made ofcopper or copper alloys. Rack cross bars are made of copper orcopper alloys if they are to conduct current from the splines tothe contacts, but may be made of steel if their function is solelyto strengthen and make the rack rigid. Rack contacts areusually stainless steel, alth

30、ough titanium has also been used. Ifspring action is necessary, phosphor bronze may be used as thecontact member with a short stainless steel piece for the tip.5.6.3.3 The entire rack is sandblasted, primed, and coatedwith plastisol before use, except for the stainless steel contacts.During the prep

31、aration process, the rack coating may becomecoated with metal, but this does not usually occur becausehexavalent chromium is absorbed in the plastisol and preventsautocatalytic metal deposition from occurring.5.6.3.4 Control of immersion times in neutralizing, cata-lyzing, and accelerating steps is

32、critical to prevent metaldeposition on the rack coating.5.6.3.5 Parts are positioned on racks to optimize the thick-ness and appearance of electrodeposited coatings, and tominimize solution dragout.5.6.3.6 It may be necessary to use current thieves, shields,or auxiliary anodes to obtain uniform meta

33、l distribution. Thenumber of contacts is greater for plastic parts than forcomparable metal parts. For example, if the total area beingelectroplated in less than 0.02 m2, one contact point is usuallysufficient; if the area is 0.25 to 0.60 m2, 16 contact points arerecommended.5.6.3.7 Metal deposited

34、autocatalytically or electrolyticallymust be chemically removed from contacts after each cycle.This is usually accomplished by using nitric acid-containingsolutions, or proprietary rack strippers.6. Preparation of Plastic Substrates66.1 Alkaline Cleaning:6.1.1 Cleaning in alkaline solutions is optio

35、nal. If the partsare carefully handled and kept clean after molding, alkalinecleaning can usually be avoided.6.1.2 Fingerprints, grease, and other shop soil should beremoved by soaking plastic-molded parts in mild alkalinesolutions that are commercially available. A suitable solutionmay contain 25 g

36、/L of sodium carbonate and 25 g/L oftrisodium phosphate operated at 55 to 65C. Parts are im-mersed in the solution for 2 to 5 min (see Note 1).5Standards and GuidelinesElectroplated Plastics, American Society of Elec-troplated Plastics, Washington, DC, Second Edition, 1979.6Adcock, J. L., “Electropl

37、ating Plasticsan AES Illustrated Lecture,” AmericanElectroplaters Society, Inc., Winter Park, FL, 1978.B727 04 (2009)2NOTE 1Thorough rinsing after alkaline cleaning and after each of thefollowing processing steps is essential. Multiple water rinses are recom-mended.6.2 Conditioning:6.2.1 Conditionin

38、g is an optional step that precedes theetching step. Conditioning can eliminate adhesion problemsassociated with inadequate etching. The conditioner may be asolution of chromic and sulfuric acids, or it may contain anorganic solvent. Proprietary solutions are available and shouldbe operated accordin

39、g to suppliers directions.6.2.2 Chromic/Sulfuric Acid TypeThis type of conditionermay contain 30 g/L of chromic acid and 300 mL/L of sulfuricacid (93 mass %; density 1.83 g/mL) dissolved in water and ismaintained at a temperature of 60C 6 3C. Parts are im-mersed in the solution for 1 to 2 min. Becau

40、se of the relativelylarge amount of sulfuric acid in the solution, the acrylonitrile-styrene matrix, as well as the butadiene phase, are attacked.6.2.3 Organic Solvent TypeThis type of conditioner is asolution of an organic solvent in deionized water. The organicsolvent may be acetone or other keton

41、e; for example, 2,4-pentadione is sometimes used.7The solution may contain 100to 125 mL/L of the appropriate organic solvent and is main-tained at a temperature of 40 to 45C. Treatment is byimmersion of the plastic parts for 2.0 to 2.5 min (see Note 2and Note 3).NOTE 2Solutions containing volatile o

42、rganic solvents require ad-equate ventilation and must not contact metals. These materials chelateionic metal contaminants. Annealed polypropylene tanks are thereforeused to hold this type of solution.NOTE 3Multiple hot water rinses are required after using the organicsolvent-type conditioner. Becau

43、se organic solvents soften and swell theplastic surface, time of immersion and of transfer to rinse tanks may affectthe appearance of the final product, and should be controlled.6.3 Etching:6.3.1 Etchants are strong oxidizing solutions that micror-oughen and chemically alter the surface of molded pl

44、asticparts. The etching step is the most important step in achievingserviceable adhesion of metals to plastics. Commercially usedetchants are either chromic acid types, chromic/sulfuric acidtypes, or chromic-sulfuric-phosphoric acid types.6.3.2 Chromic Acid TypeConcentrated etchants usuallycontain g

45、reater than 850 g/L of chromic acid and as much as1200 g/L.8,9The temperature of the solution is maintained at 506 3C and treatment is by immersion for 8 to 10 min.Concentrated solutions of chromic acid tend to oxidize buta-diene rubber particles in the case of ABS, selectively.6.3.3 Chromic/Sulfuri

46、c Acid TypeThis type of etchantmay contain 250 to 350 g/L of chromic acid and 200 to 250mL/L of sulfuric acid (93 mass %, density 1.83 mL/L) dis-solved in water. Immersion times of 5 to 10 min at a solutiontemperature of 65 6 5C are commonly used. Several propri-etary baths are available.6.3.4 Chrom

47、ic-Sulfuric-Phosphoric Acid Type10This typeof etchant solution normally consists of 3 % by mass chromicacid, 56 % by mass sulfuric acid (density 1.83 g/mL), 10.5 %by mass phosphoric acid (density 1.87 g/mL), and the balancewater. An immersion time of about 3 min at 74 to 77C iscommonly used.6.4 Neut

48、ralizing (Sensitizing):6.4.1 After thorough rinsing, all residual chromic acid mustbe chemically removed from the surface of the molded-plasticparts. Neutralizers are used and are typically mild acid oralkaline solutions containing complexing or reducing agents.In the case of ABS, it is common to us

49、e a solution containinga mixture of an acidsalt and a reducing agent, such as sodiumbisulfite, to eliminate all traces of chromic acid. Typicalprocessing conditions are 1 to 2 min immersion at 40C.6.4.2 Neutralizers may also contain ionic surfactants toincrease the adsorption of catalyst. The use of surfactants,however, can lead to activation of the rack coating andsubsequent metal deposition on the rack. Surfactants shouldtherefore be used with caution. Ionic surfactants are notnormally used in processing ABS (see Note 4).NOTE 4Some plastics, for example, po