ASTM D975-2008ae1 Standard Specification for Diesel Fuel Oils.pdf

1、Designation: D 975 08a1An American National StandardStandard Specification forDiesel Fuel Oils1This standard is issued under the fixed designation D 975; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A

2、number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1NOTERemoved effective date from Table 1 editorially in December 2

3、008.1. Scope*1.1 This specification covers seven grades of diesel fuel oilssuitable for various types of diesel engines. These grades aredescribed as follows:1.1.1 Grade No. 1-D S15A special-purpose, light middledistillate fuel for use in diesel engine applications requiring afuel with 15 ppm sulfur

4、 (maximum) and higher volatility thanthat provided by Grade No. 2-D S15 fuel.21.1.2 Grade No. 1-D S500Aspecial-purpose, light middledistillate fuel for use in diesel engine applications requiring afuel with 500 ppm sulfur (maximum) and higher volatility thanthat provided by Grade No. 2-D S500 fuel.2

5、1.1.3 Grade No. 1-D S5000A special-purpose, lightmiddle distillate fuel for use in diesel engine applicationsrequiring a fuel with 5000 ppm sulfur (maximum) and highervolatility than that provided by Grade No. 2-D S5000 fuels.1.1.4 Grade No. 2-D S15A general purpose, middledistillate fuel for use in

6、 diesel engine applications requiring afuel with 15 ppm sulfur (maximum). It is especially suitable foruse in applications with conditions of varying speed and load.21.1.5 Grade No. 2-D S500A general-purpose, middledistillate fuel for use in diesel engine applications requiring afuel with 500 ppm su

7、lfur (maximum). It is especially suitablefor use in applications with conditions of varying speed andload.21.1.6 Grade No. 2-D S5000A general-purpose, middledistillate fuel for use in diesel engine applications requiring afuel with 5000 ppm sulfur (maximum), especially in conditionsof varying speed

8、and load.1.1.7 Grade No. 4-DA heavy distillate fuel, or a blend ofdistillate and residual oil, for use in low- and medium-speeddiesel engines in applications involving predominantly con-stant speed and load.NOTE 1Amore detailed description of the grades of diesel fuel oils isgiven in X1.2.NOTE 2The

9、Sxxx designation has been adopted to distinguish gradesby sulfur rather than using words such as “Low Sulfur” as previouslybecause the number of sulfur grades is growing and the word descriptionswere thought to be not precise. S5000 grades correspond to the so-called“regular” sulfur grades, the prev

10、ious No. 1-D and No. 2-D. S500 gradescorrespond to the previous “Low Sulfur” grades. S15 grades were not inthe previous grade system and are commonly referred to as “Ultra-LowSulfur” grades or ULSD.1.2 This specification, unless otherwise provided by agree-ment between the purchaser and the supplier

11、, prescribes therequired properties of diesel fuels at the time and place ofdelivery.1.2.1 Nothing in this specification shall preclude observanceof federal, state, or local regulations which may be morerestrictive.NOTE 3The generation and dissipation of static electricity can createproblems in the

12、handling of distillate diesel fuel oils. For more informa-tion on the subject, see Guide D 4865.1.3 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.2. Referenced Documents2.1 ASTM Standards:3D56 Test Method for Flash Point by Ta

13、g Closed Cup TesterD86 Test Method for Distillation of Petroleum Products atAtmospheric Pressure1This specification is under the jurisdiction of ASTM Committee D02 onPetroleum Products and Lubricants and is the direct responsibility of SubcommitteeD02.E0.02 on Diesel Fuel Oils.Current edition approv

14、ed Oct. 1, 2008. Published October 2008. Originallyapproved in 1948. Last previous edition approved in 2008 as D 97508.2This fuel complies with 40 CFR Part 80Control of Air Pollution from NewMotor Vehicles: HeavyDuty Engines and Vehicle Standards and Highway DieselFuel Sulfur Control Requirements: F

15、inal Rule. Regulation of Fuels and FuelAdditives: Fuel Quality Regulations for Highway Diesel Fuel Sold in 1993 andLater Calendar Years.3For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume in

16、formation, refer to the standards Document Summary page onthe ASTM website.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.D93 Test Methods for Flash Point by Pensky-M

17、artensClosed Cup TesterD 129 Test Method for Sulfur in Petroleum Products (Gen-eral Bomb Method)D 130 Test Method for Corrosiveness to Copper fromPetroleum Products by Copper Strip TestD 445 Test Method for Kinematic Viscosity of Transparentand Opaque Liquids (and Calculation of Dynamic Viscos-ity)D

18、 482 Test Method for Ash from Petroleum ProductsD 524 Test Method for Ramsbottom Carbon Residue ofPetroleum ProductsD 613 Test Method for Cetane Number of Diesel Fuel OilD 1266 Test Method for Sulfur in Petroleum Products(Lamp Method)D 1319 Test Method for Hydrocarbon Types in LiquidPetroleum Produc

19、ts by Fluorescent Indicator AdsorptionD 1552 Test Method for Sulfur in Petroleum Products(High-Temperature Method)D 1796 Test Method forWater and Sediment in Fuel Oils bythe Centrifuge Method (Laboratory Procedure)D 2274 Test Method for Oxidation Stability of DistillateFuel Oil (Accelerated Method)D

20、 2500 Test Method for Cloud Point of Petroleum ProductsD 2622 Test Method for Sulfur in Petroleum Products byWavelength Dispersive X-ray Fluorescence SpectrometryD 2624 Test Methods for Electrical Conductivity of Avia-tion and Distillate FuelsD 2709 Test Method for Water and Sediment in MiddleDistil

21、late Fuels by CentrifugeD 2880 Specification for Gas Turbine Fuel OilsD 2887 Test Method for Boiling Range Distribution ofPetroleum Fractions by Gas ChromatographyD3117 Test Method for WaxAppearance Point of DistillateFuelsD 3120 Test Method for Trace Quantities of Sulfur in LightLiquid Petroleum Hy

22、drocarbons by Oxidative Microcou-lometryD 3828 Test Methods for Flash Point by Small Scale ClosedCup TesterD 4057 Practice for Manual Sampling of Petroleum andPetroleum ProductsD 4177 Practice for Automatic Sampling of Petroleum andPetroleum ProductsD 4294 Test Method for Sulfur in Petroleum and Pet

23、roleumProducts by Energy Dispersive X-ray Fluorescence Spec-trometryD 4306 Practice for Aviation Fuel Sample Containers forTests Affected by Trace ContaminationD 4308 Test Method for Electrical Conductivity of LiquidHydrocarbons by Precision MeterD 4539 Test Method for Filterability of Diesel Fuels

24、byLow-Temperature Flow Test (LTFT)D 4737 Test Method for Calculated Cetane Index by FourVariable EquationD 4865 Guide for Generation and Dissipation of StaticElectricity in Petroleum Fuel SystemsD 5453 Test Method for Determination of Total Sulfur inLight Hydrocarbons, Spark Ignition Engine Fuel, Di

25、eselEngine Fuel, and Engine Oil by Ultraviolet FluorescenceD 5771 Test Method for Cloud Point of Petroleum Products(Optical Detection Stepped Cooling Method)D 5772 Test Method for Cloud Point of Petroleum Products(Linear Cooling Rate Method)D 5773 Test Method for Cloud Point of Petroleum Products(Co

26、nstant Cooling Rate Method)D 5842 Practice for Sampling and Handling of Fuels forVolatility MeasurementD 5854 Practice for Mixing and Handling of LiquidSamples of Petroleum and Petroleum ProductsD 6078 Test Method for Evaluating Lubricity of DieselFuels by the Scuffing Load Ball-on-Cylinder Lubricit

27、yEvaluator (SLBOCLE)D 6079 Test Method for Evaluating Lubricity of DieselFuels by the High-Frequency Reciprocating Rig (HFRR)D 6217 Test Method for Particulate Contamination inMiddle Distillate Fuels by Laboratory FiltrationD 6371 Test Method for Cold Filter Plugging Point ofDiesel and Heating Fuels

28、D 6468 Test Method for High Temperature Stability ofMiddle Distillate FuelsD 6469 Guide for Microbial Contamination in Fuels andFuel SystemsD 6751 Specification for Biodiesel Fuel Blend Stock(B100) for Middle Distillate FuelsD 6890 Test Method for Determination of Ignition Delayand Derived Cetane Nu

29、mber (DCN) of Diesel Fuel Oils byCombustion in a Constant Volume ChamberD 6898 Test Method for Evaluating Diesel Fuel Lubricityby an Injection Pump Rig2.2 Other Documents:26 CFR Part 48 Manufacturers and Realtors Excise Taxes440 CFR Part 80 Regulation of Fuels and Fuel Additives4API RP 2003 Protecti

30、on Against Ignitions Arising Out ofStatic, Lightning, and Stray Currents5EN 14078 Liquid petroleum products - Determination offatty acid methyl esters (FAME) in middle distillates -Infrared spectroscopy method63. Terminology3.1 Definitions:3.1.1 biodiesel, nfuel comprised of mono-alkyl esters oflong

31、 chain fatty acids derived from vegetable oils or animalfats, designated B100.3.1.2 biodiesel blend (BXX), nblend of biodiesel fuel withdiesel fuel oils.3.1.2.1 DiscussionIn the abbreviation, BXX, the XXrepresents the volume percentage of biodiesel fuel in the blend.3.2 Definitions of Terms Specific

32、 to This Standard:4Available from U.S. Government Printing Office, Superintendent of Docu-ments, 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401.5Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036, http:/www.ansi.org.6Available from

33、 the National CEN members listed on the CEN website(www.cenorm.be) or from the CEN/TC 19 Secretariat (astm.nen.nl).D 975 08a123.2.1 S(numerical specification maximum)indicates themaximum sulfur content, in weight ppm (g/g), allowed by thisspecification in a diesel fuel grade.3.2.1.1 DiscussionOf the

34、 seven diesel fuel grades speci-fied in this standard, six have important distinguishing maxi-mum sulfur regulatory requirements.These are Grades No. 1-DS15, No. 1-D S500, No. 1-D S5000, No. 2-D S15, No. 2-DS500 and No. 2-D S5000. The seventh grade, No. 4-D, isdistinguished from these other grades b

35、y many major proper-ties in addition to sulfur (unregulated maximum), and thereforeis not included in this designation system.Thus, Grade No. 4-Ddoes not have the designation S20000 as part of its grade name.4. Sampling, Containers, and Sample Handling4.1 It is strongly advised to review all test me

36、thods prior tosampling to understand the importance and effects of samplingtechnique, proper containers, and special handling required foreach test method.4.2 Correct sampling procedures are critical to obtaining arepresentative sample of the diesel fuel oil to be tested. Referto Appendix X2 for rec

37、ommendations. The recommendedprocedures or practices provide techniques useful in the propersampling or handling of diesel fuels.5. Test Methods5.1 The requirements enumerated in this specification shallbe determined in accordance with the following methods:5.1.1 Flash PointTest Methods D93, except

38、where othermethods are prescribed by law. For all grades, Test MethodD 3828 may be used as an alternate with the same limits. ForGrades No. 1-D S15, No. 1-D S500 , No. 1-D S5000, No. 2-DS15, No. 2-D S500, and No. 2-D S5000, Test Method D56may be used as an alternate with the same limits, provided th

39、eflash point is below 93C and the viscosity is below 5.5 mm2/sat 40C. This test method will give slightly lower values. Incases of dispute,Test Methods D93shall be used as the refereemethod. Test Method D56can not be used as the alternatemethod for Grade No. 4-D because its minimum viscosity limitis

40、 5.5 mm2/s at 40C.5.1.2 Cloud PointTest Method D 2500. For all fuel gradesin Table 1, the automatic Test Methods D 5771, D 5772,orD 5773 can be used as alternates with the same limits. TestMethod D3117can also be used since it is closely related toTest Method D 2500. In case of dispute, Test Method

41、D 2500shall be the referee method.5.1.3 Water and SedimentTest Method D 2709 is used forfuel Grades No. 1-D S15, No. 1-D S500, No. 1-D S5000, No.2-D S15, No. 2-D S500, and No. 2-D S5000. Test MethodD 1796 is used for Grade No. 4-D.5.1.4 Carbon ResidueTest Method D 524 is used for fuelGrades No. 1-D

42、S15, No. 1-D S500, No. 1-D S5000, No. 2-DS15, No. 2-D S500 and No. 2-D S5000. Grade No. 4-D doesnot have a limit for carbon residue.5.1.5 AshTest Method D 482 is used for all grades inTable 1.5.1.6 DistillationTest Method D86 is used for GradesNo. 1-D S15, No. 1-D S500, No. 1-D S5000, No. 2-D S15, N

43、o.2-D S500, and No. 2-D S5000. For all grades, Test MethodD 2887 can be used as an alternate. Results from Test MethodD 2887 shall be reported as “Predicted D86” results byapplication of the correlation in Appendix X5 of Test MethodD 2887 to convert the values. In case of dispute, Test MethodD86shal

44、l be the referee method. Grade No. 4-D does not havedistillation requirements.5.1.7 ViscosityTest Method D 445 is used for all fuelgrades in Table 1.5.1.8 SulfurThe following list shows the referee testmethods and alternate test methods for sulfur, the range overwhich each test method applies and th

45、e corresponding fuelgrades.SulfurTest MethodRange GradesD 129(referee)0.1 mass % No. 1-D S5000, No. 2-D S5000,No. 4-DD 1266 0.0005 to 0.4 mass %5 to 4000 mg/kg (wt ppm)No. 1-D S500, No. 2-D S500D 1552 0.06 mass % No. 1- D S5000, No. 2-D S5000,No. 4-DD 2622(referee forS500 Grades)0.0003 to 5.3 mass %

46、3 to 53 000 mg/kg (wt ppm)All GradesD 3120 3.0 to 100 mg/kg (wt ppm) No. 1-D S15, No. 2-D S15No. 1-D S500, No. 2-D S500(S500 grades must be dilutedbefore testing)D 4294 0.0150 to 5.00 mass %150 to 50 000 mg/kg (wt ppm)No. 1- D S5000, No. 2-D S5000,No. 4-DD 5453(referee forS15 grades)0.0001 to 0.8 ma

47、ss %1.0 to 8000 mg/kg (wt ppm)All GradesNOTE 4The units used to report results in the above test methods are:D 129 mass %D 1266 mass %D 1552 mass %D 2622 mass %D 3120 ppm (g/g)D 4294 mass %D 5453 ppm (g/g)Results reported in mg/kg and in ppm (g/g) are numerically the same.The units used in Table 1 f

48、or the sulfur requirements are the units in whichresults for the referee test are reported.5.1.9 Copper CorrosionTest Method D 130, 3-h test at aminimum control temperature of 50C. This test method isused for fuel Grades No. 1-D S15, No. 1-D S500, No. 1-DS5000, No. 2-D S15, No. 2-D S500 and No. 2-D

49、S5000. GradeNo. 4-D does not have a copper corrosion requirement.5.1.10 Cetane NumberTest Method D 613 is used for allfuel grades in Table 1. Test Method D 6890 is used for all No.1-D and No. 2-D grades with the DCN result being comparedto the cetane number specification requirement of 40. TestMethod D 613 shall be the referee method.5.1.11 Cetane IndexTest Methods D 97680 is used forfuel Grades No. 1-D S15, No. 1-D S500, No. 2-D S15 and No.2-D S500. Grades No. 1-D S5000, No. 2-D S5000 and No. 4-Ddo not have an aromatics content requirement