ASTM D6065-2005 Standard Practice for Handling Transportation and Storage of HFC-227ea 1 1 1 2 3 3 3-Heptafluoropropane (CF3CHFCF3)《HFC227ea 1 1 1 2 3 3 3-荧光丙烷(CF3CHFCF3)的装卸、运输和储存的.pdf

1、Designation: D 6065 05Standard Practice forHandling, Transportation, and Storage of HFC-227ea1,1,1,2,3,3,3-Heptafluoropropane (CF3CHFCF3)1This standard is issued under the fixed designation D 6065; the number immediately following the designation indicates the year oforiginal adoption or, in the cas

2、e of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 This practice covers guidance and direction to suppliers,reclaimers, purchasers, and users

3、 in the handling, transporta-tion, and storage of HFC-227ea.1.2 The values stated in inch-pound units are to be regardedas the standard. The SI units given in parentheses are forinformation only.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use.

4、 It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D 6064 Specification for HFC-227ea, 1,1,1,2,3,3,3-Heptafluoropropane (CF3CHFC

5、F3)2.2 CGA Standards:3C-1 Methods for Hydrostatic Testing of Compressed GasCylindersC-6 Standards for Visual Inspection of Steel CompressedGas CylindersC-7 Guide to Preparation of Precautionary Labeling andMarking of Compressed Gas ContainersP-1 Safe Handling of Compressed Gases in ContainersSB-1 Ha

6、zards of Refilling Compressed Refrigerant (Halo-genated Hydrocarbon) Gas CylindersSB-5 Hazards of Reusing Disposable Refrigerant (Haloge-nated Hydrocarbon) Gas CylindersSB-18 Use of Refrigerant (Halogenated Hydrocarbons) Re-covery Cylinders2.3 U.S. Government Standards:4Code of Federal Regulations (

7、CFR) Title 40, Part 82.106Code of Federal Regulations (CFR) Title 49, Part 173, U.S.Department of Transportation (DOT) Specifications,Shippers-General Requirements for Shipping and Packag-ingsCode of Federal Regulations (CFR) Title 49, Part 178, U.S.DOT Specifications, Specifications for PackagingsC

8、ode of Federal Regulations (CFR) Title 49, Part 180, U.S.DOT, Continuing Qualifications and Maintenance ofPackagings3. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 containersstorage vessels for HFC-227ea.3.1.2 cylinderscontainers of HFC-227ea.3.1.3 HFC-227ea1,1,1,2,3,3,3-Hepta

9、fluoropropane; acompound used to inert or suppress a fire or explosion hazard.3.1.4 insulatedplaced in an isolated situation to protectand prevent the transfer of damage.4. Significance and Use4.1 This practice provides requirements for the handling,transportation, and storage of HFC-227ea encounter

10、ed indistribution through both commercial and military channels. Itis intended to ensure that HFC-227ea is handled, transported,and stored in such a way that its physical property virtues arenot degraded. Transport may be by various means, such as, butnot limited to, highway, rail, water, and air.5.

11、 Practice5.1 To ensure safe handling, loading, unloading, storing,and transporting of material, personnel shall be trained in theCGA publications and Title 49 CFR regulations as listed in 2.2and 2.3, respectively.5.2 Handling:5.2.1 Handling shall be in accordance with CGA Publica-tion No. P-1, and a

12、s specified by the manufacturer.1This practice is under the jurisdiction of ASTM Committee D26 on Haloge-nated Organic Solvents and Fire Extinguishing Agents and is the direct responsi-bility of Subcommittee D26.09 on Fire Extinguishing Agents.Current edition approved June 1, 2005. Published July 20

13、05. Originally approvedin 1996. Last previous edition approved in 2000 as D 6065 00.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary p

14、age onthe ASTM website.3Available from Compressed Gas Association.4Available from Superintendent of Documents, U.S. Government PrintingOffice, Washington, DC 20036.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.5.2.1.1 Personnel who

15、 handle or store, or both, cylinders ofHFC-227ea shall be trained properly to recognize and identifythe characteristics of the product and the proper methods ofsafely handling full, partially full, and empty cylinders.5.2.2 All HFC-227ea transfers between storage containersand recycling processes sh

16、all be performed by personneltrained in handling procedures.5.2.3 HFC-227ea handling shall be in nonsmoking, heater-free, ventilated areas to preclude product accumulation. Provi-sions shall be made to ensure that service areas limit HFC-227ea concentrations do not exceed 10.5 % for 1 min and0.1 % f

17、or 8 h.5.2.4 Cylinders shall not be overfilled. The liquid portion ofthe liquefied gases must not completely fill the containersinternal volume at any temperature up to and including 130F(54C). The maximum permitted filling density for pureHFC-227ea shall be 79 lb/ft3(1265 kg/m3). The maximumpermitt

18、ed filling density for HFC-227ea super pressurized withnitrogen to 600 psig (25.8 bar) at 70F (21C) shall be 72 lb/ft3(1153 kg/m3). The maximum filling density for HFC-227easuper pressurized with nitrogen to 600 psig (42.4 bar) at 70Fshall be 68 lb/ft3. Filling density requirements are specified inT

19、itle 49 CFR, 173.304 and Title 49 CFR, 173.305.5.2.5 Handling of materials should be done in a manner thatprevents contamination or comingling of halocarbons otherthan of HFC-227ea.5.2.6 Cylinders shall be free of dirt and contamination thatwould contribute to or would cause deterioration of product

20、during shipment or storage. Precautions should be taken toprevent the entry of oil, water, or any other foreign matter intocontainers. Unique coatings or preservatives applied prior toshipment to protect the containers are not considered contami-nation.5.3 Transportation:5.3.1 Transportation shall b

21、e as specified in accordance withDOT regulations of Title 49 CFR.5.3.1.1 Shipment of materials between collectors, recyclers,and reclaimers should be within approved DOT guidelines forClass 2, Division 2.2, regulated materials. Any further provi-sions for special transportation or packaging should b

22、e agreedupon between the collectors, recyclers, and reclaimers.5.3.1.2 The minimum design pressure requirements shall beas indicated in Title 49 CFR, Part 173.301. The pressure insidethe container at 70F (21C) shall not exceed the servicepressure for which the container is marked. The pressure insid

23、ethe container at 130F (54C) shall not exceed54 times theservice pressure for which the container is marked. Fig. 1illustrates the effect of temperature on cylinders filled withHFC-227ea. Fig. 2 and Fig. 3 illustrate the effect of tempera-ture on mixtures of HFC-227ea and nitrogen for the cases ofHF

24、C-227ea superpressurized at 70F with nitrogen to a totalpressure of 360 psig (25.8 bar) and 600 psig (42.4 bar),respectively.5.3.2 Transportation shall be by suitable vehicles to pre-clude cylinder damage by excessive mechanical vibration,shock, freezing, or deleterious high temperatures throughoutt

25、he entire transport route.5.3.2.1 Should cylinders be expected to be subjected tounacceptable transport conditions, the cylinders should beplaced under insulated conditions.FIG. 1 HFC-227ea Isometric DiagramD60650525.3.3 Compressed gas cylinder permanent marking require-ments shall be as specified u

26、nder Part 178 of Title 49 CFR andmust be maintained in legible condition as required by Part 173of Title 49 CFR. Warning labels shall be affixed to cylindersconforming to requirements of Part 82.106 of Title 40 CFR.5.4 Storage:5.4.1 Storage shall be in accordance with CGA PublicationNo. P-1, in qual

27、ified cylinders in accordance with Title 49CFR, Parts 173 and 178.5.4.2 Cylinders should be stored in areas that will protectvessels from physical and environmental damage and tamper-ing from unauthorized personnel.5.4.2.1 Facilities should be of construction and orientationso that safety requiremen

28、ts are fulfilled for the storage ofpressurized cylinders.5.4.3 Storage cylinders shall be fitted with pressure releasemechanisms to limit vessel pressure to not more than the ratedworking pressure of the HFC-227ea container in use at anyparticular time.5.4.3.1 Periodic hydrostatic testing and reinsp

29、ection of cyl-inders used for recycled HFC-227ea shall comply with Title 49CFR, Part 173.34.5.4.4 Containers shall be clearly marked and labeled toidentify whether the HFC-227ea contained does or does notconform to this specification.5.4.5 Insulation shall be placed on pallets or shoring, andprovisi

30、ons should be made to prevent excessive shock orthermal fluctuations to cylinders.5.4.6 Cylinders shall be stored in a manner that will preventcontamination from external sources.5.4.6.1 If HFC-227ea meeting the standards of this specifi-cation is stored in the same area as material not meeting this

31、requirement, storage shall be segregated or clearly identifiableas not being similar.6. Inspection6.1 HFC-227ea that is reclaimed using approved HFC-227ea reclamation systems may be released for reissue, pro-vided test examination to validate the material to specificationis fulfilled.6.1.1 Reclaimed

32、 HFC-227ea that cannot be proven to com-ply with this specification shall not be reissued. The materialwill be processed by environmentally safe methods untilconformance to product standard is achieved.7. Keywords7.1 CF3CHFCF3; compressed gas; cylinders; explosion sup-pressant; fire suppressant; FE-

33、227y; FM-200t; handling;heptafluoropropane;1,1,1,2,3,3,3-heptafluoropropane; HFC-227ea; reclamation; recovery; recycling; storage; transportFIG. 2 Isometric Diagram HFC-227ea Pressurized to 360 psig (25.8 bar) With Nitrogen at 70F (21C)D6065053ASTM International takes no position respecting the vali

34、dity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subj

35、ect to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquar

36、ters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standar

37、d is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).FIG. 3 Isometric Diagram HFC-227ea Pressurized to 600 psig (42.4 bar) With Nitrogen at 70F (21C)D6065054