ASTM D6065-2011(2015) 2506 Standard Practice for Handling Transportation and Storage of HFC-227ea 1 1 1 2 3 3 3-Heptafluoropropane (CF3CHFCF3)《HFC-227ea 1 1 1 2 3 3 3-七氟丙烷 (CF3CHFC.pdf

1、Designation: D6065 11 (Reapproved 2015)Standard Practice forHandling, Transportation, and Storage of HFC-227ea1,1,1,2,3,3,3-Heptafluoropropane (CF3CHFCF3)1This standard is issued under the fixed designation D6065; the number immediately following the designation indicates the year oforiginal adoptio

2、n or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This practice covers guidance and direction to suppliers,reclaimers, purcha

3、sers, and users in the handling,transportation, and storage of HFC-227ea.1.2 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that are provided for information onlyand are not considered standard.1.3 This sta

4、ndard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1

5、ASTM Standards:2D6064 Specification for HFC-227ea, 1,1,1,2,3,3,3-Heptafluoropropane (CF3CHFCF3)2.2 CGA Standards:3C-1 Methods for Hydrostatic Testing of Compressed GasCylindersC-6 Standards for Visual Inspection of Steel CompressedGas CylindersC-7 Guide to Preparation of Precautionary Labeling andMa

6、rking of Compressed Gas ContainersP-1 Safe Handling of Compressed Gases in ContainersSB-1 Hazards of Refilling Compressed Refrigerant (Haloge-nated Hydrocarbon) Gas CylindersSB-5 Hazards of Reusing Disposable Refrigerant (Haloge-nated Hydrocarbon) Gas CylindersSB-18 Use of Refrigerant (Halogenated H

7、ydrocarbons) Re-covery Cylinders2.3 U.S. Government Standards:4Code of Federal Regulations (CFR) Title 40, Part 82.106Code of Federal Regulations (CFR) Title 49, Part 173, U.S.Department of Transportation (DOT) Specifications,Shippers-General Requirements for Shipping and Packag-ingsCode of Federal

8、Regulations (CFR) Title 49, Part 178, U.S.DOT Specifications, Specifications for PackagingsCode of Federal Regulations (CFR) Title 49, Part 180, U.S.DOT, Continuing Qualifications and Maintenance ofPackagings3. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 containersstorage ves

9、sels for HFC-227ea.3.1.2 cylinderscontainers of HFC-227ea.3.1.3 HFC-227ea1,1,1,2,3,3,3-Heptafluoropropane; acompound used to inert or suppress a fire or explosion hazard.3.1.4 insulatedplaced in an isolated situation to protectand prevent the transfer of damage.4. Significance and Use4.1 This practi

10、ce provides requirements for the handling,transportation, and storage of HFC-227ea encountered indistribution through both commercial and military channels. Itis intended to ensure that HFC-227ea is handled, transported,and stored in such a way that its physical property virtues arenot degraded. Tra

11、nsport may be by various means, such as, butnot limited to, highway, rail, water, and air.5. Practice5.1 To ensure safe handling, loading, unloading, storing,and transporting of material, personnel shall be trained in theCGA publications and Title 49 CFR regulations as listed in 2.2and 2.3, respecti

12、vely.5.2 Handling:1This practice is under the jurisdiction of ASTM Committee D26 on Haloge-nated Organic Solvents and Fire Extinguishing Agents and is the direct responsi-bility of Subcommittee D26.09 on Fire Extinguishing Agents.Current edition approved June 1, 2015. Published June 2015. Originally

13、approved in 1996. Last previous edition approved in 2011 as D6065 11. DOI:10.1520/D6065-11R15.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document

14、 Summary page onthe ASTM website.3Available from Compressed Gas Association, 14501 George Carter Way, Suite103, Chantilly VA 20151-1788, http:/.4Available from U.S. Government Publishing Office, 732, N. Capitol St., NW,Washington, DC 20401-0001, http:/www.gpo.gov.Copyright ASTM International, 100 Ba

15、rr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States15.2.1 Handling shall be in accordance with CGA Publica-tion No. P-1, and as specified by the manufacturer.5.2.1.1 Personnel who handle or store, or both, cylinders ofHFC-227ea shall be trained properly to recognize and ide

16、ntifythe characteristics of the product and the proper methods ofsafely handling full, partially full, and empty cylinders.5.2.2 All HFC-227ea transfers between storage containersand recycling processes shall be performed by personneltrained in handling procedures.5.2.3 HFC-227ea handling shall be i

17、n nonsmoking, heater-free, ventilated areas to preclude product accumulation. Provi-sions shall be made to ensure that service areas limit HFC-227ea concentrations do not exceed 10.5 % for 1 min and0.1 % for 8 h.5.2.4 Cylinders shall not be overfilled. The liquid portion ofthe liquefied gases must n

18、ot completely fill the containersinternal volume at any temperature up to and including 130F(54C). The maximum permitted filling density for pureHFC-227ea shall be 79 lb/ft3(1265 kg/m3). The maximumpermitted filling density for HFC-227ea super pressurized withnitrogen to 600 psig (25.8 bar) at 70F (

19、21C) shall be 72 lb/ft3(1153 kg/m3). The maximum filling density for HFC-227easuper pressurized with nitrogen to 600 psig (42.4 bar) at 70Fshall be 68 lb/ft3. Filling density requirements are specified inTitle 49 CFR, 173.304 and Title 49 CFR, 173.305.5.2.5 Handling of materials should be done in a

20、manner thatprevents contamination or comingling of halocarbons otherthan of HFC-227ea.5.2.6 Cylinders shall be free of dirt and contamination thatwould contribute to or would cause deterioration of productduring shipment or storage. Precautions should be taken toprevent the entry of oil, water, or a

21、ny other foreign matter intocontainers. Unique coatings or preservatives applied prior toshipment to protect the containers are not considered contami-nation.5.3 Transportation:5.3.1 Transportation shall be as specified in accordance withDOT regulations of Title 49 CFR.5.3.1.1 Shipment of materials

22、between collectors, recyclers,and reclaimers should be within approved DOT guidelines forClass 2, Division 2.2, regulated materials. Any further provi-sions for special transportation or packaging should be agreedupon between the collectors, recyclers, and reclaimers.5.3.1.2 The minimum design press

23、ure requirements shall beas indicated in Title 49 CFR, Part 173.301. The pressure insidethe container at 70F (21C) shall not exceed the servicepressure for which the container is marked. The pressure insidethe container at 130F (54C) shall not exceed54 times theservice pressure for which the contain

24、er is marked. Fig. 1illustrates the effect of temperature on cylinders filled withHFC-227ea. Fig. 2 and Fig. 3 illustrate the effect of tempera-ture on mixtures of HFC-227ea and nitrogen for the cases ofHFC-227ea superpressurized at 70F with nitrogen to a totalpressure of 360 psig (25.8 bar) and 600

25、 psig (42.4 bar),respectively.5.3.2 Transportation shall be by suitable vehicles to pre-clude cylinder damage by excessive mechanical vibration,shock, freezing, or deleterious high temperatures throughoutthe entire transport route.FIG. 1 HFC-227ea Isometric DiagramD6065 11 (2015)25.3.2.1 Should cyli

26、nders be expected to be subjected tounacceptable transport conditions, the cylinders should beplaced under insulated conditions.5.3.3 Compressed gas cylinder permanent marking require-ments shall be as specified under Part 178 of Title 49 CFR andmust be maintained in legible condition as required by

27、 Part 173of Title 49 CFR. Warning labels shall be affixed to cylindersconforming to requirements of Part 82.106 of Title 40 CFR.5.4 Storage:5.4.1 Storage shall be in accordance with CGA PublicationNo. P-1, in qualified cylinders in accordance with Title 49CFR, Parts 173 and 178.5.4.2 Cylinders shoul

28、d be stored in areas that will protectvessels from physical and environmental damage and tamper-ing from unauthorized personnel.5.4.2.1 Facilities should be of construction and orientationso that safety requirements are fulfilled for the storage ofpressurized cylinders.5.4.3 Storage cylinders shall

29、be fitted with pressure releasemechanisms to limit vessel pressure to not more than the ratedworking pressure of the HFC-227ea container in use at anyparticular time.5.4.3.1 Periodic hydrostatic testing and reinspection of cyl-inders used for recycled HFC-227ea shall comply with Title 49CFR Part 180

30、.5.4.4 Containers shall be clearly marked and labeled toidentify whether the HFC-227ea contained does or does notconform to this specification.5.4.5 Insulation shall be placed on pallets or shoring, andprovisions should be made to prevent excessive shock orthermal fluctuations to cylinders.5.4.6 Cyl

31、inders shall be stored in a manner that will preventcontamination from external sources.5.4.6.1 If HFC-227ea meeting the standards of this specifi-cation is stored in the same area as material not meeting thisrequirement, storage shall be segregated or clearly identifiableas not being similar.6. Ins

32、pection6.1 HFC-227ea that is reclaimed using approved HFC-227ea reclamation systems may be released for reissue, pro-vided test examination to validate the material to specificationis fulfilled.6.1.1 Reclaimed HFC-227ea that cannot be proven to com-ply with this specification shall not be reissued.

33、The materialwill be processed by environmentally safe methods untilconformance to product standard is achieved.FIG. 2 Isometric Diagram HFC-227ea Pressurized to 360 psig (25.8 bar) With Nitrogen at 70F (21C)D6065 11 (2015)37. Keywords7.1 CF3CHFCF3; compressed gas; cylinders; explosion sup-pressant;

34、FE-227; fire suppressant; FM-200; handling;heptafluoropropane; 1,1,1,2,3,3,3-heptafluoropropane; HFC-227ea; reclamation; recovery; recycling; storage; transportASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this stan

35、dard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be revie

36、wed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsibl

37、e technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Con

38、shohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ 3 Isometric Diagram HFC-227ea Pressurized to 600 psig (42.4 bar) With Nitrogen at 70F (21C)D6065 11 (2015)4