ASTM D5213-2007 Standard Specification for Polymeric Resin Film for Electrical Insulation and Dielectric Applications《电绝缘和电介质用聚合树脂薄膜的标准规范》.pdf

1、Designation: D 5213 07An American National StandardStandard Specification forPolymeric Resin Film for Electrical Insulation and DielectricApplications1This standard is issued under the fixed designation D 5213; the number immediately following the designation indicates the year oforiginal adoption o

2、r, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope

3、*1.1 This specification covers requirements for the material,dimensions and tolerances, and property values of film, in sheetor strip form, with or without heat-sealable coatings.1.2 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for informationo

4、nly.NOTE 1This document is similar to IEC 60674, Part 3, Sheets 2, 4, 5,6, and 7.2. Referenced Documents2.1 ASTM Standards:2D 149 Test Method for Dielectric Breakdown Voltage andDielectric Strength of Solid Electrical Insulating Materialsat Commercial Power FrequenciesD 883 Terminology Relating to P

5、lasticsD 1711 Terminology Relating to Electrical InsulationD 2305 Test Methods for Polymeric Films Used for Elec-trical InsulationD 3636 Practice for Sampling and Judging Quality of SolidElectrical Insulating MaterialsD 4088 Practice for Preparation for Shipment of SolidElectrical Insulating Materia

6、ls32.2 IEC Standards:Publication 60674-3 Specification for Electrical Films forElectrical Purposes43. Terminology3.1 DefinitionsDefinitions are in accordance with Termi-nologies D 1711 and D 883 unless otherwise specified.3.2 Definitions of Terms Specific to This Standard:3.2.1 sheet, nmaterial grea

7、ter than 75 mm in width.3.2.2 strip, nmaterial 75 mm or less in width.4. Classification4.1 This specification covers the following:4.1.1 Type IGeneral purpose,4.1.2 Type IIHeat sealable,4.1.2.1 Grade 1One side coated, and4.1.2.2 Grade 2Two sides coated.4.2 Materials:4.2.1 Item APoly(N,N8-p,p8-oxydip

8、henylene pyromelliti-mide),4.2.2 Item BPoly(N,N8-p,p8-oxydiphenylene biphenyltet-racarboxylimide,4.2.3 Item CPoly(N,N8-p-phenylene biphenyltetracar-boxylimide),4.2.4 Item DFEP-fluorocarbon, and4.2.5 Item EPolyethylene terephthalate.4.2.6 Item FPolyethylene naphthalate.4.2.7 Item GPolyetherimide.5. O

9、rdering Information5.1 Order the film covered by this specification stating thetype, grade, class, thickness, width, and roll dimensions.6. Materials6.1 Type I material is flexible, unsupported film.6.2 Type II material is film meeting all of the requirementsof Type I, and having a heat-sealable coa

10、ting on one or bothsides.7. Requirements7.1 The film covered by this specification shall meet theproperty requirements given in Tables 1-7 and Table 8 whentested by the methods given in Test Methods D 2305.7.1.1 Type II films, prior to coating, shall meet all of therequirements given in Table 1 for

11、films of the thicknesses givenin Table 9.1This specification is under the jurisdiction of ASTM Committee D09 onElectrical and Electronic Insulating Materials and is the direct responsibility ofSubcommittee D09.07 on Flexible and Rigid Insulating Materials.Current edition approved Oct. 1, 2007. Publi

12、shed October 2007. Orginallyapproved in 1991. Last previous edition approved in 2004 as D 5213 04.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Docu

13、ment Summary page onthe ASTM website.3Withdrawn.4Available from American National Standards Institute (ANSI), 25 W. 43rd St.,4th Floor, New York, NY 10036, http:/www.ansi.org.1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Bo

14、x C700, West Conshohocken, PA 19428-2959, United States.TABLE 1 Property Values for Type I, Class A Film poly(N,N*-p-p*-oxydiphenylene pyromellitimide)Average Property ValueNominal Thickness, m (mils)7.5 (0.3) 13 (0.5) 20 (0.8) 25 (1.0) 50 (2.0) 75 (3.0) 100 (4.0) 130 (5.0)Tensile strength, min MPa

15、(psi),machine direction and transversedirection69(10 000)97(14 000)138(20 000)138(20 000)138(20 000)138(20 000)138(20 000)138(20 000)Elongation, min percent, machineand transverse direction10 20 35 35 40 45 45 45Shrinkage, max percent, afterexposure to 200 C (392 F),machine and transverse direction.

16、 . 0.30 0.30 0.35 0.35 0.35 0.35Moisture absorption, max percent, 100 % RH 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0Dielectric strength, min kV/mm(V/mil), 60 HzA,B120(3000)120(3000)180(4500)180(4500)150(3800)140(3600)100(2500)100(2500)Volume resistivity, min V-cm,B,C10151015101510151015101510151015Permittivit

17、y, max at 1 kHzB4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0Dissipation factor, max at 1 kHzB0.007 0.005 0.005 0.004 0.004 0.004 0.004 0.004AUse Type 3 electrodes in air of Table 1 of Test Method D 149 (opposing 6.4-mm diameter rods).BAt 23 C (73.4 F), 50 % RH.CThe median value of 5 measurements should be used f

18、or compliance.TABLE 2 Property Values for Type I, Class B Film poly(N,N*-p-p*-oxydiphenylene biphenyltetracarboxylimide)Average Property ValueNominal Thickness, m (mils)7.5 (0.3) 13 (0.5) 20 (0.8) 25 (1.0) 40 (1.6) 50 (2.0) 75 (3.0) 100 (4.0) 130 (5.0)Tensile strength, min MPa (psi),machine directio

19、n and transversedirection110(15 000)138(20 000)196(28 000)196(28 000)196(28 000)196(28 000)196(28 000)196(28 000)196(28 000)Elongation, min percent, machineand transverse direction24 40 80 80 80 80 80 80 80Shrinkage, max percent, afterexposure to 200 C (392 F),machine and transverse direction. . 0.3

20、0 0.30 0.35 0.35 0.35 0.35 0.35Moisture absorption, max percent, 100 % RH 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0Dielectric strength, min kV/mm(V/mil), 60 HzA,B120(3000)120(3000)180(4500)180(4500)150(3800)140(3500)130(3300)100(2500)95(2400)Volume resistivity, min V-cm,B,C10151015101510151015101510151015

21、1015Permittivity, max at 1 kHzB4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0Dissipation factor, max at 1 kHzB0.007 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005AUse Type 3 electrodes in air of Table 1 of Test Method D 149 (opposing 6.4-mm diameter rods).BAt 23 C (73.4 F), 50 % RH.CThe median value of 5 meas

22、urements should be used for compliance.TABLE 3 Property Values for Type I, Class C Film poly(N,N*-p-phenylene biphenyltetracarboxylimide)Average Property ValueNominal Thickness, m (mils)7.5 (0.3) 13 (0.5) 20 (0.8) 25 (1.0) 40 (1.6) 50 (2.0) 75 (3.0) 100 (4.0) 130 (5.0)Tensile strength, min MPa (psi)

23、,machine direction and transversedirection133(19 000)176(25 000)241(34 000)241(34 000)241(34 000)241(34 000)241(34 000)241(34 000)241(34 000)Elongation, min percent, machineand transverse direction25 25 25 25 25 25 25 25 25Shrinkage, max percent, afterexposure to 200 C (392 F),machine and transverse

24、 direction. . 0.15 0.15 0.15 0.20 0.20 0.20 0.20Moisture absorption, max percent, 100 % RH 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8 1.8Dielectric strength, min kV/mm(V/mil), 60 HzA,B120(3000)120(3000)180(4500)180(4500)150(3800)140(3500)120(3000)100(2500)95(2400)Volume resistivity, min V-cm,B,C101510151015101

25、510151015101510151015Permittivity, max at 1 kHzB4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0Dissipation factor, max at 1 kHzB0.007 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005AUse Type 3 electrodes in air of Table 1 of Test Method D 149 (opposing 6.4-mm diameter rods).BAt 23 C (73.4 F), 50 % RH.CThe media

26、n value of 5 measurements should be used for compliance.D52130727.1.2 Type II films, after coating, shall meet all of therequirements given in Table 1 for elongation, before and afterheating, and for shrinkage as given in Table 1 for films of thethicknesses given in Table 9.7.2 Roll Diameters:7.2.1

27、The outside diameters of rolls of film shall not varyfrom the value specified on the purchase order by more than6 6 mm (0.25 in.).7.2.2 The inside diameters of cores of standard rolls of filmshall not vary from the value specified on the purchase order bymore than 6 1.5 mm (0.060 in.).7.3 The widths

28、 of film in rolls shall be within the followingtolerances:7.3.1 Twenty-five mm (1 in.) wide or less, 6 0.4 mm (0.015in.).7.3.2 Over 25 to 100 mm (over 1 to 4 in.), 6 0.8 mm (0.030in.).7.3.3 Over 100 mm (4 in.), 6 1.6 mm (0.062 in.).7.4 The number of splices in standard rolls shall not exceedthe valu

29、es given in Table 10 for Type I film or Table 11 andTable 12 for Type II films.7.5 The thicknesses shall be within the tolerances specifiedin Table 13 for Type I film or Table 3 for Type II film.7.6 The color of the sheet or strip shall be uniform within agiven lot, as determined by visual examinati

30、on.7.7 The film shall be uniform in appearance, as determinedby visual examination. The film shall be clean and free fromcontamination, wrinkles, holes, scratches, and other defectsthat might affect either appearance or serviceability. Theheat-sealable coating for Type II material shall be uniform i

31、nappearance.8. Sampling8.1 Sample in accordance with Practice D 3636, unlessotherwise agreed upon between the supplier and the purchaser.8.2 For purposes of sampling, an inspection lot for exami-nation shall consist of all film of the same type, grade, class,TABLE 4 Property Values for Type I, Class

32、 D Film (FEPFluorocarbon)Average Property ValueNominal Thickness, m (mils)13(0.50)25(1.0)51(2.0)76(3.0)102(4.0)127(5.0)254(10.0)356(14.0)508(20.0)762(30.0)1016(40.0)1524(60.0)2413(95.0)Tensile strength, min MPa (psi),machine direction and transversedirection13.8(2000)17.25(2500)17.25(2500)17.25(2500

33、)17.25(2500)17.25(2500)17.25(2500)17.25(2500)17.25(2500)17.25(2500)17.25(2500)17.25(2500)17.25(2500)Elongation, min, %, machinedirection and transversedirection175 250 250 250 250 250 250 250 250 250 250 250 250Shrinkage, max percent, afterexposure to 200 C (392 F)5.0 5.0 3.0 2.0 2.0 2.0 2.0 2.0 2.0

34、 4.0 4.0 4.0 5.0Moisture absorption, max percent,100 %, RH0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1Dielectric strength, min at 60 HzkV/mm (V/mil)A,B160(4000)160(4000)140(3500)120(3000)110(2750)100(2500)72(1800)64(1600)56(1400). . . .Volume resistivity, min, V-cmB,C1017101710171017101710171

35、017101710171017101710171017Permittivity, max at 1 kHzB2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15Dissipation factor, max at 1 kHzB0.0003 0.0003 0.0003 0.0003 0.0003 0.0003 0.0003 0.0003 0.0003 0.0003 0.0003 0.0003 0.0003AUse Type 3 electrodes in air of Table 1 of Test Method D 1

36、49 (opposing 6.4-mm diameter rods).BAt 23 C (73.4 F), 50 % RH.CThe median value of 5 measurements should be used for compliance.TABLE 5 Property Values for Type I, Class E Film (Polyethylene Terephthalate)Average Property ValueNominal Thickness, m (mils)12 (0.48) 15 (0.60) 23 (0.92) 36 (1.42) 75 (3.

37、00) 100 (4.00) 190 (7.50) 250 (10.00)19 (0.75) 50 (2.00) 125 (5.00) 225 (9.00) 250Tensile strength, min MPa (psi),machine direction and transversedirection145 (21 000) 145 (21 000) 138 (20 000) 138 (20 000) 138 (20 000) 138 (20 000) 138 (20 000) 110(16 000)Elongation, min % machinedirection and tran

38、sverse direction60 60 65 70 70 70 70 70Shrinkage, max percent afterexposure to 150 C (302 F), 30 min3.5 3.0 3.0 3.0 3.0 3.0 3.0 2.0Moisture absorption, max %, 100 % RH 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8Dielectric strength, min at 60 Hz,kV/mm (V/mil)A,B208 (5300) 190 (4800) 174 (4400) 130 (3300) 105 (27

39、00) 80 (2000) 60 (1500) 50 (1300)Volume resistivity, min, V-cmB,C10151015101510151015101510151015Permittivity, max at 1 kHzB3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5Dissipation factor, max at 1 kHzB0.006 0.006 0.006 0.006 0.006 0.006 0.006 0.006AUse Type 3 electrodes in air of Table 1 of Test Method D 149 (op

40、posing 6.4-mm diameter rods).BAt 23 C (73.4 F), 50 % RH.CThe median value of 5 measurements should be used for compliance.D5213073and nominal thickness submitted for inspection at one time. Ifa single shipment contains film having different lot numbersassigned by the film manufacturer, sample each l

41、ot numberseparately.8.3 The total quantity of material to be taken from each lotshall be approximately twice that estimated to be required forthe tests that are to be made, in order to permit repeat testswithout resampling.8.4 These materials are normally made in master rolls ofapproximately 360 kg

42、(800 lb) in weight. Take samples forexamination and testing from the end of the master rolls.9. Number of Tests9.1 Unless otherwise agreed upon by the purchaser and theseller, routine lot inspection tests shall consist of evaluation ofall of the properties specified in 7.4-7.7. For these properties,

43、each master roll shall be considered a lot for sampling. Allsamples must pass inspection.9.2 Routine lot inspection tests for properties specified in7.1, including definition of the number of master rolls per lot,shall be agreed upon between the purchaser and the seller. Allsamples must pass inspect

44、ion.TABLE 6 Property Values for Type I, Class F Film (Polyethylene Naphthalate) Average Property ValueNominal Thickness, m (mils)12 (0.48) 16 (0.65) 25 (1.00) 38 (1.50) 50 (2.00) 75 (3.00) 100 (4.00) - 250 (10.00)Tensile strength, min MPa (psi),machine direction and transversedirection172 (25 000) 1

45、72 (25 000) 172 (25 000) 172 (25 000) 172 (25 000) 172 (25 000) 172 (25 000)Elongation, min percent, machineand transverse direction50 50 50 50 50 50 50Shrinkage, max percent, afterexposure to 150 C (302 F), 30 min2.00 2.00 2.00 2.00 2.00 2.00 2.00Moisture absorption, max %,at 100 % RH0.6 0.6 0.6 0.

46、6 0.6 0.6 0.6Dielectric strength, min at 60 Hz,kV/mm (V/mil)A,B215 (5500) 215 (5500) 195 (5000) 145 (3700) 145 (3700) 120 (3000) 120 (3000)Volume resistivity, min, V-cmB,Cohm-cm1015101510151015101510151015Permittivity, max at 1 kHzB3.4 3.4 3.4 3.4 3.4 3.4 3.4Dissipation factor, max at 1 kHzB0.006 0.

47、006 0.006 0.006 0.006 0.006 0.006AUse Type 3 electrodes in air of Table 1 of Test Method D 149 (opposing 6.4-mm diameter rods).BAt 23 C (73.4 F), 50 % RH.CThe median value of 5 measurements should be used for compliance.TABLE 7 Property Values for Type 1, Class G Film (Polyetherimide)Average Propert

48、y ValueNominal Thickness, m (mils)25 (1.00) 50 (2.00) 75 (3.00) 100 (4.00) 125 (5.00)Tensile Strength, min Mpa (psi), machine direction and transversedirection93 (13500) 93 (13500) 93 (13500) 93 (13500) 93 (13500)Elongation, min percent, machine direction and transverse direction 100.00 100.00 100.0

49、0 100.00 100.00Shrinkage, max percent, after exposure to 200 C (392 F) 0.60 0.60 0.50 0.40 0.40Moisture Absorption, max percent 100 % RH 1.20 1.20 1.20 1.20 1.20Dielectric strength, min kV/mm (V/mil)A,B284 (7100) 196 (4900) 148 (3700) 124 (3100) 108 (2400)Volume Resistivity, min V-cmB,C10171017101710171017Permittivity, max at 1kHzB3.40 3.40 3.40 3.40 3.40Dissipation Factor, max at 1kHzB0.0080 0.0080 0.0080 0.0080 0.0080AUse Type 3 electrodes in air of Table 1 of Test Method D 149 (opposing 6.4-mm diameter rods).BAt 23 C (73.4 F), 50