ASTM D7042-2012a red 6875 Standard Test Method for Dynamic Viscosity and Density of Liquids by Stabinger Viscometer (and the Calculation of Kinematic Viscosity)《用Stabinger粘度计 (和动粘度.pdf

1、Designation: D7042 121D7042 12aStandard Test Method forDynamic Viscosity and Density of Liquids by StabingerViscometer (and the Calculation of Kinematic Viscosity)1This standard is issued under the fixed designation D7042; the number immediately following the designation indicates the year oforigina

2、l adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1 NOTEUpdated Table 2 editorially in August 2012.1. Scope*1.1 This test method

3、 covers and specifies a procedure for the concurrent measurement of both the dynamic viscosity, , and thedensity, , of liquid petroleum products and crude oils, both transparent and opaque. The kinematic viscosity, , can be obtainedby dividing the dynamic viscosity, , by the density, , obtained at t

4、he same test temperature.1.2 The result obtained from this test method is dependent upon the behavior of the sample and is intended for application toliquids for which primarily the shear stress and shear rate are proportional (Newtonian flow behavior).1.3 The precision has only been determined for

5、those materials, viscosity ranges, density ranges, and temperatures as indicatedin Section 15 on Precision and Bias. The test method can be applied to a wider range of materials, viscosity, density, andtemperature. For materials not listed in Section 15 on Precision and Bias, the precision and bias

6、may not be applicable.1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibilityof the user of this s

7、tandard to establish appropriate safety and health practices and to determine the applicability of regulatorylimitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D445 Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity)D975 Speci

8、fication for Diesel Fuel OilsD2162 Practice for Basic Calibration of Master Viscometers and Viscosity Oil StandardsD2270 Practice for Calculating Viscosity Index from Kinematic Viscosity at 40 and 100CD4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Mete

9、rD6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measure-ment System PerformanceD6300 Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and LubricantsD6617 Practice for Laboratory Bias

10、 Detection Using Single Test Result from Standard MaterialD6708 Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purportto Measure the Same Property of a Material2.2 ISO Standards:3ISO 5725 Accuracy (trueness and precision) of measurement method

11、s and resultsISO/IEC 17025 General Requirements for the Competence of Testing and Calibration Laboratories2.3 Other Documents:4NIST Technical Note 1297 Guideline for Evaluating and Expressing the Uncertainty of NIST Measurement Results1 This test method is under the jurisdiction of ASTM Committee D0

12、2 on Petroleum Products and Lubricants and is the direct responsibility of Subcommittee D02.07 onFlow Properties.Current edition approved April 15, 2012Nov. 1, 2012. Published July 2012March 2013. Originally approved in 2004. Last previous edition approved in 20112012 asD704211a.121 DOI:10.1520/D704

13、2-12E01 DOI:10.1520/D7042-12A.2 For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at serviceastm.org. For Annual Book of ASTM Standardsvolume information, refer to the standards Document Summary page on the ASTM website.3 Available from American Natio

14、nal Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http:/www.ansi.org.4 Available from National Institute of Standards and Technology (NIST), 100 Bureau Dr., Stop 1070, Gaithersburg, MD 20899-1070, http:/www.nist.gov.This document is not an ASTM standard and is intended o

15、nly to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Becauseit may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current ver

16、sionof the standard as published by ASTM is to be considered the official document.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States13. Terminology3.1 Definitions:3.1.1 de

17、nsity (), nmass per unit volume.3.1.2 dynamic viscosity (), nthe ratio between the applied shear stress and rate of shear of a liquid.3.1.2.1 DiscussionIt is sometimes called the coefficient of dynamic viscosity or, simply, viscosity. Thus, dynamic viscosity is a measure of theresistance to flow or

18、to deformation of a liquid under external shear forces.3.1.2.2 DiscussionThe term dynamic viscosity can also be used in a different context to denote a frequency-dependent quantity in which shear stressand shear rate have a sinusoidal time dependence.3.1.3 kinematic viscosity (), nthe ratio of the d

19、ynamic viscosity () to the density () of a liquid.3.1.3.1 DiscussionFor gravity flow under a given hydrostatic head, the pressure head of a liquid is proportional to its density (). Therefore thekinematic viscosity () is a measure of the resistance to flow of a liquid under gravity.3.1.4 relative de

20、nsity (also called specific gravity (SG), nthe ratio of the density of a material at a stated temperature to thedensity of a reference material (usually water) at a stated temperature.4. Summary of Test Method4.1 The test specimen is introduced into the measuring cells, which are at a closely contro

21、lled and known temperature. Themeasuring cells consist of a pair of rotating concentric cylinders and an oscillating U-tube. The dynamic viscosity is determinedfrom the equilibrium rotational speed of the inner cylinder under the influence of the shear stress of the test specimen and an eddycurrent

22、brake in conjunction with adjustment data. The density is determined by the oscillation frequency of the U-tube inconjunction with adjustment data. The kinematic viscosity is calculated by dividing the dynamic viscosity by the density.5. Significance and Use5.1 Many petroleum products, and some non-

23、petroleum materials, are used as lubricants and the correct operation of theequipment depends upon the appropriate viscosity of the liquid being used. In addition, the viscosity of many petroleum fuels isimportant for the estimation of optimum storage, handling, and operational conditions. Thus, the

24、 accurate determination ofviscosity is essential to many product specifications.5.2 Density is a fundamental physical property that can be used in conjunction with other properties to characterize both thelight and heavy fractions of petroleum and petroleum products.5.3 Determination of the density

25、or relative density of petroleum and its products is necessary for the conversion of measuredvolumes to volumes at the standard temperature of 15C.6. Apparatus6.1 Stabinger Viscometer5,66.1.1 Viscosity MeasurementThe Stabinger viscometer uses a rotational coaxial cylinder measuring system.The outer

26、cylinder(tube) is driven by a motor at a constant and known rotational speed. The low-density inner cylinder (rotor) is held in the axis ofrotation by the centrifugal forces of the higher density sample and in its longitudinal position by the magnet and the soft iron ring.Consequently, the system wo

27、rks free of bearing friction as found in rotational viscometers. A permanent magnet in the innercylinder induces eddy currents in the surrounding copper casing. The rotational speed of the inner cylinder establishes itself as theresult of the equilibrium between the driving torque of the viscous for

28、ces and the retarding eddy current torque. This rotationalspeed is measured by an electronic system (Hall effect sensor) by counting the frequency of the rotating magnetic field (see Fig.1 and Fig. 2, No. 2).5 The Stabinger viscometer is covered by a patent. Interested parties are invited to submit

29、information regarding the identification of an alternative to this patented itemto the ASTM International headquarters. Your comments will receive careful consideration at a meeting of the responsible technical committee, which you may attend.6 The sole source of supply of the apparatus known to the

30、 committee at this time is Anton Paar GmbH, Anton-Paar-Str. 20, A-8054 Graz, Austria. If you are aware ofalternative suppliers, please provide this information to ASTM International headquarters. Your comments will receive careful consideration at a meeting of the responsibletechnical committee, whi

31、ch you may attend.D7042 12a26.1.2 Density MeasurementThe digital density analyzer uses a U-shaped oscillating sample tube and a system for electronicexcitation and frequency counting (see Fig. 2, No. 3).6.1.3 Temperature ControlThe copper block surrounds both the viscosity and the density measuring

32、cell in a way that bothcells are held at the same temperature. A thermoelectric heating and cooling system (see Fig. 2, No. 1) ensures the temperaturestability of the copper block within 60.005C from the set temperature at the position of the viscosity cell over the wholetemperature range. The uncer

33、tainty (k = 2; 95 %95?% confidence level) of the temperature calibration shall be no more than60.03C over the range from 15 to 100C. Outside this range the calibration uncertainty shall be no more than 60.05C.6.1.4 The thermal equilibration time depends on the heat capacity and conductivity of the l

34、iquid and on the difference betweeninjection temperature and test temperature. Adequate temperature equilibration of the test specimen is automatically determinedwhen successive viscosity values are constant within 60.07 %60.07?% over 1 min and successive density values are constantwithin 60.00003 g

35、/cm3 over 60 s.NOTE 1The Stabinger Viscometer, manufactured by Anton Paar GmbH, fulfills the stated requirements when operated in the most precise mode ofoperation.6.2 Syringes, commercially available, at least 5 mL in volume, with a Luer tip. All construction materials for syringes shall befully co

36、mpatible with all sample liquids and cleaning agents, which contact them.6.3 Flow-Through or Pressure Adapter, for use as an alternative means of introducing the test specimen into the measuring cellseither by pressure or by suction, provided that sufficient care and control is used to avoid any bub

37、ble formation in the test specimen.All construction materials for adaptors shall be fully compatible with all sample liquids and cleaning agents, which contact them.6.4 Autosampler, for use in automated injection analyses. The autosampler shall be designed to ensure the integrity of the testspecimen

38、 prior to and during the analysis and be equipped to transfer a representative portion of test specimen into the measuringcells. The autosampler shall transfer the test specimen from the sample vial to the measuring cells of the apparatus withoutinterfering with the integrity of the test specimen. T

39、he autosampler shall be able to mimic the procedure for sample handling asset forth in 11.1 and 11.2. The autosampler may have heating capability as a means to lower the viscosity of the sample for fillingthe measuring cells.FIG. 1 Viscosity CellFIG. 2 Cell BlockD7042 12a36.5 Screen, with an apertur

40、e of 75 m, to remove particles from the sample.6.6 Magnet, strong enough to remove iron fillings from the sample. Magnetic stirring rods are suitable.7. Reagents and Materials7.1 Sample Solvent, completely miscible with the sample.7.1.1 For most samples, a volatile petroleum spirit or naphtha is sui

41、table. If the solvent dries up without residues in an applicabletime frame, the use of a separate drying solvent is not required.7.1.2 For residual fuels, a prewash with an aromatic solvent such as toluene or xylene may be necessary to remove asphalticmaterial.7.2 Drying Solvent, a volatile solvent

42、miscible with the sample solvent (see 7.1).7.2.1 Highly concentrated ethanol (96 %(96?% or higher) is suitable.7.3 Dry Air or Nitrogen, for blowing the measuring cells.7.3.1 If the measuring cell temperature is below or near the dew point temperature of the ambient air, the use of an appropriatedesi

43、ccator is required.8. Sampling, Test Specimens, and Test Units8.1 Sampling is defined as all the steps required to obtain an aliquot of the contents of any pipe, tank, or other system, and toplace the sample into the laboratory test container. The laboratory test container and sample volume shall be

44、 of sufficient capacityto mix the sample and obtain a homogeneous sample for analysis.8.2 ParticlesFor samples that are likely to contain particles (for example, used oils or crude oils) pass the sample through a75-m screen to remove the particles. For the removal of iron filings the use of a magnet

45、 is appropriate. Waxy samples must beheated to dissolve the wax crystals prior to filtration and a preheated filter shall be used.8.3 Test SpecimenA portion or volume of sample obtained from the laboratory sample and delivered to the measuring cells.The test specimen is obtained as follows:8.3.1 Mix

46、 the sample, if required, to homogenize. Mixing at room temperature in an open container can result in the loss ofvolatile material; mixing in closed, pressurized containers, or at sub-ambient temperatures is recommended.8.3.2 Draw the test specimen from a properly mixed laboratory sample using an a

47、ppropriate syringe.Alternatively, if the properattachments and connecting tubes are used, the test specimen may be delivered directly to the measuring cells using a flow throughor pressure adapter (see 6.3) or autosampler (see 6.4) from the mixing container. For waxy or other samples with a high pou

48、r point,before drawing the test specimen, heat the laboratory sample to the desired test temperature, which has to be high enough todissolve the wax crystals.9. Calibration and Verification9.1 Use only a calibrated apparatus as described in 6.1. The calibration shall be checked periodically using ce

49、rtified referencestandards as described in 9.2 and 9.3. The recommended interval for viscosity and density calibration is once a month, fortemperature control once a year. For the calibration procedure follow the instructions of the manufacturer of the apparatus.9.2 Certified Viscosity and Density Reference StandardsThese are for use as confirmatory checks on the procedure in thelaboratory. Certified viscosity and density reference standards shall be certified by a laboratory, which has shown to meet therequirements of ISO/IEC 17025 or a