ASTM D4216-2006 Standard Specification for Rigid Poly(Vinyl Chloride) (PVC) and Related PVC and Chlorinated Poly(Vinyl Chloride) (CPVC) Building Products Compounds《硬质聚氯乙烯(PVC)和相关PV.pdf

1、Designation: D 4216 06Standard Specification forRigid Poly(Vinyl Chloride) (PVC) and Related PVC andChlorinated Poly(Vinyl Chloride) (CPVC) Building ProductsCompounds1This standard is issued under the fixed designation D 4216; the number immediately following the designation indicates the year ofori

2、ginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of

3、Defense.1. Scope*1.1 This specification covers rigid plastic PVC and CPVCExterior compounds composed of poly(vinyl chloride), chlori-nated poly(vinyl chloride), vinyl chloride copolymers or vinylchloride blends, and the necessary compound ingredientsintended for use in making building products. The

4、compound-ing ingredients may consist of lubricants, stabilizers, nonpoly-(vinyl chloride) resin modifiers, colorants or pigments, or both,and inorganic fillers.1.2 This specification is intended to provide classification ofbase compounds used to manufacture PVC and CPVC exteriorbuilding products. Ph

5、ysical properties may be determined byevaluating compounds of any color.NOTE 1Two year weathering studies, without specific requirementsfor color change and physical property change, are recommended for allcolors of new compounds and compounds for new applications to providethe basis for agreement b

6、etween producer and buyer on the suitability ofthe compound for the intended application.1.3 The requirements in this specification are intended forqualification, as well as for quality control of compounds usedto manufacture building products. They are not applicable tofinished building products. S

7、ee Specifications D 3679, D 4477,D 4726, and F 964 for requirements for finished products.1.4 It may be necessary, in special cases, to select specificcompounds for unusual applications that require considerationof other properties not covered in this specification.1.5 The rate of burning test, Test

8、 Method D 635, is used inthis specification only as a screening test for identification ofcertain properties of the PVC compound; there is no flamma-bility test or flammability requirement for the compound.1.6 The values stated in SI units are to be regarded asstandard. The values given in brackets

9、are for information only.1.7 The following safety hazards caveat pertains only to thetest methods portion, Section 11, of this specification: Thisstandard does not purport to address all of the safety concerns,if any, associated with its use. It is the responsibility of the userof this standard to e

10、stablish appropriate safety and healthpractices and determine the applicability of regulatory limita-tions prior to use.NOTE 2There are no ISO standards covering the primary subjectmatter of this specification.1.8 The text of this standard references notes and footnotes,which provide explanatory mat

11、erial. These notes and footnotes(excluding those in tables and figures) shall not be consideredas requirements of this standard.1.9 Rigid PVC recycle plastic meeting the requirements ofthis specification may be usable in some applications. Refer tothe specific requirements in the Materials and Manuf

12、actureSection of the applicable product standard.2. Referenced Documents2.1 ASTM Standards:2D 256 Test Methods for Determining the Izod PendulumImpact Resistance of PlasticsD 618 Practice for Conditioning Plastics for TestingD 635 Test Method for Rate of Burning and/or Extent andTime of Burning of P

13、lastics in a Horizontal PositionD 638 Test Method for Tensile Properties of PlasticsD 648 Test Method for Deflection Temperature of PlasticsUnder Flexural Load in the Edgewise PositionD 696 Test Method for Coefficient of Linear Thermal Ex-pansion of Plastics Between 30C and 30C with aVitreous Silica

14、 DilatometerD 883 Terminology Relating to PlasticsD 1435 Practice for Outdoor Weathering of PlasticsD 1600 Terminology for Abbreviated Terms Relating toPlasticsD 1898 Practice for Sampling of Plastics31This specification is under the jurisdiction of ASTM Committee D20 onPlastics and is the direct re

15、sponsibility of Subcommittee D20.15 on ThermoplasticMaterials (Section D20.15.08).Current edition approved Dec. 1, 2006. Published January 2007. Originallyapproved in 1983. Last previous edition approved in 2003 as D 4216 03.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcon

16、tact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Withdrawn.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Bo

17、x C700, West Conshohocken, PA 19428-2959, United States.D 3010 Practice for Preparing Compression-Molded TestSample Plaques of Rigid Poly(Vinyl Chloride) Com-pounds3D 3679 Specification for Rigid Poly(Vinyl Chloride) (PVC)SidingD 4226 Test Methods for Impact Resistance of Rigid Poly-(Vinyl Chloride)

18、 (PVC) Building ProductsD 4477 Specification for Rigid (Unplasticized) Poly(VinylChloride) (PVC) SoffitD 4726 Specification for Rigid Poly(Vinyl Chloride) (PVC)Exterior-Profile Extrusions Used for Assembled Windowsand DoorsD 5260 Classification for Chemical Resistance of Poly(Vi-nyl Chloride) (PVC)

19、Homopolymer and Copolymer Com-pounds and Chlorinated Poly(Vinyl Chloride) (CPVC)CompoundsF 964 Specification for Rigid Poly (Vinyl Chloride) (PVC)Exterior Profiles Used for Fencing and Railing3. Terminology3.1 Definitions:3.1.1 GeneralDefinitions are in accordance with Termi-nology D 883 and Termino

20、logy D 1600, unless otherwiseindicated.3.2 Definitions of Terms Specific to This Standard:3.2.1 temperate northern climatein weather testing, aNorth American metropolitan area testing site located within73 to 100W longitude and 37 to 45N latitude.4. Classification4.1 The means for classifying and id

21、entifying rigid PVCbuilding products compounds are provided in Table 1. Theproperties enumerated in this table and the tests defined areexpected to provide identification of the compounds selected.They are not necessarily suitable for direct application indesign because of differences in shape of pa

22、rt, size, loading,environmental conditions, etc.4.2 Classes are designated by the cell number for eachproperty in the order in which they are listed in Table 1.NOTE 3Because of the large number of property requirements, theproperties of classes are divided into groups for easy identification of thes

23、elected materials. The groups are the following: kind of resin incompound, strength properties, and dimensional stability. The classnumbers are grouped as shown by the following example:TABLE 1 Class Requirements for Rigid Poly(Vinyl Chloride) and Related PVC and CPVC Compounds for Building Products

24、NOTEThe minimum property value will determine the cell number, although the maximum expected values may fall within the next higher cell.DesignationOrder No.Property and UnitCell Limits012345671 Kind of resin in compound Unspecified poly(vinylchloride)(PVC)chlorinatedpoly(vinylchloride)(CPVC)vinyl c

25、hloridecopolymervinyl chlorideblend2 Impact resistance, J/m of notchft lbf/in. of notchUnspecified 34.7 53.4 107 2670.65 1.0 2.0 5.03 Impact resistance, drop dart,Procedure A, Test MethodD 4226, J/m in.-lb/milUnspecified 4450 6675 8900 13 3501.0 1.5 2.0 3.04 Impact resistance, drop dart,Procedure B,

26、 Test MethodD 4226, J/m in.-lb/milUnspecified 4450 6675 8900 13 3501.0 1.5 2.0 3.05 Tensile strength, MPa psi Unspecified 34 37.7 41.4 44.9 48.35000 5500 6000 6500 70006 Modulus of elasticity in tension,MPa psiUnspecified2000 2400 2600 2800290 000 348 000 377 000 406 0007 Deflection temperature unde

27、rload, 1.82 MPa 264 psi CFUnspecified 60 65 70 75 80 85140 149 158 167 176 1858 Coefficient of linear expansion,cm/cm/C in/in/FUnspecified 4 3 1056 3 1058 3 10510 3 1052.2 3 105 3.3 3 105 4.4 3 105 5.5 3 105D 4216 062NOTE 4The manner in which selected materials are identified by thisclassification s

28、ystem is illustrated by a Class 1-32021-22-2020 PVCbuilding products compound having the following requirements (see Table1):NOTE 5The cell-type format provides the means for classification andclose characterization and specification of material properties, alone or incombination, for a broad range

29、of materials. This type format, however, issubject to possible misapplication since unobtainable property combina-tions can be selected if the user is not familiar with commercially availablematerials. The manufacturer should be consulted.4.3 Product application chemical resistance when specifiedsha

30、ll be classified according to the Classification Section ofClassification D 5260.5. Ordering Information5.1 The purchase order, or inquiry, for these materials shallstate this specification number and identify the class selected;for example, D 4216, Class 1-32021-22.5.2 Further definition, as may be

31、 required for the following,shall be on the basis of agreement between the purchaser andthe seller.5.2.1 Physical form and particle size (see 6.2 and 6.3).5.2.2 Contamination level (see 6.4).5.2.3 Other supplementary definition, if necessary.5.2.4 Inspection (see 12.1).6. Materials and Manufacture6.

32、1 Resin (Polymer) Requirements:6.1.1 Poly(vinyl chloride) (PVC) resin (polymer) meetingCell 1 in Designation Order 1 shall have a polymerized vinylchloride content not less than 99.0 %.6.1.2 Unless otherwise stated, vinyl chloride copolymerresin (polymer) meeting Cell 3 in Designation Order 1 shallc

33、ontain not less than polymerized 80 % vinyl chloride content.6.1.3 Vinyl chloride resin (polymer) blends with non-PVCpolymers meeting Cell 4 of Designation Order 1 shall have notless than 50 % PVC content.6.2 Materials supplied under this specification shall be PVCcompound in the form of cubes, pell

34、ets, granules, free-flowingpowder blends, or compacted powder blends.6.3 Materials shall be of uniform composition and size, asagreed upon between the purchaser and the seller.6.4 Materials shall be free of foreign matter to a level that isnot expected to affect processability, serviceability, or fi

35、nishedproduct appearance adversely.6.5 Color and transparency or opacity of molded or ex-truded articles formed under the conditions recommended bythe seller shall be comparable, within commercial matchtolerances, to the color and transparency or opacity of standardmolded or extruded samples of the

36、same thickness supplied inadvance by the seller of the material.7. Sampling7.1 A batch or lot shall be considered as a unit of manufac-ture and may consist of a blend of two or more production runsof material.7.2 The material shall be sampled in accordance with theprocedure described in the General

37、and Specific SamplingProcedures, as applicable, of Practice D 1898. Adequate statis-tical sampling prior to packaging shall be considered anacceptable alternative.8. Physical Requirements8.1 Test values for specimens of the material prepared asspecified in Section 10 and tested in accordance with Se

38、ction11 shall conform to the requirements given in Table 1 for theclass selected.8.2 The compound, when tested in accordance with TestMethod D 635, shall not exceed an average extent of burn of100 mm 4 in. with an average time of burn not to exceed 10s. A sample thickness of 1 mm 0.040 in. 6 10 % is

39、 recom-mended.8.3 StabilityThe compound shall be adequately stabilizedagainst thermal degradation without sacrificing weatheringperformance.NOTE 6The type and amount of stabilizer may vary with thecompound formulation, the equipment on which the compound is pro-cessed, the temperatures during proces

40、sing steps, and the amount ofregrind (reworked) material or rigid PVC recycled plastic employed. Todate, no test procedure has been found that is suitable for use inspecifications of this type. Research methods that vary among laboratoriesand that have not been amenable to standardization are used.8

41、.4 Weatherability The compound shall be stabilizedadequately against changes in color, physical properties, andappearance due to weathering.8.4.1 Specific weathering requirements are covered withinproduct Specifications D 3679, D 4477, D 4726, and F 964 forthe applications related to these standards

42、.8.4.2 New compounds and compounds for new applicationsshall demonstrate minimal color, physical property, and ap-pearance change when tested in accordance with 11.8.9. Conformance Testing9.1 The minimum properties identified by the class desig-nations in Table 1 specified in the purchase order (see

43、 5.1) shallbe verified by the tests described in Section 11.9.2 Conformance with this specification shall be determinedwith one set of test results for each batch or lot. If there aremultiple test results, the average value for all test samples shallbe used to determine conformance.9.3 If the averag

44、e test value for a lot produces values belowthe minimum property values of the Class designation in Table1, the material does not conform to this specification.D 4216 06310. Specimen Preparation10.1 Compliance with the designated requirements chosenfrom Table 1 shall be determined with compression-m

45、olded,extruded or injection-molded test specimens for Izod impactresistance, tensile strength, tensile modulus of elasticity, de-flection temperature under load, and coefficient of linearexpansion. Specimens cut from laminates of compression-molded sections shall not be used unless it is shown by te

46、st thatcomplete fusion is obtained. Specimens cut from flat extrudedprofile samples shall be used for dropped dart impact andweatherability tests. It is understood that a material shall not betested without also specifying the method of specimen prepa-ration. When comparative tests of materials are

47、desired, thegreatest care shall be taken to ensure that all specimens areprepared in exactly the same way used to certify the cell classof the compound. Procedures used in preparing the testspecimens shall be as recommended by the supplier for eachspecific compound.NOTE 7It is possible that a specim

48、en taken from a finished productwill not produce the same results as a specimen prepared by the methodused for purposes of cell class testing and certification.11. Test Methods11.1 Conditioning Condition the test specimen for deflec-tion temperature (Test Method D 648) in accordance withProcedure B

49、of Practice D 618, except that the minimumconditioning time in the oven shall be 24 h. Condition all othertest specimens in accordance with Procedure A of PracticeD 618. The minimum conditioning time shall be 24 h.11.2 Test Conditions Unless otherwise specified in thetesting methods or in this specification, conduct tests in theStandard Laboratory Atmosphere of 23 6 2C 73.4 6 3.6Fand 50 6 5 % relative humidity. In cases of disagreement, thetolerances shall be 61