ASTM C1159-1998(2003) Standard Specification for Sulfur Polymer Cement and Sulfur Modifier for Use in Chemical-Resistant Rigid Sulfur Concrete《耐化学腐蚀、硬性含硫混凝土用含硫高聚物水泥的标准规范》.pdf

1、Designation: C 1159 98 (Reapproved 2003)Standard Specification forSulfur Polymer Cement and Sulfur Modifier for Use inChemical-Resistant, Rigid Sulfur Concrete1This standard is issued under the fixed designation C 1159; the number immediately following the designation indicates the year oforiginal a

2、doption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers the requirements for sulfurpolymer cement

3、and sulfur modifier for use in rapid setting andhigh strength applications of chemical-resistant sulfur con-crete.1.2 The values stated in inch-pound units are to be regardedas the standard. The values given in parentheses are providedfor information only.1.3 This standard does not purport to addres

4、s all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2C 267 Test Metho

5、d for Chemical Resistance of Mortars,Grouts, Monolithic Surfacings, and Polymer ConcretesC 904 Terminology Relating to Chemical-Resistant Non-metallic MaterialsD 70 Test Method for Specific Gravity and Density ofSemi-Solid Bituminous Materials (Pycnometer Method)3. Terminology3.1 DefinitionsFor defi

6、nitions of terms used in this speci-fication, see Terminology C 904.4. Types and Composition of Sulfur Concretes4.1 There are currently two types of commercial sulfurconcrete technology in use. Both utilize cyclopentadiene-typehydrocarbons reacted polymerically with sulfur, but the sulfurconcrete pr

7、oduction processes differ. Each technology is de-scribed further in 4.1.1 and 4.1.2.4.1.1 Type 1Type 1 sulfur concrete uses sulfur polymercement made by reacting a blend of dicyclopentadiene andoligomers of cyclopentadiene with sulfur. The sulfur polymercement shall conform to the chemical and physi

8、cal require-ments prescribed in Table 1.4.1.2 Type 2Type 2 sulfur concrete uses a sulfur modifiermade by reacting sulfur with an oligomeric polymer ofcyclopentadiene. The sulfur modifier shall conform to thechemical and physical requirements prescribed in Table 2. Thesulfur modifier is mixed with el

9、emental sulfur on site duringthe sulfur concrete production process.5. Physical Properties5.1 Particles of sulfur polymer cement and sulfur modifiershall be small enough (generally less than in. nominal size)to melt efficiently when exposed to heated aggregate whileminimizing the amount of dust part

10、icles (generally less than 74m) to reduce potential dust hazards.6. Methods of Sampling and Testing6.1 Sulfur polymer cement and sulfur modifier shall besampled and tested to determine the properties enumerated inthis specification in accordance with the following methods:6.1.1 SamplingWhen the purc

11、haser desires that the sulfurpolymer cement or sulfur modifier be sampled and tested toverify compliance with this specification, every precautionshall be taken to obtain representative random samples that willshow the true nature and condition of the material. Samplesshall be taken to represent as

12、nearly as possible an average ofthe bulk material sampled or to ascertain the maximumvariation in characteristics which the material possesses.6.1.2 Sulfur and carbon contents shall be determined bycombustion of a small sample of sulfur polymer cement orsulfur modifier using carbon/sulfur analyzing

13、equipment. Typi-cal equipment is that used for analyzing coal samples.6.1.3 Hydrogen content shall be determined by combustionof a small sample of sulfur polymer cement or sulfur modifierin an oxygen environment converting the hydrogen to watervapor measured using gravimetric procedures by absorptio

14、ninto calcium chloride.1This specification is under the jurisdiction of ASTM Committee C03 onChemical-Resistant Nonmetallic Materials and is the direct responsibility ofSubcommittee C03.02 on Mortar and Monolithics.Current edition approved Oct. 1, 2003. Published October 2003. Originallyaproved in 1

15、990. Last previous edition approved in 1998 as C 1159 98.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.1Cop

16、yright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.6.1.4 Specific gravity shall be determined in accordancewith Test Method D 70. Measurements are made at 77F(25C).6.1.5 Viscosity shall be determined at 275F (135C) usinga rotating spindle-t

17、ype viscometer equipped with an electri-cally heated cell and temperature controller.7. Inspection7.1 Inspection of the material shall be made as agreed uponby the purchaser and the seller as part of the purchase contract.8. Rejection8.1 At the discretion of the purchaser, sulfur polymercement or su

18、lfur modifier may be rejected if it fails to meet anyof the requirements of this specification.9. Packaging and Package Marking9.1 The sulfur polymer cement or sulfur modifier shall bepackaged in suitable containers, plainly marked to denote thecontents, the name and brand of the manufacturer, batch

19、number, and the weight of cement contained therein. Similarinformation shall be provided with bulk shipments of thesematerials. All packages shall be in good condition at the timeof inspection.9.2 Packages may be marked at the discretion of thesupplier and on his responsibility, indicating that the

20、productsatisfies this specification.10. Storage10.1 Materials should be stored in a clean, dry, area in sucha manner as to permit easy access for proper inspection of eachshipment. Sulphur modifier should be stored at ambient tem-peratures, generally less than 105F (40C).11. Manufacturers Certificat

21、ion11.1 Upon request of the purchaser in the contract or order,a manufacturers report shall be furnished at the time ofshipment stating the results of tests made on samples of thematerial taken during production or transfer and certifying thatthe applicable requirements of this specification have be

22、en met.12. Keywords12.1 chemical-resistant; sulfur concrete; sulfur modifier;sulfur polymer cement (SPC); sulfur polymer cement concreteASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this stan

23、dard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and

24、if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, w

25、hich you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959

26、,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).TABLE 1 Sulfur Polymer Cement for Use in Type

27、 1 SulfurConcreteProperty ValueSulfur, % by weight 95.0 6 1.0Carbon, % by weight 5.0 6 0.5Hydrogen, % by weight 0.5 6 0.05Specific gravity at 77F (25C) 1.90 6 0.02Viscosity, cP at 275F (135C) 25 to 100TABLE 2 Sulfur Modifier for Use in Type 2 Sulfur ConcreteProperty ValueSulfur, % by weight 80 6 2.0Carbon, % by weight 18 6 1.0Hydrogen, % by weight 2.0 6 0.1Specific gravity at 77F (25C) 1.71 6 0.02Viscosity, cP at 275F (135C) 35 to 100C 1159 98 (2003)2