ASTM D720 D720M-2015 Standard Test Method for Free-Swelling Index of Coal《煤的自由膨胀指数的标准试验方法》.pdf

1、Designation: D720/D720M 15Standard Test Method forFree-Swelling Index of Coal1This standard is issued under the fixed designation D720/D720M; the number immediately following the designation indicates the yearof original adoption or, in the case of revision, the year of last revision. A number in pa

2、rentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of Defense.1. Scope1.1 This test method2is a small-scale test for obtaininginformati

3、on regarding the free-swelling properties of a coal.The results may be used as an indication of the cakingcharacteristic of the coal when burned as a fuel. This test is notrecommended as a method for the determination of expansionof coals in coke ovens.1.2 WarningBreathing of asbestos dust is hazard

4、ous.Asbestos and asbestos products present demonstrated healthrisks for users and for those with whom they come into contact.In addition to other precautions, when working with asbestos-cement products, minimize the dust that results. For informa-tion on the safe use of chrysoltile asbestos, refer t

5、o, Safe Useof Chrysotile Asbestos: A Manual on Preventive and ControlMeasures.31.3 The values stated in either SI units or inch-pound unitsare to be regarded separately as standard. The values stated ineach system may not be exact equivalents; therefore, eachsystem shall be used independently of the

6、 other. Combiningvalues from the two systems may result in non-conformancewith the standard.1.4 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health pract

7、ices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:4D2013 Practice for Preparing Coal Samples for AnalysisE691 Practice for Conducting an Interlaboratory Study toDetermine the Precision of a Test Method3. Significance and Use3.1 Thi

8、s test method, in addition to indicating the cakingproperties of a coal when burned as a fuel, can be used to givea broad indication of the degree of oxidation of a coal.4. Apparatus4.1 This test method can be made with either electric or gasheating. When using electric heating, the results obtained

9、 mustbe the same as those obtained when using the gas heatingmethod. The apparatus common to both electric and gasmethods shall consist of the following:4.1.1 Crucible, translucent silica, low-form, with a flat,close-fitting silica ring-handle lid and an extra pierced lid foruse in determining the c

10、rucible temperature, conforming to thefollowing requirements:Weight, g 11.0 to 12.75External height, mm 26 0.5External diameter at top, mm 41 0.75Internal diameter at base, min, mm 11Capacity (approximate), cm3174.1.2 Sight Tube, as shown in Fig. 1, for viewing the cokebuttons so that the effect of

11、parallax will be eliminated. Makethe tube of any rigid and preferably opaque material andsupport vertically on a ring stand.4.1.3 Thermocouple and Potentiometer.4.1.4 Weight, 500 g.4.2 The electric apparatus shall consist of the following:4.2.1 Furnace, consisting of a base, a heating element, anda

12、chimney. The unit is shown in Fig. 2.4.2.1.1 ChimneyFig. 2 shows the chimney design. Makethe unit from firebrick and coat with firebrick bonding mortar.Maintain the chimney under compression by a sheet-metal1This test method is under the jurisdiction of ASTM Committee D05 on Coaland Coke and is the

13、direct responsibility of Subcommittee D05.15 on MetallurgicalProperties of Coal and Coke.Current edition approved Jan. 1, 2015. Published January 2015. Originallyapproved in 1943. Last previous edition approved in 2010 as D720 91 (2010).DOI: 10.1520/D0720/D0720M-15.2This test method is an adaptation

14、 of the Crucible Swelling Test for Coal of theBritish Standards Institution. For information concerning the experimental work onwhich this adaptation is based, see paper by Ostborg, H. N., Limbacker, H. R., andSherman, R. A., “An Experimental Investigation of the British Standard Method forthe Cruci

15、ble Swelling Test for Coal,” Proceedings, Am. Soc. Testing Mats., Vol 42,1042, p. 851. See also a paper by Selvig, W. A., and Ode, W. H., “An Investigationof a Laboratory Test for Determination of the Free-Swelling Index of Coal,” U.S.Bureau of Mines Report of Investigation 4238, Revision of R. I. 3

16、989, 1948.3Safe Use of Chrysotile Asbestos: A Manual on Preventive and ControlMeasures Chrysotile Institute 1200, McGill College Suite 1640 Montreal, QuebecCanada H3B 4G74For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annu

17、al Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1envelope (Fig. 2) to prevent cracking. Make the envelope infour pieces, each

18、piece covering a corner. The pieces shalloverlap at the center of the flat faces and be held together bybolts and springs. Place two layers of asbestos paper betweenthe chimney brick and the envelope. Cut two grooves in theupper inside chimney walls to accommodate the cruciblesupport. In cases in wh

19、ich the furnace is located in a draftyarea, it is advisable to shield the chimney to prevent largefluctuations in furnace temperature.4.2.2 Crucible SupportAconvenient crucible support con-sists of a cradle support made from nickel-chromium wiresuspended from a metal ring. The height of the support

20、insidethe furnace can be adjusted by loosening the two screws thathold the wire legs of the support in place.4.2.3 Electric Controls, consisting of a rheostat, an a-cammeter, and two timers. These components shall conform tothe following specifications:Ammeter a-c, 0 to 10-A rangeRheostat 100 W, 10

21、Variable transformer 7.4 A, 120 VTimer mechanical, 05 min minimum span, with a holdposition, and electrical contact closed duringtiming cycle4.2.3.1 One timer shall actuate the rheostat, at a predeter-mined setting, after 112 min of operation. Preset the rheostat toreduce the rate of heating of the

22、furnace so that a temperatureof 820 6 5C 1508 6 9F is achieved at the end of 212 min.A variable transformer is desirable for establishing the inputvoltage to the furnace.4.3 The gas apparatus shall consist of the following:4.3.1 Burner AssemblyAgas burner with a grid of externaldiameter, 30 to 42 mm

23、 1.18 to 1.65 in., a draft shield, and atriangular crucible support as shown in Fig. 3. Make the draftshield, conforming to the dimensions shown in Fig. 3 from theasbestos-cement pipe, and at the top it shall have three slots, 25mm 1 in. in depth, in which the wires of the crucible supportrest. Supp

24、ort the draft shield on a ring stand, so that thedistance between the base of the crucible and the top of theburner grid may be adjusted by raising or lowering the draftshield. Make the triangular crucible support from three piecesof translucent silica tubing each 63 mm 2.5 in. in length, 6 to6.5 mm

25、 0.24 to 0.26 in. in external diameter, and mounted onchromium-nickel wire so that the diameter of the inscribedcircle is approximately 32 mm 1.26 in. The twisted ends ofthe triangle may be joined together by a loop of wire tofacilitate removal of the hot crucible.4.3.2 FlowmeterA capillary flowmete

26、r with water ma-nometer placed in the gas line before the burner as a guide tothe control of the rate of gas flow (Fig. 3).5. Calibration5.1 Electric Furnace:5.1.1 Turn the main power switch on and set the timer to theHOLD position. Adjust the variable transformer so that theammeter reads 5.8 A. All

27、ow at least 45 min for the furnacetemperature to reach equilibrium.5.1.2 Set the timer just beyond the 112-min mark. At 112min, lower an empty crucible with pierced lid into the furnace.Measure the temperature at the inside base of the crucible witha thermocouple and a potentiometer. The unprotected

28、 junctionof the thermocouple must be in contact with the inside base ofthe crucible.At the end of 112 min, the temperature should read800 6 10C 1472 6 18F. Adjust the variable transformer asnecessary to provide this temperature.5.1.3 A temperature of 820 6 5C 1508 6 9F must beattained at the end of

29、212 min. The second timer shall be usedhere. The control unit rheostat must be properly adjusted toreduce the heating rate at the end of 212 min. If the rheostat isset initially so that at the end of 112 min the ammeter readingis reduced by 0.6 or 0.7 A, the specified temperature at the endof 212 mi

30、n should be attained. Several trials will no doubt benecessary before the proper temperatures at 112 and 212 minare reached; however, the information given above provides ageneral guide for calibration. The silica crucible and covermust be at room temperature before each calibration run.5.1.4 After

31、each calibration attempt or sample run, switchthe timer to the HOLD position, and allow about 1 min for thefurnace to reach equilibrium.5.2 Gas Burner:5.2.1 With the burner assembly arranged as shown in Fig. 3,and with an empty crucible in position, light the burner about15 min before making a deter

32、mination to allow the draft shieldto rise to an equilibrium temperature.5.2.2 After placing a crucible in position adjust the flow ofgas and the relative positions of the burner and the draft shieldso that the temperature of the inner surface of the bottom of thecrucible reaches 800 6 10C 1472 6 18F

33、 in 112 min and820 6 5C 1508 6 9F in 212 min. These desired tempera-tures may usually be obtained by setting the draft shield so thatthe bottom of the crucible is approximately 10 mm 0.4 in.above the burner grid, and then adjusting the gas flame.Determine the crucible temperature by means of a therm

34、o-couple and a potentiometer. Insert the thermocouple throughthe pierced crucible lid so that the unprotected junction of thethermocouple is in contact with the base of the crucible.FIG. 1 Sight TubeD720/D720M 1526. Preparation of Sample6.1 Grind the sample of coal to pass a 250-m (No. 60)sieve and

35、prepare it in accordance with the requirements ofPractice D2013.6.1.1 The test should be performed within 24 h of the timethat a sample is pulverized to 60 mesh.NOTE 1For some coals, size consist of the sample is a variable thatcan affect the size of the coke button produced.7. Procedure7.1 Preparat

36、ion of Coke Buttons:7.1.1 Electric MethodWeigh1goftheprepared sampleinto a cold crucible and level by lightly tapping the crucibletwelve times on a solid surface, rotating it between taps. Coverthe crucible with a solid lid. Set the control-unit timer just pastthe 112-min mark and set a separate tim

37、er at the 212-min mark.As the control-unit timer passes the 112-min mark, lower thecrucible into the furnace and at the same time start the 212-mintimer. The rheostat will be actuated at the end of 112 min. Therun will be finished at the end of 212 min. Remove the cokebutton carefully and remove the

38、 carbon residue remaining inthe crucible by ignition. Make three buttons in this manner foreach sample of coal tested.7.1.2 Gas MethodWeigh1goftheprepared sample into acold crucible, and level by lightly tapping the crucible twelvetimes on a solid surface, rotating it between taps. Cover thecrucible

39、 with a solid lid and place it upright in the silicatriangle supported in the draft shield, directly over the gasflame. Heat the covered crucible in the gas flame for the timerequired for the flame of the burning volatile matter to die out,but in any case for not less than 212 min. Remove the cokebu

40、tton carefully and remove the carbon residue remaining inthe crucible by ignition. Make three buttons in this manner foreach sample of coal tested.7.2 Measurement of Coke Button:FIG. 2 Furnace Base and ChimneyFIG. 3 Details of Burner AssemblyD720/D720M 1537.2.1 View each coke button through the sigh

41、t tube andcompare it with the series of standard profiles shown in Fig. 4.Place the standard profile with which a button is to becompared exactly in the center of the field of vision as viewedfrom the top of the tube. Place the button on the profile androtate it on its axis until, viewed with the ey

42、e placed immedi-ately over the top of the tube, the maximum cross-sectionalarea is obtained. Record the number of the standard profilemost nearly matched by the maximum cross-sectional area ofthe button as the swelling index. If any button deviates by morethan one unit from the other two buttons, ma

43、ke a newdetermination.7.2.2 Some coals give buttons that do not conform in shapeto the standard profiles. For such coals, measure the maximumcross-sectional areas of the buttons and determine the indexfrom the relationship of the areas of the standard profiles toswelling indexes as shown in Fig. 5.

44、For measuring thecross-sectional areas, mount the buttons on graph paper ruledinto square centimetres and square millimetres, and trace theoutlines of the buttons on the paper while viewing through thesight tube shown in Fig. 1. The buttons may be mountedconveniently by means of modeling clay. The s

45、quares insidethe outline may be counted, and fractions of squares along theboundary line estimated.NOTE 2To take care of buttons whose cross-sectional area is greaterthan that of standard profile 9, the curve shown in Fig. 5 has been extendedto include about 700 mm21.08 in.2 which is the maximum cro

46、ss-sectional area of the silica crucibles used in the test.7.2.3 Mechanical or electronic devices may be used todetermine the standard profiles if they give results equivalent tothose obtained with measurement techniques described in 7.2.1and 7.2.2.7.2.4 If the residue is coherent but nonswollen, pl

47、ace it on aflat surface and carefully place a 500-g weight on the button. Ifthe button disintegrates, report the swelling index as one half.If the button supports the weight or merely cracks into two orthree hard coherent pieces, report the number as one.8. Report8.1 Report the average swelling inde

48、x of a series of threebuttons expressed to the nearest one-half unit. If this testmethod is to be used for International Classification of hardcoal by type, make five buttons. Report the swelling index aszero if the residue from the test sample is noncoherent.9. Precision and Bias59.1 PrecisionThe r

49、elative precision of this test method forthe determination of free-swelling index covers the index rangefrom one to nine.NOTE 3A test result is considered to be an average of three FSIdeterminations.9.1.1 RepeatabilityThe difference in absolute value be-tween two consecutive tests results, carried out on the samesample in the same laboratory by the same operator using thesame apparatus, should not exceed the repeatability intervalI(r) more than 5 % of such paired values (95 % confidencelevel). When such a di