ASTM D2287-1996(2001) Standard Specification for Nonrigid Vinyl Chloride Polymer and Copolymer Molding and Extrusion Compounds《非刚性氯乙烯聚合物和共聚物模塑和挤压复合物(X-15-360)第19项(X-15-372-1)规范》.pdf

1、Designation: D 2287 96 (Reapproved 2001)Standard Specification forNonrigid Vinyl Chloride Polymer and Copolymer Moldingand Extrusion Compounds1This standard is issued under the fixed designation D 2287; the number immediately following the designation indicates the year oforiginal adoption or, in th

2、e case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This

3、 specification covers nonrigid vinyl chloride poly-mer and copolymer classes in which the resin portion of thecomposition contains at least 90 % vinyl chloride. The remain-ing 10 % may include one or more monomers copolymerizedwith vinyl chloride or consist of other resins mechanicallyblended with p

4、olyvinyl chloride or copolymers thereof.1.2 These nonrigid vinyl compounds are defined by ahardness range and include the necessary stabilizers, plasticiz-ers, fillers, dyes, and pigments to meet the designated require-ments.1.3 This specification includes nonrigid vinyl chloride com-pounds recommen

5、ded for compression molding, injectionmolding, and extrusion, but it must be recognized that particu-lar compounds may not be suitable for all these means offabrication.NOTE 1This standard is similar in content, but not technicallyequivalent to ISO 2898-1:1986 and ISO 2898-2:1989.1.4 The values stat

6、ed in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.1.5 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety an

7、d health practices and determine the applica-bility of regulatory limitations prior to use.1.6 The text of this specification references notes andfootnotes which provide explanatory material. These notes andfootnotes (excluding those in tables and figures) shall not beconsidered as requirements of t

8、his specification.1.7 Recycle PVC plastics meeting the requirements of thisspecification may be used in some applications. Refer to thespecific requirements in the Materials and Manufacture sectionof the applicable product standard.2. Referenced Documents2.1 ASTM Standards:D 257 Test Methods for DC

9、Resistance or Conductance ofInsulating Materials2D 412 Test Methods for Vulcanized Rubber and Thermo-plastic Elastomers Tension3D 618 Practice for Conditioning Plastics for Testing4D 635 Test Method for Rate of Burning and/or Extent andTime of Burning of Self-Supporting Plastics in a Horizon-tal Pos

10、ition4D 746 Test Method for Brittleness Temperature of Plasticsand Elastomers by Impact4D 792 Test Methods for Density and Specific Gravity (Rela-tive Density) of Plastics by Displacement4D 883 Terminology Relating to Plastics4D 1203 Test Methods for Volatile Loss from Plastics UsingActivated Carbon

11、 Methods4D 1600 Terminology for Abbreviated Terms Relating toPlastics4D 1898 Practice for Sampling of Plastics5D 2240 Test Method for Rubber Property Durometer Hard-ness3D 3182 Practice for RubberMaterials, Equipment, andProcedures for Mixing Standard Compounds and Prepar-ing Standard Vulcanized She

12、ets3D 3892 Practice for Packaging/Packing of Plastics62.2 ISO Standards:7ISO 2898-1:1986 PlasticsPlasticide Compounds of Ho-mopolymers and Copolymers of Vinyl Chloride (PVC-P)ISO 2898-2:1989 PlasticsPlasticide Compounds of Ho-mopolymers and Copolymers of Vinyl Chloride (PVC-P)Part 2 Preparation of T

13、est Specimens and Determina-tion of Properties1This specification is under the jurisdiction of ASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterials (Section D20.15.07).Current edition approved Nov. 10, 1996. Published February 1997. Original

14、lypublished as D 2287 64 T. Last previous edition D 2287 92.This edition contains changes in 1.6 to accommodate BOCA requirements and to1.7 and 14.1 to reference recycle plastics.2Annual Book of ASTM Standards, Vol 10.01.3Annual Book of ASTM Standards, Vol 09.01.4Annual Book of ASTM Standards, Vol 0

15、8.01.5Discontinued; see 1997 Annual Book of ASTM Standards, Vol 08.01.6Annual Book of ASTM Standards, Vol 08.02.7Available from American National Standards Institute, 11 W. 42nd St., 13thFloor, New York, NY 10036.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, P

16、A 19428-2959, United States.3. Terminology3.1 GeneralDefinitions are in accordance with Terminol-ogy D 883 and abbreviations with Terminology D 1600, unlessotherwise indicated.4. Classification4.1 Provision is made in this specification for the identifi-cation of vinyl chloride polymers and copolyme

17、rs by use ofTerminology D 1600. Additionally, there is provision for dis-tinguishing electrical grades and burning rate by suffix. Thesystem of classification provided in Table 1 permits character-ization and identification of all compounds having propertieswithin the ranges of the combinations that

18、 may be selectedfrom the table. Following type identification in accordancewith Terminology D 1600, grades are designated by the cellnumber for each property in the order in which they are listedin Table 1, including the suffixes identifying electrical gradesand flammability when required. When a pr

19、operty is notspecified, a “0” is entered as the cell number unless identifi-cation is terminated prior to that point.NOTE 2The manner in which selected materials are identified isillustrated by the examples given below:NOTE 3The cell-type format provides means for close characteriza-tion and specifi

20、cation of material properties, alone or in combination, fora broad range of materials. This format, however, is subject to possiblemisapplication since unobtainable property combinations can be selectedif the user is not familiar with commercially available materials. Themanufacturer should be consu

21、lted.5. General Requirements5.1 Material shall be of uniform composition and be socompounded as to meet the requirements designated for it.5.2 The designated material shall contain the ingredientsnecessary to permit satisfactory processing with appropriateequipment under recommended or commercially

22、acceptableconditions. There shall be no separation of components underconditions of application normal for these compounds.6. Significance and Use6.1 Means for selecting and identifying nonrigid vinylchloride compounds are provided in Table 1. The propertiesenumerated in this table and the tests def

23、ined are expected toprovide identification of the compounds selected. They are notnecessarily suitable for direct application in design because ofdifferences in shape of part, size, loading, environmentalconditions, etc. Only when specimens are molded in accor-dance with 11.1.1 can comparative data

24、be expected. The testsselected may be employed for inspection or quality controlprovided that they are performed strictly in accordance with theinstructions given herein and in the designated methods so thatextraneous variables are minimized and results are reproducedwithin the limits of variability

25、 of the material being examinedand of the tests used for its examination.7. Detail Requirements7.1 Compliance with the designated requirements shall bedetermined with test specimens prepared of sheets molded inaccordance with 11.1.1 of this specification.7.2 Test values for specimens so prepared sha

26、ll comply withthe designated requirements as given in Table 1.7.3 Subject to agreement between the purchaser and theseller, tests may be made on specimens prepared of finishedmolded articles. Results of such tests may not agree with thevalues given in Table 1. Therefore, in reports of such tests,met

27、hods, and conditions of preparation, dimensions, and allother pertinent information shall be included.8. Contractual Requirements8.1 Nonrigid vinyl chloride plastics ordinarily are suppliedin either diced or granulated form. Particle size shall be asagreed between the purchaser and the seller. Other

28、 formssometimes are available and may be obtained by arrangementwith the seller.8.2 Color and transparency or opacity of the materials, whenmolded under the conditions recommended by the seller, shallbe comparable within commercial tolerances with a standardspecimen of the same thickness furnished i

29、n advance by theseller.9. Number of Tests9.1 One set of test specimens as needed to verify therequirements selected in Table 1 and as prescribed in Section11 shall be considered sufficient for testing the material.D 2287210. Sampling10.1 Material shall be sampled in accordance with PracticeD 1898. A

30、dequate statistical sampling before packaging is anacceptable alternative. A batch or lot of material shall beconsidered as a unit of manufacture prepared for shipment andmay consist of a blend of two or more production runs ofmaterial.10.2 Material shall be free of foreign matter to such a levelof

31、contamination as may be agreed between the purchaser andthe seller.11. Test Methods11.1 The properties enumerated herein shall be determinedin accordance with the following methods:11.1.1 Test SpecimensUnless otherwise specified, testspecimens shall be prepared of sheets 1.9 6 0.2 mm (0.075 60.010 i

32、n.) thick molded by compression as described inPractice D 3182. The conditions of molding shall be either asrecommended by the seller or in keeping with acceptedcommercial practice for the material being used. Specimensshall be of the shape and dimensions specified in the individualtest methods.11.1

33、.2 ConditioningTest specimens of nonrigid vinylchloride plastics shall be conditioned in accordance withProcedure A of Practice D 618.11.1.3 Test ConditionsTests shall be conducted in theStandard Laboratory Atmosphere of 23 6 2C (73.46 3.6F)and 50 6 5 % relative humidity unless otherwise specifiedhe

34、rein or in the individual test methods.11.1.4 Durometer HardnessTest Method D 2240 using a15-s interval as described in 10.2 of that method.11.1.5 Specific GravityMethod A of Test Methods D 792.The use of alternative methods of equal accuracy is permittedexcept for referee tests.11.1.6 Tensile Stren

35、gthTest Methods D 412 using speci-mens prepared with Die C.11.1.7 Volatile LossTest Methods D 1203 using Method Aexcept that the test temperature shall be 105C.11.1.8 Brittleness TemperatureProcedure A of TestMethod D 746.11.1.9 Volume ResistivityTest Methods D 257. Test speci-mens may be of any uni

36、form thickness between 0.5 mm (0.020in.) and 2.2 mm (0.085 in.), test temperature shall be 50 61.0C, and electrodes may be either mercury, conductivepaints, or sprayed or evaporated metal as described in thesection on Electrode Systems of Test Methods D 257 andmounted as shown in the figures illustr

37、ating a flat specimen formeasuring volume and surface resistances or conductances andmercury electrodes for flat, solid specimens in that method.Applied voltage within the range 100 to 500 V is recom-mended.11.1.10 Burning RateTest Method D 635.12. Retest and Rejection12.1 If any failure occurs, the

38、 materials may be retested toestablish conformity in accordance with agreement betweenthe purchaser and the seller.13. Packaging and Package Marking13.1 PackagingThe material shall be packaged in stan-dard commercial containers so constructed as to ensure accep-tance by common or other carriers for

39、safe transportation at thelowest rate to the point of delivery, unless otherwise specifiedin the contract or order.13.2 Package MarkingUnless otherwise agreed betweenthe seller and the purchaser, shipping containers shall bemarked with the name of the material, the batch or lot number,and the quanti

40、ty contained therein, as defined by the contract ororder under which shipment is made, the name of the seller,and the number of the contract or order.13.3 All packing, packaging, and marking provisions ofPractice D 3892 shall apply to this specification.14. Keywords14.1 compounds; poly(vinyl chlorid

41、e); recycle plastics; vi-nyl chloride copolymersTABLE 1 Detail Grade RequirementsDesignationOrder No.Property and UnitCell Limits0 1234567891 Durometer hardness, A scale unspecified 1.5923/23C 1.24 1.29 1.34 1.39 1.44 1.49 1.593 Tensile strength, min:MPa 24.1psi 35004 Volatile loss at 105C, max, % u

42、nspecified 1.0 2.0 3.0 4.0 5.0 6.0 7.0 7.05 Brittleness temperature, max, C unspecified 0 5 10 15 20 30 40 50 60E Volume resistivity at 50C, min, V-cm unspecified 101110121013. . . . . .X Burning rate unspecified .A. . . . . . . .AWhen tested in accordance with Test Method D 635, the compounds of th

43、is cell unit designation shall yield the following results: average extent of burning of 25 mm;average time of burning of 10 s.D 22873ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standa

44、rd are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif

45、 not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, whi

46、ch you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).D 22874