ASTM D3013-2013 Standard Specification for Epoxy Molding Compounds《环氧基树脂模塑化合物的标准规格》.pdf

1、Designation: D3013 99 (Reapproved 2012)D3013 13Standard Specification forEpoxy Molding Compounds1This standard is issued under the fixed designation D3013; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision.

2、A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification covers requirements for epoxy th

3、ermosetting molding compounds. It provides for their identification,quality control, and purchase in such a manner that the purchaser and the seller can agree on the substantial similarity of differentcommercial lots or shipments.1.2 The compounds covered under this specification consist of mixtures

4、 or blends of epoxy resins and curing agents intimatelycombined, in an unreacted or partially reacted condition, with fillers, reinforcements, colorants, and other chemical agents.1.3 The values stated in SI units are to be regarded as the standard.NOTE 1The properties included in this specification

5、 are those required to identify the kinds of molding compounds covered. There may be otherrequirements necessary to define particular characteristics. These will be added to the specification as their inclusion becomes generally desirable and thenecessary test data and methods become available.NOTE

6、2There is no similar or equivalent ISO known ISO equivalent to this standard.2. Referenced Documents2.1 ASTM Standards:2D149 Test Method for Dielectric Breakdown Voltage and Dielectric Strength of Solid Electrical Insulating Materials atCommercial Power FrequenciesD150 Test Methods for AC Loss Chara

7、cteristics and Permittivity (Dielectric Constant) of Solid Electrical InsulationD256 Test Methods for Determining the Izod Pendulum Impact Resistance of PlasticsD495 Test Method for High-Voltage, Low-Current, Dry Arc Resistance of Solid Electrical Insulation (Withdrawn 2013)3D570 Test Method for Wat

8、er Absorption of PlasticsD618 Practice for Conditioning Plastics for TestingD638 Test Method for Tensile Properties of PlasticsD648 Test Method for Deflection Temperature of Plastics Under Flexural Load in the Edgewise PositionD790 Test Methods for Flexural Properties of Unreinforced and Reinforced

9、Plastics and Electrical Insulating MaterialsD883 Terminology Relating to PlasticsD1896 Practice for Transfer Molding Test Specimens of Thermosetting CompoundsD2863 Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-Like Combustion of Plastics(Oxygen Index)D3892 Practice for

10、 Packaging/Packing of Plastics2.2 IEC Standards:IEC 61621 Dry Solid Insulating MaterialsResistance Test to High-Voltage, Low-Current Arc Discharges33. Terminology3.1 DefinitionsDefinitions of terms used in this specification are in accordance with Terminology D883.1 This specification is under the j

11、urisdiction of ASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.16 on Thermosetting Materials.Current edition approved Dec. 1, 2012Sept. 1, 2013. Published December 2012September 2013. Originally approved in 1972. Last previous edition approved in 20042012as D3013

12、- 99(2004)(2012).1. DOI: 10.1520/D3013-99R12.10.1520/D3013-13.2 For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at serviceastm.org. For Annual Book of ASTM Standardsvolume information, refer to the standards Document Summary page on the ASTM website

13、.3 The last approved version of this historical standard is referenced on www.astm.org.Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4thFloor, New York, NY 10036, http:/www.ansi.org.This document is not an ASTM standard and is intended only to provide the user of an AS

14、TM standard an indication of what changes have been made to the previous version. Becauseit may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current versionof the standard as published

15、 by ASTM is to be considered the official document.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States14. Classification4.1 GradesThis specification is subdivided into vario

16、us grades of epoxy molding compounds based on physical properties.This specification provides for a system of characterization and identification which enables coverage for all commerciallyavailable grades having properties within the range of the possible combinations as may be selected from Table

17、1. A grade isdesignated by the cell numbers for each property in the order in which they are listed in Table 1. When a property is not specified,a “0” is entered as the cell number.4.2 ClassesEach of the grades of epoxy molding compound may be further subdivided into classes according to specialrequ

18、irements. A class is designated by a capital letter followed by cell designation corresponding to the requirements detailed inTable 2. Where no special requirements, in addition to grade properties, are needed, no class designation is shown.NOTE 3An example of this classification system would be gra

19、de 12324-D-00200-F-3 an epoxy molding compound having the following requirements(see Table 1 and Table 2):NOTE 4Although the values listed in Table 1 and Table 2 are necessary to include the range of properties available in existing materials, they shouldnot be interpreted as implying that every pos

20、sible combination of the properties exists or can be obtained commercially.5. General Requirements5.1 The molding compounds shall be of uniform composition and so formulated as to conform to the requirements of thisspecification.5.2 The apparent density, bulk factor, flow, particle size, and color o

21、f the compounds shall be as agreed upon between thepurchaser and the seller in the order or contract. Properties other than those specified in this specification may also be agreed upon.TABLE 1 Detail Grade Requirements for Epoxy Molding CompoundsDesig-nationOrderNo.Property and UnitGrades (Cell Lim

22、its)0 1 2 3 4 51 Water absorption, % in 24 h unspecified 3.02 Flexural strength, MPa unspecified 2073 Impact resistance, unspecifiedJ/m of notch 5344 Tensile strength, unspecifiedMPa 1385 Deflection temperature unspecifiedunder load,C 70 to 100 101 to 150 151 to 200 201 to 250 250D3013 1326. Detail

23、Requirements6.1 Test specimens molded by transfer in accordance with Practice D1896, or compression methods in accordance with thesuppliers recommendations shall conform to the requirements prescribed in Section 4 and Table 1 and Table 2 for the grade andclasses specified.7. Sampling7.1 A batch or l

24、ot shall be considered as a unit of manufacture and may consist of a blend of two or more production runs ofa resin.7.2 Adequate statistical sampling procedures shall be used.8. Specimen Preparation8.1 Unless otherwise agreed between the purchaser and the seller, test specimens shall be molded by tr

25、ansfer or compressionmethods in accordance with the suppliers recommendations. The method of sample preparation shall be reported.9. Conditioning9.1 Unless otherwise specified in the test methods or in this specification for those tests where conditioning is required, themolded test specimen shall b

26、e conditioned in accordance with Procedure B of Practice D618.9.2 Test ConditionsConduct tests in the standard laboratory atmosphere of 23 6 2C and 50 6 5 %10 % relative humidity,unless otherwise specified in the test methods or in this specification. In cases of disagreement, the tolerances shall b

27、e 61C and62 %65 % relative humidity.10. Test Methods10.1 The properties enumerated in this specification shall be determined in accordance with the following test methods:10.2 Water AbsorptionTest Method D570.Test specimens shall be 51 by 3.2-mm disks.The 24-h immersion test shall be used.10.3 Flexu

28、ral StrengthTest Method D790. Procedure A shall be used with test specimens, 6.4 by 12.7 by 127-mm bars.10.4 Impact Resistance (Izod)Test Method D256, Method A. Specimens shall be 12.7 by 12.7 by 63.5 mm.10.5 Tensile StrengthTest Method D638. The Type I specimen, 3.2 6 0.4-mm thick, shall be used.10

29、.6 Deflection Temperature Under LoadTest Method D648. Test specimens shall be 12.7 by 12.7 by 127-mm bars tested ata fiber stress of 1.8 MPa.10.7 Permittivity and Dissipation FactorTest Methods D150. Measure the permittivity and dissipation factor at 1 kHz using102 by 3.2-mm disks.10.8 Dielectric St

30、rength (Dry)Test Methods D149. Specimens shall be 102 by 3.2-mm disks tested under oil betweencylindrical brass electrodes 25.4 mm in diameter, with edge rounded to a radius of 3.2 mm.10.9 Dielectric Strength (Wet)Same test as for dielectric strength (dry) only using test specimens conditioned in ac

31、cordancewith Procedure E of Practice D618.10.10 Arc ResistanceTest Method D495IEC 61621, using tungsten rod electrodes.10.11 FlammabilityTest Method D2863.11. Number of Tests11.1 Routine testing of each batch or lot shall be limited to the specified properties chosen from Table 1 and Table 2 of this

32、specification unless otherwise designated.TABLE 2 Detail Class Requirements for Epoxy Molding CompoundsClass ClassDesignationDesigna-tion OrderNo.Property and UnitClasses (Cell Limits)0 1 2 3 4 5Dielectric D 1 permittivity unspecified 6.002 dissipation factor unspecified 0.20dielectric strength, V/m

33、il(short-time):3 dry unspecified 4004 wet unspecified min 80 % of dry value using same test5 arc resistance, s unspecified 180Flame-retardant F 1 flammability unspecified 40 . .D3013 13311.2 One set of specimens for those tests in Section 11 that are designated shall be considered sufficient for tes

34、ting the batchor lot. If the number of that specimen should not be stipulated in the test methods, the number required may be agreed uponbetween the purchaser and the seller. The average results for those specimens shall comply with the requirements prescribed inthis specification.12. Packaging and

35、Package Marking12.1 PackagingThe material shall be packaged in airtight standard commercial containers, so constructed as to ensureacceptance by common or other carriers for safe transportation at the lowest rate to the point of delivery, unless otherwise specifiedin the contract or order.12.2 Packa

36、ge MarkingUnless otherwise agreed upon between the purchaser and the seller, shipping containers shall identifythe material and its supplier, the batch or lot number, its type, and the quantity contained.12.3 All packing, packaging, and marking provisions of Practice D3892 shall apply to this specif

37、ication.13. Keywords13.1 epoxy; molding compounds (thermosetting)SUMMARY OF CHANGESCommittee D20 has identified the location of selected changes to this standard since the last issue,D3013 - 99(2004)(2012),1, that may impact the use of this standard. (December(September 1, 2012)2013)(1) Five year re

38、view andUpdated humidity tolerances in 9.2reapproval without editorial changes(2) Replaced references to Test Method D495, which was withdrawn, with IEC 61621.ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this stand

39、ard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be review

40、ed every five years andif not revised, either reapproved or withdrawn.Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible

41、technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Consh

42、ohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D3013 134