ASTM D5325-2003(2014) Standard Test Method for Determination of Weight Percent Volatile Content of Water-Borne Aerosol Paints《测定水性气溶胶油漆挥发物质重量百分比的标准试验方法》.pdf

1、Designation: D5325 03 (Reapproved 2014)Standard Test Method forDetermination of Weight Percent Volatile Content of Water-Borne Aerosol Paints1This standard is issued under the fixed designation D5325; the number immediately following the designation indicates the year oforiginal adoption or, in the

2、case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method is for the determination of the weightpercent volatile content of water

3、-borne paints in aerosols.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this

4、standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D2369 Test Method for Volatile Content of CoatingsD3792 Test Method for Water Content of Coatings by DirectInjection Into

5、a Gas ChromatographD4017 Test Method for Water in Paints and Paint Materialsby Karl Fischer MethodE180 Practice for Determining the Precision of ASTMMethods for Analysis and Testing of Industrial and Spe-cialty Chemicals (Withdrawn 2009)32.2 Other Standard:Method 36 Determination of Percent Volatile

6、 Organic Com-pounds (VOC) in Water Based Aerosol Paints43. Summary of Test Method3.1 The propellant is released from the can and the contentremaining is tested for percent water and nonvolatiles.4. Significance and Use4.1 Calculation of the weight percent volatile organic con-tent of water-borne pai

7、nts, requires that the water content beknown. This test method provides a direct way to determine theweight percent volatile organic matter of water-borne aerosolpaints minus the matter content. This test method is modeledafter Method 36.45. Apparatus5.1 Freezer.5.2 Ice Pick.5.3 Hammer.5.4 Applicato

8、r Sticks.5.5 Masking Tape.5.6 Tin Snips or Metal Cutter.5.7 Shaker, similar to Eberbach shaker in Fig. 1.6. Procedure6.1 Preparation of Aerosol Contents for Analysis:6.1.1 Mix the aerosol paint container thoroughly for about15 min, using a shaker similar to the Eberbach shaker shown inFig. 1, at the

9、 low speed setting. It is essential that the samplesbe well mixed to obtain valid results.6.1.2 Remove the cap and actuator from the can. Put the capon the can and weigh the can to 0.01 g.6.1.3 Place the can in an upside down position in a freezerfor2hatatemperature that is 0C.6.1.4 Put the can upsi

10、de down in a fume hood. Puncture thebottom of the can near the edge with a very sharp ice pick.Slowly remove the ice pick from the hole. Leave the holeuncovered for about 12 to 16 h to allow most of the propellantto escape.6.1.5 Enlarge the hole slightly by tapping the ice pickfurther into the can.

11、Swirl the can gently for 1 to 2 min toremove any remaining propellant.6.1.6 Wipe off any condensate that may have accumulatedon the can. Weigh the can to 60.01 g.6.1.7 Plug the hole with a small applicator stick (about12cm long) and then place masking tape over the plugged hole.1This test method is

12、under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.21 on Chemical Analysis of Paints and Paint Materials.Current edition approved July 1, 2014. Published July 2014. Originally approvedin 1992. Las

13、t previous edition approved in 2008 as D5325 03 (2008)1. DOI:10.1520/D5325-03R14.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page

14、 onthe ASTM website.3The last approved version of this historical standard is referenced onwww.astm.org.4Bay Area Air Quality Management District, (BAAQMD) Manual ofProcedures, Vol III, 939 Ellis St., San Francisco, CA 94109.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Cons

15、hohocken, PA 19428-2959. United States16.1.8 Place the can on the shaker in a position so that thehole is at the highest possible position to prevent leakage ofcontents. Shake the can for about 15 min at the low speedsetting.6.1.9 Cut the bottom of the can using a metal cutter. Stir thecontents with

16、 a spatula, then transfer the contents to a pint canwith lid.6.1.10 Rinse the aerosol can, agitators, and bottom severaltimes using solvent.Allow the can, agitators, and the bottom todry. Weigh to 60.01 g.7. Calculations7.1 Calculate the weight percent nonvolatile content (NV),of the paint in accord

17、ance with Test Method D2369.7.2 Calculate the total weight percent nonvolatile content(TNV), in the aerosol can as follows:TNV,%5NV!W5!W43100 (1)where:W4=W1W3,W5=W2W3,W1= total weight of aerosol container plus contents, g,W2= total weight of aerosol container minus propellant, g,W3= empty weight of

18、aerosol container, g,W4= contents including propellant, g, andW5= contents minus propellant, g.7.3 The total volatile percent (TV) in the aerosol containermay be calculated by difference as follows:TV,%5 100 2 TNV (2)7.4 Determine the water content of the coating in accor-dance with Test Method D379

19、2 or Test Method D4017.7.5 The weight percent volatile content (VC), equals totalvolatile percent TV, minus percent of water.7.6 The percent of grams of volatile content/grams of solidsequalsVCTNV.8. Precision and Bias8.1 PrecisionEstimates are based on an interlaboratorystudy in which 1 operator in

20、 each of 5 laboratories analyzed induplicate on 2 different days 1 sample of a water-borne aerosolcontaining 69 to 72 % organic volatiles. The coatings werecommercially supplied. The results were analyzed in accor-dance with Practice E180. The within laboratory coefficient ofvariation was found to b

21、e 1.67 % relative at 9 df and thebetween laboratory coefficient of variation was 2.14 % relativeat 7 df. Based on these coefficients, the following criteriashould be used for judging the acceptability of results at the95 % confidence level.8.1.1 RepeatabilityTwo results, each the mean of dupli-cate

22、determinations, obtained by the same operator on differentdays should be considered suspect if they differ by more than5.36 % relative.8.1.2 ReproducibilityTwo results each the mean of dupli-cate determinations obtained by operators in differentlaboratories, should be considered suspect if they diff

23、er bymore than 7.16 %.8.2 BiasBias cannot be determined because there are noaccepted standards for weight percent volatile content ofwater-borne aerosol paints.9. Keywords9.1 aerosols; volatile content; water-borne paintsASTM International takes no position respecting the validity of any patent righ

24、ts asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any

25、time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments wil

26、l receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by AST

27、M International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 1 Aerosol Can on Eberbach ShakerD5325 03 (2014)2