ASTM D3013-1999(2012) Standard Specification for Epoxy Molding Compounds《环氧基树脂模塑化合物的标准规格》.pdf

1、Designation: D3013 99 (Reapproved 2012)Standard Specification forEpoxy Molding Compounds1This standard is issued under the fixed designation D3013; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number

2、 in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification covers requirements for epoxy ther-moset

3、ting molding compounds. It provides for theiridentification, quality control, and purchase in such a mannerthat the purchaser and the seller can agree on the substantialsimilarity of different commercial lots or shipments.1.2 The compounds covered under this specification consistof mixtures or blend

4、s of epoxy resins and curing agentsintimately combined, in an unreacted or partially reactedcondition, with fillers, reinforcements, colorants, and otherchemical agents.1.3 The values stated in SI units are to be regarded as thestandard.NOTE 1The properties included in this specification are those r

5、equiredto identify the kinds of molding compounds covered. There may be otherrequirements necessary to define particular characteristics. These will beadded to the specification as their inclusion becomes generally desirableand the necessary test data and methods become available.NOTE 2There is no s

6、imilar or equivalent ISO standard.2. Referenced Documents2.1 ASTM Standards:2D149 Test Method for Dielectric Breakdown Voltage andDielectric Strength of Solid Electrical Insulating Materialsat Commercial Power FrequenciesD150 Test Methods for AC Loss Characteristics and Permit-tivity (Dielectric Con

7、stant) of Solid Electrical InsulationD256 Test Methods for Determining the Izod PendulumImpact Resistance of PlasticsD495 Test Method for High-Voltage, Low-Current, Dry ArcResistance of Solid Electrical InsulationD570 Test Method for Water Absorption of PlasticsD618 Practice for Conditioning Plastic

8、s for TestingD638 Test Method for Tensile Properties of PlasticsD648 Test Method for Deflection Temperature of PlasticsUnder Flexural Load in the Edgewise PositionD790 Test Methods for Flexural Properties of Unreinforcedand Reinforced Plastics and Electrical Insulating Materi-alsD883 Terminology Rel

9、ating to PlasticsD1896 Practice for Transfer Molding Test Specimens ofThermosetting CompoundsD2863 Test Method for Measuring the Minimum OxygenConcentration to Support Candle-Like Combustion ofPlastics (Oxygen Index)D3892 Practice for Packaging/Packing of Plastics3. Terminology3.1 DefinitionsDefinit

10、ions of terms used in this specifica-tion are in accordance with Terminology D883.4. Classification4.1 GradesThis specification is subdivided into variousgrades of epoxy molding compounds based on physical prop-erties. This specification provides for a system of characteriza-tion and identification

11、which enables coverage for all commer-cially available grades having properties within the range of thepossible combinations as may be selected from Table 1.Agrade is designated by the cell numbers for each property in theorder in which they are listed in Table 1. When a property is notspecified, a

12、“0” is entered as the cell number.4.2 ClassesEach of the grades of epoxy molding com-pound may be further subdivided into classes according tospecial requirements. A class is designated by a capital letterfollowed by cell designation corresponding to the requirementsdetailed in Table 2. Where no spe

13、cial requirements, in additionto grade properties, are needed, no class designation is shown.1This specification is under the jurisdiction of ASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.16 on ThermosettingMaterials.Current edition approved Dec. 1, 2012. Publish

14、ed December 2012. Originallyapproved in 1972. Last previous edition approved in 2004 as D3013 - 99(2004)1.DOI: 10.1520/D3013-99R12.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume informa

15、tion, refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1NOTE 3An example of this classification system woul

16、d be grade12324-D-00200-F-3 an epoxy molding compound having the followingrequirements (see Table 1 and Table 2):NOTE 4Although the values listed in Table 1 and Table 2 arenecessary to include the range of properties available in existing materials,they should not be interpreted as implying that eve

17、ry possible combinationof the properties exists or can be obtained commercially.5. General Requirements5.1 The molding compounds shall be of uniform composi-tion and so formulated as to conform to the requirements of thisspecification.5.2 The apparent density, bulk factor, flow, particle size, andco

18、lor of the compounds shall be as agreed upon between thepurchaser and the seller in the order or contract. Propertiesother than those specified in this specification may also beagreed upon.6. Detail Requirements6.1 Test specimens molded by transfer in accordance withPractice D1896, or compression me

19、thods in accordance withthe suppliers recommendations shall conform to the require-ments prescribed in Section 4 and Table 1 and Table 2 for thegrade and classes specified.7. Sampling7.1 A batch or lot shall be considered as a unit of manufac-ture and may consist of a blend of two or more production

20、 runsof a resin.7.2 Adequate statistical sampling procedures shall be used.8. Specimen Preparation8.1 Unless otherwise agreed between the purchaser and theseller, test specimens shall be molded by transfer or compres-sion methods in accordance with the suppliers recommenda-tions. The method of sampl

21、e preparation shall be reported.9. Conditioning9.1 Unless otherwise specified in the test methods or in thisspecification for those tests where conditioning is required, themolded test specimen shall be conditioned in accordance withProcedure B of Practice D618.TABLE 1 Detail Grade Requirements for

22、Epoxy Molding CompoundsDesig-nationOrderNo.Property and UnitGrades (Cell Limits)01 23451 Water absorption, % in 24 h unspecified 3.02 Flexural strength, MPa unspecified 2073 Impact resistance, unspecifiedJ/m of notch 5344 Tensile strength, unspecifiedMPa 1385 Deflection temperature unspecifiedunder

23、load,C 70 to 100 101 to 150 151 to 200 201 to 250 250TABLE 2 Detail Class Requirements for Epoxy Molding CompoundsClassClassDesignationDesigna-tion OrderNo.Property and UnitClasses (Cell Limits)012345Dielectric D 1 permittivity unspecified 6.002 dissipation factor unspecified 0.20dielectric strength

24、, V/mil(short-time):3 dry unspecified 4004 wet unspecified min 80 % of dry value using same test5 arc resistance, s unspecified 180Flame-retardant F 1 flammability unspecified 40 . .D3013 99 (2012)29.2 Test ConditionsConduct tests in the standard labora-tory atmosphere of 23 6 2C and 50 6 5 % relati

25、ve humidity,unless otherwise specified in the test methods or in thisspecification. In cases of disagreement, the tolerances shall be61C and 62 % relative humidity.10. Test Methods10.1 The properties enumerated in this specification shall bedetermined in accordance with the following test methods:10

26、.2 Water AbsorptionTest Method D570. Test specimensshall be 51 by 3.2-mm disks. The 24-h immersion test shall beused.10.3 Flexural StrengthTest Method D790. Procedure Ashall be used with test specimens, 6.4 by 12.7 by 127-mm bars.10.4 Impact Resistance (Izod)Test Method D256, MethodA. Specimens shal

27、l be 12.7 by 12.7 by 63.5 mm.10.5 Tensile StrengthTest Method D638. The Type Ispecimen, 3.2 6 0.4-mm thick, shall be used.10.6 Deflection Temperature Under LoadTest MethodD648. Test specimens shall be 12.7 by 12.7 by 127-mm barstested at a fiber stress of 1.8 MPa.10.7 Permittivity and Dissipation Fa

28、ctorTest MethodsD150. Measure the permittivity and dissipation factor at 1 kHzusing 102 by 3.2-mm disks.10.8 Dielectric Strength (Dry)Test Methods D149. Speci-mens shall be 102 by 3.2-mm disks tested under oil betweencylindrical brass electrodes 25.4 mm in diameter, with edgerounded to a radius of 3

29、.2 mm.10.9 Dielectric Strength (Wet)Same test as for dielectricstrength (dry) only using test specimens conditioned in accor-dance with Procedure E of Practice D618.10.10 Arc ResistanceTest Method D495, using tungstenrod electrodes.10.11 FlammabilityTest Method D2863.11. Number of Tests11.1 Routine

30、testing of each batch or lot shall be limited tothe specified properties chosen from Table 1 and Table 2 of thisspecification unless otherwise designated.11.2 One set of specimens for those tests in Section 11 thatare designated shall be considered sufficient for testing thebatch or lot. If the numb

31、er of that specimen should not bestipulated in the test methods, the number required may beagreed upon between the purchaser and the seller. The averageresults for those specimens shall comply with the requirementsprescribed in this specification.12. Packaging and Package Marking12.1 PackagingThe ma

32、terial shall be packaged in airtightstandard commercial containers, so constructed as to ensureacceptance by common or other carriers for safe transportationat the lowest rate to the point of delivery, unless otherwisespecified in the contract or order.12.2 Package MarkingUnless otherwise agreed upo

33、n be-tween the purchaser and the seller, shipping containers shallidentify the material and its supplier, the batch or lot number,its type, and the quantity contained.12.3 All packing, packaging, and marking provisions ofPractice D3892 shall apply to this specification.13. Keywords13.1 epoxy; moldin

34、g compounds (thermosetting)SUMMARY OF CHANGESCommittee D20 has identified the location of selected changes to this standard since the last issue,D3013 - 99(2004)1, that may impact the use of this standard. (December 1, 2012)(1) Five year review and reapproval without editorial changes.ASTM Internati

35、onal takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely thei

36、r own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should b

37、e addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standard

38、s, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D3013 99 (2012)3