BS EN 3475-602-2007 Aerospace series - Cables electrical aircraft use - Test methods - Part 602 Toxicity《航空航天系列 航空器用电缆 试验方法 第602部分 毒性》.pdf

1、Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSIg49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58m

2、ethods Part 602: ToxicityICS 49.060Aerospace series Cables, electrical, aircraft use Test BRITISH STANDARDBS EN 3475-602:2007BS EN 3475-602:2007Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSIThis British Standard was published under the authority o

3、f the Standards Policy and Strategy Committee on 29 February 2008 BSI 2008ISBN 978 0 580 61215 2Amendments/corrigenda issued since publicationDate Commentscontract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunity from legal obligations. Nat

4、ional forewordThis British Standard is the UK implementation of EN 3475-602:2007.The UK participation in its preparation was entrusted by Technical Committee ACE/6, Aerospace avionic electrical and fibre optic technology, to Panel ACE/6/-/2, Aerospace Cables.A list of organizations represented on th

5、is committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 3475-602August 2007ICS 49.060English VersionAerospace series - Cables, electrical, aircraft use - Testmethods - Pa

6、rt 602: ToxicitySrie arospatiale - Cbles lectriques usagearonautique - Mthodes dessais - Partie 602 : ToxicitLuft- und Raumfahrt - Elektrische Leitungen frLuftfahrzeuge - Prfverfahren - Teil 602: GiftigkeitThis European Standard was approved by CEN on 21 June 2007.CEN members are bound to comply wit

7、h the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Cent

8、re or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial v

9、ersions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, S

10、pain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Me

11、mbers.Ref. No. EN 3475-602:2007: ELicensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSI2 Contents Page Foreword3 1 Scope 4 2 Normative references 4 3 Terms and definitions .4 4 Principle of method .5 5 Preparation for analysis5 5.1 General5 5.2 Probes fo

12、r gas sampling.5 5.3 Gas sampling system for non-reactive gases 6 5.4 Gas sampling for reactive Gases.7 5.5 Checking of sampling systems8 6 Analytical chemistry9 6.1 Colorimetric method of measurement.9 6.2 Potentiometric method of measurement (Wet Analysis) for determination of the halogenides F, C

13、l .9 7 Requirements.11 8 Report .11 EN 3475-602:2007Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSI3 Foreword This document (EN 3475-602:2007) has been prepared by the Aerospace and Defence Industries Association of Europe - Standardization (ASD-ST

14、AN). After enquiries and votes carried out in accordance with the rules of this Association, this Standard has received the approval of the National Associations and the Official Services of the member countries of ASD, prior to its presentation to CEN. This European Standard shall be given the stat

15、us of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2008, and conflicting national standards shall be withdrawn at the latest by February 2008. Attention is drawn to the possibility that some of the elements of this document may be the s

16、ubject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium,

17、 Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. EN 3475-602:2007Licens

18、ed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSI4 1 Scope This test method is intended for use in determining the concentration of specific gas components of smoke released by cable insulation materials. This test method should be used to measure and desc

19、ribe the properties of cable insulation materials in response to heat and flame under controlled laboratory conditions. This standard should be used to measure and describe the properties of products in response to heat and flame under controlled laboratory conditions and should not be used to descr

20、ibe or appraise the fire hazard or fire risk of materials, products, or assemblies under actual fire conditions. However results of this test may be used as elements of a fire risk assessment which takes into account all of the factors which are pertinent to an assessment of the fire hazard of a par

21、ticular end use. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 3475-6

22、01, Aerospace series Cables, electrical, aircraft use Test methods Part 601: Smoke density. 3 Terms and definitions For the purposes of this standard, the following terms and definitions apply. 3.1 ppm parts per million, concentration 3.2 colorimetry analytical procedure using colour comparison 3.3

23、potentiometry determination of ionic concentration by electrochemical measurements 3.4 in situ at the site (in this case: in the NBS chamber) 3.5 halogenides group of chlorides, fluorides, bromides and iodides They have a strong electrophilic character and are therefore very reactive. 3.6 absorbent

24、liquid suitable for collecting gas components EN 3475-602:2007Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSI5 3.7 impinger bottle special glass vessel for the absorption solution 3.8 test tube glass tube filled with a special reagent for quantitat

25、ive identification of a specific gas component 3.9 molarity concentration of a solution expressed as mol (gr/molecular weight) of solute per litre of solution 3.10 ISA lonic Strength Adjuster 3.11 NTP Normal Temperature and Pressure 3.12 NBS National Bureau of Standards, Washington 4 Principle of me

26、thod The smoke gas produced under the conditions of the smoke density test described in EN 3475-601 is subjected to an analysis depending on the gas components to be investigated. The concentration of non-reactive gas components is determined by means of the colorimetric procedure. In this case, tes

27、t tubes filled with a solid reagent are used; if a specific gas component exists, the indicating layer discolours due to chemical reactions. The length of the colour change is a measure for the concentration. The concentration of the reactive gases is determined by potentiometry; in this case, elect

28、rochemical potentials which can be converted into ppm concentrations after plotting of a calibration curve are measured with ion-specific electrodes in connection with a special reference electrode. 5 Preparation for analysis 5.1 General The specimens arranged vertically in a closed test chamber, ar

29、e chemically decomposed according to EN 3475-601 by thermal radiation alone or in combination with flaming. The resulting smoke portions are optically measured according to this test method. In this connection, a gas sample is taken at a time, which has to specified in a test plan. The decomposition

30、 gases resulting from thermal degradation are determined qualitatively and quantitatively by means of the analytical procedure described herein. 5.2 Probes for gas sampling The gases are sampled by means of three probes (internal diameter 6-8 mm) extending into the geometric center of the chamber. E

31、N 3475-602:2007Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSI6 Resistant probe materials (such as polypropylene or PTFE) are to be selected due to the reactive behaviour of the halogenides. The probes are to be connected gastight to the tube fitti

32、ngs for gas sampling at the upper side of the test chamber. Connections not used are to be sealed. One of the probes inserted into the chamber is to be provided with a rubber sleeve for attachment of the test tube for colorimetric “in situ“ measurement. 5.3 Gas sampling system for non-reactive gases

33、 5.3.1 General Figures 1 and 2 show the basic set-ups for allowable gas sampling systems. 5.3.2 Pipe system for the gas bag A pipe system with a maximum length of 3 m is to be installed between the gas sampling point at the chamber and the place of gas collection. If the gas pipe system cannot be he

34、ated, thermal insulation of the pipes is to be provided so as to avoid the formation of condensates. The pipes must have an inner width of 6 mm to 8 mm. Plastic hoses or pipes must be used and, depending on the suitability, polyethylene; butadiene or silicone rubber types can also be used. PTFE are

35、recommended for special requirements with regard to corrosion resistance with temperature load. The gas pipe end facing the chamber is to be provided with a stopcock. 5.3.3 Collection of gases Foil bags with a capacity of 10 l to 15 l and a high mechanical and chemical resistance are to be used for

36、the collection of the non-reactive gas components to be analyzed. Polyvinylidene fluoride with low gaseous diffusion and water vapour permeability is recommended as foil material so that a change in the gas composition due to diffusion processes is negligible: Permeability of gas for O2max. 20 cm3NT

37、P/m2per 24 h N2max. 6 cm3NTP/m2per 24 h CO2 max. 140 cm3NTP/m2per 24 h Water vapour max. 13 g/m2per 24 h Furthermore, the bags used must be provided with a stopcock. 5.3.4 Gas collection Two approved gas collection processes are available, collection by means of vacuum or by suction pump. Vacuum met

38、hod: A vacuum tank with a minimum capacity of 15 l is recommended for collecting the gas components to be analyzed in the above-stated foil bag. The design of the tank should be 5 l greater then the volume of the bag. The evacuation pressure is to be monitored by a vacuum gauge. The vacuum tank is t

39、o be provided with a ventilation valve and a connection for the vacuum pump. The tank cover of 10 mm thick acrylic glass minimum is provided with a hole into which a quick-release coupling is to be installed gastight in order to connect the gas bag, on the one side, with the gas pipe, on the other s

40、ide. A vacuum pump producing a vacuum in the tank capable of filling a gas bag according to within 20 s is to be used. EN 3475-602:2007Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 18/04/2008 03:14, Uncontrolled Copy, (c) BSI7 Procedure: The shut-off valve at the chamber is to be closed. Th

41、e gas bag is to be connected to the gas sampling system via the quick-release coupling while ensuring that the shut-off valve at the gas bag is open. The tank is to be sealed with a cover. The vacuum pump is to be switched on and the following components are to be evacuated: gas pipe; gas bag; vacuu

42、m tank. At the time of sampling, the stopcock at the test chamber (1) and the stopcock at the vacuum tank (2) are opened. The other shut-off valves are still closed. After filling of the gas bag, both stopcocks (1) and (2) in the supply line are to be closed. Then the vacuum tank is vented via the v

43、entilation valve (5) and the pump is switched off. The stopcock at the bag is closed and the filled bag is disconnected from the quick-release coupling and to be immediately analyzed. Suction pump method: The following procedure can also be used as an alternative to the vacuum method for filling the

44、 foil bag. The set-up of the equipment up to the suction pump is in accordance with 5.3.2. A manifold is to be installed at the inlet and outlet of the pump as shown in Figure 2. The manifold is used to vent the gas bag and to flush the gas pipe. The suction pump capable of filling a gas bag accordi

45、ng to within 20 s is to be used. Procedure: The shut-off valve (1) at the chamber is to be closed. The gas bag is to be connected to the coupling (8) in front of the pump manifold. The shut-off valves (2) and (4) are to be opened. The shut-off valve at the gas bag is to be opened. The suction pump i

46、s to be switched on and the gas bag is to be evacuated. The shut-off valve at the gas bag and the shut-off valve (2) are to be closed and the pump is to be switched off. The shut-off valve (3) is opened and the shut-off valve (4) is closed. The closed gas bag is to be connected to the coupling (6) a

47、t the pump outlet and the shut-off valve at the gas bag is to be opened. At the time of sampling, the shut-off valve (1) at the test chamber is opened. The suction pump is to be switched on. After 30 s at the earliest, the shut-off valve (3) is closed and the shut-off valve (4) in front of the gas b

48、ag is opened. After filling the gas bag, the shut-off valve (4), the gas bag valve and the chamber shut-off valve (1) are all to be closed. The suction pump is to be switched off. The filled bag is disconnected from the suction pump and the contents immediately analyzed. 5.4 Gas sampling for reactiv

49、e Gases 5.4.1 “In situ” measurements for colorimetric determination of Hydrogenchloride (HCI) and Hydrogenfluoride (HF) The samples for measuring the hydrogen fluoride and chloride with colorimetric test tubes are taken directly from test chamber by means of a suction pump. The suction capacity of the pump under load must comply with the values specified by the manufacturer of the test tubes. A gas pipe of the material and diameter recommended in 5.3.2 connects the probe to the suction pump. A shut-off valve is to be installed in front of the suction