BS EN 71-5-2015 Safety of toys Chemical toys (sets) other than experimental sets《玩具的安全性 实验装置除外的化学玩具》.pdf

1、BSI Standards PublicationBS EN 71-5:2015Safety of toysPart 5: Chemical toys (sets) other thanexperimental setsBS EN 71-5:2015 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 71-5:2015. Itsupersedes BS EN 71-5:2013 which is withdrawn.The UK participation in its p

2、reparation was entrusted to TechnicalCommittee CW/15/5, Toys - Chemical.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplic

3、ation. The British Standards Institution 2015. Published by BSI StandardsLimited 2015ISBN 978 0 580 87325 6ICS 71.040.99; 97.200.50Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strate

4、gy Committee on 30 September 2015.Amendments issued since publicationDate Text affectedBS EN 71-5:2015EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 71-5 September 2015 ICS 97.200.50 Supersedes EN 71-5:2013English Version Safety of toys - Part 5: Chemical toys (sets) other than experimental se

5、ts Scurit des jouets - Partie 5 : Jouets chimiques (coffrets) autres que les coffrets dexpriences Sicherheit von Spielzeug - Teil 5: Chemisches Spielzeug (Sets) ausgenommen Experimentierksten This European Standard was approved by CEN on 10 August 2015. CEN members are bound to comply with the CEN/C

6、ENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centr

7、e or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the

8、official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherla

9、nds, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights

10、of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 71-5:2015 EBS EN 71-5:2015EN 71-5:2015 (E) 2 Contents Page European foreword . 5 Introduction 7 1 Scope 8 2 Normative references 8 3 Terms and definitions . 9 4 Plaster of Paris (gypsum) moulding se

11、ts . 10 4.1 Marking 10 4.2 First aid information . 10 4.3 Safety rules . 10 5 Oven-hardening plasticised PVC modelling clay sets 11 5.1 Chemical substances . 11 5.2 Marking 11 5.3 First aid information . 11 5.4 Safety rules . 12 6 Moulding sets . 12 6.1 Polystyrene granules sets . 12 6.1.1 Chemical

12、substances . 12 6.1.2 Marking 12 6.1.3 First aid information . 12 6.1.4 Safety rules . 13 6.2 Embedding sets . 13 6.2.1 General . 13 6.2.2 Packaging 13 6.2.3 Marking 13 6.2.4 First aid information . 13 6.2.5 Safety rules . 13 7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (so

13、lvents) supplied or recommended in model sets 14 7.1 General . 14 7.2 Adhesives 14 7.2.1 Water-based adhesives 14 7.2.2 Solvent-based adhesives 17 7.3 Water-based paints or lacquers 20 7.3.1 General . 20 7.3.2 Packaging 20 7.3.3 Marking 20 7.3.4 First aid information . 21 7.3.5 Safety rules . 21 7.4

14、 Solvent-based paints, lacquers, thinners and cleaning solvents 21 7.4.1 General . 21 7.4.2 Packaging 22 7.4.3 Marking 22 7.4.4 First aid information . 22 BS EN 71-5:2015EN 71-5:2015 (E) 3 7.4.5 Safety rules 23 8 Marking 23 8.1 General . 23 8.2 Marking of the primary packaging . 23 8.2.1 General . 2

15、3 8.2.2 Manufacturers identification 23 8.2.3 Warning phrases . 23 8.3 Marking of individual containers and any packagings . 24 9 Instructions for use 24 9.1 General . 24 9.2 Contents list 24 9.3 Advice for adult supervision . 24 9.4 Safety rules 25 9.5 Instructions for carrying out the activities .

16、 25 9.6 Spills and disposal of chemicals 25 10 Test methods 26 10.1 General . 26 10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets 26 10.2.1 Principle . 26 10.2.2 Standards and reagents 26 10.2.3 Apparatus 27 10.2.4 Preparation of standard solutions .

17、28 10.2.5 Sampling 29 10.2.6 Sample preparation . 30 10.2.7 Procedure 30 10.2.8 Evaluation of results 31 10.2.9 Test report 33 10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets . 33 10.3.1 Principl

18、e . 33 10.3.2 Standards and reagents 34 10.3.3 Apparatus 34 10.3.4 Preparation of standard solutions . 36 10.3.5 Sampling 36 10.3.6 Sample preparation . 36 10.3.7 Procedure 36 10.3.8 Evaluation of results 36 10.3.9 Test report 37 10.3.10 Critical control points . 37 10.4 Determination of styrene con

19、tent in polystyrene granules 37 10.4.1 Principle . 37 10.4.2 Standards and reagents 37 10.4.3 Apparatus 38 10.4.4 Preparation of the standard solutions 39 10.4.5 Sampling 39 10.4.6 Sample preparation . 39 10.4.7 Procedure 39 10.4.8 Evaluation of results 39 10.4.9 Test report 39 10.5 Determination of

20、 organic solvents . 40 10.5.1 General . 40 BS EN 71-5:2015EN 71-5:2015 (E) 4 10.5.2 Principle 42 10.5.3 Standards and reagents . 43 10.5.4 Apparatus 44 10.5.5 Preparation of the standard solutions . 46 10.5.6 Sampling 53 10.5.7 Sample preparation . 53 10.5.8 Procedure 55 10.5.9 Evaluation of results

21、 . 60 10.5.10 Test report 61 10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers 61 10.6.1 Principle 61 10.6.2 Determination of to

22、tal extract . 62 10.6.3 Identification of nitrocellulose 63 10.6.4 Determination of plasticisers 65 10.6.5 Determination of film-forming agents . 65 10.6.6 Determination of the modifiers 71 10.6.7 Test report 71 Annex A (normative) Environmental, health and safety precautions for using the methods o

23、f analysis . 72 Annex B (informative) Organic solvents . 73 Annex C (informative) Validation of test methods 75 Annex D (informative) Rationale . 76 D.1 General remark . 76 D.2 Primary packaging (4.1; 5.2; 6.1.2; 6.2.2; 7.2.1.2.2; 7.2.2.6; 7.3.2; 7.4.3; 8.2) . 76 D.3 Minimum age (4.1; 5.2;6.1.2; 6.2

24、.3; 7.2.1.2.3; 7.2.1.3.3; 7.2.2.6; 7.3.3; 7.4.3) . 76 D.4 Benzene (5.1, Table 2; 7.2.2.4, Table 11; 7.4.1, Table 15) . 76 D.5 Preservatives (6.2.1; 7.2.1.1; 7.3.1) . 77 Annex E (informative) Significant technical changes between this European Standard and the previous version . 78 Annex ZA (informat

25、ive) Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC 79 Bibliography . 80 BS EN 71-5:2015EN 71-5:2015 (E) 5 European foreword This document (EN 71-5:2015) has been prepared by Technical Committee CEN/TC 52 “Safety of toys”, the secretariat of whi

26、ch is held by DS. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by March 2016, and conflicting national standards shall be withdrawn at the latest by March 2016. Attention is drawn to the possibili

27、ty that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 71-5:2013. This document has been prepared under a mandate given to CEN by the European Commi

28、ssion and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive 2009/48/EC, see informative Annex ZA, which is an integral part of this document. The significant changes from the previous edition of this standard are detailed

29、in Annex E. This standard is Part 5 of the European Standard for safety of toys, EN 71. This Part 5 of the EN 71 series is intended to be read in conjunction with EN 71, Part 1, Part 2 and Part 3, particularly the Introduction and Clause 1 of Part 1. EN 71, Safety of toys, consists of the following

30、parts: Part 1: Mechanical and physical properties; Part 2: Flammability; Part 3: Migration of certain elements; Part 4: Experimental sets for chemistry and related activities; Part 5: Chemical toys (sets) other than experimental sets; Part 7: Finger paints Requirements and test methods; Part 8: Acti

31、vity toys for domestic use; Part 9: Organic chemical compounds Requirements; Part 10: Organic chemical compounds Sample preparation and extraction; Part 11: Organic chemical compounds Methods of analysis; Part 12: N-Nitrosamines and N-nitrosatable substances; Part 13: Olfactory board games, gustativ

32、e board games, cosmetic kits and gustative kits; BS EN 71-5:2015EN 71-5:2015 (E) 6 Part 14: Trampolines for domestic use. NOTE 1 In addition to the above parts of EN 71, the following guidance documents have been published: CEN Report, CR 14379, Classification of toys Guidelines, CEN Technical Repor

33、t CEN/TR 15071, Safety of toys National translations of warnings and instructions for use in EN 71, and CEN Technical Report CEN/TR 15371, Safety of toys Replies to requests for interpretation of EN 711, EN 712, and EN 718. NOTE 2 Words in italics are defined in Clause 3 (Terms and definitions). Acc

34、ording to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, German

35、y, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 71-5:2015EN 71-5:2015 (E) 7 Introduction This European Standard is intended to reduc

36、e the risks which may present health hazards to a child when the chemical toys are used as intended or in a foreseeable way, bearing in mind the behaviour of children. When using these chemical toys, potential risks should be kept to a minimum by inclusion of appropriate information to give special

37、attention to possible hazards, risks and other problems. Chemical Abstract Service Registry Number (CAS) and European Inventory of Existing Chemical Substances Number (EINECS) given in various tables are provided for information purposes only. BS EN 71-5:2015EN 71-5:2015 (E) 8 1 Scope This European

38、Standard specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are: those classified as dangerous by the EU-legislation applying to dangerous substances and dangerous mixtures 5; substances an

39、d mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and any other chemical substance(s) and mixture(s) delivered with the chemical toy. NOTE The terms “substance” and “mixture” are define

40、d in the REACH regulation No. (EC)1907/2006 and in the CLP regulation (EC) No. 1272/2008. Additionally, requirements are specified for markings, warnings, safety rules, contents list, instructions for use and first aid information. This Part of EN 71 applies to: plaster of Paris (gypsum) moulding se

41、ts; oven-hardening plasticised PVC modelling clay sets; polystyrene granules sets; embedding sets; adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets. 2 Normative references The following documents, in whole or in part, are normativ

42、ely referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN ISO 3104, Petroleum products Transparent and opaque liquids De

43、termination of kinematic viscosity and calculation of dynamic viscosity (ISO 3104) EN ISO 3219, Plastics Polymers/resins in the liquid state or as emulsions or dispersions Determination of viscosity using a rotational viscometer with defined shear rate (ISO 3219) EN ISO 3696, Water for analytical la

44、boratory use Specification and test methods (ISO 3696) EN ISO 22854, Liquid petroleum products Determination of hydrocarbon types and oxygenates in automotive-motor gasoline and in ethanol (E85) automotive fuel - Multidimensional gas chromatography method (ISO 22854) BS EN 71-5:2015EN 71-5:2015 (E)

45、9 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 chemical toy toy intended for the direct handling of chemical substances and mixtures and which is used in a manner appropriate to a given age-group and under the supervision of an adult SOURC

46、E: EN 71-4:2013, 3.1 3.2 experimental set chemical toy where the experimental and explorative character in playing with single chemical substances and mixtures along strict instructions dominates over the creative ideas of the user SOURCE: EN 71-4:2013, 3.2 3.3 plaster of Paris (gypsum) moulding set

47、 toy containing moulds into which a mixture of water and gypsum is poured and allowed to harden Note 1 to entry: The gypsum consists predominantly of calcium sulfate hemihydrate CaSO4 0,5 H2O. Note 2 to entry: Plaster of Paris (gypsum) moulding sets are for example used for preparing figures and pla

48、tes. 3.4 oven-hardening plasticised PVC modelling clay set toy to be used for creating all kinds of figures, brooches, fashion jewellery etc. prepared by hardening in the oven at temperatures between (100130) C 3.5 polystyrene granules set toy to be used in substitution of ceramic materials to creat

49、e decorative articles or models by fusion of a polymer by heating in an oven up to a maximum of 180 C 3.6 embedding set toy to be used to preserve certain products in a transparent material 3.7 model set product used to assemble and coat models which are supplied with or recommend adhesives, paints, lacquers, varnishes, thinners and cleaning agents Note 1 to entry: Examples for these models are motorcars, aeroplanes, houses and ships. 3.8 adhesive non-metallic substance capable of joining material