ASTM D4673-2002 Standard Classification System for Acrylonitrile-Butadiene-Styrene (ABS) Plastics and Alloys Molding and Extrusion Materials《丙烯腈-丁二烯-苯乙烯(ABS)塑料及合金模压和挤压材料的标准分类系统》.pdf

1、Designation: D 4673 02Standard Classification System forAcrylonitrileButadieneStyrene (ABS) Plastics and AlloysMolding and Extrusion Materials1This standard is issued under the fixed designation D 4673; the number immediately following the designation indicates the year oforiginal adoption or, in th

2、e case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 Thi

3、s classification system covers only ABS materialsand ABS alloys suitable for injection molding and extrusion.Some of these compositions may also be suitable for compres-sion molding. Recycle ABS and alloys will be addressed in aseparate standard.1.2 This classification system is not intended for the

4、 selec-tion of materials, but only as a means of calling out materialsto be used in the manufacture of parts. Materials are to beselected by personnel with expertise in the plastics field wherethe economics, the environment to be encountered, the inherentproperties of the materials, the part design,

5、 the part perfor-mance required, and the manufacturing process to be employedall enter into the selection.1.3 The properties included in this classification system arethose required to identify the compositions covered. There maybe other requirements necessary to identify particular charac-teristics

6、 important to specialized applications. These will beagreed upon between the user and the supplier by using thesuffixes given in Section 5.1.4 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationonly.1.5 The following precautionary cave

7、at pertains only to thetest methods portion, Section 12, of this classification system:This standard does not purport to address all of the safetyconcerns, if any, associated with its use. It is the responsibilityof the user of this standard to establish appropriate safety andhealth practices and de

8、termine the applicability of regulatorylimitations prior to use.NOTE 1This classification system and ISO 2580 are technicallyequivalent for those tests contained in both standards.2. Referenced Documents2.1 ASTM Standards:2D 256 Test Method for Determining the Pendulum ImpactResistance of Notched Sp

9、ecimens of PlasticsD 618 Practice for Conditioning Plastics for TestingD 638 Test Method for Tensile Properties of PlasticsD 648 Test Method for Deflection Temperature of PlasticsUnder Flexural LoadD 790 Test Methods for Flexural Properties of Unreinforcedand Reinforced Plastics and Electrical Insul

10、ating MaterialsD 883 Terminology Relating to PlasticsD 1003 Test Method for Haze and Luminous Transmittanceof Transparent PlasticsD 1525 Test Method for Vicat Softening Temperature ofPlasticsD 1999 Guide for the Selection of Specimens and TestParameters for International CommerceD 3641 Practice for

11、Injection Molding Test Specimens ofThermoplastic Molding and Extrusion MaterialsD 3892 Practice for Packaging/Packing of PlasticsD 4000 Classification System for Specifying Plastic Mate-rialsD 5630 Test Method for Ash Content in PlasticsE 105 Practice for Probability Sampling of Materials2.2 ISO Sta

12、ndards:3ISO/DIS 75 Plastics and EboniteDetermination of Tem-peratures of Deflection under LoadISO 179 PlasticsDetermination of Charpy ImpactStrength of Rigid MaterialsISO 291 PlasticsStandard Atmosphere for Conditioningand TestingISO/DIS 294 PlasticsInjection Moulding Test Specimen1This classificati

13、on system is under the jurisdiction ofASTM Committee D20 onPlastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterials.Current edition approved March 10, 2002. Published May 2002. Originallypublished as D 467396. Last previous edition D 467398.2For referenced ASTM stan

14、dards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor

15、, New York, NY 10036.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.of Thermoplastics MaterialsISO 306 PlasticsDetermination of Vicat Softening Tem-peratureISO/DIS 52

16、7, Parts 1 and 2, PlasticsDetermination ofTensile PropertiesISO 2580 Acrylonitrile/Butadiene/Styrene (ABS) Mouldingand Extrusion Materials, Part 2ISO 3167 Preparation and Use of Multipurpose Test Speci-men3. Terminology3.1 DefinitionsDefinitions of technical terms used in thisclassification system a

17、re in accordance with TerminologyD 883.4. Classification4.1 ABS materials, based on three or more monomers, aregrouped rather than rigidly classified. These groups are thensubdivided by class and then grades. In cases in which a resinmay be classed into more than one group, the supplier willdetermin

18、e the specific callout(s). Table ABS has both ASTMprocedure method and ISO procedure versions for calloutunder the preferred test system.TABLE ABS ASTM/ISO Values, Requirements, Natural Color OnlyANOTE 1For property test parameters, see Section 12.Group Description Class Description Grade Descriptio

19、nTensileStrength,MPa,BTestMethodD 638/ISO 527Modulus,MPa,TestMethodFlexuralD 790/TensileISO 527ImpactSoftening,TestMethodD 1525,C, 120/hTempera-ture orISO 306,C, 50/hIzodJ/m,CTestMethodD 256CharpykJ/m2,DISO 17901 Molding 1 medium impact 1 45 2600 40 - 90 852 40 2400 125 6 90 853 40 2200 150 8 90 854

20、 35 2200 80 5 90 855 32 1600 70 3 90 850 other2 high impact 1 35 2100 200 13 90 852 35 2000 250 16 90 853 30 1700 275 19 90 854 30 1700 325 25 90 855 25 1500 400 30 90 856 30 1600 184 12 90 850 other3 high heat 1 45 2300 100 5 115 1102 40 2000 125 6 110 1053 40 2400 125 6 105 1004 35 2000 150 10 105

21、 1005 35 2100 80 3 105 1006 34 1700 65 2 98 937 32 1800 50 - 105 1000 other4 platingE1 45 2500 150 8 105 1002 40 2600 80 3 105 1003 40 2200 200 13 100 954 35 2000 200 13 95 905 34 2200 80 3 93 880 other5 clearF1 40 2300 80 3 85 800 other6 additive FRG1 40 2200 200 13 85 802 40 2000 150 8 85 803 35 2

22、400 80 3 90 854 30 2000 150 8 90 855 25 1800 80 3 85 800 other0 other 0 other02 Extrusion 1 medium impact 1 50 2600 80 3 95 902 45 2400 80 3 90 853 40 2200 150 8 90 854 40 2000 80 3 90 855 35 2200 125 6 90 850 other2 high impact 1 35 2400 200 13 90 852 35 2200 325 25 90 853 30 2000 275 19 90 85D4673

23、022TABLE ContinuedGroup Description Class Description Grade DescriptionTensileStrength,MPa,BTestMethodD 638/ISO 527Modulus,MPa,TestMethodFlexuralD 790/TensileISO 527ImpactSoftening,TestMethodD 1525,C, 120/hTempera-ture orISO 306,C, 50/hIzodJ/m,CTestMethodD 256CharpykJ/m2,DISO 1794 30 2000 360 28 90

24、855 25 1800 400 30 90 856 25 1800 440 34 90 850 other3 FR 1 40 2300 280 19 90 852 35 2000 275 19 90 853 35 2000 210 17 85 800 other 0 other03 Alloys ABS/PVC 1 1 50 2700 80 5 100 952 40 1800 200 13 90 853 40 1800 275 19 80 754 35 2000 400 30 70 655 50 2100 440 34 110 1056 35 2000 475 38 70 657 45 240

25、0 200 13 80 750 other0 other 0 other04 Alloys ABS/PC 1 medium impact 1 55 2200 360 28 115 1102 55 2400 325 25 110 1053 50 2200 275 21 120 1154 45 2100 275 21 110 1055 40 1900 70 3 105 1000 other2 high impact 1 55 2400 400 30 125 1202 50 2300 400 30 115 1103 50 2200 475 39 125 1204 48 2100 275 21 110

26、 1055 45 2000 255 19 119 1140 other3 high heat 1 60 2400 275 21 140 1352 55 2400 400 30 130 1253 55 2000 500 41 125 1204 50 2300 360 28 135 1305 45 2100 600 50 130 1256 45 2000 325 25 128 1237 45 2000 325 25 119 1140 other4 plating 1 50 2300 440 36 130 1252 45 2200 400 30 120 1153 45 2100 360 28 110

27、 1050 other5 additive FR 1 60 2400 125 6 110 1052 55 2400 200 13 110 1053 55 2400 400 30 90 854 50 2000 440 36 110 1055 45 2100 275 21 110 1056 40 2000 440 36 110 1050 other0 other 0 otherAAll cell values are minimums.BMPa 3 145 = psi.CJ/m 3 18.73 3 103= ftlbf/in.DkJ/m23 0.476 = ftlbf/in.2. Test con

28、figuration 1aE.EPlating grades are those specifically recommended for plating or sputtering applications.FClear ABS has a light transmission of 70 % minimum. It may be tested using Test Method D 1003.GSpecific flammability requirements shall be specified by the user.NOTE 2An example of this classifi

29、cation system is as follows:The designation ABS0111 would indicate:ABS = acrylonitrilebutadienestyrene,01 (group) = injection-molding resin,1 (class) = medium impact, and1 (grade) = requirements given in Table ABS.D46730234.1.1 To facilitate the incorporation of future or specialmaterials, the “othe

30、r/unspecified” category (0) for group, class,and grade is shown in Table ABS. The basic properties can beobtained from Cell Table A, B, and C as they apply.4.2 Reinforced and lubricated versions of theABS materialsare classified in accordance with Table ABS and Cell Table A.TableABS specifies the un

31、reinforced material and Cell TableAspecifies the properties by either ASTM or ISO proceduresafter the addition of reinforcements or lubricants at the nominallevel indicated.4.2.1 A single letter shall be used for the major reinforce-ment or combination, or both, along with two digits thatindicate th

32、e percentage of addition by mass, with the toleranceas tabulated below:Symbol Material ToleranceC Carbon- and graphite-fiber reinforced 62%G Glass-reinforced 62%L Lubricants (for example,PTFE), graphite, siliconeand molybdenum disulfidedepends on material andprocessto be speci-fiedM Mineral-reinforc

33、ed 6 2%R Combinations of reinforcements orfillers, or both6 3 % for the total rein-forcementNOTE 3This part of the system uses percent of reinforcements oradditives, or both, in the callout of the modified basic material. The typesand percentages of reinforcements and additives should be shown on th

34、esuppliers technical data sheet unless this information is proprietary innature. If necessary, additional callout of these reinforcements andadditives can be accomplished by the use of the suffix part of the systemas described in Section 8.4.2.2 Specific requirements for reinforced, filled, or lubri

35、-cated materials shall be shown by a six-character designation.The designation shall consist of the letter A and the five digitscomprising the cell numbers for the property requirements inthe order in which they appear in Cell Table A.CELL TABLE A Reinforced ABS/Alloys(For property test parameters,

36、see Section 12.)Designa-tionGradePropertyCell Limits0 1 2 3 456 7891 Tensile strength, MPaA,minTest Method D 638 unspecified 40 50 60 70 80 90 100 110BISO 527, 1, 2 unspecified 40 50 60 70 80 90 100 110B2 Modulus, MPa, minTest Methods D 790 Flexural unspecified 3000 4000 5000 6000 7500 9000 11 000 1

37、5 000BISO 527 Tensile, chord unspecified 3000 4000 5000 6000 7500 9000 11 000 15 000B3 Impact, minTest Method D 256, Izod, J/mCunspecified 30 45 60 75 90 105 120 140BISO 179, Charpy, kJ/m2Dunspecified 234567810B4 Heat deflection temperature, C, minTest Method D 648 unspecified 65 85 90 95 100 105 11

38、0 115BISO/DIS 75 unspecified 65 85 89 94 98 103 108 112B5 To be determined unspecified . . . . . . . .AMPa 3 145 = psi.BSpecific value appears on drawing or contract, or both.CJ/m 3 18.73 3 103= ftlbf/in.DkJ/m23 0.476 = ft lbf/in2. Test configuration 1aE.CELL TABLE B Unreinforced ABS(For property te

39、st parameters, see Section 12.)Designa-tionGradePropertyCell Limits0 1 2 3 456 7891 Tensile strength, MPaA,minTest Method D 638 unspecified 20 25 30 35 40 45 50 55BISO 527, 1, 2 unspecified 20 25 30 35 40 45 50 55B2 Modulus, MPa, minTest Methods D 790, Flexural unspecified 1400 1600 1800 2000 2200 2

40、400 2600 2800BISO 527, Tensile, chord unspecified 1400 1600 1800 2000 2200 2400 2600 2800B3 Impact, minTest Method D 256, Izod, J/mCunspecified 30 100 150 200 250 300 350 400BISO 179, Charpy, kJ/m2Dunspecified 1 5 9 13 19 22 25 30B4 Softening temperature, C, minTest Method D 1525 unspecified 75 90 9

41、5 100 105 110 115 120BISO 306 unspecified 70 85 90 95 100 105 110 115B5 To be determined unspecified . . . . . . . .AMPa 3 145 = psi.BSpecific value appears on drawing or contract, or both.CJ/m 3 18.73 3 103= ftlbf/in.DkJ/m23 0.476 = ftlbf/in2. Test configuration 1aE.D46730244.2.2.1 Although the val

42、ues listed are necessary to includethe range of properties available in existing materials, usersshould not infer that every possible combination of theproperties exists or can be obtained.4.2.3 When the grade of the basic material is not known, oris not important, the use of “0” grade classificatio

43、n shall beused for reinforced materials in this system.NOTE 4An example of this classification for a reinforced ABS is asfollows:The designation ABS 120G30A55130 indicates:ABS 120 = Acrylonitrile-butadiene-styrene, molding resin, high im-pactG30 = Glass reinforced at 30 % nominal level,A = Cell Tabl

44、e A, property requirements,5 = 80 MPa tensile strength, min,5 = 7500 MPa flexural modulus, D 790, or tensile modulus,chord, ISO 527, min,1 = 30 J/m Izod or 2 kj/m2Charpy impact strength, min,3 = 90C heat deflection temperature, D 648, 89C, ISO 75min, and0 = unspecified.If no properties are specified

45、, the designation would be ABS120G30A00000.4.3 Cell Table B has been incorporated into this classifica-tion system to facilitate the classification of special materialswhere Table ABS or Cell Table A does not reflect the requiredproperties of ABS material. Cell Table B shall be used in thesame manne

46、r as Cell Table A.NOTE 5An example of a special material using this classificationsystem is as follows:The designation ABS 210B54220 would indicate the following, withthe material requirements from Cell Table B:ABS 210 = Acrylonitrilebutadienestyrene, extrusion resin, me-dium impact,B = Cell Table B

47、 property requirements,5 = 40 MPa tensile strength, min,4 = 2000 MPa Flexural modulus, D 790, or tensile modulus,chord, ISO 527, min,2 = 100 J/m Izod impact or 5 kj/m2Charpy impact strength,min,2 = 90C vicat softening point, D 1525 or 85C, ISO 306,min, and0 = unspecified.NOTE 6Mechanical properties

48、of pigmented or colored ABS or alloymaterials can differ from the mechanical properties of natural ABS oralloy material, depending on the choice and concentration of colorants.The main property affected is ductility, as illustrated by a reduction in Izodimpact strength and tensile-elongation values.

49、 If specific properties ofpigmented ABS or alloy materials are necessary, prior testing between thematerials supplier and end user should be initiated.CELL TABLE C Unreinforced ABS Alloy(For property test parameters, see Section 12.)Designa-tionGradePropertyCell Limits0 1 2 3 456 7891 Tensile strength, MPaA,minTest Method D 638 unspecified 30 35 40 45 50 55 60 65BISO 527, 1, 2 unspecified 30 35 40 45 50 55 60 65B2 Modulus, MPa, minTest Methods D 790, Flexural unspecified 1600 1800 2000 2200 2400 2600 2800 3000BISO 527, Tensile, chord unspe