ASTM G102-1989(2015)e1 Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements《计算电化学测量的腐蚀速率和相关信息的标准实施规程》.pdf

1、Designation: G102 89 (Reapproved 2015)1Standard Practice forCalculation of Corrosion Rates and Related Informationfrom Electrochemical Measurements1This standard is issued under the fixed designation G102; the number immediately following the designation indicates the year oforiginal adoption or, in

2、 the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1NOTEEditorially corrected the legend below Eq 1 in 4.1 in November 2015.1. Scope1.1 This pract

3、ice covers the providing of guidance inconverting the results of electrochemical measurements to ratesof uniform corrosion. Calculation methods for convertingcorrosion current density values to either mass loss rates oraverage penetration rates are given for most engineering alloys.In addition, some

4、 guidelines for converting polarization resis-tance values to corrosion rates are provided.1.2 The values stated in SI units are to be regarded asstandard. No other units of measurement are included in thisstandard.2. Referenced Documents2.1 ASTM Standards:2D2776 Methods of Test for Corrosivity of W

5、ater in theAbsence of Heat Transfer (Electrical Methods) (With-drawn 1991)3G1 Practice for Preparing, Cleaning, and Evaluating Corro-sion Test SpecimensG5 Reference Test Method for Making PotentiodynamicAnodic Polarization MeasurementsG59 Test Method for Conducting Potentiodynamic Polariza-tion Resi

6、stance Measurements3. Significance and Use3.1 Electrochemical corrosion rate measurements often pro-vide results in terms of electrical current. Although the con-version of these current values into mass loss rates or penetra-tion rates is based on Faradays Law, the calculations can becomplicated fo

7、r alloys and metals with elements havingmultiple valence values. This practice is intended to provideguidance in calculating mass loss and penetration rates for suchalloys. Some typical values of equivalent weights for a varietyof metals and alloys are provided.3.2 Electrochemical corrosion rate mea

8、surements may pro-vide results in terms of electrical resistance. The conversion ofthese results to either mass loss or penetration rates requiresadditional electrochemical information. Some approaches forestimating this information are given.3.3 Use of this practice will aid in producing more consi

9、s-tent corrosion rate data from electrochemical results. This willmake results from different studies more comparable andminimize calculation errors that may occur in transformingelectrochemical results to corrosion rate values.4. Corrosion Current Density4.1 Corrosion current values may be obtained

10、 from galvaniccells and polarization measurements, including Tafel extrapo-lations or polarization resistance measurements. (See Refer-ence Test Method G5 and Practice G59 for examples.) The firststep is to convert the measured or estimated current value tocurrent density. This is accomplished by di

11、viding the totalcurrent by the geometric area of the electrode exposed to thesolution. The surface roughness is generally not taken intoaccount when calculating the current density. It is assumed thatthe current distributes uniformly across the area used in thiscalculation. In the case of galvanic c

12、ouples, the exposed area ofthe anodic specimen should be used. This calculation may beexpressed as follows:icor5IcorA(1)where:icor= corrosion current density, A/cm2,Icor= total anodic current, A, and1This practice is under the jurisdiction of ASTM Committee G01 on Corrosionof Metalsand is the direct

13、 responsibility of Subcommittee G01.11 on Electrochemi-cal Measurements in Corrosion Testing.Current edition approved Nov. 1, 2015. Published December 2015. Originallyapproved in 1989. Last previous edition approved in 2010 as G10289 (2010). DOI:10.1520/G0102-89R15E01.2For referenced ASTM standards,

14、 visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this historical standard is referenced onwww.astm.org.Copyrigh

15、t ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States1A = exposed specimen area, cm2.Other units may be used in this calculation. In somecomputerized polarization equipment, this calculation is madeautomatically after the specimen area is programme

16、d into thecomputer. A sample calculation is given in Appendix X1.4.2 Equivalent WeightEquivalent weight, EW, may bethought of as the mass of metal in grams that will be oxidizedby the passage of one Faraday (96 489 6 2 C (amp-sec) ofelectric charge.NOTE 1The value of EW is not dependent on the unit

17、system chosenand so may be considered dimensionless.For pure elements, the equivalent weight is given by:EW 5Wn(2)where:W = the atomic weight of the element, andn = the number of electrons required to oxidize an atom ofthe element in the corrosion process, that is, the valenceof the element.4.3 For

18、alloys, the equivalent weight is more complex. It isusually assumed that the process of oxidation is uniform anddoes not occur selectively to any component of the alloy. If thisis not true, then the calculation approach will need to beadjusted to reflect the observed mechanism. In addition, somerati

19、onale must be adopted for assigning values of n to theelements in the alloy because many elements exhibit more thanone valence value.4.4 To calculate the alloy equivalent weight, the followingapproach may be used. Consider a unit mass of alloy oxidized.The electron equivalent for1gofanalloy, Q is th

20、en:Q 5(nifiWi(3)where:fi = the mass fraction of the ithelement in the alloy,Wi = the atomic weight of the ithelement in the alloy, andni = the valence of the ithelement of the alloy.Therefore, the alloy equivalent weight, EW, is the reciprocalof this quantity:EW 51(nifiWi(4)Normally only elements ab

21、ove 1 mass percent in the alloyare included in the calculation. In cases where the actualanalysis of an alloy is not available, it is conventional to use themid-range of the composition specification for each element,unless a better basis is available. A sample calculation is givenin Appendix X2 (1)

22、.44.5 Valence assignments for elements that exhibit multiplevalences can create uncertainty. It is best if an independenttechnique can be used to establish the proper valence for eachalloying element. Sometimes it is possible to analyze thecorrosion products and use those results to establish the pr

23、opervalence. Another approach is to measure or estimate theelectrode potential of the corroding surface. Equilibrium dia-grams showing regions of stability of various phases as afunction of potential and pH may be created from thermody-namic data. These diagrams are known as Potential-pH (Pour-baix)

24、 diagrams and have been published by several authors (2,3). The appropriate diagrams for the various alloying elementscan be consulted to estimate the stable valence of each elementat the temperature, potential, and pH of the contacting electro-lyte that existed during the test.NOTE 2Some of the old

25、er publications used inaccurate thermody-namic data to construct the diagrams and consequently they are in error.4.6 Some typical values of EW for a variety of metals andalloys are given in Table 1.4.7 Calculation of Corrosion RateFaradays Law can beused to calculate the corrosion rate, either in te

26、rms of penetra-tion rate (CR) or mass loss rate (MR) (4):CR 5 K1icorEW (5)MR 5 K2icorEW (6)where:CR is given in mm/yr, icorin A/cm2,K1= 3.27 103, mm g/A cm yr (Note 3), = density in g/cm3, (see Practice G1 for density valuesfor many metals and alloys used in corrosion testing),MR = g/m2d, andK2= 8.9

27、54 103,gcm2/A m2d(Note 3).NOTE 3EW is considered dimensionless in these calculations.Other values for K1and K2for different unit systems aregiven in Table 2.4.8 Errors that may arise from this procedure are discussedbelow.4.8.1 Assignment of incorrect valence values may causeserious errors (5).4.8.2

28、 The calculation of penetration or mass loss fromelectrochemical measurements, as described in this standard,assumes that uniform corrosion is occurring. In cases wherenon-uniform corrosion processes are occurring, the use of thesemethods may result in a substantial underestimation of the truevalues

29、.4.8.3 Alloys that include large quantities of metalloids oroxidized materials may not be able to be treated by the aboveprocedure.4.8.4 Corrosion rates calculated by the method above whereabrasion or erosion is a significant contributor to the metal lossprocess may yield significant underestimation

30、 of the metal lossrate.5. Polarization Resistance5.1 Polarization resistance values may be approximatedfrom either potentiodynamic measurements near the corrosionpotential (see Practice G59) or stepwise potentiostatic polar-ization using a single small potential step, E, usually either4The boldface

31、numbers in parentheses refer to the list of references at the end ofthis standard.G102 89 (2015)12TABLE 1 Equivalent Weight Values for a Variety of Metals and AlloysNOTE 1Alloying elements at concentrations below 1 % by mass were not included in the calculation, for example, they were considered par

32、t of thebasis metal.NOTE 2Mid-range values were assumed for concentrations of alloying elements.NOTE 3Only consistent valence groupings were used.NOTE 4Eq 4 was used to make these calculations.CommonDesignationUNSElementsw/ConstantValenceLowest Second Third FourthVariableValenceEquivalentWeightVaria

33、bleValenceEquivalentWeightElement/ValenceEquivalentWeightElement/ValenceEquivalentWeightAluminum Alloys:AA1100AA91100 Al/3 8.99AA2024 A92024 Al/3, Mg/2 Cu/1 9.38 Cu/2 9.32AA2219 A92219 Al/3 Cu/1 9.51 Cu/2 9.42AA3003 A93003 Al/3 Mn/2 9.07 Mn/4 9.03 Mn 7 8.98AA3004 A93004 Al/3, Mg/2 Mn/2 9.09 Mn/4 9.0

34、6 Mn 7 9.00AA5005 A95005 Al/3, Mg/2 9.01AA5050 A95050 Al/3, Mg/2 9.03AA5052 A95052 Al/3, Mg/2 9.05AA5083 A95083 Al/3, Mg/2 9.09AA5086 A95086 Al/3, Mg/2 9.09AA5154 A95154 Al/3, Mg/2 9.08AA5454 A95454 Al/3, Mg/2 9.06AA5456 A95456 Al/3, Mg/2 9.11AA6061 A96061 Al/3, Mg/2 9.01AA6070 A96070Al/3, Mg/2,Si/4

35、8.98AA6101 A96161 Al/3 8.99AA7072 A97072 Al/3, Zn/2 9.06AA7075 A97075Al/3, Zn/2,Mg/2Cu/1 9.58 Cu/2 9.55AA7079 A97079Al/3, Zn/2,Mg/29.37AA7178 A97178Al/3, Zn/2,Mg/2Cu/1 9.71 Cu/2 9.68Copper Alloys:CDA110 C11000 Cu/1 63.55 Cu/2 31.77CDA220 C22000 Zn/2 Cu/1 58.07 Cu/2 31.86CDA230 C23000 Zn/2 Cu/1 55.65

36、 Cu/2 31.91CDA260 C26000 Zn/2 Cu/1 49.51 Cu/2 32.04CDA280 C28000 Zn/2 Cu/1 46.44 Cu/2 32.11CDA444 C44300 Zn/2 Cu/1, Sn/2 50.42 Cu/1, Sn/4 50.00 Cu/2, Sn/4 32.00CDA687 C68700 Zn/2, Al/3 Cu/1 48.03 Cu/2 30.29CDA608 C60800 Al/3 Cu/1 47.114 Cu/2 27.76CDA510 C51000 Cu/1, Sn/2 63.32 Cu/1, Sn/4 60.11 Cu/2,

37、 Sn/4 31.66CDA524 C52400 Cu/1, Sn/2 63.10 Cu/1, Sn/4 57.04 Cu/2, Sn/4 31.55CDA655 C65500 Si/4 Cu/1 50.21 Cu/2 28.51CDA706 C70600 Ni/2 Cu/1 56.92 Cu/2 31.51CDA715 C71500 Ni/2 Cu/1 46.69 Cu/2 30.98CDA752 C75200 Ni/2, Zn/2 Cu/1 46.38 Cu/2 31.46Stainless Steels:304 S30400 Ni/2 Fe/2, Cr/3 25.12 Fe/3, Cr/

38、3 18.99 Fe/3, Cr/6 15.72321 S32100 Ni/2 Fe/2, Cr/3 25.13 Fe/3, Cr/3 19.08 Fe/3, Cr/6 15.78309 S30900 Ni/2 Fe/2, Cr/3 24.62 Fe/3, Cr/3 19.24 Fe/3, Cr/6 15.33310 S31000 Ni/2 Fe/2, Cr/3 24.44 Fe/3, Cr/3 19.73 Fe/3, Cr/6 15.36316 S31600 Ni/2 Fe/2, Cr/3, Mo/3 25.50 Fe/2, Cr/3, Mo/4 25.33 Fe/3, Cr/6, Mo/6

39、 19.14 Fe/3, Cr/6, Mo/6 16.111317 S31700 Ni/2 Fe/2, Cr/3, Mo/3 25.26 Fe/2, Cr/3, Mo/4 25.03 Fe/3, Cr/3, Mo/6 19.15 Fe/3, Cr/6, Mo/6 15.82410 S41000 Fe/2, Cr/3 25.94 Fe/3, Cr/3 18.45 Fe/3, Cr/6 16.28430 S43000 Fe/2, Cr/3 25.30 Fe/3, Cr/3 18.38 Fe/3, Cr/6 15.58446 S44600 Fe/2, Cr/3 24.22 Fe/3, Cr/3 18

40、.28 Fe/3, Cr/6 14.4620CB3AN08020 Ni/2Fe/2, Cr/3, Mo/3,Cu/123.98Fe/2, Cr/3, Mo/4, Cu/123.83Fe/3, Cr/3, Mo/6, Cu/218.88Fe/3, Cr/6, Mo/6,Cu/215.50Nickel Alloys:200 N02200 NI/2 29.36 Ni/3 19.57400 N04400 Ni/2 Cu/1 35.82 Cu/2 30.12600 N06600 Ni/2 Fe/2, Cr/3 26.41 Fe/3, Cr/3 25.44 Fe/3, Cr/6 20.73800 N088

41、00 Ni/2 Fe/2, Cr/3 25.10 Fe/3, Cr/3 20.76 Fe/3, Cr/6 16.59825 N08825 Ni/2Fe/2, Cr/3, Mo/3,Cu/125.52Fe/2, Cr/3, Mo/4, Cu/125.32Fe/3, Cr/3, Mo/6, Cu/221.70Fe/3, Cr/6, Mo/6,Cu/217.10B N10001 Ni/2 Mo/3, Fe/2 30.05 Mo/4, Fe/2 27.50 Mo/6, Fe/2 23.52 Mo/6, Fe/3 23.23C-22BN06022 Ni/2Fe/2, Cr/3, Mo/3,W/426.0

42、4Fe/2, Cr/3, Mo/4, W/425.12Fe/2, Cr/3, Mo/6, W/623.28Fe/3, Cr/6, Mo/6,W/617.88C-276 N10276 Ni/2Fe/2, Cr/3, Mo/3,W/427.09 Cr/3, Mo/4 25.90Fe/2, Cr/3, Mo/6, W/623.63Fe/3, Cr/6, Mo/6,W/619.14G102 89 (2015)1310 mV or 10 mV, (see Test Method D2776). Values of 65 and620 mV are also commonly used. In this

43、case, the specimencurrent, I, is measured after steady state occurs, and E/I iscalculated. Potentiodynamic measurements yield curves of Iversus E and the reciprocal of the slope of the curve (dE/dI) atthe corrosion potential is measured. In most programmablepotentiodynamic polarization equipment, th

44、e current is con-verted to current density automatically and the resulting plot isof i versus E. In this case, the polarization resistance is givenby dE/di at the corrosion potential and 5.2 is not applicable.5.2 It is necessary to multiply the dE/dI or E/I valuecalculated above by the exposed speci

45、men geometric area toobtain the polarization resistance. This is equivalent to thecalculation shown in 4.1 for current density.5.3 The Stern-Geary constant B must be estimated orcalculated to convert polarization resistance values to corrosioncurrent density (6, 7).5.3.1 Calculate Stern-Geary consta

46、nts from known Tafelslopes where both cathodic and anodic reactions are activationcontrolled, that is, there are distinct linear regions near thecorrosion potential on an E log i plot:B 5babc2.303 ba1bc!(7)where:ba = slope of the anodic Tafel reaction, when plotted on base10 logarithmic paper in V/d

47、ecade,bc = slope of the cathodic Tafel reaction when plotted onbase 10 logarithmic paper in V/decade, andB = Stern-Geary constant, V.5.3.2 In cases where one of the reactions is purely diffusioncontrolled, the Stern-Geary constant may be calculated:B 5b2.303(8)where:b = the activation controlled Taf

48、el slope in V/decade.5.3.3 It should be noted in this case that the corrosioncurrent density will be equal to the diffusion limited currentdensity. A sample calculation is given in Appendix X4.5.3.4 Cases where both activation and diffusion effects aresimilar in magnitude are known as mixed control.

49、 The reactionunder mixed control will have an apparently larger b value thanpredicted for an activation control, and a plot of E versus logI will tend to curve to an asymptote parallel to the potentialaxis.The estimation of a B value for situations involving mixedcontrol requires more information in general and is beyond thescope of this standard. In general, Eq 7 and Eq 8 may be used,and the corrosion rate calculated by these two approximationsmay be used as lower and upper limits of the true rate.NOTE 4Electrodes exhibiting stable passivity