ASTM D6779-2011 red 0625 Standard Classification System for Polyamide Molding and Extrusion Materials (PA)《聚酰胺模制和挤压材料标准分类体系》.pdf

1、Designation:D677910 Designation: D6779 11Standard Classification System forPolyamide Molding and Extrusion Materials (PA)1This standard is issued under the fixed designation D6779; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, th

2、e year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This classification system covers polyamide materials suitable for molding and extrusion. Some of these com

3、positions arealso suitable for application from solution.1.2 This classification system allows for the use of recycled polyamide materials provided that the requirements as stated in thisclassification system are met. The proportions of recycled material used, as well as the nature and amount of any

4、 contaminant,however, cannot be covered practically in this specification.1.3 The properties included in this classification system are those required to identify the compositions covered. There may beother requirements necessary to identify particular characteristics important to specialized applic

5、ations. These may be specified byusing the suffixes as given in Section 5.1.4 This classification system and subsequent line callout (specification) are intended to provide a means of calling out plasticmaterials used in the fabrication of end items or parts. It is not intended for the selection of

6、materials. Material selection shouldbe made by those having expertise in the plastic field after careful consideration of the design and the performance required of thepart, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherentprope

7、rties of the material other than those covered by this classification system.1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.6 The following precautionary caveat pertains only to the test methods portion, Section 11, of

8、this classification system. Thisstandard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the userof this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirementsprior

9、to use.NOTE 1This classification system is similar to ISO 1874-1/-2,although the technical content is significantly different.2. Referenced Documents2.1 ASTM Standards:2D257 Test Methods for DC Resistance or Conductance of Insulating MaterialsD789 Test Methods for Determination of Solution Viscositi

10、es of Polyamide (PA)D792 Test Methods for Density and Specific Gravity (Relative Density) of Plastics by DisplacementD883 Terminology Relating to PlasticsD1600 Terminology for Abbreviated Terms Relating to PlasticsD3892 Practice for Packaging/Packing of PlasticsD4000 Classification System for Specif

11、ying Plastic MaterialsD6260 Test Method for Gravimetric Determination of Carbon Black in Nylon Materials (PA)E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications2.2 IEC/ISO Standards:3IEC 60243-1 Electrical Strength of Insulating MaterialsTest MethodsPa

12、rt 1: Tests at Power FrequenciesIEC 60250 Recommended Methods for the Determination of the Permittivity and Dielectric Dissipation Factor of ElectricalInsulating Materials at Power, Audio and Radio Frequencies Including Metre WavelengthsISO 75-1 PlasticsDetermination of Temperature of Deflection Und

13、er LoadPart 1: General Test MethodsISO 75-2 PlasticsDetermination of Temperature of Deflection Under LoadPart 2: Plastic and Ebonite1This classification system is under the jurisdiction of ASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.15 on ThermoplasticMaterial

14、s.Current edition approved JulyFeb. 1, 2010.2011. Published July 2010.March 2011. Originally approved in 2002. Last previous edition approved in 20082010 asD6779-08a.D6779 - 10. DOI: 10.1520/D6779-101.2For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Serv

15、ice at serviceastm.org. For Annual Book of ASTM Standardsvolume information, refer to the standards Document Summary page on the ASTM website.3Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http:/www.ansi.org.1This document is not an ASTM

16、standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Becauseit may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all

17、cases only the current versionof the standard as published by ASTM is to be considered the official document.*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.ISO 179-1 P

18、lasticsDetermination of Charpy Impact StrengthPart 1: Non-instrumented Impact TestISO 294-1 PlasticsInjection Moulding of Test Specimens of Thermoplastic MaterialsPart 1: General Principles,Multipurpose-Test Specimens and BarsISO 307 Determination of Viscosity Number of Polyamides In Dilute Solution

19、sISO 527-1 PlasticsDetermination of Tensile PropertiesPart 1: General PrinciplesISO 527-2 PlasticsDetermination of Tensile PropertiesPart 2: Testing ConditionsISO 1183 PlasticsMethods for Determining the Density and Relative Density of Non-Cellular PlasticsISO 1874-1 PlasticsPolyamide (PA) Homopolym

20、ers and Copolymers for Moulding and ExtrusionPart 1: DesignationISO 1874-2.2 PlasticsPolyamide (PA) Homopolymers and Copolymers for Moulding and ExtrusionPart 2: Preparation ofTest Specimens and Determination of PropertiesISO 3167 Plastics, Multipurpose Test SpecimensISO 3451-4 PlasticsDetermination

21、 of AshPart 4: PolyamidesISO 11357-1 PlasticsDifferential Scanning CalorimetryPart 1: General PrinciplesISO 11357-3 PlasticsDifferential Scanning CalorimetryPart 3: Determination of Temperature and Enthalpy of Melting andCrystallizationISO 15512 PlasticsDetermination of Water Content3. Terminology3.

22、1 The terminology used in this classification system is in accordance with Terminologies D883 and D1600.4. Classification4.1 Polyamide materials are classified into groups in accordance with their composition. These groups are subdivided intoclasses and grades as shown in the Basic Property Table (T

23、able PA).NOTE 2An example of this classification system for unreinforced polyamide is given as follows: The designation PA0123 indicates the following:PA = polyamide as found in Terminology D1600,01 (group) = polyamide 66,2 (class) = heat stabilized, and3 (grade) = with a minimum viscosity number of

24、 210 and the requirements given in Table PA.4.1.1 Grades of reinforced or filled versions, or both, of the basic materials are identified by a single letter that indicates thereinforcement or filler used and two digits, in multiples of 5, that indicate the nominal quantity in percent by weight. Thus

25、, a letterdesignation G for glass reinforced and 35 for percent or reinforcement, G35, specifies a material with a nominal glass level of35 %. The reinforcement letter designations and associated tolerance levels are shown as follows:Symbol MaterialTolerance(Based on the Total Mass)C carbon- and gra

26、phite-fiber-reinforced 62%G glass-reinforced 62%L lubricants (such as PTFE, graphite,silicone, and molybdenum disulfide)Depends upon material andprocessto be specified.M mineral-reinforced 62%R combinations of reinforcements orfillers, or both63%NOTE 3An example of this classification system for rei

27、nforced polyamide is given as follows: The designation PA012G35 indicates the following:PA = polyamide as found in Terminology D1600,01 (group) = polyamide 66,2 (class) = heat stabilized, andG35 (grade) = nominal 35 % glass with the requirements given in Table PA.NOTE 4This part of the classificatio

28、n system uses percent of reinforcements or additives, or both, in the callout of the modified basic material. Thetypes and percentages of reinforcements and additives should be shown on the suppliers technical data sheet unless they are proprietary in nature. Ifnecessary, additional control of these

29、 reinforcements and additives can be accomplished by use of the suffix part of the system (see Section 5).NOTE 5Materials containing reinforcements or fillers, or both, at nominal levels not in multiples of 5 are included in the nearest PAgrade designation.For example, a material with a nominal glas

30、s fiber level of 33 % is included with Grade G35 as shown in Note 4.NOTE 6Ash content of filled or reinforced materials may be determined using Test Method ISO 3451-4.4.2 Variations of polyamide materials that are not in Table PA are classified in accordance with Tables PA and A or B. TablePA is use

31、d to specify the group of polyamide and Table A or B is used to specify property requirements.4.2.1 Specific requirements for variations of polyamide materials shall be shown by a six-character designator. The designationwill consist of the letter “A” or “B” and the five digits comprising the cell n

32、umbers for the property requirements in the order asthey appear in Tables A and B.D6779 1124.2.1.1 Although the values listed are necessary to include the range of properties available in existing material, users shouldnot infer that every possible combination of the properties exists or can be obta

33、ined.4.2.2 When the grade of the basic material is not known, is not important or does not meet the Table PA requirements, the useof “0” grade classification shall be used for reinforced materials in this classification system.NOTE 7An example of this classification system for a reinforced polyamide

34、 material is given as follows. The designation PA0110G30A42270 wouldindicate the following material requirements:PA0110 = Polyamide 66, from Table PA,G30 = Glass reinforced at 30 % nominal,A = Table A property requirements,4 = Tensile strength, 140 MPa, min,2 = Tensile modulus, 4500 MPa, min,2 = Cha

35、rpy impact, 5.0 kJ/m2, min,7 = Deflection temperature at 1.8 MPa, 200C, min, and0 = Unspecified.If no properties are specified, the designation would be PA0110G30A00000.NOTE 8When a grade of polyamide is not fully identified by a standard callout, it is possible to specify all table properties by th

36、e use of an additionof Classification D4000 suffixes. Suffix values will override the PA table values. An example of an unreinforced polyamide material is given as follows:PA0212KN023. This example is a general purpose, low viscosity PA6 material where K denotes tensile properties, N denotes tensile

37、 modulus with ISO527 as the test method, and 023 denotes a value of 2300 MPa. This value for tensile modulus overrides the normal table value. This example can be appliedto replace all table values, that is, tensile stress, notched Charpy impact, and heat deflection temperature.4.3 To facilitate the

38、 specification of special materials where the basic property table does not reflect the properties required,Table B has been incorporated into this classification system. This table will be used in a manner similar to Table A.NOTE 9Pigmented or colored polyamides can differ significantly from the na

39、tural polymers in mechanical properties depending on the choice ofcolorants and concentrations. The main property affected is ductility, as illustrated by a reduction in Charpy impact and elongation values. In a typicalwhite pigmented polyamide, elongation losses of up to 50 % and Charpy impact loss

40、es of up to 30 % are common. If specific properties of pigmentedmaterials are necessary, Table B may be employed to specify property requirements.NOTE 10An example of a special material using this classification system is as follows: The designation PA0220B54220 would indicate the followingmaterial

41、requirements from Table B:PA0220 = Polyamide 6, heat stabilized, from Table PA,B = Table B property requirements,5 = Tensile strength, 70 MPa, min,4 = Tensile modulus, 2400 MPa, min,2 = Charpy impact, 4.0 kJ/m2, min,2 = Deflection temperature at 1.8 MPa, 55C, min, and0 = unspecified.TABLE PA Require

42、ments for Polyamides Dry-as-MoldedA,BGroup Description Class Description Grade DescriptionCViscosityNumber,ISO 307,min, mL/gDensity,DISO 1183g/cm3TensileStrength,ISO 527-1andISO 527-2,MPa, minTensileModulus,EISO 527-1andISO 527-2,MPa, minCharpyImpactResistance,ISO 179/1eA, kJ/m2,minDeflectionTempera

43、ture,FISO 75-1andISO 75-2,at 1.8 MPa,C, min01 PA66 1 General-purpose1 135 1.13 to 1.15 70 2300 3.3 602 165 1.13 to 1.15 70 2300 3.3 603 210 1.13 to 1.15 70 2300 3.3 604 270 1.13 to 1.15 70 2300 3.3 605 recycled 115 1.13 to 1.15 70 2300 3.3 606 recycled 135 1.13 to 1.15 70 2300 3.3 607 115 1.13 to 1.

44、15 70 2300 3.3 60G15 15 % glass . . . 1.20 to 1.26 100 4000 3.0 215G20 20 % glass . . . 1.25 to 1.33 115 5000 4.0 220G25 25 % glass . . . 1.29 to 1.37 140 6000 5.0 225G35 35 % glass . . . 1.35 to 1.45 170 8000 7.0 235G40 40 % glass . . . 1.42 to 1.52 175 9000 8.0 235G45 45 % glass . . . 1.45 to 1.55

45、 180 10 000 9.0 240G50 50 % glass . . . 1.51 to 1.61 190 11 000 10.0 245M40 40 % mineral . . . 1.45 to 1.55 80 5000 2.0 1000 other2 Heat-stabilized1 135 1.13 to 1.15 70 2300 3.0 602 165 1.13 to 1.15 70 2300 3.0 60D6779 113TABLE PA Requirements for Polyamides Dry-as-MoldedA,BGroup Description Class D

46、escription Grade DescriptionCViscosityNumber,ISO 307,min, mL/gDensity,DISO 1183g/cm3TensileStrength,ISO 527-1andISO 527-2,MPa, minTensileModulus,EISO 527-1andISO 527-2,MPa, minCharpyImpactResistance,ISO 179/1eA, kJ/m2,minDeflectionTemperature,FISO 75-1andISO 75-2,at 1.8 MPa,C, min3 210 1.13 to 1.15

47、70 2300 3.0 604 270 1.13 to 1.15 70 2300 3.0 605 recycled 115 1.13 to 1.15 70 2300 3.0 606 recycled 135 1.13 to 1.15 70 2300 3.0 60G15 15 % glass . . . 1.20 to 1.26 100 4000 3.0 220G25 25 % glass . . . 1.29 to 1.37 140 6000 5.0 225G30 30 % glass . . . 1.32 to 1.42 160 7000 6.0 230G35 35 % glass . .

48、. 1.35 to 1.45 170 8000 7.0 235G40 40 % glass . . . 1.43 to 1.53 175 9000 8.0 235G45 45 % glass . . . 1.45 to 1.55 180 10 000 9.0 240G50 50 % glass . . . 1.51 to 1.61 190 11 000 10.0 245M40 40 % mineral . . . 1.45 to 1.55 80 5000 2.0 100R20 20 % filler . . . 1.23 to 1.31 70 3200 1.5 . . .R40 40 % fi

49、ller . . . 1.43 to 1.53 100 5500 2.5 2000 other3 Nucleated 1 135 1.13 to 1.15 80 2500 2.8 602 165 1.13 to 1.15 80 2500 2.8 603 210 1.13 to 1.15 80 2500 2.8 604 270 1.13 to 1.15 80 2500 2.8 605 recycled 115 1.13 to 1.15 80 2500 2.8 606 recycled 135 1.13 to 1.15 80 2500 2.8 600 other4 Nucleated,heat-stabilized1 Requirements the same as corresponding grades under Group 01, Class 323450 other5 Impact-modified1 . . . 1.06 to 1.12 52 1700 9.0 502 recycled . . . 1.06 to 1.12 50 1600 8.0 50G15 15 % glass . . . 1.15 to 1.23 85 3000 6.0 210G35 35 %