ASTM D6127-2003 Standard Practice for Handling Transportation and Storage of HFC-23 (Trifluoromethane CHF3)《HFC-23(三氟甲烷、CHF)的搬运、运输和储存用标准实施规程》.pdf

1、Designation: D 6127 03Standard Practice forHandling, Transportation, and Storage of HFC-23(Trifluoromethane, CHF3)1This standard is issued under the fixed designation D 6127; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year

2、 of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.1. Scope1.1 This practice covers guidance and direction to suppliers,purchasers, and users in the handling, transportation, a

3、ndstorage of HFC-23.1.2 The values stated in inch-pound units are to be regardedas the standard. The values given in parentheses are forinformation only.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of th

4、is standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:D 6126 Specification for HFC-23 trifluoromethane (CHF3)22.2 CGA Standards:No. C-1, Methods for Hydrostatic Testing of Co

5、mpressedGas Cylinders3No. C-4, American National Standard Method of MarkingPortable Compressed Gas Containers to Identify theMaterial Contained3No. C-6, Standards for Visual Inspection of Steel Com-pressed Gas Cylinders3No. P-1, Safe Handling of Compressed Gases in Contain-ers3No. SB-1, Hazards of R

6、efilling Compressed Refrigerant(halogenated hydrocarbon) Gas Cylinders32.3 U.S. Government Standards:Code of Federal Regulations (CFR) Title 40, Part 82.1064Code of Federal Regulations (CFR) Title 40, Part 173, U.S.Department of Transportation (DOT) Specifications,Shippers-General Requirements for S

7、hipping and Packag-ings4DOT Exemption DOT-E 9491 to Code of Federal Regula-tions (CFR) Title 40, Part 173,U.S. Department of Transportation (DOT) Specifications,Shippers-General Requirements for Shipping and Packag-ings4Code of Federal Regulations (CFR) Title 40, Part 178, U.S.DOT Specifications for

8、 Packagings43. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 containersstorage vessel for HFC-23.3.1.2 cylinderscontainers of HFC-23.3.1.3 HFC-23trifluoromethane, a compound used to inertor suppress a fire or explosion hazard.3.1.4 insulatedplaced in an isolated situation to pr

9、otectand prevent the transfer of damage.4. Significance and Use4.1 This practice provides requirements for the handling,transportation, and storage of HFC-23 encountered in distribu-tion through both commercial and military channels. It isintended to ensure that HFC-23 is handled, transported, andst

10、ored in such a way its physical property values are notdegraded. Transport may be by various means, such as, but notlimited to, highway, rail, water, and air.5. Practice5.1 Personnel shall be trained in Title 49 CFR, Part 172,Subpart H, to ensure safe handling, loading, unloading, storageand transpo

11、rtation of material.5.2 Handling:5.2.1 Handling shall be in accordance with C.G.A. Publica-tion No. P-1.5.2.2 Personnel who handle or store, or both, cylinders ofHFC-23 shall be trained properly to recognize and identify thecharacteristics of the product and the proper methods of safelyhandling full

12、, partly full, and empty cylinders.1This practice is under the jurisdiction of ASTM Committee D26 on Haloge-nated Organic Solvents and is the direct responsibility of Subcommittee D26.09 onHalogenated Fire Extinguishants.Current edition approved June 10, 2003. Published August 2003. Originallyapprov

13、ed in 1997. Last previous edition approved in 1997 as D 612797.2Annual Book of ASTM Standards, Vol 15.05.3Available from the Compressed Gas Association.4Available from Superintendent of Documents, U.S. Government PrintingOffice, Washington, DC 20036.1Copyright ASTM International, 100 Barr Harbor Dri

14、ve, PO Box C700, West Conshohocken, PA 19428-2959, United States.5.2.3 Facility personnel must be trained in applicable Title49 CFR, Parts 173 and 178, and the GCA documents refer-enced in 2.2.5.2.4 Halon handling shall be in nonsmoking, heater-free,ventilated areas to preclude product accumulation.

15、 Provisionsshall be made to ensure that service areas limit HFC-23concentrations to not exceed 30 % for 1 min and 0.1 % for 8 h.5.2.5 Cylinders shall not be over filled. The maximumpermitted filling density shall conform to specifications aslisted in DOT-E 9491. The pressure at the critical temperat

16、uredoes not exceed one and one-forth times the service pressure ofthe cylinder. Filling density requirement are specified in Title49 CFR, 173 and Title 49 CFR, 173.305.5.2.6 Handling of materials should be done in a manner thatprevents contamination or commingling of halons other thanHFC-23.5.2.7 Cy

17、linders shall be free of dirt and contamination thatwould contribute to or would cause deterioration of the productduring shipment or storage. Precautions should be taken toprevent the entry of oil, water, or any other foreign matter intothe container. Unique coatings or preservatives applied prior

18、toshipment to protect the containers are not considered contami-nation.5.3 Transportation:5.3.1 Transportation shall be as specified in accordance withDOT regulations of Title 49 CFR.5.3.2 Transportation shall be in suitable vehicles to precludecylinder damage by excessive mechanical vibration, shoc

19、k,freezing, or deleterious high temperatures throughout the entiretransport route.5.3.2.1 Should cylinders be expected to be subjected tounacceptable transport conditions, the cylinders should beplaced under insulated conditions.5.3.3 Compressed gas cylinder permanent marking require-ments shall be

20、as specified under Part 178 of Title 49 CFR andmust be maintained in legible condition as required by Part 173of Title 49 CFR. Warning labels shall be affixed to the cylindersconforming to requirements of Part 82.106 of Title 40 CFR.5.4 Storage:5.4.1 Storage shall be in accordance with C.G.A. Public

21、a-tion No. P-1, in qualified cylinders in accordance with Parts173 and 178 of Title 49 CFR.5.4.2 Cylinder should be stored in areas that will protectvessels form physical and environmental damage, and tamper-ing from unauthorized personnel.5.4.2.1 Facilities should be in construction and orientation

22、so that safety requirements are fulfilled for storage of pressur-ized cylinders.5.4.3 Storage cylinders shall be fitted with pressure releasemechanisms to limit vessel pressure to not more than the ratedworking pressure of the container in use at any particular time.5.4.3.1 Periodic hydrostatic test

23、ing and re-inspection ofcylinders used for HFC-23 shall comply with Part 173.34 ofTitle 49 CFR.5.4.4 Containers shall be clearly marked and labeled toidentify whether the HFC-23 contained conforms to Specifi-cation D 6126.5.4.5 Insulation shall be placed on pallets or shoring andprovisions should be

24、 made to prevent excessive shock orthermal fluctuations to cylinders.FIG. 1 HFC-23 Fluorocarbon IsometricsD61270325.4.6 Cylinders shall be stored in a manner that will preventcontamination from external sources.6. Keywords6.1 CHF3; compressed gas; compressed liquefied gas; cyl-inders; explosion supp

25、ressant; fire suppressant; handling; HFC-23; storage; transport; trifluoromethaneASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the va

26、lidity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your co

27、mments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments hav

28、e not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).D6127033