ASTM D5900-2008 317 Standard Specification for Physical and Chemical Properties of Industry Reference Materials (IRM).pdf

1、Designation: D 5900 08Standard Specification forPhysical and Chemical Properties of Industry ReferenceMaterials (IRM)1This standard is issued under the fixed designation D 5900; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the y

2、ear of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers the chemical and physicalquality specifications or requirements, or both, for Industr

3、yReference Materials (IRMs) as cited in Practice D 4678 andother standards.1.2 IRMs, as evaluated and referenced in Practice D 4678,are vitally important to conduct product, specification, anddevelopment testing in the rubber and carbon black industries.1.3 Before a new lot of material can be accept

4、ed as an IRM,it must comply with the specifications prescribed in thisspecification. However, these specifications are only part of therequirements. Other requirements as given in Practice D 4678shall be met before a candidate material can be formallyaccepted as an IRM.1.4 This standard does not pur

5、port to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D8

6、8 Test Method for Saybolt ViscosityD92 Test Method for Flash and Fire Points by ClevelandOpen Cup TesterD97 Test Method for Pour Point of Petroleum ProductsD 280 Test Methods for Hygroscopic Moisture (and OtherMatter Volatile Under the Test Conditions) in PigmentsD 287 Test Method forAPI Gravity of

7、Crude Petroleum andPetroleum Products (Hydrometer Method)D 445 Test Method for Kinematic Viscosity of Transparentand Opaque Liquids (and Calculation of Dynamic Viscos-ity)D611 Test Methods for Aniline Point and Mixed AnilinePoint of Petroleum Products and Hydrocarbon SolventsD 1278 Test Methods for

8、Rubber from Natural SourcesChemical AnalysisD 1416 Test Methods for Rubber From Synthetic SourcesChemical Analysis3D 1500 Test Method for ASTM Color of Petroleum Prod-ucts (ASTM Color Scale)D 1519 Test Methods for Rubber ChemicalsDetermination of Melting RangeD 1646 Test Methods for RubberViscosity,

9、 Stress Relax-ation, and Pre-Vulcanization Characteristics (Mooney Vis-cometer)D 1747 Test Method for Refractive Index of Viscous Mate-rialsD 1951 Test Method for Ash in Drying Oils and FattyAcids3D 1959 Test Method for Iodine Value of Drying Oils andFatty Acids3D 1960 Test Method for Loss on Heatin

10、g of Drying Oils3D 1965 Test Method for Unsaponifiable Matter in DryingOils, Fatty Acids, and Polymerized Fatty Acids3D 1980 Test Method for Acid Value of Fatty Acids andPolymerized Fatty Acids3D 1982 Test Method for Titer of Fatty AcidsD 1993 Test Method for Precipitated Silica-SurfaceArea byMultip

11、oint BET Nitrogen AdsorptionD 2007 Test Method for Characteristic Groups in RubberExtender and Processing Oils and Other Petroleum-Derived Oils by the Clay-Gel Absorption Chromato-graphic MethodD 2140 Test Method for Carbon-Type Composition of In-sulating Oils of Petroleum OriginD 2161 Practice for

12、Conversion of Kinematic Viscosity toSaybolt Universal Viscosity or to Saybolt Furol ViscosityD 2501 Test Method for Calculation of Viscosity-GravityConstant (VGC) of Petroleum OilsD 3037 Test Methods for Carbon BlackSurface Area byNitrogen Adsorption3D 3157 Test Method for Rubber from Natural Source

13、sColor1This specification is under the jurisdiction ofASTM Committee D11 on Rubberand is the direct responsibility of Subcommittee D11.20 on Compounding Materialsand Procedures.Current edition approved July 1, 2008. Published August 2008. Originallyapproved in 1996. Last previous edition approved in

14、 2003 as D 5900 03.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Withdrawn.1Copyright ASTM International,

15、100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.D 3194 Test Method for Rubber From Natural SourcesPlasticity Retention Index (PRI)D 3280 Test Methods for Analysis of White Zinc PigmentsD 4004 Test Methods for RubberDetermination of MetalContent by Flame Atomic Abs

16、orption (AAS) AnalysisD 4075 Test Methods for Rubber CompoundingMaterialsFlame Atomic Absorption AnalysisDetermination of MetalsD 4315 Test Methods for Rubber Compounding MaterialZinc OxideD 4569 Test Method for Rubber Compounding MaterialsDetermination of Acidity in SulfurD 4570 Test Method for Rub

17、ber ChemicalsDetermination of Particle Size of Sulfur by Sieving (Dry)D 4571 Test Methods for Rubber CompoundingMaterialsDetermination of Volatile MaterialD 4572 Test Method for Rubber ChemicalsWet SieveAnalysis of SulfurD 4574 Test Methods for Rubber CompoundingMaterialsDetermination of Ash Content

18、D 4578 Test Methods for Rubber ChemicalsDetermination of Percent Sulfur by ExtractionD 4678 Practice for RubberPreparation, Testing, Accep-tance, Documentation, and Use of Reference MaterialsD 4934 Test Method for Rubber Compounding Materials:2-Benzothiazyl Sulfenamide AcceleratorsInsolublesD 4936 T

19、est Method for Mercaptobenzothiazole Sulfena-mide Assay by Reduction/TitrationD 5289 Test Method for Rubber PropertyVulcanizationUsing Rotorless Cure MetersD 5712 Test Method for Analysis of Aqueous ExtractableProtein in Natural Rubber and Its Products Using theModified Lowry MethodD 6499 Test Metho

20、d for The Immunological Measurementof Antigenic Protein in Natural Rubber and its ProductsD 7427 Test Method for Immunological Measurement ofFour PrincipalAllergenic Proteins (Hev b 1, 3, 5 and 6.02)in Natural Rubber and Its Products Derived from Latex3. Significance and Use3.1 IRMs are vitally impo

21、rtant in product and specificationtesting, in research and development work, in technical servicework, and in quality control operations in the rubber andcarbon black industries. They are especially valuable forreferee purposes. Many ASTM rubber standards for the evalu-ation of natural or synthetic

22、rubber require the use of specificIRMs in their test recipes for better laboratory repeatability andreproducibility.3.2 New material lots that have been selected as candidatesfor IRM approval shall conform to the appropriate specifica-tions given in this standard and meet requirements given inPracti

23、ce D 4678 before the lots may be accepted as IRMs.3.3 The chemical and physical IRM specifications shownwill ensure some consistency in IRM properties from one lot tothe next. However, the specifications cannot ensure exactinter-lot consistency.4. Specifications4.1 The following are specifications f

24、or Industry ReferenceMaterials (IRMs).4.2 Specification for IRM 14Tetramethyl Thiuram Disul-fide (TMTD):4.2.1 Material description:Appearance is light buff to whitepowder. Specific gravity is 1.4. This material is commonlyused in certain ASTM rubber test recipes as an accelerator insulfur vulcanizat

25、ion.4.2.2 Specifications are given in Table 1.4.3 Specification for IRM 25Benzothiazyl Disulfide(MBTS)4.3.1 Material description: Appearance is cream-coloredpowder. Specific gravity is 1.5. This material shall contain 2 60.2 % mineral oil. This material is commonly used as anaccelerator in certain A

26、STM rubber test recipes in sulfurvulcanization.4.3.2 Specifications are given in Table 2.4.4 Specification for IRM 36N-tert-butyl-benzothiazoleSulfenamide (TBBS)4.4.1 Material description: Appearance is light tan or beigepellets approximately18 in. long. Specific gravity is 1.28.4.4.2 Specifications

27、 are given in Table 3.4.5 Specification for IRM 217Stearic Acid4.5.1 Material description: Appearance is a fine powder orflakes.4.5.2 Specifications are given in Table 4.4.6 Specification for IRM 318Sulfur4.6.1 Material description: Appearance is light to paleyellow powder.4.6.2 Specifications are g

28、iven in Table 5.4.7 Specification for IRM 439Naphthenic Process Oil:4.7.1 Material description: Appearance is translucent darkliquid. Specific gravity is 0.9. This material is commonly usedin certain ASTM rubber test recipes as a process oil. This oilhas been hydrotreated.4.7.2 Specifications are gi

29、ven in Table 6.4Lot IRM 1a is no longer available; IRM 1b has not been approved.5A lot IRM 2a has been depleted. Lot IRM 2b has not been approved.6An approved lot, IRM 3, has been reserved and is available fromAkron RubberDevelopment Lab Inc., 300 Kenmore Blvd., Akron, OH 44301, website: www.ard-.7A

30、n approved lot, IRM 21, has been reserved and is available from AkronRubber Development Lab Inc., 300 Kenmore Blvd., Akron, OH 44301, website:.8An approved lot, IRM 31, has been reserved and is available from AkronRubber Development Lab Inc., 300 Kenmore Blvd., Akron, OH 44301, website:.9No approved

31、 lot of IRM 43 has been established.TABLE 1 Specification for IRM 1Tetramethyl Thiuram Disulfide(TMTD)Property ASTM Designation LimitsMelting point, C D 1519 142 minAsh, % D 4574 0.10 maxLoss on heating at 105C, % loss D 4571 0.5 maxWet sieve analysis, % retaining on 100mesh screenD 4572 0.05 maxD59

32、000824.8 Specification for IRM 9110Zinc Oxide (ZnO):4.8.1 Material description: Appearance is a white powder.Specific gravity is 5.6. This material is commonly used inmany ASTM rubber test recipes as an activator and in ASTMtest recipes for testing halogenated elastomers as a vulcanizingagent.4.8.2

33、Specifications are given in Table 7.4.9 Specification for IRM 24111Butyl Rubber4.9.1 Material description: Appearance is pale white solidrubber. This is a copolymer of isobutylene and isoprene (IIR).The rubber shall be stabilized with a non-staining antioxidantsuitable for long-term storage. Specifi

34、c gravity is 0.92. Thismaterial is commonly used for the quality control monitoringof Mooney viscometers in accordance with Test MethodsD 1646.4.9.2 Specifications are given in Table 8.4.10 Specification for IRM 90212Petroleum Oil:4.10.1 Material description: Appearance is a light yellow,translucent

35、 liquid. Specific gravity is 0.8. This oil is a severelyhydrotreated naphthenic distillate. Its CAS registry number is64742-52-5. This oil is commonly used in ASTM oil immer-sion tests. Typical properties are as follows: Aromatics, Ca inaccordance with Test Method D 2140 is 12 %; pour point inaccord

36、ance with Test Method D97is 12C; color in accor-dance with Test Method D 1500 is L2.5; refractive index inaccordance with Test Method D 1747 is 1.5105; and UVabsorbance 260 nm is 4.0.4.10.2 Specifications are given in Table 9.4.11 Specification for IRM 90313Petroleum Oil:4.11.1 Material description:

37、 Appearance is a light yellow,translucent liquid. Specific gravity is 0.8. This oil is a severely10An approved lot, IRM 91a, has been reserved and is available from R. E.Carroll, Inc., P.O. Box 5806, Trenton, NJ 08638-0806.11An approved lot, IRM 241b, has been reserved and is available from AkronRub

38、ber Development Lab Inc., 300 Kenmore Blvd., Akron, OH 44301.12An approved lot, IRM 902a, has been reserved and is available from R. E.Carroll, Inc., P.O. Box 5806, Trenton, NJ 08638-0806.13An approved lot, IRM 903a, has been reserved and is available from R. E.Carroll, Inc., P.O. Box 5806, Trenton,

39、 NJ 08638-0806.TABLE 2 Specification for IRM 2Benzothiazyl Disulfide (MBTS)Property ASTM Designation LimitsMelting point, C D 1519 165 minAsh, % D 4574 0.7 maxLoss on heating at 105C, % loss D 4571 0.5 maxWet sieve analysis, % retained on 100mesh screenD 4572 0.1 maxTABLE 3 Specification for IRM 3N-

40、tert-butyl-benzothiazoleSulfenamide (TBBS)Property ASTM Designation Limit/TargetAssay, % D 4936 96 minMelting Point, Initial, C D 1519 108 minMelting Point, Final, C D 1519 109 minVolatile Matter, % D 1416 0.1 maxAsh, % D 4574 0.2 maxInsolubles in Methanol, % D 4934 0.3 maxTABLE 4 Specification for

41、IRM 21Stearic AcidProperty ASTM Designation Limit/TargetMineral Acid NoneAcid Value D 1980 193 to 199minTiter, C D 1982 66 minIodine Value, % D 1959 1.0 maxLoss on Heating, % D 1960 0.2 maxAsh, % D 1951 0.05 maxFat, Unsaponifiables and Insoluble, % D 1965 0.5 maxTABLE 5 Specification for IRM 31Sulfu

42、rProperty ASTM Designation Limit/TargetOrganic Material, % 0.05 maxVolatile Matter, C D 4571 0.5 maxAsh, % D 4574 0.3 maxInsoluble in CS2,% D 4578 0.3 maxAcidity, % D 4569 0.005 maxDry analysis, % retained on 100 meshscreenD 4570 0.0 maxDry analysis, % retained on 200 meshscreenD 4570 5to10TABLE 6 S

43、pecification for IRM 43Napthenic Process OilProperty ASTM Designation Limits/TargetsClay-gel absorption chromatographicanalysisD 2007% Asphaltenes 0.3 max% Polar compounds 6.0 max% Saturated hydrocarbon 35.1 to 65.0Viscosity 100C, mm2/s D88and D 2161 16.8 6 1.2Viscosity-gravity constant D 2501 0.889

44、 6 0.002TABLE 7 Specification for IRM 91Zinc Oxide (ZnO)Property ASTM Designation Limits/TargetsSurface area, m2/g D 4315 and D 3037 4.3 6 0.3% Zinc oxide D 3280 99.5 min% Lead D 4075 0.08 max% Cadmium D 4075 0.08 maxLoss on heating 105C % loss D 280 0.50 maxWet sieve analysis, %, retains on 45 m D

45、4315 0.10 maxTABLE 8 Specification for IRM 241Butyl RubberProperty ASTM Designation Limits/TargetsMooney Viscosity mL 1 + 8 125C(unmassed)D 1646 50.0 6 1.0Mooney Viscosity mL 1 + 4 100C(unmassed)D 1646 73.5 6 2.0Volatile matter, % D 1416 0.30 maxAsh, % D 1416 0.50 maxTABLE 9 Specification for IRM 90

46、2Petroleum OilProperty ASTM Designation Limits/TargetsViscosity: cst 99C D 445 20.35 6 1.15Gravity, API 16C D 287 20.0 6 1.0Flash pt. COC, C D92 240 minAniline point, C D611 93.0 6 3.0Viscosity-gravity constant D 2140 0.865 6 0.005Naphthenics Cn% D 2140 35 minParaffinics Cp% D 2140 50 maxD5900083hyd

47、rotreated naphthenic distillate. Its CAS registry number is64742-52-5. This IRM is commonly used in ASTM oilimmersion tests. Typical properties are as follows: Aromatics,Ca in accordance with Test Method D 2140 is 14 %; pour pointin accordance with Test Method D97 is 31C; color inaccordance with Tes

48、t Method D 1500 is L0.5; refractive indexin accordance with Test Method D 1747 is 1.5026; and UVabsorbance 260 nm is 2.2.4.11.2 Specifications are given in Table 10.4.12 Specification for IRM 91314Ammoniated Latex An-tigenic Protein4.12.1 Material description: Sealed vial for hypodermicextraction500

49、 test quantity.4.12.2 Specifications are given in Table 11.4.13 Specification for IRM 91415Rabbit Anti AL Antisera4.13.1 Material description: Sealed vial for hypodermicextraction7500 test quantity.4.13.2 Specifications are given in Table 12.4.14 Specification for IRM 91516Mouse monoclonal an-tibody Hb1-54.14.1 Material description:Vials with freezed materialupto 13 400 test quantity.4.14.2 Specifications are given in Table 13.4.15 Specification for IRM 91616Mouse monoclona