ASTM D7215-2016 9450 Standard Test Method for Calculated Flash Point from Simulated Distillation Analysis of Distillate Fuels《通过馏出燃料的模拟馏出分析计算闪点的标准试验方法》.pdf

1、Designation: D7215 16Standard Test Method forCalculated Flash Point from Simulated Distillation Analysisof Distillate Fuels1This standard is issued under the fixed designation D7215; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision,

2、the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This test method covers the calculated flash pointformula, which represents a means for directly estimati

3、ng theflash point temperature of distillate fuels from Test MethodD2887 data. The value computed from the equation is termedthe “calculated flash point.” The calculated flash point formulais applicable to diesel fuel samples based on a correlation toTest Method D93 over the range from 47 C to 99 C,

4、and to jetfuel samples based on a correlation to Test Method D56 andTest Method D3828 over the range from 35 C to 67 C.1.2 The calculated flash point formula is valid for diesel andjet fuels with an IBP between 90 C and 162 C (194 F and324 F), Test Method D2887 5 % recovery temperature be-tween 136

5、C and 207 C (277 F and 405 F), and TestMethod D2887 10 % recovery temperature between 142 Cand 222 C (288 F and 432 F). For each flash point testmethod (Test Method D56, Test Method D93, and Test MethodD3828) a separate equation has been established. See 4.4 for adetailed overview of the simulated d

6、istillation IBP, 5 %, and10 % ranges per equation.1.3 A calculated diagnostic parameter, not exceeding agiven threshold value, is a prerequisite for acceptance of thecalculated flash point.1.4 The diagnostic parameter MSPEX(Mean SummedPrediction Error) checks the sample compliance, based onreconstru

7、ction of TIBP,T5%, and T10 %of the sample, via acalculation procedure. A value for MSPEXnot exceeding thethreshold level of 1.9 C is a prerequisite for accepting thecalculated flash point, CFP.NOTE 1It is important to note that calculated flash point results, at thistime, are not recognized by regul

8、atory organizations in verifying confor-mance to applicable regulations.NOTE 2The calculated flash point derived from simulated distillationdata depends upon the accuracy of determination of the IBP temperatureand the 5 % and 10 % recovery temperatures.NOTE 3If the users specification requires a def

9、ined flash point testmethod other than this test method, neither this test method nor any othertest method should be substituted for the prescribed test method withoutobtaining comparative data and an agreement from the specifier.1.5 The values stated in SI units are to be regarded as thestandard.1.

10、5.1 ExceptionThe values given in parentheses are forinformation only.1.6 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the

11、applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D56 Test Method for Flash Point by Tag Closed Cup TesterD93 Test Methods for Flash Point by Pensky-MartensClosed Cup TesterD975 Specification for Diesel Fuel OilsD1655 Specification for Aviation Turbine

12、FuelsD2887 Test Method for Boiling Range Distribution of Pe-troleum Fractions by Gas ChromatographyD3828 Test Methods for Flash Point by Small Scale ClosedCup TesterD6708 Practice for Statistical Assessment and Improvementof Expected Agreement Between Two Test Methods thatPurport to Measure the Same

13、 Property of a Material3. Terminology3.1 Definitions:3.1.1 diesel fuel, nfuel for diesel engines, as described inSpecification D975.3.1.2 flash point, nlowest temperature, corrected to apressure of 101.3 kPa (760 mm Hg), at which application of anignition source causes the vapors of a specimen of th

14、e sampleto ignite under specified conditions of test.3.1.3 jet fuel (kerosene type), naviation turbine fuel asdescribed in Specification D1655.1This test method is under the jurisdiction of ASTM Committee D02 onPetroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility ofSubco

15、mmittee D02.04.0K on Correlative Methods.Current edition approved July 1, 2016. Published July 2016. Originally approvedin 2008. Last previous edition approved in 2013 as D7215 08 (2013). DOI:10.1520/D7215-16.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Custom

16、er Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA

17、 19428-2959. United States13.1.4 simulated distillation, ndistillation, simulated bygas chromatography, to obtain a boiling range distribution.3.2 Definitions of Terms Specific to This Standard:3.2.1 calculated flash point (CFP), nflash point calculatedusing this test method from the IBP, 5 %, and 1

18、0 % recoverytemperature obtained from simulated distillation according toTest Method D2887.3.2.2 mean sum of prediction errors of variable X (MSPEX),nmean of summed prediction errors of the predictorvariables, that is, the recovery temperatures.3.2.3 partial least squares (PLS) regression, nextensio

19、nof the multiple linear regression model, specifying a linearrelationship between a dependent variable and a set of predic-tor variables.4. Significance and Use4.1 The flash point temperature is one measure of thetendency of the test specimen to form a flammable mixturewith air under controlled labo

20、ratory conditions. It is only oneof a number of properties that must be considered in assessingthe overall flammability hazard of a material.4.2 Flash point is used in shipping and safety regulations todefine flammable and combustible materials. Consult theparticular regulation involved for precise

21、definitions of theseclassifications.4.3 Flash point can indicate the possible presence of highlyvolatile and flammable materials in a relatively non-volatile ornon-flammable material.4.4 In cases where Test Method D2887 data are available,that is, for determination of boiling range distribution orca

22、lculation of other physical properties, this test methodprovides a calculation method for flash point without perform-ing an additional analysis. Table 1 shows the ranges for theIBP, 5 %, and 10 % results for each equation.4.5 In the case where the flash point of a fuel has beeninitially established

23、, the calculated flash point is useful as aflash point check on subsequent samples of that fuel, providedits source and mode of manufacture remain unchanged.5. Procedure5.1 Obtain the IBP, 5 % and 10 % recovered temperatures ofthe specimen by performing a simulated distillation accordingto Test Meth

24、od D2887.5.2 Calculate reconstruction values of TIBP,T5%, and T10 %recovery temperatures according to Eq 1-3:TIBP5 2.7510.944TIBP10.163T5%2 0.124T10 %C# (1)T5%5 2.2110.163TIBP10.363T5%10.455T10 %C# (2)T10 %523.71 2 0.124TIBP10.455T5%10.694T10 %C# (3)5.3 Compute the sample compliance mean sum of pred

25、ic-tion errors of the recovery temperatures, MSPEXof thespecimen according to Eq 4:MSPEX513=TIBP2 TIBP#21T5%2 T5%#21T10 %2 T10 %#2C#(4)where TIBP,T5%, and T10 %refer to the experimental sampleboiling point temperatures.5.4 Compare MSPEXto the critical value of 1.9 C. IfMSPEXexceeds this critical val

26、ue, then the sample is notsuitable for calculation of flash point according to this testmethod. Do not proceed with this test method.6. Calculation6.1 Calculation of the CFP using the appropriate Eq 5-7:6.1.1 For correlation to Test Method D56:CFPD565255.510.164TIBP10.095T5%10.453T10 %C# (5)6.1.2 Fo

27、r correlation to Test Method D93:CFPD935251.710.403TIBP10.163T5%10.214T10 %C# (6)6.1.3 For correlation to Test Method D3828:CFPD38285261.410.223TIBP2 0.201T5%10.721T10 %C# (7)7. Report7.1 Report the calculated flash point to the nearest 0.1 C(0.2 F), including the correlating subscript.8. Precision

28、and Bias38.1 Within the range of 47 C to 99 C (117 F to 210 F),for diesel fuel samples and within the range of 35 C to 67 C(95 F to 153 F) for jet fuel samples, the difference betweenthe calculated flash point and the experimental flash point willbe less than 64 C (7 F) for 95 % of the distillate fu

29、elsevaluated.8.2 PrecisionThe precision of this test method as deter-mined by the statistical evaluation of the published repeatabil-ity and reproducibility of the Test Method D2887 method andthe Test Method D56, Test Method D93 and Test MethodD3828 correlation models, is as follows:8.3 Repeatabilit

30、yThe difference between successive testresults, obtained by the same operator using the same apparatusunder constant operating conditions on identical test material,3Supporting data have been filed at ASTM International Headquarters and maybe obtained by requesting Research Report RR:D02-1636.TABLE

31、1 OverviewIBP 5 % 10 %Min temp Max temp Min temp Max temp Min temp Max tempTest Method D93 Diesel 103 C (217 F) 163 C (326 F) 144 C (291 F) 210 C (410 F) 159 C (318 F) 236 C (457 F)Test Method D56 Jet Fuel 101 C (213 F) 136 C (277 F) 135 C (275 F) 169 C (337 F) 141 C (285 F) 183 C (362 F)Test Method

32、 D3828 Jet Fuel 101 C (213 F) 136 C (277 F) 135 C (275 F) 169 C (337 F) 141 C (285 F) 183 C (362 F)D7215 162would in the long run, in normal and correct operation of thistest method, exceed the values in Table 2 in only one case intwenty.8.4 ReproducibilityThe difference between two single andindepe

33、ndent results obtained by different operators working indifferent laboratories on identical test material would, in thelong run, exceed the values in Table 3 in only one case intwenty.8.5 BiasBias between flash points from Test Method D56,Test Method D93, and Test Method D3828 and calculated flashpo

34、int from simulated distillation data has been evaluated usingPractice D6708. No significant bias was found between thecalculated flash point and the flash point determined using theabove flash point methods.8.6 Cross-method ReproducibilityThe difference betweentwo single and independent results obta

35、ined by differentoperators working in different laboratories on identical testmaterial and applying the correlated and reference methodrespectively, would in the long run, exceed the values in Table4 in only one case in twenty.8.7 This correlation model and determination of the cross-method reproduc

36、ibility was validated by an analysis of vari-ance procedure in accordance with Practice D6708.8.8 The statistical evaluation and validation can be found inthe research report.9. Keywords9.1 calculated flash point; diesel fuel; flash point; jet fuel;MSPEX; PLS; simulated distillationANNEX(Mandatory I

37、nformation)A1. CORRELATION DATAA1.1 Development of the CorrelationA1.1.1 A database with 117 representative samples wascollected and divided into a correlation data set and a valida-tion data set. The complete data set included 56 diesel fuelsamples and 61 jet fuel samples. The detailed data set str

38、uctureis given in Tables A1.1 and A1.2.A1.1.2 The empirical equation for the calculated flash pointcorrelation was derived using a partial least squares (PLS)regression. Other correlation techniques have been investi-gated.3A1.1.3 The correlation equations were developed using TestMethod D2887 disti

39、llation data and Test Method D93 flashpoint data for diesel fuel and Test Method D56 and TestMethod D3828 flash point data for jet fuel.TABLE 2 RepeatabilityCalculatedRepeatability, rC FTest Method D56 0.5 0.9Test Method D93 0.8 1.4Test Method D3828 0.8 1.4TABLE 3 ReproducibilityCalculatedReproducib

40、ility, RC FTest Method D56 2.0 3.6Test Method D93 4.4 7.9Test Method D3828 2.9 5.2TABLE 4 Cross-Method ReproducibilityCalculatedCross-method Reproducibility, RXYC FTest Method D56 4.3 7.7Test Method D93 5.2 9.9Test MethodD38283.6 6.4TABLE A1.1 Number of Samples Used for the CorrelationJet Fuel Diese

41、l Fuel TotalEurope USA/CanadaEurope USA/CanadaTest Method D56 14 10 24Test Method D93 13 20 33Test MethodD3828410 14Total 71D7215 163SUMMARY OF CHANGESSubcommittee D02.04 has identified the location of selected changes to this standard since the last issue(D7215 08 (2013) that may impact the use of

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45、a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of thi

46、s standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ A1.2 Number of Samples Used for the ValidationJet Fuel Diesel Fuel TotalEurope USA/CanadaEurope USA/CanadaTest Method D56 13 4 17Test Method D93 12 11 23Test MethodD382833 6Total 46D7215 164