ASTM B921-2008 Standard Specification for Non-hexavalent Chromium Conversion Coatings on Aluminum and Aluminum Alloys《铝和铝合金上覆盖的非六价铬层的标准规范》.pdf

1、Designation: B 921 08Standard Specification forNon-hexavalent Chromium Conversion Coatings onAluminum and Aluminum Alloys1This standard is issued under the fixed designation B 921; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, th

2、e year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers the requirements relating torinsed and non-rinsed non-hexavalent chromium convers

3、ioncoatings on aluminum and aluminum alloys intended to giveprotection against corrosion and as a base for other coatings.1.2 Aluminum and aluminum alloys are conversion coatedin order to retard corrosion; as a base for organic filmsincluding paints, plastics, and adhesives; and as a protectivecoati

4、ng having a low electrical contact impedance.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regula

5、tory requirements prior to use.2. Referenced Documents2.1 ASTM Standards:2B117 Practice for Operating Salt Spray (Fog) ApparatusB 602 Test Method for Attribute Sampling of Metallic andInorganic CoatingsD 1730 Practices for Preparation of Aluminum andAluminum-Alloy Surfaces for PaintingD 3359 Test Me

6、thods for Measuring Adhesion by Tape Test2.2 ISO Standards:ISO 2409 Paint and VarnishesCross-Cut Test3ISO 3768 Metallic CoatingsNeutral Salt Spray Test (NSSTest)3ISO 4519 Electrodeposited Metallic Coatings and RelatedFinishesSampling Procedures for Inspection by At-tributes32.3 Federal Standard:Fed.

7、 Std. No. 141 Paints, Varnish, Lacquer, and RelatedMaterials; Methods of Inspection42.4 Military Specification:MIL-DTL-5541 Chemical Conversion Coatings on Alumi-num and Aluminum Alloys4MIL-DTL-81706 Chemical Conversion Materials For Coat-ing Aluminum and Aluminum Alloys43. Terminology3.1 Definition

8、s:3.1.1 non-rinsedconversion coatings that are dried imme-diately after the conversion coating step without receiving awater rinse.3.1.1.1 DiscussionThis special type of coating is typicallyused on long coils of aluminum sheet stock that receive animmediate subsequent paint or adhesive coating.NOTE

9、1Non-rinsed conversion coatings are finding increased usageon fabricated parts and castings.3.1.2 rinsedconversion coatings that are rinsed in waterprior to drying.3.1.2.1 DiscussionThis type of coating is typically ap-plied to extruded aluminum fabricated parts and castings.4. Classification4.1 A c

10、lass one conversion coating provides for maximumsalt fog corrosion protection to bare metal. A class twoconversion coating is designed to give painted salt fog corro-sion resistance and some bare salt fog corrosion resistance. Aclass three conversion coating provides little salt fog corrosionresista

11、nce, but low electrical contact resistance (see MIL-DTL-5541). Class four conversion coatings only provide for paintedsalt fog corrosion resistance.4.2 The finishes are divided into four classes; their mostimportant characteristics are listed in Table 1.5. Surfaces Preparation5.1 The surfaces of the

12、 parts to be conversion coated shallbe clean and free of any oxidation, scale, or soils such as metalturnings, grinding dust, oil, grease, lubricants, hand-sweat, orany other contamination detrimental to the conversion coating1This specification is under the jurisdiction of ASTM Committee B08 onMeta

13、llic and Inorganic Coatings and is the direct responsibility of SubcommitteeB08.07 on Conversion Coatings.Current edition approved April 1, 2008. Published April 2008. Originallyapproved in 2002. Last previous edition approved in 2002 as B 92102.2For referenced ASTM standards, visit the ASTM website

14、, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036.4Availab

15、le from Standardization Documents Order Desk, DODSSP, Bldg. 4,Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.process. The parts shall therefore, as far as necessary, becleaned

16、 in a non-hexavalent chromium cleaner before conver-sion coating and, if necessary, be pickled.6. Methods of Application of Conversation Coatings6.1 Metallic material other than aluminum shall not betreated with the parts to be conversion coated.6.2 Conversion coatings are normally applied by dippin

17、g:the coating may also be applied by inundation, spraying, rollercoating, or by wipe-on techniques. The application methodused shall be taken from the operating instructions for theconversion coating process employed. Conversion coatingsolutions are usually acidic and may contain various salts thatm

18、ay be varied to affect the appearance and hardness of the film.The type of conversion coating depends on the composition ofthe solution and may also be affected by the pH, temperature,duration of the treatment, and the nature and surface conditionof the alloy being treated.6.3 Those coatings receivi

19、ng a final water rinse. If thecoating is meant to be a basis for additional coatings, the detailshall be subject to a rinse in deionized water with a conduc-tivity less than 100t S/cm. Hot water shall be used only ifallowed by the manufacturer of the conversion coating inquestion. The drying of the

20、coating shall be carried out inaccordance with the specifications of the manufacturer of theconversion or conversion coating in question.6.4 Any additional subsequent treatments will depend uponthe direction of the manufacture of the conversion or conver-sion coating in question.7. Coating Requireme

21、nts7.1 Electrical ResistanceWhen specified, the purchaserand supplier shall agree to an electrical resistive maximum andfrequency of testing. The method shall be in accordance withMIL-DTL-81706.7.2 AdhesionThe coatings shall be adherent and non-powdery. A practical evaluation of the adhesion can be

22、madeby measuring the adhesion of a secondary organic film appliedto the conversion coating in question. When specified, theconversion coating shall pass the organic coating adhesion testin Test Methods D 3359 or the equivalent ISO 2409.7.2.1 Class 4 coatings intended for use under MIL-DTL-5541 shall

23、 have their adhesion evaluated by Method 6301 ofFed. Std. No. 141.7.2.2 Additional treatments applied under MIL-DTL-5541can be found in Practices D 1730, Methods 5, 6, and 7.7.3 Corrosion ResistanceWhen subjected to the neutralsalt spray test specified in Test Method B117 or in theequivalent ISO 376

24、8, three separate test specimens of thecoating shall withstand exposure for the hours shown in Table2 without giving evidence, to the unaided eye, of more than atotal of 8 isolated spots or pits. None shall be larger than 1 mmin diameter. Each individual test specimen shall not have morethan 5 isola

25、ted spots or pits, none larger than 1 mm in diameteron their respective surfaces. Spots within 10 mm of the edgesof the panels are not counted.7.4 Test Specimens and SamplingsUnless otherwisespecified, the sampling plans of Test Method B 602 or theequivalent ISO 4519 shall be used to test the coatin

26、gs.7.4.1 Test specimens shall be of the same alloy and surfacecondition as the articles represented. Test specimens shall be150 by 100 mm.8. Keywords8.1 conversion coating; non-hexavalent chromium conver-sion coating; non-rinsed; rinsedASTM International takes no position respecting the validity of

27、any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to r

28、evision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Yo

29、ur comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is cop

30、yrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.o

31、rg (e-mail); or through the ASTM website(www.astm.org).TABLE 1 Classification of Non-hexavalent ChromiumConversation CoatingsClass Corrosion Protection1 Maximum corrosion resistance generally used as a final finish2 Moderate corrosion resistance, used as a paint base and forbonding to rubber3 Decora

32、tive, slight corrosion resistance, low electrical contactresistance4 Moderate corrosion resistance, used as a paint base and forbonding to rubberTABLE 2 Relative Corrosion ResistanceExposure Time, hACoatingClassNon-Heat-TreatableWrought AlloysHeat-Treatable Alloysand Cast Alloys witha Nominal Silico

33、nContent 1 %1 500 336 482 250 168 243 168 120 124 500 336 48AThe exposure times are indicative of the relative corrosion resistance of thevarious coating classes on the different alloys, but no direct relationship existsbetween performance in the neutral salt spray test and performance in service.B921082