ASTM D910-2014a Standard Specification for Leaded Aviation Gasolines《航空含铅汽油的标准规格》.pdf

1、Designation: D910 14a An American National StandardStandard Specification forLeaded Aviation Gasolines1This standard is issued under the fixed designation D910; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revis

2、ion. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the U.S. Department of Defense.1. Scope*1.1 This specification covers formulating spe

3、cifications forpurchases of aviation gasoline under contract and is intendedprimarily for use by purchasing agencies.1.2 This specification defines specific types of aviationgasolines for civil use. It does not include all gasolinessatisfactory for reciprocating aviation engines. Certain equip-ment

4、or conditions of use may permit a wider, or require anarrower, range of characteristics than is shown by thisspecification.1.3 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.2. Referenced Documents2.1 ASTM Standards:2D86 Test M

5、ethod for Distillation of Petroleum Products atAtmospheric PressureD93 Test Methods for Flash Point by Pensky-MartensClosed Cup TesterD130 Test Method for Corrosiveness to Copper from Petro-leum Products by Copper Strip TestD323 Test Method for Vapor Pressure of Petroleum Products(Reid Method)D357 M

6、ethod of Test for Knock Characteristics of MotorFuels Below 100 Octane Number by the Motor Method;Replaced by D 2700 (Withdrawn 1969)3D381 Test Method for Gum Content in Fuels by Jet Evapo-rationD614 Method of Test for Knock Characteristics of AviationFuels by the Aviation Method; Replaced by D 2700

7、(Withdrawn 1970)3D873 Test Method for Oxidation Stability of Aviation Fuels(Potential Residue Method)D909 Test Method for Supercharge Rating of Spark-IgnitionAviation GasolineD1094 Test Method for Water Reaction of Aviation FuelsD1266 Test Method for Sulfur in Petroleum Products (LampMethod)D1298 Te

8、st Method for Density, Relative Density, or APIGravity of Crude Petroleum and Liquid Petroleum Prod-ucts by Hydrometer MethodD1948 Method of Test for Knock Characteristics of MotorFuels Above 100 Octane Number by the Motor Method;Replaced by D 2700 (Withdrawn 1968)3D2386 Test Method for Freezing Poi

9、nt of Aviation FuelsD2392 Test Method for Color of Dyed Aviation GasolinesD2622 Test Method for Sulfur in Petroleum Products byWavelength Dispersive X-ray Fluorescence SpectrometryD2624 Test Methods for Electrical Conductivity of Aviationand Distillate FuelsD2700 Test Method for Motor Octane Number

10、of Spark-Ignition Engine FuelD3338 Test Method for Estimation of Net Heat of Combus-tion of Aviation FuelsD3341 Test Method for Lead in GasolineIodine Mono-chloride MethodD4052 Test Method for Density, Relative Density, and APIGravity of Liquids by Digital Density MeterD4057 Practice for Manual Samp

11、ling of Petroleum andPetroleum ProductsD4171 Specification for Fuel System Icing InhibitorsD4177 Practice for Automatic Sampling of Petroleum andPetroleum ProductsD4306 Practice for Aviation Fuel Sample Containers forTests Affected by Trace ContaminationD4529 Test Method for Estimation of Net Heat o

12、f Combus-tion of Aviation FuelsD4809 Test Method for Heat of Combustion of LiquidHydrocarbon Fuels by Bomb Calorimeter (PrecisionMethod)1This specification is under the jurisdiction of ASTM Committee D02 onPetroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility ofSubcommitt

13、ee D02.J0.02 on Spark and Compression Ignition Aviation EngineFuels.Current edition approved Oct. 1, 2014. Published October 2014. Originallyapproved in 1947 (replacing former D615). Last previous edition approved in 2014as D910 14. DOI: 10.1520/D0910-14A.2For referenced ASTM standards, visit the AS

14、TM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this historical standard is referenced onwww.astm.org.*A Summary of Changes

15、 section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1D4865 Guide for Generation and Dissipation of Static Elec-tricity in Petroleum Fuel SystemsD5006 Test Method for Measurement of Fuel System Ic

16、ingInhibitors (Ether Type) in Aviation FuelsD5059 Test Methods for Lead in Gasoline by X-Ray Spec-troscopyD5191 Test Method for Vapor Pressure of Petroleum Prod-ucts (Mini Method)D6469 Guide for Microbial Contamination in Fuels and FuelSystemsE29 Practice for Using Significant Digits in Test Data to

17、Determine Conformance with Specifications3. Terminology3.1 Definitions:3.1.1 aviation gasoline, ngasoline possessing specificproperties suitable for fueling aircraft powered by reciprocat-ing spark ignition engines.3.1.1.1 DiscussionPrincipal properties include volatilitylimits, stability, detonatio

18、n-free performance in the engine forwhich it is intended, and suitability for low temperatureperformance.3.2 Abbreviations:3.2.1 LLlow lead3.2.2 VLLvery low lead4. General4.1 This specification, unless otherwise provided, prescribesthe required properties of aviation gasoline at the time andplace of

19、 delivery.5. Classification5.1 Five grades of leaded aviation gasoline are provided,known as:Grade 80Grade 91Grade 100Grade 100LLGrade 100VLLNOTE 1The above grade names are based on their octane/performancenumbers as measured by the now obsolete Test Method D614 (Discon-tinued 1970). A table for con

20、verting octane/performance numbers ob-tained by Test Method D2700 motor method into aviation ratings was lastpublished in Specification D91094 in the 1995 Annual Book of ASTMStandards, Vol 05.01.5.2 Grades 100, 100LL, and 100VLL represent aviationgasolines identical in minimum antiknock quality but

21、differingin maximum lead content and color. The color identifies thedifference for engines that have a low tolerance to lead.NOTE 2Listing of, and requirements for, Avgas Grades 91/98,108/135 and 115/145 appeared in the 1967 version of this specification.U.S. Military Specification MIL-G-5572F, date

22、d January 24, 1978 (with-drawn March 22, 1988), also covers grade 115/145 aviation gasoline, andis available as a research report.45.3 Although the grade designations show only a singleoctane rating for each grade, they shall meet a minimum leanmixture motor rating and a minimum rich mixture superch

23、argerating (see X1.2.2).6. Materials and Manufacture6.1 Aviation gasoline, except as otherwise specified in thisspecification, shall consist of blends of refined hydrocarbonsderived from crude petroleum, natural gasoline, or blends,thereof, with synthetic hydrocarbons or aromatichydrocarbons, or bot

24、h.6.2 AdditivesMandatory, shall be added to each grade ofaviation gasoline in the amount and of the compositionspecified in the following list of approved materials.6.2.1 Tetraethyl Lead, shall be added in the form of anantiknock mixture containing not less than 61 mass percent oftetraethyl lead and

25、 sufficient ethylene dibromide to provide twobromine atoms per atom of lead. The balance shall contain noadded ingredients other than kerosine, an approved oxidationinhibitor, and blue dye, as specified herein. The maximumconcentration limit for each grade of gasoline is specified inTable 1.6.2.1.1

26、If mutually agreed upon by the fuel producer andadditive vendor, tetraethyl lead antiknock mixture may bediluted with 20 mass percent of a mixed aromatic solventhaving a minimum flash point of 60 C according to TestMethods D93 when the product is to be handled in coldclimates. The TEL content of the

27、 dilute product is reduced to49 mass percent, so that the amount of antiknock additive mustbe adjusted to achieve the necessary lead level. The diluteproduct still delivers two bromine atoms per atom of lead.6.2.2 DyesThe maximum concentration limits in eachgrade of gasoline are specified in Table 1

28、.6.2.2.1 The only blue dye that shall be present in thefinished gasoline shall be essentially 1,4-dialkylaminoanthraquinone.6.2.2.2 The only yellow dyes that shall be present in thefinished gasoline shall be essentiallyp-diethylaminoazobenzene (Color Index No. 11021) or 1,3-benzenediol 2,4-bis (alky

29、lphenyl)azo-.6.2.2.3 The only red dye that shall be present in the finishedgasoline shall be essentially alkyl derivatives of azobenzene-4-azo-2-naphthol.6.2.2.4 The only orange dye that shall be present in thefinished gasoline shall be essentially benzene-azo-2-napthol(Color Index No. 12055).6.3 Ad

30、ditivesThese may be added to each grade of avia-tion gasoline in the amount and of the composition specified inthe following list of approved materials.5The quantities andtypes shall be declared by the manufacturer. Additives addedafter the point of manufacture shall also be declared.6.3.1 Antioxida

31、ntsThe following oxidation inhibitors maybe added to the gasoline separately, or in combination, in total4Supporting data have been filed at ASTM International Headquarters and maybe obtained by requesting Research Report RR:D02-1255.5Supporting data (guidelines for the approval or disapproval of ad

32、ditives) havebeen filed at ASTM International Headquarters and may be obtained by requestingResearch Report RR:D02-1125.D910 14a2TABLE 1 Detailed Requirements for Leaded Aviation GasolinesAGrade80Grade91Grade100VLLGrade100LLGrade100ASTM TestMethodBPropertyCOMBUSTIONNet heat of combustion, MJ/kgCmin

33、43.5 43.5 43.5 43.5 43.5 D4529 or D3338Octane RatingKnock value, lean mixtureDMotor Octane Number min 80.7 90.8 99.6 99.6 99.6 D2700Aviation Lean Rating min 80.0 91.0 100.0 100.0 100.0 D2700Knock value, rich mixtureOctane number min 87 98 D909Performance numberE,Fmin 130.0 130.0 130.0 D909COMPOSITIO

34、NSulfur, mass percent max 0.05 0.05 0.05 0.05 0.05 D1266 or D2622Tetraethyl lead D3341 or D5059mL TEL/L max 0.13 0.53 0.43 0.53 1.06g Pb/L max 0.14 0.56 0.45 0.56 1.12Color red brown blue blue green D2392Dye contentG, mg/LBlue dye max 0.2 3.1 2.7 2.7 2.7Yellow dye max none none none none 2.8Red dye

35、max 2.3 2.7 none none noneOrange dye max none 6.0 none none noneRequirements for All GradesVOLATILITYVapor pressure, 38 C, kPa minmax38.049.0D323 or D5191HDensity at 15 C, kg/m3Report D1298 or D4052Distillation, C D86Initial boiling point ReportFuel Evaporated10 volume percent at C max 7540 volume p

36、ercent at C min 7550 volume percent at C max 10590 volume percent at C max 135Final boiling point max 170Sumof10%+50%evaporatedtemperaturesmin 135Recovery volume percent min 97Residue volume percent max 1.5Loss volume percent max 1.5FLUIDITYFreezing point, C max 58ID2386CORROSIONCopper strip, 2 h at

37、 100 C max No. 1 D130CONTAMINANTSOxidation stability, mg/100 mL(5 h aging)J,KD873Potential gum max 6Lead precipitate max 3Water reaction D1094Volume change, mL max 2OTHERElectrical conductivity, pS/m max 450LD2624AFor compliance of test results against the requirements of Table 1, see 7.2.BThe test

38、methods indicated in this table are referred to in Section 11.CFor all grades use either Eq 1 or Table 1 in Test Method D4529 or Eq 2 in Test Method D3338. Test Method D4809 may be used as an alternative. In case of dispute,Test Method D4809 shall be used.DBoth Motor Octane Number (MON) and Aviation

39、 Lean Mixture values shall be reported.EA performance number of 130.0 is equivalent to a knock value determined using iso-octane plus 0.34 mL TEL/L.FKnock ratings shall be reported to the nearest 0.1 octane/performance number.GThe maximum dye concentrations shown do not include solvent in dyes suppl

40、ied in liquid form.HTest Method D5191 shall be the referee vapor pressure method.IIf no crystals have appeared on cooling to 58 C, the freezing point may be reported as less than 58 C.JIf mutually agreed upon between the purchaser and the supplier, a 16 h aging gum requirement may be specified inste

41、ad of the 5 h aging gum test; in such case thegum content shall not exceed 10 mg/100 mL and the visible lead precipitate shall not exceed 4 mg/100 mL. In such fuel the permissible antioxidant shall not exceed 24mg/L.KTest Method D381 existent gum test can provide a means of detecting quality deterio

42、ration or contamination, or both, with heavier products following distribution fromrefinery to airport. Refer to X1.7.1.LApplies only when an electrical conductivity additive is used; when a customer specifies fuel containing conductivity additive, the following conductivity limits shall applyunder

43、the condition at point of use:Minimum 50 pS/mMaximum 450 pS/m.The supplier shall report the amount of additive added.D910 14a3concentration not to exceed 12 mg of inhibitor (not includingweight of solvent) per litre of fuel.6.3.1.1 2,6-ditertiary butyl-4-methylphenol.6.3.1.2 2,4-dimethyl-6-tertiary

44、butylphenol.6.3.1.3 2,6-ditertiary butylphenol.6.3.1.4 75 % minimum 2,6-ditertiary butylphenol plus 25 %maximum mixed tertiary and tritertiary butylphenols.6.3.1.5 75 % minimum di- and tri-isopropyl phenols plus25 % maximum di- and tri-tertiary butylphenols.6.3.1.6 72 % minimum 2,4-dimethyl-6-tertia

45、ry butylphenolplus 28 % maximum monomethyl and dimethyl tertiary butyl-phenols.6.3.1.7 N,N-di-isopropyl-para-phenylenediamine.6.3.1.8 N,N-di-secondary-butyl-para-phenylenediamine.6.3.2 Fuel System Icing Inhibitor (FSII)One of the fol-lowing may be used.6.3.2.1 Isopropyl Alcohol (IPA, propan-2-ol), i

46、n accordancewith the requirements of Specification D4171 (Type II). Maybe used in concentrations recommended by the aircraft manu-facturer when required by the aircraft owner/operator.NOTE 3Addition of isopropyl alcohol (IPA) may reduce knock ratingsbelow minimum specification values (see X1.2.4).66

47、.3.2.2 Di-Ethylene Glycol Monomethyl Ether (Di-EGME),conforming to the requirements of Specification D4171 (TypeIII). May be used in concentrations of 0.10 to 0.15 volumepercent when required by the aircraft owner/operator.6.3.2.3 Test Method D5006 can be used to determine theconcentration of Di-EGM

48、E in aviation fuels.6.3.3 Electrical Conductivity AdditiveStadis 4507in con-centrations up to 3 mg/L is permitted. When loss of fuelconductivity necessitates retreatment with electrical conductiv-ity additive, further addition is permissible up to a maximumcumulative level of 5 mg/L of Stadis 450.6.

49、3.4 Corrosion Inhibitor AdditiveThe following corro-sion inhibitors may be added to the gasoline in concentrationsnot to exceed the maximum allowable concentration (MAC)listed for each additive.DCI-4A MAC=24g/m3DCI-6A MAC=15g/m3HITEC 580 MAC = 22.5 g/m3NALCO 5403 MAC = 22.5 g/m3NALCO 5405 MAC = 11.0 g/m3PRI-19 MAC = 22.5 g/m3UNICOR J MAC = 22.5 g/m3SPEC-AID 8Q22 MAC = 24.0 g/m3TOLAD 351 MAC = 24.0 g/m3TOLAD 4410 MAC = 22.5 g/m37. Detailed Requirements7.1 The aviation gasoline shall conform to the requirementsprescribed in Table 1.7.2 Test result