ASTM D6583-2004(2010) 5625 Standard Test Method for Porosity of Paint Film by Mineral Oil Absorption《用矿物油吸收法测定涂料薄膜孔隙度的标准试验方法》.pdf

1、Designation: D6583 04 (Reapproved 2010)Standard Test Method forPorosity of Paint Film by Mineral Oil Absorption1This standard is issued under the fixed designation D6583; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of

2、last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method is applicable to air-dry architecturalcoatings of any type, both solvent and water-borne, and of anyc

3、olor, dark as well as light. It cannot be used with films that aredissolved or excessively softened by mineral oil, but practicalexamples of such films will be encountered rarely, if ever.1.2 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are for inf

4、ormationonly.1.3 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2.

5、 Referenced Documents2.1 ASTM Standards:2D1475 Test Method For Density of Liquid Coatings, Inks,and Related ProductsD2369 Test Method for Volatile Content of CoatingsD3258 Test Method for Porosity of White or Near WhitePaint Films by Staining3. Terminology3.1 Definitions:3.1.1 porosity, npresence of

6、 numerous minute voids in acured material; that is, the fraction of air by volume in the dryfilm.4. Summary of Test Method4.1 The test paint is applied to a preweighed nonporouspanel, air dried, then reweighed to obtain the weight of thefilm.4.2 Mineral oil is applied to the surface of the paint fil

7、m,allowed to absorb for a fixed period of time, and the excessremoved in a specified manner. The test panel is then re-weighed to determine the amount of mineral oil absorbed.4.3 Porosity is calculated from the weight ratio of absorbedoil to dry paint film and from previously determined values ofnon

8、-volatile and density for the whole paint.5. Significance and Use5.1 The porosity of a paint film is closely related to theimportant practical characteristics of stain resistance, abrasionresistance, durability, and the hold-out of any paint subse-quently applied.5.2 This test provides a precise mea

9、ns for evaluating andcomparing the quality of paint films, insofar as it pertains toporosity as determined on a coating applied to a nonporoussubstrate. Porosity measured using this test method may not bean accurate predictor of coating porosity when the coating isapplied to substrate of higher abso

10、rption characteristics.5.3 Unlike current Test Method D3258 Porosity of PaintFilms, which is effective only with light colored paints, this testmethod is equally effective with paints of any color, both darkand light. Also unlike Test Method D3258, its results are notinfluenced by the hiding charact

11、eristics of the paint film.6. Apparatus and Materials6.1 Bird Type Film Applicator, 150-mm wide with a clear-ance of 150 m.6.2 Bird Type Film Applicator, 150-mm wide with a clear-ance of 100 m.6.3 Vacuum Drawdown Plate.6.4 Test Panel.36.5 Mineral Oil, specific gravity 0.8200 to 0.8350; viscosity6.5

12、to 7.8 cSt at 40C.6.6 Absorbent Wipers.7. Procedure7.1 Weigh each test panel to the nearest milligram. Recordas Wp.7.2 Place the test panel on the vacuum plate and apply thepaint under test with the 150-m clearance drawdown blade.1This test method is under the jurisdiction of ASTM Committee D01 on P

13、aintand Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.42 on Architectural Coatings.Current edition approved Feb. 1, 2010. Published February 2010. Originallyapproved in 2000. Last previous edition approved in 2004 as D6583 04. DOI:10.1520/D6583-04R

14、10.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Transparency film AF 4300, from 3M Visual Systems Divisio

15、n, Austin, TX78726-4599 was used in this test method. If you are aware of alternative suppliers,please provide this information to ASTM International Headquarters. Your com-ments will receive careful consideration at a meeting of the responsible technicalcommittee,1which you may attend.1Copyright AS

16、TM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.Remove the test panel from the vacuum plate and air dry as 48h under standard conditions of 23 6 2C (73 6 3.5F) and 506 5 % relative humidity.7.3 Weigh the coated test panel to the nearest milligram

17、.Record this weight as Wp+f.7.4 Place the coated test panel on the vacuum plate andapply the mineral oil with the 100-m clearance drawdownblade making sure the entire surface of the coating is coveredby the oil.7.5 After 3 min, wipe off excess mineral oil with theabsorbent wipers. Hold the test pane

18、l at an angle to a lightsource to ascertain from its sheen if all mineral oil is removedfrom the test panel. Repeat wiping, if necessary, until the filmhas no sheen. Failure to remove this excess will produceerroneous results. Results are invalid if paint film is removedduring this process.7.6 Weigh

19、 the test panel from 7.5 to the nearest milligramand record as Wo.7.7 Determine the density D of the paint in g/mL and thedensity d of the saturant in g/mL, in accordance with TestMethod D1475.7.8 Determine the nonvolatile by weight N of the paint, inaccordance with Test Method D2369.8. Calculation8

20、.1 Weight of Applied Paint Film:8.1.1 Calculate the weight of the applied paint film asfollows:Wf5 Wp1f2 Wp(1)where:Wf= paint film, g,Wp+f= test panel and paint film, g, andWp= test panel, g.8.2 Weight of Mineral Oil Absorbed:8.2.1 Calculate the weight of the mineral oil m absorbed bythe paint film

21、as follows:Wm5 Wo2 Wp1f(2)where:Wm= mineral oil absorbed by the paint film, g,Wo= oiled test paint, g, andWp+f= test panel and paint film, g.8.3 Weight Ratio of absorbed Oil to Dry Paint Film:8.3.1 Calculate the ratio of absorbed oil to dry paint film Ras follows:R 5 Wm/ Wf(3)where:R = weight ratio

22、of absorbed oil to dry paint film,Wm= mineral oil absorbed by the paint film, g, andWf= paint film, g.8.4 Porosity:8.4.1 Calculate porosity P as follows:P 5CRNDCRND 1 d C 1 ND 2D!3 100 (4)where:C = constant of:1.00 for water-based systems, and0.78 for solvent-based systems.NOTE 1the constant C is to

23、 adjust the calculation for the difference indensity of the solvent (water in water-based systems and a generic solventin solvent-based systems).P = porosity of paint film, expressed as a percentage,R = ratio by weight of absorbed oil to dry paint film,N = nonvolatile by weight of the whole paint,D

24、= density of the whole paint, g/mL, andd = density of the saturant, g/mL.9. Report9.1 Report the porosity of the paint film as determined in8.4.1 to 1 decimal place.10. Precision and Bias10.1 PrecisionThe precision of this test method for mea-suring porosity is being determined.10.2 BiasSince there

25、is no accepted reference materialsuitable for determining the bias for the procedure in this testmethod for measuring porosity, no statement on bias is beingmade.11. Keywords11.1 film porosity; porosity; resistancepenetration (intopaint films)ASTM International takes no position respecting the valid

26、ity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subje

27、ct to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquart

28、ers. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard

29、 is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D6583 04 (2010)2