ASTM D7719-2017 red 3750 Standard Specification for High Aromatic Content Unleaded Hydrocarbon Aviation Gasoline《高芳烃含量无铅烃航空汽油的标准规格》.pdf

1、Designation: D7719 16aD7719 17 An American National StandardStandard Specification forHigh Aromatic Content Unleaded Hydrocarbon AviationGasoline1This standard is issued under the fixed designation D7719; the number immediately following the designation indicates the year oforiginal adoption or, in

2、the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This specification covers formulating specifications for purchases of a high aromat

3、ic content unleaded hydrocarbon aviationgasoline under contract and is intended solely for use by purchasing agencies.21.2 This specification defines a specific type of high aromatic content unleaded hydrocarbon aviation gasoline (hereafter alsoreferred to as “D7719 fuel”) for use as an aviation spa

4、rk-ignition fuel. It does not include all fuels satisfactory for reciprocatingaviation engines. Certain equipment or conditions of use may permit a wider, or require a narrower, range of characteristics thanis shown by this specification.1.3 The D7719 fuel defined by this specification does not exhi

5、bit identical performance to those leaded fuels for which theexisting aircraft and ground-based fuel handling equipment have been designed to operate on. Therefore, the suitability of this fuelfor use on any specific aircraft, aircraft engine, or ground-based fuel handling equipment should be evalua

6、ted before use on thatequipment.1.4 Issuance of this specification does not constitute approval to operate certificated aircraft with this fuel. Fuels used in certifiedengines and aircraft are ultimately approved by the certifying authority subsequent to formal submission of evidence to theauthority

7、 as part of the certification program for that aircraft and engine model.1.5 This specification, unless otherwise provided, prescribes the required properties of unleaded fuel at the time and place ofdelivery.1.6 The values stated in SI units are to be regarded as standard. No other units of measure

8、ment are included in this standard.1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibilityof the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine theapplic

9、ability of regulatory limitations prior to use.1.8 This international standard was developed in accordance with internationally recognized principles on standardizationestablished in the Decision on Principles for the Development of International Standards, Guides and Recommendations issuedby the Wo

10、rld Trade Organization Technical Barriers to Trade (TBT) Committee.2. Referenced Documents2.1 ASTM Standards:3D86 Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric PressureD130 Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip TestD323 T

11、est Method for Vapor Pressure of Petroleum Products (Reid Method)D873 Test Method for Oxidation Stability of Aviation Fuels (Potential Residue Method)D909 Test Method for Supercharge Rating of Spark-Ignition Aviation GasolineD910 Specification for Leaded Aviation GasolinesD1094 Test Method for Water

12、 Reaction of Aviation FuelsD1266 Test Method for Sulfur in Petroleum Products (Lamp Method)1 This specification is under the jurisdiction ofASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of SubcommitteeD02.J0.02 on Spark and Compression Igniti

13、on Aviation Engine Fuels.Current edition approved Dec. 1, 2016Oct. 1, 2017. Published January 2017October 2017. Originally approved in 2011. Last previous edition approved in 2016 asD7719 16.D7719 16a. DOI: 10.1520/D7719-16A.10.1520/D7719-17.2 Supporting data have been filed at ASTM International He

14、adquarters and may be obtained by requesting Research Report RR:D02-1721.3 For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at serviceastm.org. For Annual Book of ASTM Standardsvolume information, refer to the standards Document Summary page on the A

15、STM website.This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Becauseit may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consu

16、lt prior editions as appropriate. In all cases only the current versionof the standard as published by ASTM is to be considered the official document.*A Summary of Changes section appears at the end of this standardCopyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken,

17、PA 19428-2959. United States1D1298 Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products byHydrometer MethodD2386 Test Method for Freezing Point of Aviation FuelsD2622 Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Flu

18、orescence SpectrometryD2624 Test Methods for Electrical Conductivity of Aviation and Distillate FuelsD2700 Test Method for Motor Octane Number of Spark-Ignition Engine FuelD3237 Test Method for Lead in Gasoline by Atomic Absorption SpectroscopyD3606 Test Method for Determination of Benzene and Tolue

19、ne in Finished Motor and Aviation Gasoline by Gas Chromatog-raphyD4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density MeterD4057 Practice for Manual Sampling of Petroleum and Petroleum ProductsD4171 Specification for Fuel System Icing InhibitorsD4177 Practic

20、e for Automatic Sampling of Petroleum and Petroleum ProductsD4306 Practice for Aviation Fuel Sample Containers for Tests Affected by Trace ContaminationD4809 Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter (Precision Method)D4814 Specification for Automotive Spark-

21、Ignition Engine FuelD4865 Guide for Generation and Dissipation of Static Electricity in Petroleum Fuel SystemsD5006 Test Method for Measurement of Fuel System Icing Inhibitors (Ether Type) in Aviation FuelsD5059 Test Methods for Lead in Gasoline by X-Ray SpectroscopyD5191 Test Method for Vapor Press

22、ure of Petroleum Products (Mini Method)D5580 Test Method for Determination of Benzene, Toluene, Ethylbenzene, p/m-Xylene, o-Xylene, C9 and Heavier Aromatics,and Total Aromatics in Finished Gasoline by Gas ChromatographyD6469 Guide for Microbial Contamination in Fuels and Fuel SystemsD6733 Test Metho

23、d for Determination of Individual Components in Spark Ignition Engine Fuels by 50-Metre Capillary HighResolution Gas ChromatographyD7826 Guide for Evaluation of New Aviation Gasolines and New Aviation Gasoline AdditivesE29 Practice for Using Significant Digits in Test Data to Determine Conformance w

24、ith Specifications3. Terminology3.1 Definitions:3.1.1 binary, adjcharacterized by, or consisting of, two components.3.1.2 biomass, nbiological material including any material other than fossil fuels which is or was a living organism orcomponent or product of a living organism.3.1.3 non-hydrocarbon,

25、ncompound or compounds composed of carbon, hydrogen, and other elements such as oxygen,nitrogen, sulfur, and phosphorus.3.1.4 unleaded hydrocarbon aviation gasoline, ngasoline intended for use in aircraft powered by reciprocating spark-ignitionengines, where lead and lead-containing compounds are no

26、t intentionally added for the purpose of enhancing octane performanceand which excludes non-hydrocarbons, except for additives approved in this specification.4. General4.1 This specification, unless otherwise provided, prescribes the required properties of a high aromatic content unleadedhydrocarbon

27、 aviation gasoline at the time and place of delivery.5. Classification5.1 One grade of high aromatic content unleaded hydrocarbon aviation gasoline is provided, known as UL102.6. Materials and Manufacture6.1 D7719 fuel, except as otherwise specified in this specification, shall consist of blends of

28、refined hydrocarbons. The sourcesfor these hydrocarbons include biomass, natural gas, or crude petroleum.6.1.1 See Appendix X1 for one particular composition that meets the parameters of Table 1.6.2 AdditivesThese can be added to each grade of D7719 fuel in the amount, and of the composition, specif

29、ied in the followinglist of approved materials:6.2.1 DyesThe total maximum concentration of dye in the fuel is 6.0 mg/L. (See X1.1.1 and X2.2.7.)6.2.1.1 The only blue dye present in the finished fuel shall be essentially 1,4-dialkylaminoanthraquinone.6.2.1.2 The only yellow dyes in the finished fuel

30、 shall be essentially p-diethylaminoazobenzene (Color Index No. 11021) or1,3-benzenediol 2,4-bis (alkylphenyl)azo-.6.2.1.3 The only red dye present in the finished fuel shall be essentially alkyl derivatives of azobenzene-4-azo-2-naphthol.D7719 1726.2.1.4 The only orange dye present in the finished

31、fuel shall be essentially benzene-azo-2-napthol (Color Index No. 12055).6.2.2 Other AdditivesThese may be added in the amount and of the composition specified in the following list of approvedmaterials. The quantities and types shall be declared by the manufacturer.Additives added after the point of

32、 manufacture shall alsobe declared.6.2.2.1 AntioxidantsThe following oxidation inhibitors may be added to the fuel separately, or in combination, in totalconcentration not to exceed 12 mg of inhibitor (not including weight of solvent) per litre of fuel.(1) 2,6-ditertiary butyl-4-methylphenol.(2) 2,4

33、-dimethyl-6-tertiary butylphenol.(3) 2,6-ditertiary butylphenol.(4) 75 % minimum 2,6-ditertiary butylphenol plus 25 % maximum mixed tertiary and tritertiary butylphenols.(5) 75 % minimum di- and tri-isopropyl phenols plus 25 % maximum di- and tri-tertiary butylphenols.(6) 72 % minimum 2,4-dimethyl-6

34、-tertiary butylphenol plus 28 % maximum monomethyl and dimethyl tertiary butylphenols.(7) N,N-di-isopropyl-para-phenylenediamine.(8) N,N-di-secondary-butyl-para-phenylenediamine.TABLE 1 Detailed Requirements for High Aromatic Content Unleaded Hydrocarbon Aviation GasolineAGrade UL102 ASTM Test Metho

35、dBPropertyCOMBUSTIONOctane Rating min 102.2 D2700Knock value, Motor Octane NumberCNet heat of combustion, MJ/kg min 41.5 D4809COMPOSITIONSulfur, mass % max 0.05 D1266 or D2622Tetraethyl Lead, g Pb/L max 0.013 D3237 or D5059Total Aromatics, % (m/m) min 70 D6733Benzene, % (m/m) max 0.1 D3606D or D5580

36、Requirements for All GradesVOLATILITYVapor pressure, 37.8 C, kPa min 38.0 D323 or D5191Emax 49.0Density at 15 C, kg/m3 min 790 D1298 or D4052max 825Distillation D86Initial boiling point, C Report D86Fuel Evaporated D8610 volume % at C max 75 D8640 volume % at C min 75 D8650 volume % at C max 165 D86

37、90 volume % at C max 165 D86Final boiling point, C max 180 D86Sum of 10 % + 50 % evaporated temperatures, C min 135 D86Recovery, volume % min 97 D86Residue, volume % max 1.5 D86Loss, volume % max 1.5 D86FLUIDITYFreezing point, C max 58F D2386CORROSIONCopper strip, 2 h at 100 C max No. 1 D130CONTAMIN

38、ANTSOxidation stability (5 h aging)G D873Potential gum, mg/100 mL max 6Water reaction D1094Volume change, mL max 2OTHERElectrical conductivity, pS/m max 450H D2624A For compliance of test results against the requirements of Table 1, see 7.2.B The test methods indicated in this table are referred to

39、in Section 11.C Knock ratings shall be reported to the nearest 0.1 octane number.D In case of dispute, Test Method D3606 shall be used as the referee method.E Test Method D5191 shall be the referee vapor pressure method.F If no crystals have appeared on cooling to 58 C, the freezing point may be rep

40、orted as less than 58 C.GIf mutually agreed upon between the purchaser and the supplier, a 16 h aging gum requirement may be specified instead of the 5 h aging gum test; in such case thegum content shall not exceed 10 mg 100 mL. In such fuel the permissible antioxidant shall not exceed 24 mg L.H App

41、lies only when an electrical conductivity additive is used; when a customer specifies fuel containing conductivity additive, the following conductivity limits shall applyunder the condition at point of use:Minimum 50 pS mMaximum 450 pS m.The supplier shall report the amount of additive added.D7719 1

42、736.2.2.2 Fuel System Icing Inhibitor (FSII)One of the following materials may be used:(1) Isopropyl Alcohol (IPA, propan-2-ol), in accordance with the requirements of Specification D4171 (Type II). May be usedin concentrations recommended by the aircraft manufacturer when required by the aircraft o

43、wner/operator.(2) Di-Ethylene Glycol Monomethyl Ether (Di-EGME), conforming to the requirements of Specification D4171 (Type III).May be used in concentrations of 0.10 to 0.15 volume % when required by the aircraft owner/operator.(3) Test Method D5006 can be used to determine the concentration of Di

44、-EGME in aviation fuels.NOTE 1Addition of isopropyl alcohol (IPA) may reduce knock ratings below minimum specification values. See X2.2.3.6.2.2.3 Electrical Conductivity AdditiveStadis 450 in concentrations up to 3 mg/Lis permitted. When loss of fuel conductivitynecessitates retreatment with electri

45、cal conductivity additive, further addition is permissible6.2.2.4 Corrosion Inhibitor AdditiveThe following corrosion inhibitors may be added to the fuel in concentrations not toexceed the maximum allowable concentration (MAC) listed for each additive.DCI-4A MAC = 24.0 g/m3DCI-6A MAC = 15.0 g/m3HITE

46、C 580 MAC = 22.5 g/m3NALCO 5403 MAC = 22.5 g/m3NALCO 5405 MAC = 11.0 g/m3UNICOR J MAC = 22.5 g/m3SPEC-AID 8Q22 MAC = 24.0 g/m3TOLAD 351 MAC = 24.0 g/m3TOLAD 4410 MAC = 22.5 g/m37. Detailed Requirements7.1 The D7719 fuel shall conform to the requirements prescribed in Table 1.7.2 Test results shall n

47、ot exceed the maximum or be less than the minimum values specified in Table 1. No allowance shall bemade for the precision of the test methods. To determine the conformance to the specification requirement, a test result may berounded to the same number of significant figures as in Table 1 using Pra

48、ctice E29. Where multiple determinations are made, theaverage result, rounded according to Practice E29, shall be used.8. Workmanship, Finish, and Appearance8.1 The D7719 fuel specified in this specification shall be free from undissolved water, sediment, and suspended matter. Nosubstances of known

49、dangerous toxicity, under usual conditions of handling and use, shall be present except as permitted in thisspecification.9. Sampling9.1 Because of the importance of proper sampling procedures in establishing fuel quality, use the appropriate procedures inPractice D4057 or Practice D4177.9.1.1 Although automatic sampling following Practice D4177 may be useful in certain situations, initial manufacturer/supplierspecification compliance testing shall be performed on a sample taken following procedures in Practice D4057.9.2 Anumber of D7719 fu