ASTM D8061-2016 3667 Standard Practice for Handling Transportation and Storage of 2-Bromo-3 3 3-Trifluoro-1-Propene (CF3CBr=CH2)《2-溴-3 3 3-三氟-1-丙烯 (CF3CBr=CH2) 搬动 运输和存放的标准实施规程》.pdf

1、Designation: D8061 16Standard Practice forHandling, Transportation, and Storage of 2-Bromo-3,3,3-Trifluoro-1-Propene (CF3CBr=CH2)1This standard is issued under the fixed designation D8061; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revi

2、sion, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This practice covers guidance and direction to suppliers,reclaimers, purchasers, and users in the ha

3、ndling,transportation, and storage of 2-Bromo-3,3,3-Trifluoro-1-Propene (“2-BTP”).1.2 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that are provided for information onlyand are not considered standard.1.3

4、 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Docu

5、ments2.1 ASTM Standards:2D8060 Specification for 2-Bromo-3,3,3-Trifluoro-1-Propene(CF3CBr=CH2)2.2 U.S. Government Standards:3CFR Title 49, Part 172 U.S. Department of Transportation(DOT), Hazardous Materials Table, Special Provisions,Hazardous Materials Communications, Emergency Re-sponse Informatio

6、n, and Training RequirementsCFR Title 49, Part 172.101 U.S. DOT, Tables of HazardousMaterials and Special Provisions3. Terminology3.1 Definitions of Terms Specific to This Standard:3.1.1 2-BTP, n2-Bromo-3,3,3-Trifluoro-1-Propene(CF3CBr=CH2); a compound used to inert, extinguish, orsuppress a fire or

7、 explosion hazard.3.1.2 containers, nstorage vessels for 2-BTP.3.1.3 cylinders, ncontainers of 2-BTP.3.1.4 insulated, vplaced in an isolated situation to protectand prevent the transfer of damage.4. Significance and Use4.1 This practice provides requirements for the handling,transportation, and stor

8、age of 2-BTP encountered in distribu-tion through both commercial and military channels. It isintended to ensure that 2-BTP is handled, transported, andstored in such a way that its physical property virtues are notdegraded. Transport may be by various means, such as, but notlimited to, highway, rai

9、l, water, and air.5. Practice5.1 To ensure safe handling, loading, unloading, storing,and transporting of material, personnel shall be trained tofollow guidance contained within the manufacturers SafetyData Sheet for this substance.5.2 Handling:5.2.1 Handling shall be in accordance with the currentm

10、anufacturers Safety Data Sheet for this substance.5.2.1.1 Personnel who handle or store, or both, containers of2-BTP shall be trained properly to recognize and identify thecharacteristics of the product and the proper methods of safelyhandling full, partially full, and empty containers.5.2.2 All 2-B

11、TP transfers between storage containers andrecycling processes shall be performed by personnel trained inhandling procedures.5.2.2.1 2-BTP recycling and transfer processes shall be inconjunction with the equipment specified by the manufacturer.5.2.3 To preclude product accumulation and decomposition

12、,2-BTP handling shall be performed in ventilated areas that arenonsmoking and free of portable heaters with high-temperatureelements. Provisions shall be made to ensure that 2-BTPconcentrations do not exceed 10 000 ppm (1 %) by volume for1 min in service areas.5.2.4 Containers shall not be overfille

13、d. The liquid portionof the 2-BTP must not completely fill the containers internalvolume at any temperature up to and including 130F (54C).The maximum permitted filling density for 2-BTP shall be87 lb ft3(1400 kg/m3).1This practice is under the jurisdiction of ASTM Committee D26 on Haloge-nated Orga

14、nic Solvents and Fire Extinguishing Agents and is the direct responsi-bility of Subcommittee D26.09 on Fire Extinguishing Agents.Current edition approved July 1, 2016. Published July 2016. DOI: 10.1520/D8061-16.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Cust

15、omer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3Available from U.S. Government Publishing Office, 732 N. Capitol St., NW,Washington, DC 204010001, http:/www.gpo.gov.Copyright ASTM International, 10

16、0 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States15.2.5 Handling of materials should be done in a manner thatprevents contamination or commingling of halocarbons otherthan 2-BTP.5.2.6 Containers shall be free of dirt and contamination thatwould contribute to or would

17、cause deterioration of productduring shipment or storage. Precautions should be taken toprevent the entry of oil, water, or any other foreign matter intocontainers. Unique coatings or preservatives applied prior toshipment to protect the containers are not considered contami-nation.5.2.7 Containers

18、shall be vacuumed, minimum of 27 in.(686 mm) mercury at sea level, or purged with dry nitrogen toremove air and moisture contamination prior to being filledwith this substance. This material is sensitive to air andmoisture.5.3 Transportation:5.3.1 This substance is not classified as hazardous underD

19、OT regulations of Title 49 CFR. A container super-pressurized with nitrogen above the inherent vapor pressure ofthe neat substance may require classification (for example, fireextinguisher system bottle). Any classification will dependupon the specifications of the container and its fill pressure.5.

20、3.1.1 Shipment of materials between collectors, recyclers,and reclaimers should be in containers agreed upon betweenthe collectors, recyclers, and reclaimers.5.3.1.2 Typical container fill density variations do not im-pact the pressure enough to provide an isometric diagram. (SeeFigs. 1 and 2.)5.3.2

21、 Transportation shall be by suitable vehicles to pre-clude container damage by excessive mechanical vibration,shock, or deleterious low or high temperatures throughout theentire transport route.5.3.2.1 If containers are expected to be subjected to unac-ceptable transport conditions, the containers s

22、hould be placedunder insulated conditions.5.4 Storage:5.4.1 Containers should be stored in areas that will protectvessels from physical and environmental damage and tamper-ing from unauthorized personnel.5.4.2 Containers shall be clearly marked and labeled toidentify whether the 2-BTP contained does

23、 or does not con-form to Specification D8060.5.4.3 Insulation shall be placed on pallets or shoring, andprovisions should be made to prevent excessive shock orthermal fluctuations to containers.5.4.4 Containers shall be stored in a manner that willprevent contamination from external sources.5.4.4.1

24、If 2-BTP meeting the standards of SpecificationD8060 is stored in the same area as material not meeting thestandards, storage shall be segregated or clearly identifiable asnot being similar.6. Inspection6.1 2-BTP that is reclaimed using 2-BTP manufacturer-approved reclamation systems may be released

25、 for reissue,provided test examination to validate the material to specifi-cation is fulfilled.6.1.1 Reclaimed 2-BTP that cannot be proven to complywith Specification D8060 shall not be reissued. The materialwill be processed by environmentally safe methods untilconformance to the product standard i

26、s achieved.FIG. 1 Pressure Versus Temperature Diagram of 2-BTP, English UnitsD8061 1627. Keywords7.1 2-bromo-3,3,3-trifluoro-1-propene; 2-bromo-3,3,3-trifluoropropene; 2-BTP; bromotrifluoropropene; BTP;CF3CBr=CH2; fire extinguishant; fire suppressant; Halotron4BrX; handling; R-1233B1; reclamation; r

27、ecovery; storage;transportASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infrin

28、gement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard

29、 or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views

30、 known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting

31、 ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the Copyright Clearance Center, 222Rosewood Drive, Danvers, MA 01923, Tel: (978) 646-2600; http:/ is a trademark of American Pacific Corporation.FIG. 2 Pressure Versus Temperature Diagram of 2-BTP, SI UnitsD8061 163