ASTM D613-2013 Standard Test Method for Cetane Number of Diesel Fuel Oil《柴油的十六烷值标准试验方法》.pdf

1、Designation: D613 13Designation: 41/2000Standard Test Method forCetane Number of Diesel Fuel Oil1This standard is issued under the fixed designation D613; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A

2、 number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of Defense.1. Scope*1.1 This test method covers the determination of th

3、e ratingof diesel fuel oil in terms of an arbitrary scale of cetanenumbers using a standard single cylinder, four-stroke cycle,variable compression ratio, indirect injected diesel engine.1.2 The cetane number scale covers the range from zero (0)to 100, but typical testing is in the range of 30 to 65

4、 cetanenumber.1.3 The values for operating conditions are stated in SI unitsand are to be regarded as the standard. The values given inparentheses are the historical inch-pound units for informationonly. In addition, the engine measurements continue to be ininch-pound units because of the extensive

5、and expensivetooling that has been created for these units.1.4 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bi

6、lity of regulatory limitations prior to use. For more specificwarning statements, see Annex A1.2. Referenced Documents2.1 ASTM Standards:2D975 Specification for Diesel Fuel OilsD1193 Specification for Reagent WaterD2500 Test Method for Cloud Point of Petroleum ProductsD4057 Practice for Manual Sampl

7、ing of Petroleum andPetroleum ProductsD4175 Terminology Relating to Petroleum, PetroleumProducts, and LubricantsD4177 Practice for Automatic Sampling of Petroleum andPetroleum ProductsE456 Terminology Relating to Quality and StatisticsE542 Practice for Calibration of Laboratory VolumetricApparatusE8

8、32 Specification for Laboratory Filter Papers3. Terminology3.1 Definitions:3.1.1 accepted reference value (ARV), na value that servesas an agreed-upon reference for comparison, and which isderived as: (1) a theoretical or established value, based onscientific principles, or (2) an assigned or certif

9、ied value, basedon experimental work of some national or internationalorganization, or (3) a consensus or certified value, based oncollaborative experimental work under the auspices of ascientific or engineering group. E4563.1.1.1 DiscussionIn the context of this test method,accepted reference value

10、 is understood to apply to the cetanenumber of specific reference materials determined empiricallyunder reproducibility conditions by the National ExchangeGroup or another recognized exchange testing organization.3.1.2 cetane number (CN), na measure of the ignitionperformance of a diesel fuel oil ob

11、tained by comparing it toreference fuels in a standardized engine test. D41753.1.2.1 DiscussionIn the context of this test method,ignition performance is understood to mean the ignition delayof the fuel as determined in a standard test engine undercontrolled conditions of fuel flow rate, injection t

12、iming andcompression ratio.3.1.3 compression ratio (CR), nthe ratio of the volume ofthe combustion chamber including the precombustion chamberwith the piston at bottom dead center to the comparable volumewith the piston at top dead center.3.1.4 ignition delay, nthat period of time, expressed indegre

13、es of crank angle rotation, between the start of fuelinjection and the start of combustion.3.1.5 injection timing (injection advance), nthat time inthe combustion cycle, measured in degrees of crank angle, atwhich fuel injection into the combustion chamber is initiated.1This test method is under the

14、 jurisdiction of ASTM Committee D02 onPetroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility ofSubcommittee D02.01 on Combustion Characteristics.Current edition approved Dec. 1, 2013. Published December 2013. Originallyapproved in 1941. Last previous edition approved in 20

15、10 as D613 10a1. DOI:10.1520/D0613-13.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes s

16、ection appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States13.1.6 repeatability conditions, nconditions where inde-pendent test results are obtained with the same method onidentical test items in the same

17、 laboratory by the same operatorusing the same equipment within short intervals of time. E4563.1.6.1 DiscussionIn the context of this test method, ashort time interval between two ratings on a sample fuel isunderstood to be not less than the time to obtain at least onerating on another sample fuel b

18、etween them but not so long asto permit any significant change in the sample fuel, testequipment, or environment.3.1.7 reproducibility conditions, nconditions where testresults are obtained with the same method on identical testitems in different laboratories with different operators usingdifferent

19、equipment. E4563.2 Definitions of Terms Specific to This Standard:3.2.1 cetane meter (ignition delay meter), nthe electronicinstrument which displays injection advance and ignition delayderived from input pulses of multiple transducers (pickups).3.2.2 Check Fuels, nfor quality control testing, a die

20、selfuel oil of selected characteristics having a cetane numberaccepted reference value determined by round-robin testingunder reproducibility conditions.3.2.3 combustion pickup, npressure transducer exposed tocylinder pressure to indicate the start of combustion.3.2.4 handwheel reading, nan arbitrar

21、y numerical value,related to compression ratio, obtained from a micrometer scalethat indicates the position of the variable compression plug inthe precombustion chamber of the engine.3.2.5 injector opening pressure, nthe fuel pressure thatovercomes the resistance of the spring which normally holdsth

22、e nozzle pintle closed, and thus forces the pintle to lift andrelease an injection spray from the nozzle.3.2.6 injector pickup, ntransducer to detect motion of theinjector pintle, thereby indicating the beginning of injection.3.2.7 primary reference fuels (PRF), nn-cetane, heptam-ethyl nonane (HMN)

23、and volumetrically proportioned mixturesof these materials which now define the cetane number scale bythe relationship:Cetane Number 5 % n 2 cetane10.15 % HMN! (1)3.2.7.1 DiscussionIn the context of this test method, thearbitrary cetane number scale was originally defined as thevolume percent of n-c

24、etane in a blend with alpha-methylnaphthalene (AMN) where n-cetane had an assignedvalue of 100 and AMN an assigned value of zero (0). A changefrom alpha-methylnaphthalene to heptamethylnonane as thelow cetane ingredient was made in 1962 to utilize a material ofbetter storage stability and availabili

25、ty. Heptamethylnonanewas determined to have a cetane number accepted referencevalue (CNARV) of 15 based on engine testing by the ASTMDiesel National Exchange Group, using blends of n-cetane andAMN as primary reference fuels.3.2.7.2 DiscussionIn the context of this test method, theDiesel National Exc

26、hange Group of Subcommittee D02.013iscomposed of petroleum industry, governmental, and indepen-dent laboratories. It conducts regular monthly exchange sampleanalyses to generate precision data for this engine test standardand determines the CNARVof reference materials used by alllaboratories.3.2.8 r

27、eference pickups, ntransducer(s) mounted over theflywheel of the engine, triggered by a flywheel indicator, usedto establish a top-dead-center (tdc) reference and a time basefor calibration of the ignition delay meter.3.2.9 secondary reference fuels (SRF), nvolumetricallyproportioned blends of two s

28、elected, numbered, and pairedhydrocarbon mixtures designated T Fuel (high cetane) and UFuel (low cetane) that have been rated by the ASTM DieselNational Exchange Group using primary reference fuels todetermine a cetane number accepted reference value for eachindividually and for various combinations

29、 of the two.3.3 Abbreviations:3.3.1 ABDCafter bottom dead center3.3.2 AMNalpha-methylnaphthalene3.3.3 ARVaccepted reference value3.3.4 ATDCafter top dead center3.3.5 BBDCbefore bottom dead center3.3.6 BTDCbefore top dead center3.3.7 CNcetane number3.3.8 CRcompression ratio3.3.9 HMNheptamethyl nonane

30、3.3.10 HRFhigh reference fuel3.3.11 HWhand wheel3.3.12 IATintake air temperature3.3.13 LRFlow reference fuel3.3.14 NEGNational Exchange Group3.3.15 PRFprimary reference fuels3.3.16 SRFsecondary reference fuels3.3.17 TDCtop dead center3.3.18 UVultraviolet4. Summary of Test Method4.1 The cetane number

31、 of a diesel fuel oil is determined bycomparing its combustion characteristics in a test engine withthose for blends of reference fuels of known cetane numberunder standard operating conditions. This is accomplishedusing the bracketing handwheel procedure which varies thecompression ratio (handwheel

32、 reading) for the sample and eachof two bracketing reference fuels to obtain a specific ignitiondelay permitting interpolation of cetane number in terms ofhandwheel reading.5. Significance and Use5.1 The cetane number provides a measure of the ignitioncharacteristics of diesel fuel oil in compressio

33、n ignition en-gines.3Bylaws governing ASTM Subcommittee D02.01 on Combustion Characteris-tics are available from the subcommittee or from ASTM International.D613 1325.2 This test method is used by engine manufacturers,petroleum refiners and marketers, and in commerce as aprimary specification measur

34、ement related to matching of fuelsand engines.5.3 Cetane number is determined at constant speed in aprecombustion chamber type compression ignition test engine.The relationship of test engine performance to full scale,variable speed, variable load engines is not completely under-stood.5.4 This test

35、method may be used for unconventional fuelssuch as synthetics, vegetable oils, and the like. However, therelationship to the performance of such materials in full scaleengines is not completely understood.6. Interferences6.1 (WarningAvoid exposure of sample fuels and refer-ence fuels to sunlight or

36、fluorescent lamp UV emissions tominimize induced chemical reactions that can affect cetanenumber ratings.)46.1.1 Exposure of these fuels to UV wavelengths shorterthan 550 nm for a short period of time may significantly affectcetane number ratings.6.2 Certain gases and fumes present in the area where

37、 thecetane test engine is located may have a measurable effect onthe cetane number test result.6.3 This test method is not suitable for rating diesel fuel oilswith fluid properties that interfere with unimpeded gravity flowof fuel to the fuel pump or delivery through the injector nozzle.7. Apparatus

38、7.1 Engine Equipment5,6This test method uses a singlecylinder engine which consists of a standard crankcase withfuel pump assembly, a cylinder with separate head assembly ofthe precombustion type, thermal syphon recirculating jacketcoolant system, multiple fuel tank system with selectorvalving, inje

39、ctor assembly with specific injector nozzle, elec-trical controls, and a suitable exhaust pipe. The engine is beltconnected to a special electric power-absorption motor whichacts as a motor driver to start the engine and as a means toabsorb power at constant speed when combustion is occurring(engine

40、 firing). See Fig. 1 and Table 1.7.2 Instrumentation5,6This test method uses an electronicinstrument to measure injection and ignition delay timing aswell as conventional thermometry, gages and general purposemeters.7.2.1 Cetane Meter, (Ignition Delay Meter) is critical andshall be used for this tes

41、t method.7.3 Reference Fuel Dispensing EquipmentThis testmethod requires repeated blending of two secondary referencefuel materials in volumetric proportions on an as-needed basis.Measurement shall be performed accurately because ratingerror is proportional to blending error.7.3.1 Volumetric Blendin

42、g of Reference FuelsVolumetricblending has historically been employed to prepare the re-quired blends of reference fuels. For volumetric blending, a setof two burets or accurate volumetric ware shall be used and thedesired batch quantity shall be collected in an appropriatecontainer and thoroughly m

43、ixed before being introduced to theengine fuel system.7.3.1.1 Calibrated burets or volumetric ware having a ca-pacity of 400 or 500 mL and a maximum volumetric toleranceof 60.2 % shall be used. Calibration shall be verified inaccordance with Practice E542.7.3.1.2 Calibrated burets shall be outfitted

44、 with a dispensingvalve and delivery tip to accurately control dispensed volume.The delivery tip shall be of such size and design that shutoff tipdischarge does not exceed 0.5 mL.7.3.1.3 The rate of delivery from the dispensing systemshall not exceed 500 mL per 60 s.7.3.1.4 The set of burets for the

45、 reference and standardiza-tion fuels shall be installed in such a manner and be suppliedwith fluids such that all components of each batch or blend aredispensed at the same temperature.7.3.1.5 See Appendix X1, Volumetric Reference FuelBlending Apparatus and Procedures, for typical dispensingsystem

46、information.7.3.2 Gravimetric Blending of Reference FuelsUse ofblending systems that allow preparation of the volumetrically-defined blends by gravimetric (mass) measurements based onthe density of the individual components is also permitted,provided the system meets the requirement for maximum0.2 %

47、 blending tolerance limits.7.3.2.1 Calculate the mass equivalents of thevolumetrically-defined blend components from the densities ofthe individual components at 15.56C (60F).7.4 Auxiliary Apparatus:7.4.1 Injector Nozzle TesterThe injector nozzle assemblyshall be checked whenever the injector nozzle

48、 is removed andreassembled to ensure the initial pressure at which fuel isdischarged from the nozzle is properly set. It is also importantto inspect the type of spray pattern. Commercial injector nozzletesters which include a lever-operated pressure cylinder, fuelreservoir and pressure gauge are ava

49、ilable from several sourcesas common diesel engine maintenance equipment.7.4.2 Special Maintenance ToolsA number of specialtytools and measuring instruments should be utilized for easy,convenient and effective maintenance of the engine and testingequipment. Lists and descriptions of these tools and instru-ments are available from the manufacturers of the engineequipment and those organizations offering engineering andservice support for this test method.8. Reagents and Reference Materials8.1 Cylinder Jacket CoolantWater shall be us